Measurements and models of reactive transport in geological media
Abstract
Reactive chemical transport plays a key role in geological media across scales, from pore scale to aquifer scale. Systems can be altered by changes in solution chemistry and a wide variety of chemical transformations, including precipitation/dissolution reactions that cause feedbacks that directly affect the flow and transport regime. The combination of these processes with advective-dispersive-diffusive transport in heterogeneous media leads to a rich spectrum of complex dynamics. The principal challenge in modeling reactive transport is to account for the subtle effects of fluctuations in the flow field and species concentrations; spatial or temporal averaging generally suppresses these effects. Moreover, it is critical to ground model conceptualizations and test model outputs against laboratory experiments and field measurements. This paper emphasizes the integration of these aspects, considering carefully designed and controlled experiments at both laboratory and field scales, in the context of development and solution of reactive transport models based on continuum-scale and particle tracking approaches. We first discuss laboratory experiments and field measurements that define the scope of the phenomena and provide data for model comparison. We continue by surveying models involving advection-dispersion-reaction equation and continuous time random walk formulations. The integration of measurements and models is then examined, considering amore »
- Authors:
-
[1];
- Weizmann Inst. of Science, Rehovot (Israel). Dept. of Earth and Planetary Sciences
- Weizmann Inst. of Science, Rehovot (Israel). Dept. of Earth and Planetary Sciences; Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Weizmann Institute of Science, Rehovot (Israel)
- Sponsoring Org.:
- USDOE; German Federal Ministry of Education and Research (BMBF); Azrieli Foundation
- OSTI Identifier:
- 1477678
- Report Number(s):
- LA-UR-17-27823
Journal ID: ISSN 8755-1209
- Grant/Contract Number:
- AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Reviews of Geophysics (1985)
- Additional Journal Information:
- Journal Name: Reviews of Geophysics (1985); Journal Volume: 54; Journal Issue: 4; Journal ID: ISSN 8755-1209
- Publisher:
- American Geophysical Union (AGU)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 58 GEOSCIENCES; advection-dispersion-reaction equation (ADRE); continuous time random walk (CTRW); particle tracking; continuum model; laboratory experiments; field measurements
Citation Formats
Berkowitz, Brian, Dror, Ishai, Hansen, Scott K., and Scher, Harvey. Measurements and models of reactive transport in geological media. United States: N. p., 2016.
Web. doi:10.1002/2016RG000524.
Berkowitz, Brian, Dror, Ishai, Hansen, Scott K., & Scher, Harvey. Measurements and models of reactive transport in geological media. United States. https://doi.org/10.1002/2016RG000524
Berkowitz, Brian, Dror, Ishai, Hansen, Scott K., and Scher, Harvey. Tue .
"Measurements and models of reactive transport in geological media". United States. https://doi.org/10.1002/2016RG000524. https://www.osti.gov/servlets/purl/1477678.
@article{osti_1477678,
title = {Measurements and models of reactive transport in geological media},
author = {Berkowitz, Brian and Dror, Ishai and Hansen, Scott K. and Scher, Harvey},
abstractNote = {Reactive chemical transport plays a key role in geological media across scales, from pore scale to aquifer scale. Systems can be altered by changes in solution chemistry and a wide variety of chemical transformations, including precipitation/dissolution reactions that cause feedbacks that directly affect the flow and transport regime. The combination of these processes with advective-dispersive-diffusive transport in heterogeneous media leads to a rich spectrum of complex dynamics. The principal challenge in modeling reactive transport is to account for the subtle effects of fluctuations in the flow field and species concentrations; spatial or temporal averaging generally suppresses these effects. Moreover, it is critical to ground model conceptualizations and test model outputs against laboratory experiments and field measurements. This paper emphasizes the integration of these aspects, considering carefully designed and controlled experiments at both laboratory and field scales, in the context of development and solution of reactive transport models based on continuum-scale and particle tracking approaches. We first discuss laboratory experiments and field measurements that define the scope of the phenomena and provide data for model comparison. We continue by surveying models involving advection-dispersion-reaction equation and continuous time random walk formulations. The integration of measurements and models is then examined, considering a series of case studies in different frameworks. We delineate the underlying assumptions, and strengths and weaknesses, of these analyses, and the role of probabilistic effects. Finally, we also show the key importance of quantifying the spreading and mixing of reactive species, recognizing the role of small-scale physical and chemical fluctuations that control the initiation of reactions.},
doi = {10.1002/2016RG000524},
journal = {Reviews of Geophysics (1985)},
number = 4,
volume = 54,
place = {United States},
year = {Tue Aug 23 00:00:00 EDT 2016},
month = {Tue Aug 23 00:00:00 EDT 2016}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 49 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Coupled transport and dispersion of multicomponent reactive solutes in rectilinear flows
journal, November 1996
- Shapiro, M.; Fedou, R.; Thovert, J. -F.
- Chemical Engineering Science, Vol. 51, Issue 22
Multicomponent simulation of wastewater-derived nitrogen and carbon in shallow unconfined aquifers
journal, January 2001
- MacQuarrie, Kerry T. B.; Sudicky, Edward A.; Robertson, William D.
- Journal of Contaminant Hydrology, Vol. 47, Issue 1
Prediction of permeability for porous media reconstructed using multiple-point statistics
journal, December 2004
- Okabe, Hiroshi; Blunt, Martin J.
- Physical Review E, Vol. 70, Issue 6
Multicomponent reaction modelling using a stochastic algorithm
journal, October 2007
- Palanichamy, Jegathambal; Becker, Torsten; Spiller, Martin
- Computing and Visualization in Science, Vol. 12, Issue 2
Measurement and modeling of engineered nanoparticle transport and aging dynamics in a reactive porous medium: MEASUREMENT AND MODELING OF NANOPARTICLE TRANSPORT
journal, July 2016
- Naftaly, Aviv; Dror, Ishai; Berkowitz, Brian
- Water Resources Research, Vol. 52, Issue 7
Reactive transport modeling: An essential tool and a new research approach for the Earth sciences
journal, December 2005
- Steefel, C.; Depaolo, D.; Lichtner, P.
- Earth and Planetary Science Letters, Vol. 240, Issue 3-4
Role of density fluctuations in bimolecular reaction kinetics
journal, February 1978
- Ovchinnikov, A. A.; Zeldovich, Ya. B.
- Chemical Physics, Vol. 28, Issue 1-2
Enhancement of dilution and transverse reactive mixing in porous media: Experiments and model-based interpretation
journal, November 2009
- Rolle, Massimo; Eberhardt, Christina; Chiogna, Gabriele
- Journal of Contaminant Hydrology, Vol. 110, Issue 3-4
Continuous Time Random Walks with Reactions Forcing and Trapping
journal, January 2013
- Angstmann, C. N.; Donnelly, I. C.; Henry, B. I.
- Mathematical Modelling of Natural Phenomena, Vol. 8, Issue 2
Alterations of Fractures in Carbonate Rocks by CO 2 -Acidified Brines
journal, August 2015
- Deng, Hang; Fitts, Jeffrey P.; Crandall, Dustin
- Environmental Science & Technology, Vol. 49, Issue 16
Numerical algorithm for the time fractional Fokker–Planck equation
journal, December 2007
- Deng, Weihua
- Journal of Computational Physics, Vol. 227, Issue 2
A coupled model for transport of multiple chemical species and kinetic precipitation/dissolution reactions with application to reactive flow in single phase hydrothermal systems
journal, May 1994
- Steefel, C. I.; Lasaga, A. C.
- American Journal of Science, Vol. 294, Issue 5
Mixing-induced precipitation: Experimental study and multiscale numerical analysis: MIXING-INDUCED PRECIPITATION
journal, June 2008
- Tartakovsky, A. M.; Redden, G.; Lichtner, P. C.
- Water Resources Research, Vol. 44, Issue 6
CO2-induced dissolution of low permeability carbonates. Part II: Numerical modeling of experiments
journal, December 2013
- Hao, Yue; Smith, Megan; Sholokhova, Yelena
- Advances in Water Resources, Vol. 62
Upscaling solute transport in porous media in the presence of an irreversible bimolecular reaction
journal, January 2012
- Porta, Giovanni Michele; Riva, Monica; Guadagnini, Alberto
- Advances in Water Resources, Vol. 35
Convective transport of acids and bases in porous media
journal, November 1994
- Scheidegger, André; Bürgisser, Christa S.; Borkovec, Michal
- Water Resources Research, Vol. 30, Issue 11
CO2-induced dissolution of low permeability carbonates. Part I: Characterization and experiments
journal, December 2013
- Smith, Megan M.; Sholokhova, Yelena; Hao, Yue
- Advances in Water Resources, Vol. 62
Biogeochemical and Isotopic Gradients in a BTEX/PAH Contaminant Plume: Model-Based Interpretation of a High-Resolution Field Data Set
journal, November 2009
- Prommer, Henning; Anneser, Bettina; Rolle, Massimo
- Environmental Science & Technology, Vol. 43, Issue 21
Predicting the enhancement of mixing-driven reactions in nonuniform flows using measures of flow topology
journal, November 2014
- Engdahl, Nicholas B.; Benson, David A.; Bolster, Diogo
- Physical Review E, Vol. 90, Issue 5
Mixing-controlled biodegradation in a toluene plume — Results from two-dimensional laboratory experiments
journal, February 2008
- Bauer, Robert D.; Maloszewski, Piotr; Zhang, Yanchun
- Journal of Contaminant Hydrology, Vol. 96, Issue 1-4
A natural gradient experiment on solute transport in a sand aquifer: 3. Retardation estimates and mass balances for organic solutes
journal, December 1986
- Roberts, Paul V.; Goltz, Mark N.; Mackay, Douglas M.
- Water Resources Research, Vol. 22, Issue 13
Simulations of physical nonequilibrium solute transport models: Application to a large-scale field experiment
journal, September 1988
- Goltz, Mark N.; Roberts, Paul V.
- Journal of Contaminant Hydrology, Vol. 3, Issue 1
Continuous-time random-walk approach to normal and anomalous reaction-diffusion processes
journal, April 2008
- Zoia, A.
- Physical Review E, Vol. 77, Issue 4
Solubility trapping in formation water as dominant CO2 sink in natural gas fields
journal, April 2009
- Gilfillan, Stuart M. V.; Lollar, Barbara Sherwood; Holland, Greg
- Nature, Vol. 458, Issue 7238
Estimating Lithologic and Transport Properties in Three Dimensions Using Seismic and Tracer Data: The Kesterson aquifer
journal, April 1996
- Hyndman, David W.; Gorelick, Steven M.
- Water Resources Research, Vol. 32, Issue 9
Transport behavior of coupled continuous-time random walks
journal, October 2008
- Dentz, Marco; Scher, Harvey; Holder, Devora
- Physical Review E, Vol. 78, Issue 4
Transport modeling of nonlinearly adsorbing solutes in physically heterogeneous pore networks: TRANSPORT OF REACTIVE SOLUTES
journal, February 2005
- Acharya, R. C.; Van der Zee, S. E. A. T. M.; Leijnse, A.
- Water Resources Research, Vol. 41, Issue 2
A procedure for the solution of multicomponent reactive transport problems: MULTICOMPONENT REACTIVE TRANSPORT PROBLEMS
journal, November 2005
- De Simoni, M.; Carrera, J.; Sánchez-Vila, X.
- Water Resources Research, Vol. 41, Issue 11
Exact stochastic simulation of coupled chemical reactions
journal, December 1977
- Gillespie, Daniel T.
- The Journal of Physical Chemistry, Vol. 81, Issue 25
Pore‐scale simulation of carbonate dissolution in micro‐CT images
journal, February 2016
- Pereira Nunes, J. P.; Blunt, M. J.; Bijeljic, B.
- Journal of Geophysical Research: Solid Earth, Vol. 121, Issue 2
The long-term fate of CO 2 in the subsurface: natural analogues for CO 2 storage
journal, January 2004
- Baines, Shelagh J.; Worden, Richard H.
- Geological Society, London, Special Publications, Vol. 233, Issue 1
The variability and intrinsic remediation of a BTEX plume in anaerobic sulphate-rich groundwater
journal, March 1999
- Davis, G. B.; Barber, C.; Power, T. R.
- Journal of Contaminant Hydrology, Vol. 36, Issue 3-4
Dispersion of a chemically reactive solute in a spatially periodic model of a porous medium
journal, January 1988
- Shapiro, Michael; Brenner, Howard
- Chemical Engineering Science, Vol. 43, Issue 3
Mobility and Interaction of Heavy Metals in a Natural Soil
journal, February 2013
- Bianchi Janetti, Emanuela; Dror, Ishai; Riva, Monica
- Transport in Porous Media, Vol. 97, Issue 3
Measurement of Mixing-Controlled Reactive Transport in Homogeneous Porous Media and Its Prediction from Conservative Tracer Test Data
journal, April 2004
- Jose, Surabhin C.; Cirpka, Olaf A.
- Environmental Science & Technology, Vol. 38, Issue 7
A critical evaluation of recent developments in hydrogeochemical transport models of reactive multichemical components
journal, January 1989
- Yeh, G. T.; Tripathi, V. S.
- Water Resources Research, Vol. 25, Issue 1
Reactive transport modelling of biogeochemical processes and carbon isotope geochemistry inside a landfill leachate plume
journal, June 2004
- van Breukelen, Boris M.; Griffioen, Jasper; Röling, Wilfred F. M.
- Journal of Contaminant Hydrology, Vol. 70, Issue 3-4
Characterization of Bimolecular Reactive Transport in Heterogeneous Porous Media
journal, April 2016
- Edery, Yaniv; Porta, Giovanni M.; Guadagnini, Alberto
- Transport in Porous Media, Vol. 115, Issue 2
The role of scaling laws in upscaling
journal, May 2009
- Wood, Brian D.
- Advances in Water Resources, Vol. 32, Issue 5
Visualization of Mixing Processes in a Heterogeneous Sand Box Aquifer
journal, February 2012
- Castro-Alcalá, Eduardo; Fernàndez-Garcia, Daniel; Carrera, Jesus
- Environmental Science & Technology, Vol. 46, Issue 6
Fringe-Controlled Natural Attenuation of Phenoxy Acids in a Landfill Plume: Integration of Field-Scale Processes by Reactive Transport Modeling
journal, August 2006
- Prommer, Henning; Tuxen, Nina; Bjerg, Poul L.
- Environmental Science & Technology, Vol. 40, Issue 15
Experimental Study of Bimolecular Reaction Kinetics in Porous Media
journal, April 2000
- Raje, Deepashree S.; Kapoor, Vivek
- Environmental Science & Technology, Vol. 34, Issue 7
A kinetic approach for simulating redox-controlled fringe and core biodegradation processes in groundwater: model development and application to a landfill site in Piedmont, Italy
journal, December 2008
- Rolle, Massimo; Clement, T. Prabhakar; Sethi, Rajandrea
- Hydrological Processes, Vol. 22, Issue 25
Anomalous subdiffusion with multispecies linear reaction dynamics
journal, February 2008
- Langlands, T. A. M.; Henry, B. I.; Wearne, S. L.
- Physical Review E, Vol. 77, Issue 2
Stochastic analysis of the transport of kinetically sorbing solutes in aquifers with randomly heterogeneous hydraulic conductivity
journal, September 1993
- Quinodoz, Hernán A. M.; Valocchi, Albert J.
- Water Resources Research, Vol. 29, Issue 9
Arsenic in groundwater: Testing pollution mechanisms for sedimentary aquifers in Bangladesh
journal, January 2001
- McArthur, J. M.; Ravenscroft, P.; Safiulla, S.
- Water Resources Research, Vol. 37, Issue 1
Theory, modeling and experiment in reactive transport in porous media
journal, June 2001
- Bryant, Steven L.; Thompson, Karsten E.
- Current Opinion in Colloid & Interface Science, Vol. 6, Issue 3
Numerical simulation of subsurface characterization methods: application to a natural aquifer analogue
journal, June 1999
- Whittaker, Janet; Teutsch, Georg
- Advances in Water Resources, Vol. 22, Issue 8
Application of a mixing-ratios based formulation to model mixing-driven dissolution experiments
journal, May 2009
- Guadagnini, Alberto; Sanchez-Vila, Xavier; Saaltink, Maarten W.
- Advances in Water Resources, Vol. 32, Issue 5
Framework for Man-Made soil Changes—An Outline of Metapedogenesis
journal, January 1966
- Yaalon, Dan H.; Yaron, Bruno
- Soil Science, Vol. 102, Issue 4
Geochemical processes controlling fate and transport of arsenic in acid mine drainage (AMD) and natural systems
journal, June 2009
- Cheng, Hefa; Hu, Yuanan; Luo, Jian
- Journal of Hazardous Materials, Vol. 165, Issue 1-3
Thermodynamically constrained averaging theory approach for modeling flow and transport phenomena in porous medium systems: 1. Motivation and overview
journal, February 2005
- Gray, William G.; Miller, Cass T.
- Advances in Water Resources, Vol. 28, Issue 2
Anomalous transit-time dispersion in amorphous solids
journal, September 1975
- Scher, Harvey; Montroll, Elliott W.
- Physical Review B, Vol. 12, Issue 6
Implications of pore microgeometry heterogeneity for the movement and chemical reactivity of CO2 in carbonates
journal, September 2013
- Vialle, Stéphanie; Dvorkin, Jack; Mavko, Gary
- GEOPHYSICS, Vol. 78, Issue 5
Ground-Penetrating Radar for High-Resolution Mapping of soil and rock Stratigraphy1
journal, July 1989
- Davis, J. L.; Annan, A. P.
- Geophysical Prospecting, Vol. 37, Issue 5
The effect of time on the weathering of silicate minerals: why do weathering rates differ in the laboratory and field?
journal, December 2003
- White, Art F.; Brantley, Susan L.
- Chemical Geology, Vol. 202, Issue 3-4
Flow topology and scalar mixing in spatially heterogeneous flow fields: FLOW TOPOLOGY AND MIXING
journal, April 2012
- de Barros, Felipe P. J.; Dentz, Marco; Koch, Jonas
- Geophysical Research Letters, Vol. 39, Issue 8
Pattern formation on networks with reactions: A continuous-time random-walk approach
journal, March 2013
- Angstmann, C. N.; Donnelly, I. C.; Henry, B. I.
- Physical Review E, Vol. 87, Issue 3
Continuous groundwater velocity fields and path lines in linear, bilinear, and trilinear finite elements
journal, November 1992
- Cordes, Christian; Kinzelbach, Wolfgang
- Water Resources Research, Vol. 28, Issue 11
Random Walk Methods for Modeling Hydrodynamic Transport in Porous and Fractured Media from Pore to Reservoir Scale
journal, April 2016
- Noetinger, Benoit; Roubinet, Delphine; Russian, Anna
- Transport in Porous Media, Vol. 115, Issue 2
Changes in reactive surface area during limestone dissolution: An experimental and modelling study
journal, July 2009
- Noiriel, Catherine; Luquot, Linda; Madé, Benoît
- Chemical Geology, Vol. 265, Issue 1-2
Optimization of ERT Surveys for Monitoring Transient Hydrological Events Using Perturbation Sensitivity and Genetic Algorithms
journal, January 2004
- Furman, Alex; Ferré, Ty P. A.; Warrick, Art W.
- Vadose Zone Journal, Vol. 3, Issue 4
Using Surface Time Domain Reflectometry Measurements to Estimate Subsurface Chemical Movement
journal, November 2003
- Gaur, A.; Horton, R.; Jaynes, D. B.
- Vadose Zone Journal, Vol. 2, Issue 4
Nonclassical kinetics of an elementary reaction-diffusion system showing effects of a speckled initial reactant distribution and eventual self-segregation: Experiments
journal, February 2004
- Monson, Eric; Kopelman, Raoul
- Physical Review E, Vol. 69, Issue 2
Temporal behavior of a solute cloud in a heterogeneous porous medium: 1. Point-like injection
journal, December 2000
- Dentz, M.; Kinzelbach, H.; Attinger, S.
- Water Resources Research, Vol. 36, Issue 12
Evolution of hydraulic conductivity by precipitation and dissolution in carbonate rock: EVOLUTION OF HYDRAULIC CONDUCTIVITY
journal, January 2003
- Singurindy, Olga; Berkowitz, Brian
- Water Resources Research, Vol. 39, Issue 1
Modeling bimolecular reactions and transport in porous media: BIMOLECULAR REACTIONS IN POROUS MEDIA
journal, January 2009
- Edery, Yaniv; Scher, Harvey; Berkowitz, Brian
- Geophysical Research Letters, Vol. 36, Issue 2
Stochastic Simulation of Chemical Kinetics
journal, May 2007
- Gillespie, Daniel T.
- Annual Review of Physical Chemistry, Vol. 58, Issue 1
Applicability of averaged concentrations in determining geochemical reaction rates in heterogeneous porous media
journal, December 2007
- Li, L.; Peters, C. A.; Celia, M. A.
- American Journal of Science, Vol. 307, Issue 10
X-ray imaging and analysis techniques for quantifying pore-scale structure and processes in subsurface porous medium systems
journal, January 2013
- Wildenschild, Dorthe; Sheppard, Adrian P.
- Advances in Water Resources, Vol. 51
Competitive Sorption of Nickel and Cadmium in Different Soils
journal, January 2009
- Liao, Lixia; Selim, H. M.
- Soil Science, Vol. 174, Issue 10
Lamellar mixing models for structured chemical reactions and their relationship to statistical models; Macro- and micromixing and the problem of averages
journal, January 1980
- Ottino, J. M.
- Chemical Engineering Science, Vol. 35, Issue 6
Comparative assessment of continuum-scale models of bimolecular reactive transport in porous media under pre-asymptotic conditions
journal, February 2016
- Porta, G. M.; Ceriotti, G.; Thovert, J. -F.
- Journal of Contaminant Hydrology, Vol. 185-186
Nonlocal and localized analyses of conditional mean steady state flow in bounded, randomly nonuniform domains: 1. Theory and computational approach
journal, October 1999
- Guadagnini, Alberto; Neuman, Shlomo P.
- Water Resources Research, Vol. 35, Issue 10
Fractional Fokker-Planck dynamics: Numerical algorithm and simulations
journal, April 2006
- Heinsalu, E.; Patriarca, M.; Goychuk, I.
- Physical Review E, Vol. 73, Issue 4
Transport in disordered media with spatially nonuniform fields
journal, March 2010
- Scher, Harvey; Willbrand, Karen; Berkowitz, Brian
- Physical Review E, Vol. 81, Issue 3
What controls the apparent timescale of solute mass transfer in aquifers and soils? A comparison of experimental results: CONTROLLING THE TIMESCALE OF SOLUTE MASS TRANSFER
journal, January 2004
- Haggerty, Roy; Harvey, Charles F.; Freiherr von Schwerin, Claudius
- Water Resources Research, Vol. 40, Issue 1
Measurement and analysis of non-Fickian dispersion in heterogeneous porous media
journal, July 2003
- Levy, Melissa; Berkowitz, Brian
- Journal of Contaminant Hydrology, Vol. 64, Issue 3-4
Evaluation of the Effects of Porous Media Structure on Mixing-Controlled Reactions Using Pore-Scale Modeling and Micromodel Experiments
journal, May 2008
- Willingham, Thomas W.; Werth, Charles J.; Valocchi, Albert J.
- Environmental Science & Technology, Vol. 42, Issue 9
Reactive transport modeling of processes controlling the distribution and natural attenuation of phenolic compounds in a deep sandstone aquifer
journal, December 2001
- Mayer, K. U.; Benner, S. G.; Frind, E. O.
- Journal of Contaminant Hydrology, Vol. 53, Issue 3-4
Time behavior of solute transport in heterogeneous media: transition from anomalous to normal transport
journal, February 2004
- Dentz, Marco; Cortis, Andrea; Scher, Harvey
- Advances in Water Resources, Vol. 27, Issue 2
Competition among flow, dissolution, and precipitation in porous media
journal, July 1989
- Rege, Sunil D.; Fogler, H. Scott
- AIChE Journal, Vol. 35, Issue 7
Reactive Transport in Porous Media: A Comparison of Model Prediction with Laboratory Visualization
journal, June 2002
- Gramling, Carolyn M.; Harvey, Charles F.; Meigs, Lucy C.
- Environmental Science & Technology, Vol. 36, Issue 11
Anomalous reactive transport in porous media: Experiments and modeling
journal, May 2015
- Edery, Yaniv; Dror, Ishai; Scher, Harvey
- Physical Review E, Vol. 91, Issue 5
Interpretation of column experiments of transport of solutes undergoing an irreversible bimolecular reaction using a continuum approximation: MODELING IRREVERSIBLE REACTIVE TRANSPORT
journal, December 2010
- Sanchez-Vila, Xavier; Fernàndez-Garcia, Daniel; Guadagnini, Alberto
- Water Resources Research, Vol. 46, Issue 12
Particle–antiparticle annihilation in diffusive motion
journal, March 1983
- Toussaint, Doug; Wilczek, Frank
- The Journal of Chemical Physics, Vol. 78, Issue 5
Simulation of chemical reaction via particle tracking: Diffusion-limited versus thermodynamic rate-limited regimes: RAPID COMMUNICATION
journal, December 2008
- Benson, David A.; Meerschaert, Mark M.
- Water Resources Research, Vol. 44, Issue 12
MODFLOW/MT3DMS-Based Reactive Multicomponent Transport Modeling
journal, March 2003
- Prommer, H.; Barry, D. A.; Zheng, C.
- Ground Water, Vol. 41, Issue 2
Natural denitrification in the saturated zone: A review
journal, June 1992
- Korom, Scott F.
- Water Resources Research, Vol. 28, Issue 6
Dynamic Three-Dimensional Pore-Scale Imaging of Reaction in a Carbonate at Reservoir Conditions
journal, March 2015
- Menke, Hannah P.; Bijeljic, Branko; Andrew, Matthew G.
- Environmental Science & Technology, Vol. 49, Issue 7
The role of fractures on coupled dissolution and precipitation patterns in carbonate rocks
journal, May 2005
- Singurindy, Olga; Berkowitz, Brian
- Advances in Water Resources, Vol. 28, Issue 5
Interaction between CO2-rich sulfate solutions and carbonate reservoir rocks from atmospheric to supercritical CO2 conditions: Experiments and modeling
journal, September 2014
- Garcia-Rios, Maria; Cama, Jordi; Luquot, Linda
- Chemical Geology, Vol. 383
On the measurement of solute concentrations in 2-D flow tank experiments
journal, January 2008
- Konz, M.; Ackerer, P.; Meier, E.
- Hydrology and Earth System Sciences, Vol. 12, Issue 3
Pore-scale dilution of conservative solutes: An example
journal, August 1998
- Cao, J.; Kitanidis, P. K.
- Water Resources Research, Vol. 34, Issue 8
Mapping underground layers in the super arid Gidron Wadi using electrical resistivity tomography (ERT)
journal, October 2015
- Winters, Gidon; Ryvkin, Ina; Rudkov, Tali
- Journal of Arid Environments, Vol. 121
An advective-dispersive stream tube approach for the transfer of conservative-tracer data to reactive transport
journal, May 2000
- Cirpka, Olaf A.; Kitanidis, Peter K.
- Water Resources Research, Vol. 36, Issue 5
Mixing and Reaction Kinetics in Porous Media: An Experimental Pore Scale Quantification
journal, December 2013
- Anna, Pietro de; Jimenez-Martinez, Joaquin; Tabuteau, Hervé
- Environmental Science & Technology, Vol. 48, Issue 1
Calcite dissolution by mixing waters: geochemical modeling and flow-through experiments
journal, May 2011
- Sanz, E.; Ayora, C.; Carrera, J.
- geologica acta, Vol. 9, Issue 1
Experimental and modeling investigation of multicomponent reactive transport in porous media
journal, March 2011
- Katz, Guy E.; Berkowitz, Brian; Guadagnini, Alberto
- Journal of Contaminant Hydrology, Vol. 120-121
Predictions of dynamic changes in reaction rates as a consequence of incomplete mixing using pore scale reactive transport modeling on images of porous media
journal, August 2015
- Alhashmi, Z.; Blunt, M. J.; Bijeljic, B.
- Journal of Contaminant Hydrology, Vol. 179
Acid/base front propagation in saturated porous media: 2D laboratory experiments and modeling
journal, September 2012
- Loyaux-Lawniczak, Stéphanie; Lehmann, François; Ackerer, Philippe
- Journal of Contaminant Hydrology, Vol. 138-139
Ineffective Natural Attenuation of Degradable Organic Compounds in a Phenol-Contaminated Aquifer
journal, November 2000
- Lerner, David N.; Thornton, Steven F.; Spence, Michael J.
- Ground Water, Vol. 38, Issue 6
Determination of Transverse Dispersion Coefficients from Reactive Plume Lengths
journal, March 2006
- Cirpka, Olaf A.; Olsson, Asa; Ju, Qingsong
- Ground Water, Vol. 44, Issue 2
The lamellar description of mixing in porous media
journal, April 2015
- Le Borgne, T.; Dentz, M.; Villermaux, E.
- Journal of Fluid Mechanics, Vol. 770
Spatial distributions of perchloroethylene reactive transport parameters in the Borden Aquifer: SPATIAL DISTRIBUTIONS OF PCE PARAMETERS
journal, January 2006
- Allen-King, Richelle M.; Divine, Dana Packard; Robin, Michel J. L.
- Water Resources Research, Vol. 42, Issue 1
Taylor dispersion of chemically reactive species: Irreversible first-order reactions in bulk and on boundaries
journal, January 1986
- Shapiro, Michael; Brenner, Howard
- Chemical Engineering Science, Vol. 41, Issue 6
Reaction-subdiffusion equations
journal, March 2006
- Sokolov, I. M.; Schmidt, M. G. W.; Sagués, F.
- Physical Review E, Vol. 73, Issue 3
Modeling non-Fickian transport in geological formations as a continuous time random walk
journal, January 2006
- Berkowitz, Brian; Cortis, Andrea; Dentz, Marco
- Reviews of Geophysics, Vol. 44, Issue 2
The impact of medium architecture of alluvial settings on non-Fickian transport
journal, April 2013
- Zhang, Yong; Green, Christopher T.; Fogg, Graham E.
- Advances in Water Resources, Vol. 54
OpenGeoSys-Gem: A numerical tool for calculating geochemical and porosity changes in saturated and partially saturated media
journal, January 2014
- Kosakowski, Georg; Watanabe, Norihiro
- Physics and Chemistry of the Earth, Parts A/B/C, Vol. 70-71
The concept of the Dilution Index
journal, July 1994
- Kitanidis, Peter K.
- Water Resources Research, Vol. 30, Issue 7
GPR—History, Trends, and Future Developments
journal, October 2002
- Annan, A. P.
- Subsurface Sensing Technologies and Applications, Vol. 3, Issue 4, p. 253-270
Computing “Anomalous” Contaminant Transport in Porous Media: The CTRW MATLAB Toolbox
journal, August 2005
- Cortis, Andrea; Berkowitz, Brian
- Ground Water, Vol. 43, Issue 6
Dissolution and precipitation dynamics during dedolomitization: REACTION DYNAMICS DURING DEDOLOMITIZATION
journal, August 2011
- Edery, Yaniv; Scher, Harvey; Berkowitz, Brian
- Water Resources Research, Vol. 47, Issue 8
Spatial Markov processes for modeling Lagrangian particle dynamics in heterogeneous porous media
journal, August 2008
- Le Borgne, Tanguy; Dentz, Marco; Carrera, Jesus
- Physical Review E, Vol. 78, Issue 2
An investigation of the effect of pore scale flow on average geochemical reaction rates using direct numerical simulation: EFFECT OF PORE SCALE FLOW ON GEOCHEMICAL REACTION RATES
journal, March 2012
- Molins, Sergi; Trebotich, David; Steefel, Carl I.
- Water Resources Research, Vol. 48, Issue 3
A mixing ratios-based formulation for multicomponent reactive transport: A MIXING RATIO FORMULATION FOR REACTIVE
journal, July 2007
- De Simoni, M.; Sanchez-Vila, X.; Carrera, J.
- Water Resources Research, Vol. 43, Issue 7
Integrodifferential formulations of the continuous-time random walk for solute transport subject to bimolecular reactions: From micro- to mesoscopic
journal, March 2015
- Hansen, Scott K.; Berkowitz, Brian
- Physical Review E, Vol. 91, Issue 3
A natural gradient experiment on solute transport in a sand aquifer: 1. Approach and overview of plume movement
journal, December 1986
- Mackay, D. M.; Freyberg, D. L.; Roberts, P. V.
- Water Resources Research, Vol. 22, Issue 13
Geophysics and solvents: The Borden experiment
journal, April 1993
- Greenhouse, John; Brewster, Michael; Schneider, George
- The Leading Edge, Vol. 12, Issue 4
Carbonate dissolution and precipitation in coastal environments: Laboratory analysis and theoretical consideration: CARBONATE PRECIPITATION AND DISSOLUTION
journal, April 2004
- Singurindy, Olga; Berkowitz, Brian; Lowell, Robert P.
- Water Resources Research, Vol. 40, Issue 4
Particle tracking model of bimolecular reactive transport in porous media: PARTICLE TRACKING OF BIMOLECULAR REACTIVE TRANSPORT
journal, July 2010
- Edery, Yaniv; Scher, Harvey; Berkowitz, Brian
- Water Resources Research, Vol. 46, Issue 7
Reactive transport in disordered media: Role of fluctuations in interpretation of laboratory experiments
journal, January 2013
- Edery, Yaniv; Guadagnini, Alberto; Scher, Harvey
- Advances in Water Resources, Vol. 51
Flow, dissolution, and precipitation in dolomite: REACTIVE FLOWS IN DOLOMITE
journal, June 2003
- Singurindy, Olga; Berkowitz, Brian
- Water Resources Research, Vol. 39, Issue 6
Reactive transport codes for subsurface environmental simulation
journal, September 2014
- Steefel, C. I.; Appelo, C. A. J.; Arora, B.
- Computational Geosciences, Vol. 19, Issue 3
Hydrogeological characterization of the south oyster bacterial transport site using geophysical data
journal, October 2001
- Hubbard, Susan S.; Chen, Jinsong; Peterson, John
- Water Resources Research, Vol. 37, Issue 10
Scalar dissipation rates in non-conservative transport systems
journal, June 2013
- Engdahl, Nicholas B.; Ginn, Timothy R.; Fogg, Graham E.
- Journal of Contaminant Hydrology, Vol. 149
Hyporheic flow and transport processes: Mechanisms, models, and biogeochemical implications: HYPORHEIC FLOW AND TRANSPORT PROCESSES
journal, October 2014
- Boano, F.; Harvey, J. W.; Marion, A.
- Reviews of Geophysics, Vol. 52, Issue 4
Observation of Laser Speckle Effects and Nonclassical Kinetics in an Elementary Chemical Reaction
journal, July 2000
- Monson, Eric; Kopelman, Raoul
- Physical Review Letters, Vol. 85, Issue 3
First-principles derivation of reactive transport modeling parameters for particle tracking and PDE approaches
journal, July 2014
- Hansen, Scott K.; Scher, Harvey; Berkowitz, Brian
- Advances in Water Resources, Vol. 69
Changes in Hydrologic Properties of Aquifer Media Due to Chemical Reactions: A Review
journal, October 2001
- Saripalli, K. Prasad; Meyer, Philip D.; Bacon, Diana H.
- Critical Reviews in Environmental Science and Technology, Vol. 31, Issue 4
Front propagation in a one-dimensional autocatalytic reaction-subdiffusion system
journal, April 2009
- Schmidt-Martens, H. H.; Froemberg, D.; Sokolov, I. M.
- Physical Review E, Vol. 79, Issue 4
Experimental and modeling analysis of coupled non-Fickian transport and sorption in natural soils
journal, May 2012
- Rubin, Shira; Dror, Ishai; Berkowitz, Brian
- Journal of Contaminant Hydrology, Vol. 132
Stochastic analysis of sorption macrokinetics in heterogeneous aquifers
journal, June 1996
- Miralles-Wilhelm, F.; Gelhar, L. W.
- Water Resources Research, Vol. 32, Issue 6
Dissolution–precipitation processes in tank experiments for testing numerical models for reactive transport calculations: Experiments and modelling
journal, June 2015
- Poonoosamy, Jenna; Kosakowski, Georg; Van Loon, Luc R.
- Journal of Contaminant Hydrology, Vol. 177-178
Spatial connectivity in a highly heterogeneous aquifer: From cores to preferential flow paths: SPATIAL CONNECTIVITY IN A HETEROGENEOUS AQUIFER
journal, May 2011
- Bianchi, Marco; Zheng, Chunmiao; Wilson, Crystal
- Water Resources Research, Vol. 47, Issue 5
Enhanced mixing and reaction through flow focusing in heterogeneous porous media: FLOW FOCUSING
journal, December 2006
- Werth, Charles J.; Cirpka, Olaf A.; Grathwohl, Peter
- Water Resources Research, Vol. 42, Issue 12
Concentration statistics for transport in heterogeneous media due to stochastic fluctuations of the center of mass velocity
journal, February 2012
- Dentz, Marco
- Advances in Water Resources, Vol. 36
Dissolved Oxygen Imaging in a Porous Medium to Investigate Biodegradation in a Plume with Limited Electron Acceptor Supply
journal, May 2003
- Huang, Wei E.; Oswald, Sascha E.; Lerner, David N.
- Environmental Science & Technology, Vol. 37, Issue 9
Kinetic equations for reaction-subdiffusion systems: Derivation and stability analysis
journal, December 2006
- Yadav, A.; Horsthemke, Werner
- Physical Review E, Vol. 74, Issue 6
Modelling of transport and biogeochemical processes in pollution plumes: literature review and model development
journal, January 2002
- Brun, Adam; Engesgaard, Peter
- Journal of Hydrology, Vol. 256, Issue 3-4
The Method of Volume Averaging
book, January 1999
- Whitaker, Stephen
- Theory and Applications of Transport in Porous Media
Use of high-resolution geophysical data to characterize heterogeneous aquifers: Influence of data integration method on hydrological predictions: GEOPHYSICAL DATA TO CHARACTERIZE HETEROGENEOUS AQUIFERS
journal, September 2009
- Dafflon, B.; Irving, J.; Holliger, K.
- Water Resources Research, Vol. 45, Issue 9
Particle tracking and the diffusion-reaction equation: RAPID COMMUNICATION
journal, January 2013
- Paster, A.; Bolster, D.; Benson, D. A.
- Water Resources Research, Vol. 49, Issue 1
Identification of a reactive degradation zone at a landfill leachate plume fringe using high resolution sampling and incubation techniques
journal, May 2006
- Tuxen, Nina; Albrechtsen, Hans-Jørgen; Bjerg, Poul L.
- Journal of Contaminant Hydrology, Vol. 85, Issue 3-4
Reactive transport of CO2-saturated water in a cement fracture: Application to wellbore leakage during geologic CO2 storage
journal, January 2016
- Huerta, Nicolas J.; Hesse, Marc A.; Bryant, Steven L.
- International Journal of Greenhouse Gas Control, Vol. 44
Time and space nonlocalities underlying fractional-derivative models: Distinction and literature review of field applications
journal, April 2009
- Zhang, Yong; Benson, David A.; Reeves, Donald M.
- Advances in Water Resources, Vol. 32, Issue 4
Origins of anomalous transport in heterogeneous media: Structural and dynamic controls
journal, February 2014
- Edery, Yaniv; Guadagnini, Alberto; Scher, Harvey
- Water Resources Research, Vol. 50, Issue 2
Contaminant-induced irreversible changes in properties of the soil–vadose–aquifer zone: An overview
journal, April 2008
- Yaron, Bruno; Dror, Ishai; Berkowitz, Brian
- Chemosphere, Vol. 71, Issue 8
Mixing by porous media
journal, November 2012
- Villermaux, Emmanuel
- Comptes Rendus Mécanique, Vol. 340, Issue 11-12
On Characterization of Anomalous Dispersion in Porous and Fractured Media
journal, June 1995
- Berkowitz, Brian; Scher, Harvey
- Water Resources Research, Vol. 31, Issue 6
Nickel migration and retention dynamics in natural soil columns: NICKEL MIGRATION AND RETENTION DYNAMICS IN SOIL COLUMNS
journal, September 2015
- Raveh-Rubin, Shira; Edery, Yaniv; Dror, Ishai
- Water Resources Research, Vol. 51, Issue 9
Nonideal transport of reactive solutes in heterogeneous porous media 2. Quantitative analysis of the Borden natural-gradient field experiment
journal, October 1997
- Brusseau, Mark L.; Srivastava, Rajesh
- Journal of Contaminant Hydrology, Vol. 28, Issue 1-2
Present state and future directions of modeling of geochemistry in hydrogeological systems
journal, February 2001
- van der Lee, Jan; De Windt, Laurent
- Journal of Contaminant Hydrology, Vol. 47, Issue 2-4
On the measurement of solute concentrations in 2-D flow tank experiments
posted_content, November 2007
- Konz, M.; Ackerer, P.; Meier, E.
- Hydrology and Earth System Sciences Discussions
Convective transport of acids and bases in porous media : A. Scheidegger, C. S. Burgisser, M. Borkovec, H. Sticher, H. Meeussen & W. Van Riemsdijk, Water Resources Research, 30(11), 1994, pp 2937–2944
journal, September 1995
- ,
- International Journal of Rock Mechanics and Mining Sciences & Geomechanics Abstracts, Vol. 32, Issue 6, p. A267
Optimization of ERT Surveys for Monitoring Transient Hydrological Events Using Perturbation Sensitivity and Genetic Algorithms
journal, November 2004
- Furman, A.; Ferre, T. P. A.; Warrick, A. W.
- Vadose Zone Journal, Vol. 3, Issue 4
Continuous-time random-walk approach to normal and anomalous reaction-diffusion processes
text, January 2008
- Zoia, A.
- arXiv
On reaction-subdiffusion equations
text, January 2005
- Sokolov, I. M.; Schmidt, M. G. W.; Sagues, F.
- arXiv
Works referencing / citing this record:
Reactive Random Walk Particle Tracking and Its Equivalence With the Advection‐Diffusion‐Reaction Equation
journal, January 2019
- Perez, Lazaro J.; Hidalgo, Juan J.; Dentz, Marco
- Water Resources Research, Vol. 55, Issue 1
Finite‐Element Method Solution of Non‐Fickian Transport in Porous Media: The CTRW‐FEM Package
journal, August 2018
- Ben‐Zvi, Rami; Jiang, Shidong; Scher, Harvey
- Groundwater, Vol. 57, Issue 3
A continuous time random walk (CTRW) integro-differential equation with chemical interaction
journal, January 2018
- Ben-Zvi, Rami; Nissan, Alon; Scher, Harvey
- The European Physical Journal B, Vol. 91, Issue 1
Reactive Transport in Heterogeneous Porous Media Under Different Péclet Numbers
journal, December 2019
- Nissan, Alon; Berkowitz, Brian
- Water Resources Research, Vol. 55, Issue 12