Morphological instability of aqueous dissolution of silicate glasses and minerals [Nonlinear dynamics of aqueous dissolution of silicate glasses and minerals: Morphological instability]

Wang, Yifeng; Jove-Colon, Carlos F.; Kuhlman, Kristopher L.; Lenting, Christoph; Icenhower, Jonathan

doi:10.1038/s41529-018-0047-0

Title: Morphological instability of aqueous dissolution of silicate glasses and minerals [Nonlinear dynamics of aqueous dissolution of silicate glasses and minerals: Morphological instability]

Abstract

Understanding of aqueous dissolution of silicate glasses and minerals is of great importance to both Earth science and materials science. Silicate dissolution exhibits complex temporal evolution and spatial pattern formations. Recently, we showed how observed complexity could emerge from a simple self-organizational mechanism: dissolution of the silica framework in a material could be catalyzed by the cations released from the reaction itself. This mechanism enables us to systematically predict many key features of a silicate dissolution process including the occurrence of a sharp corrosion front (vs. a leached surface layer), oscillatory dissolution and multiple stages of the alteration process (e.g., an alteration rate resumption at a late stage of glass dissolution). Here, through a linear stability analysis, we show that this same mechanism can also lead to morphological instability of an alteration front, which, in combination with oscillatory dissolution, can potentially lead to a whole suite of patterning phenomena, as observed on archaeological glass samples, including wavy dissolution fronts, growth rings, incoherent bandings of alteration products, and corrosion pitting. Here, the result thus further demonstrates the importance of the proposed self-accelerating mechanism in silicate material degradation.

Authors:

Wang, Yifeng ^[1]; Jove-Colon, Carlos F. ^[1]; Kuhlman, Kristopher L. ^[1]; Lenting, Christoph ^[2]; Icenhower, Jonathan ^[1]

Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Univ. of Bonn, Bonn (Germany)

Publication Date:: Tue Sep 04 00:00:00 EDT 2018

Research Org.:: Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA)

OSTI Identifier:: 1478405

Report Number(s):: SAND-2018-0206J
Journal ID: ISSN 2397-2106; 659823

Grant/Contract Number:: AC04-94AL85000

Resource Type:: Accepted Manuscript

Journal Name:: npj Materials Degradation

Additional Journal Information:: Journal Volume: 2; Journal Issue: 1; Journal ID: ISSN 2397-2106

Publisher:: Springer

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Wang, Yifeng, Jove-Colon, Carlos F., Kuhlman, Kristopher L., Lenting, Christoph, and Icenhower, Jonathan. Morphological instability of aqueous dissolution of silicate glasses and minerals [Nonlinear dynamics of aqueous dissolution of silicate glasses and minerals: Morphological instability].  United States: N. p., 2018. 
Web.  doi:10.1038/s41529-018-0047-0.

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                    Wang, Yifeng, Jove-Colon, Carlos F., Kuhlman, Kristopher L., Lenting, Christoph, & Icenhower, Jonathan. Morphological instability of aqueous dissolution of silicate glasses and minerals [Nonlinear dynamics of aqueous dissolution of silicate glasses and minerals: Morphological instability].  United States.  https://doi.org/10.1038/s41529-018-0047-0

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                    Wang, Yifeng, Jove-Colon, Carlos F., Kuhlman, Kristopher L., Lenting, Christoph, and Icenhower, Jonathan. Tue .  
"Morphological instability of aqueous dissolution of silicate glasses and minerals [Nonlinear dynamics of aqueous dissolution of silicate glasses and minerals: Morphological instability]".  United States.  https://doi.org/10.1038/s41529-018-0047-0.  https://www.osti.gov/servlets/purl/1478405.

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@article{osti_1478405,

  title        = {Morphological instability of aqueous dissolution of silicate glasses and minerals [Nonlinear dynamics of aqueous dissolution of silicate glasses and minerals: Morphological instability]},

  author       = {Wang, Yifeng and Jove-Colon, Carlos F. and Kuhlman, Kristopher L. and Lenting, Christoph and Icenhower, Jonathan},

  abstractNote = {Understanding of aqueous dissolution of silicate glasses and minerals is of great importance to both Earth science and materials science. Silicate dissolution exhibits complex temporal evolution and spatial pattern formations. Recently, we showed how observed complexity could emerge from a simple self-organizational mechanism: dissolution of the silica framework in a material could be catalyzed by the cations released from the reaction itself. This mechanism enables us to systematically predict many key features of a silicate dissolution process including the occurrence of a sharp corrosion front (vs. a leached surface layer), oscillatory dissolution and multiple stages of the alteration process (e.g., an alteration rate resumption at a late stage of glass dissolution). Here, through a linear stability analysis, we show that this same mechanism can also lead to morphological instability of an alteration front, which, in combination with oscillatory dissolution, can potentially lead to a whole suite of patterning phenomena, as observed on archaeological glass samples, including wavy dissolution fronts, growth rings, incoherent bandings of alteration products, and corrosion pitting. Here, the result thus further demonstrates the importance of the proposed self-accelerating mechanism in silicate material degradation.},

  doi          = {10.1038/s41529-018-0047-0},

  journal      = {npj Materials Degradation},

  number       = 1,

  volume       = 2,

  place        = {United States},

  year         = {Tue Sep 04 00:00:00 EDT 2018},

  month        = {Tue Sep 04 00:00:00 EDT 2018}

}

Copy to clipboard

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Works referencing / citing this record:

Phosphatic alteration of lead-rich glazes during two centuries of burial: Bartlam, Bonnin & Morris, and Chelsea porcelain
journal, August 2019

Owen, J. Victor; Hanley, Jacob J.; Petrus, Joeseph A.
Archaeological and Anthropological Sciences, Vol. 11, Issue 12
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Simplifying a solution to a complex puzzle
journal, November 2018

Gin, Stéphane; Ryan, Joseph V.; Kerisit, Sébastien
npj Materials Degradation, Vol. 2, Issue 1
DOI: 10.1038/s41529-018-0057-y

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Similar Records

Title: Morphological instability of aqueous dissolution of silicate glasses and minerals [Nonlinear dynamics of aqueous dissolution of silicate glasses and minerals: Morphological instability]

Abstract

Citation Formats

Feldspar Weathering in Lateritic Saprolite journal, January 1985

Archaeological glass alteration products in marine and land-based environments: morphological, chemical and microtextural characterization journal, June 2005

Rate equations for sodium catalyzed quartz dissolution journal, October 2015

Surface Structure and Stability of Partially Hydroxylated Silica Surfaces journal, April 2017

Weathering of Hornblende to Ferruginous Products by a Dissolution-Reprecipitation Mechanism: Petrography and Stoichiometry journal, January 1989

Insight into silicate-glass corrosion mechanisms journal, October 2008

Oscillatory silicon and aluminum aqueous concentrations during experimental aluminosilicate weathering journal, August 1996

Open Scientific Questions about Nuclear Glass Corrosion journal, January 2014

Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism journal, June 2010

Mechanisms of classical crystal growth theory explain quartz and silicate dissolution behavior journal, October 2005

Laminated altered layers in historical glass: Density variations of silica nanoparticle random packings as explanation for the observed lamellae journal, June 2016

Mechanism of aqueous dissolution of silicate glasses yielded by fission tracks journal, February 1986

The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field? journal, December 2003

Sharpened interface journal, February 2015

Interdiffusion of hydrogen and alkali ions in a glass surface journal, December 1975

Origin of fibrosity and banding in agates from flood basalts journal, January 1995

Nanometre-scale evidence for interfacial dissolution–reprecipitation control of silicate glass corrosion journal, January 2015

Glasses on the seabed: surface study of chemical corrosion in sunken Roman glasses journal, September 2004

Permanent storage of carbon dioxide in geological reservoirs by mineral carbonation journal, November 2009

Initial Dissolution Rate of the International Simple Glass as a Function of pH and Temperature Measured Using Microchannel Flow-Through Test Method journal, October 2013

Mechanism of leached layer formation during chemical weathering of silicate minerals journal, October 2012

Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions journal, June 2016

Pattern Formation in Silicate Glass Corrosion Zones journal, October 2013

Quartz dissolution kinetics from 100–200°C as a function of pH and ionic strength journal, December 1996

Hydrated-layer formation during dissolution of complex silicate glasses and minerals journal, July 1990

The mechanism of borosilicate glass corrosion revisited journal, June 2015

The effect of silicate weathering on global temperature and atmospheric CO 2 journal, January 1991

Experimental study of the effect of pH on the kinetics of montmorillonite dissolution at 25°C journal, September 2008

GEOCARB III: A revised model of atmospheric CO2 over Phanerozoic time journal, February 2001

Control of silicate weathering by interface-coupled dissolution-precipitation processes at the mineral-solution interface journal, June 2016

Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing journal, January 2015

Origin and consequences of silicate glass passivation by surface layers journal, February 2015

Dynamics of self-reorganization explains passivation of silicate glasses journal, June 2018

Nonlinear dynamics and instability of aqueous dissolution of silicate glasses and minerals journal, July 2016

Phosphatic alteration of lead-rich glazes during two centuries of burial: Bartlam, Bonnin & Morris, and Chelsea porcelain journal, August 2019

Simplifying a solution to a complex puzzle journal, November 2018

Feldspar Weathering in Lateritic Saprolite
journal, January 1985

Archaeological glass alteration products in marine and land-based environments: morphological, chemical and microtextural characterization
journal, June 2005

Rate equations for sodium catalyzed quartz dissolution
journal, October 2015

Surface Structure and Stability of Partially Hydroxylated Silica Surfaces
journal, April 2017

Weathering of Hornblende to Ferruginous Products by a Dissolution-Reprecipitation Mechanism: Petrography and Stoichiometry
journal, January 1989

Insight into silicate-glass corrosion mechanisms
journal, October 2008

Oscillatory silicon and aluminum aqueous concentrations during experimental aluminosilicate weathering
journal, August 1996

Open Scientific Questions about Nuclear Glass Corrosion
journal, January 2014

Aqueous corrosion of borosilicate glass under acidic conditions: A new corrosion mechanism
journal, June 2010

Mechanisms of classical crystal growth theory explain quartz and silicate dissolution behavior
journal, October 2005

Laminated altered layers in historical glass: Density variations of silica nanoparticle random packings as explanation for the observed lamellae
journal, June 2016

Mechanism of aqueous dissolution of silicate glasses yielded by fission tracks
journal, February 1986

The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field?
journal, December 2003

Sharpened interface
journal, February 2015

Interdiffusion of hydrogen and alkali ions in a glass surface
journal, December 1975

Origin of fibrosity and banding in agates from flood basalts
journal, January 1995

Nanometre-scale evidence for interfacial dissolution–reprecipitation control of silicate glass corrosion
journal, January 2015

Glasses on the seabed: surface study of chemical corrosion in sunken Roman glasses
journal, September 2004

Permanent storage of carbon dioxide in geological reservoirs by mineral carbonation
journal, November 2009

Initial Dissolution Rate of the International Simple Glass as a Function of pH and Temperature Measured Using Microchannel Flow-Through Test Method
journal, October 2013

Mechanism of leached layer formation during chemical weathering of silicate minerals
journal, October 2012

Rapid carbon mineralization for permanent disposal of anthropogenic carbon dioxide emissions
journal, June 2016

Pattern Formation in Silicate Glass Corrosion Zones
journal, October 2013

Quartz dissolution kinetics from 100–200°C as a function of pH and ionic strength
journal, December 1996

Hydrated-layer formation during dissolution of complex silicate glasses and minerals
journal, July 1990

The mechanism of borosilicate glass corrosion revisited
journal, June 2015

The effect of silicate weathering on global temperature and atmospheric CO ₂
journal, January 1991

Experimental study of the effect of pH on the kinetics of montmorillonite dissolution at 25°C
journal, September 2008

GEOCARB III: A revised model of atmospheric CO2 over Phanerozoic time
journal, February 2001

Control of silicate weathering by interface-coupled dissolution-precipitation processes at the mineral-solution interface
journal, June 2016

Aqueous alteration of potassium-bearing aluminosilicate minerals: from mechanism to processing
journal, January 2015

Origin and consequences of silicate glass passivation by surface layers
journal, February 2015

Dynamics of self-reorganization explains passivation of silicate glasses
journal, June 2018

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journal, July 2016

Phosphatic alteration of lead-rich glazes during two centuries of burial: Bartlam, Bonnin & Morris, and Chelsea porcelain
journal, August 2019

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journal, November 2018