Wollastonite Carbonation in Water-Bearing Supercritical CO2: Effects of Particle Size

Min, Yujia; Li, Qingyun; Voltolini, Marco; Kneafsey, Timothy; Jun, Young -Shin

doi:10.1021/acs.est.7b04475

Title: Wollastonite Carbonation in Water-Bearing Supercritical CO₂: Effects of Particle Size

Abstract

The performance of geologic CO₂ sequestration (GCS) can be affected by CO₂ mineralization and changes in the permeability of geologic formations resulting from interactions between water-bearing supercritical CO₂ (scCO₂) and silicates in reservoir rocks. However, without an understanding of the size effects, the findings in previous studies using nanometer- or micrometer-size particles cannot be applied to the bulk rock in field sites. In this study, we report the effects of particle sizes on the carbonation of wollastonite (CaSiO₃) at 60 °C and 100 bar in water-bearing scCO₂. After normalization by the surface area, the thickness of the reacted wollastonite layer on the surfaces was independent of particle sizes. After 20 h, the reaction was not controlled by the kinetics of surface reactions but by the diffusion of water-bearing scCO₂ across the product layer on wollastonite surfaces. Among the products of reaction, amorphous silica, rather than calcite, covered the wollastonite surface and acted as a diffusion barrier to water-bearing scCO₂. The product layer was not highly porous, with a specific surface area 10 times smaller than that of the altered amorphous silica formed at the wollastonite surface in aqueous solution. As a result, these findings can help us evaluate the impactsmore »« less

Authors:

Min, Yujia ^[1]; Li, Qingyun ^[1]; Voltolini, Marco ^[2]; Kneafsey, Timothy ^[2];

^[1]

Washington Univ., St. Louis, MO (United States)
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Publication Date:: Mon Oct 02 00:00:00 EDT 2017

Research Org.:: Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Nanoscale Control of Geologic CO2 (NCGC)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1476570

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Environmental Science and Technology

Additional Journal Information:: Journal Volume: 51; Journal Issue: 21; Related Information: © 2017 American Chemical Society.; Journal ID: ISSN 0013-936X

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 54 ENVIRONMENTAL SCIENCES

Citation Formats


                    Min, Yujia, Li, Qingyun, Voltolini, Marco, Kneafsey, Timothy, and Jun, Young -Shin. Wollastonite Carbonation in Water-Bearing Supercritical CO2: Effects of Particle Size.  United States: N. p., 2017. 
Web.  doi:10.1021/acs.est.7b04475.

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                    Min, Yujia, Li, Qingyun, Voltolini, Marco, Kneafsey, Timothy, & Jun, Young -Shin. Wollastonite Carbonation in Water-Bearing Supercritical CO2: Effects of Particle Size.  United States.  https://doi.org/10.1021/acs.est.7b04475

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                    Min, Yujia, Li, Qingyun, Voltolini, Marco, Kneafsey, Timothy, and Jun, Young -Shin. Mon .  
"Wollastonite Carbonation in Water-Bearing Supercritical CO2: Effects of Particle Size".  United States.  https://doi.org/10.1021/acs.est.7b04475.  https://www.osti.gov/servlets/purl/1476570.

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@article{osti_1476570,

  title        = {Wollastonite Carbonation in Water-Bearing Supercritical CO2: Effects of Particle Size},

  author       = {Min, Yujia and Li, Qingyun and Voltolini, Marco and Kneafsey, Timothy and Jun, Young -Shin},

  abstractNote = {The performance of geologic CO2 sequestration (GCS) can be affected by CO2 mineralization and changes in the permeability of geologic formations resulting from interactions between water-bearing supercritical CO2 (scCO2) and silicates in reservoir rocks. However, without an understanding of the size effects, the findings in previous studies using nanometer- or micrometer-size particles cannot be applied to the bulk rock in field sites. In this study, we report the effects of particle sizes on the carbonation of wollastonite (CaSiO3) at 60 °C and 100 bar in water-bearing scCO2. After normalization by the surface area, the thickness of the reacted wollastonite layer on the surfaces was independent of particle sizes. After 20 h, the reaction was not controlled by the kinetics of surface reactions but by the diffusion of water-bearing scCO2 across the product layer on wollastonite surfaces. Among the products of reaction, amorphous silica, rather than calcite, covered the wollastonite surface and acted as a diffusion barrier to water-bearing scCO2. The product layer was not highly porous, with a specific surface area 10 times smaller than that of the altered amorphous silica formed at the wollastonite surface in aqueous solution. As a result, these findings can help us evaluate the impacts of mineral carbonation in water-bearing scCO2.},

  doi          = {10.1021/acs.est.7b04475},

  journal      = {Environmental Science and Technology},

  number       = 21,

  volume       = 51,

  place        = {United States},

  year         = {Mon Oct 02 00:00:00 EDT 2017},

  month        = {Mon Oct 02 00:00:00 EDT 2017}

}

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https://doi.org/10.1021/acs.est.7b04475

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Works referencing / citing this record:

Carbon dioxide mineralization for the disposition of blast‐furnace slag: reaction intensification using NaCl solutions
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Ren, Enze; Tang, Siyang; Liu, Changjun
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Title: Wollastonite Carbonation in Water-Bearing Supercritical CO2: Effects of Particle Size

Abstract

Citation Formats

Impacts of Geochemical Reactions on Geologic Carbon Sequestration journal, August 2012

Nanoscale Chemical Processes Affecting Storage Capacities and Seals during Geologic CO 2 Sequestration journal, July 2017

A review of fracturing fluid systems used for hydraulic fracturing of oil and gas wells journal, April 2014

Energized Fracturing With 50% CO2 for Improved Hydrocarbon Recovery journal, January 1982

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Effects of Salinity and the Extent of Water on Supercritical CO 2 -Induced Phlogopite Dissolution and Secondary Mineral Formation journal, February 2011

Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks journal, January 2010

Comprehensive Review of Caprock-Sealing Mechanisms for Geologic Carbon Sequestration journal, August 2012

Formation of submicron magnesite during reaction of natural forsterite in H2O-saturated supercritical CO2 journal, June 2014

Water reactivity in the liquid and supercritical CO2 phase: Has half the story been neglected? journal, February 2009

Experimental evaluation of interactions in supercritical CO2/water/rock minerals system under geologic CO2 sequestration conditions journal, December 2007

The role of H2O in the carbonation of forsterite in supercritical CO2 journal, July 2011

Carbonation of Ca-bearing silicates, the case of wollastonite: Experimental investigations and kinetic modeling journal, July 2009

Mechanism of wollastonite carbonation deduced from micro- to nanometer length scale observations journal, November 2009

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Insights into silicate carbonation processes in water-bearing supercritical CO2 fluids journal, July 2013

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Reactivity of highly cycled particles of CaO in a carbonation/calcination loop journal, April 2008

Dissolution of wollastonite during the experimental manipulation of Hubbard Brook Watershed 1 journal, February 2004

Effect of organic ligands and heterotrophic bacteria on wollastonite dissolution kinetics journal, October 2009

An Introduction to the Rock-Forming Minerals book, January 2013

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A mechanistic understanding of plagioclase dissolution based on Al occupancy and T–O bond length: from geologic carbon sequestration to ambient conditions journal, January 2013

Effects of Al/Si ordering on feldspar dissolution: Part II. The pH dependence of plagioclases’ dissolution rates journal, February 2014

Effects of Al/Si ordering on feldspar dissolution: Part I. Crystallographic control on the stoichiometry of dissolution reaction journal, February 2014

Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test, Texas, USA journal, June 2009

Reactive transport modelling of the impact of CO2 injection on the clayey cap rock at Sleipner (North Sea) journal, April 2005

Greenhouse gas sequestration in abandoned oil reservoirs: The International Energy Agency Weyburn pilot project journal, January 2004

CO2-H2O mixtures in the geological sequestration of CO2. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar journal, August 2003

Formation, growth and transformation of leached layers during silicate minerals dissolution: The example of wollastonite journal, December 2012

Unifying natural and laboratory chemical weathering with interfacial dissolution–reprecipitation: A study based on the nanometer-scale chemistry of fluid–silicate interfaces journal, February 2012

Mineralogical evolution of Fe–Si-rich layers at the olivine-water interface during carbonation reactions journal, November 2015

The role of Fe and redox conditions in olivine carbonation rates: An experimental study of the rate limiting reactions at 90 and 150 °C in open and closed systems journal, October 2013

The deleterious effect of secondary phases on olivine carbonation yield: Insight from time-resolved aqueous-fluid sampling and FIB-TEM characterization journal, October 2013

A Laboratory Evaluation of the Wettability of Fifty Oil-Producing Reservoirs journal, December 1972

Carbon dioxide mineralization for the disposition of blast‐furnace slag: reaction intensification using NaCl solutions journal, December 2018

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Title: Wollastonite Carbonation in Water-Bearing Supercritical CO₂: Effects of Particle Size

Impacts of Geochemical Reactions on Geologic Carbon Sequestration
journal, August 2012

Nanoscale Chemical Processes Affecting Storage Capacities and Seals during Geologic CO ₂ Sequestration
journal, July 2017

A review of fracturing fluid systems used for hydraulic fracturing of oil and gas wells
journal, April 2014

Energized Fracturing With 50% CO2 for Improved Hydrocarbon Recovery
journal, January 1982

The Utility of CO2 as an Energizing Component for Fracturing Fluids
journal, September 1986

Effects of Salinity and the Extent of Water on Supercritical CO ₂ -Induced Phlogopite Dissolution and Secondary Mineral Formation
journal, February 2011

Role and impact of CO2–rock interactions during CO2 storage in sedimentary rocks
journal, January 2010

Comprehensive Review of Caprock-Sealing Mechanisms for Geologic Carbon Sequestration
journal, August 2012

Formation of submicron magnesite during reaction of natural forsterite in H2O-saturated supercritical CO2
journal, June 2014

Water reactivity in the liquid and supercritical CO₂ phase: Has half the story been neglected?
journal, February 2009

Experimental evaluation of interactions in supercritical CO2/water/rock minerals system under geologic CO2 sequestration conditions
journal, December 2007

The role of H2O in the carbonation of forsterite in supercritical CO2
journal, July 2011

Carbonation of Ca-bearing silicates, the case of wollastonite: Experimental investigations and kinetic modeling
journal, July 2009

Mechanism of wollastonite carbonation deduced from micro- to nanometer length scale observations
journal, November 2009

In situ laboratory X-ray powder diffraction study of wollastonite carbonation using a high-pressure stage
journal, September 2009

Insights into silicate carbonation processes in water-bearing supercritical CO2 fluids
journal, July 2013

In Situ Infrared Spectroscopic Study of Forsterite Carbonation in Wet Supercritical CO ₂
journal, July 2011

Reaction of water-saturated supercritical CO2 with forsterite: Evidence for magnesite formation at low temperatures
journal, August 2012

Forsterite [Mg ₂ SiO ₄ )] Carbonation in Wet Supercritical CO ₂ : An in Situ High-Pressure X-ray Diffraction Study
journal, June 2012

Impacts of Organic Ligands on Forsterite Reactivity in Supercritical CO ₂ Fluids
journal, March 2015

Fayalite dissolution and siderite formation in water-saturated supercritical CO2
journal, November 2012

Reactivity of dolomite in water-saturated supercritical carbon dioxide: Significance for carbon capture and storage and for enhanced oil and gas recovery
journal, January 2013

Comparative reactivity study of forsterite and antigorite in wet supercritical CO2 by in situ infrared spectroscopy
journal, October 2013

Reactivity of highly cycled particles of CaO in a carbonation/calcination loop
journal, April 2008

Dissolution of wollastonite during the experimental manipulation of Hubbard Brook Watershed 1
journal, February 2004

Effect of organic ligands and heterotrophic bacteria on wollastonite dissolution kinetics
journal, October 2009

An Introduction to the Rock-Forming Minerals
book, January 2013

Plagioclase Dissolution during CO ₂ –SO ₂ Cosequestration: Effects of Sulfate
journal, January 2015

Structure-Dependent Interactions between Alkali Feldspars and Organic Compounds: Implications for Reactions in Geologic Carbon Sequestration
journal, August 2012

A mechanistic understanding of plagioclase dissolution based on Al occupancy and T–O bond length: from geologic carbon sequestration to ambient conditions
journal, January 2013

Effects of Al/Si ordering on feldspar dissolution: Part II. The pH dependence of plagioclases’ dissolution rates
journal, February 2014

Effects of Al/Si ordering on feldspar dissolution: Part I. Crystallographic control on the stoichiometry of dissolution reaction
journal, February 2014

Potential environmental issues of CO2 storage in deep saline aquifers: Geochemical results from the Frio-I Brine Pilot test, Texas, USA
journal, June 2009

Reactive transport modelling of the impact of CO2 injection on the clayey cap rock at Sleipner (North Sea)
journal, April 2005

Greenhouse gas sequestration in abandoned oil reservoirs: The International Energy Agency Weyburn pilot project
journal, January 2004

CO₂-H₂O mixtures in the geological sequestration of CO₂. I. Assessment and calculation of mutual solubilities from 12 to 100°C and up to 600 bar
journal, August 2003

Formation, growth and transformation of leached layers during silicate minerals dissolution: The example of wollastonite
journal, December 2012

Unifying natural and laboratory chemical weathering with interfacial dissolution–reprecipitation: A study based on the nanometer-scale chemistry of fluid–silicate interfaces
journal, February 2012

Mineralogical evolution of Fe–Si-rich layers at the olivine-water interface during carbonation reactions
journal, November 2015

The role of Fe and redox conditions in olivine carbonation rates: An experimental study of the rate limiting reactions at 90 and 150 °C in open and closed systems
journal, October 2013

The deleterious effect of secondary phases on olivine carbonation yield: Insight from time-resolved aqueous-fluid sampling and FIB-TEM characterization
journal, October 2013

A Laboratory Evaluation of the Wettability of Fifty Oil-Producing Reservoirs
journal, December 1972

Carbon dioxide mineralization for the disposition of blast‐furnace slag: reaction intensification using NaCl solutions
journal, December 2018

The Carbonation of Wollastonite: A Model Reaction to Test Natural and Biomimetic Catalysts for Enhanced CO2 Sequestration
journal, May 2018

Carbonation of natural pure and impure wollastonite
journal, March 2019

Parameter influence on the rankinite binder paste and mortar accelerated carbonation curing
journal, July 2019