Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery

Abraham, Alyson; Huang, Jianping; Smith, Paul F.; Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.

doi:10.1149/2.0371810jes

Title: Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)₂ Based Li/I₂ Battery

Abstract

While solid state electrolytes hold promise for safer batteries, the lithium/solid-state electrolyte interface has presented challenges. In this paper, we report a fully self-forming solid state rechargeable battery based on the Li/I2 couple using LiI rich lithium iodide-(3-hydroxyproprionitrile)2 electrolyte. Effective charge-discharge cycling was demonstrated, showing promise for future generations of high energy density self-forming, self-healing batteries.

Authors:

Abraham, Alyson ^[1];

^[1]; Smith, Paul F. ^[1];

^[2];

^[3];

^[2]

Stony Brook Univ., NY (United States). Dept. of Chemistry
Stony Brook Univ., NY (United States). Dept. of Chemistry and Department of Materials Science and Chemical Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
Stony Brook Univ., NY (United States). Dept. of Chemistry and Department of Materials Science and Chemical Engineering

Publication Date:: Wed Jul 11 00:00:00 EDT 2018

Research Org.:: Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE)

OSTI Identifier:: 1473649

Report Number(s):: BNL-209047-2018-JAAM
Journal ID: ISSN 0013-4651

Grant/Contract Number:: SC0012704; EE0007785

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Volume: 165; Journal Issue: 10; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; impedance; lithium battery; self-forming

Citation Formats


                    Abraham, Alyson, Huang, Jianping, Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery.  United States: N. p., 2018. 
Web.  doi:10.1149/2.0371810jes.

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                    Abraham, Alyson, Huang, Jianping, Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery.  United States.  https://doi.org/10.1149/2.0371810jes

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                    Abraham, Alyson, Huang, Jianping, Smith, Paul F., Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Wed .  
"Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery".  United States.  https://doi.org/10.1149/2.0371810jes.  https://www.osti.gov/servlets/purl/1473649.

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@article{osti_1473649,

  title        = {Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery},

  author       = {Abraham, Alyson and Huang, Jianping and Smith, Paul F. and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},

  abstractNote = {While solid state electrolytes hold promise for safer batteries, the lithium/solid-state electrolyte interface has presented challenges. In this paper, we report a fully self-forming solid state rechargeable battery based on the Li/I2 couple using LiI rich lithium iodide-(3-hydroxyproprionitrile)2 electrolyte. Effective charge-discharge cycling was demonstrated, showing promise for future generations of high energy density self-forming, self-healing batteries.},

  doi          = {10.1149/2.0371810jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 10,

  volume       = 165,

  place        = {United States},

  year         = {Wed Jul 11 00:00:00 EDT 2018},

  month        = {Wed Jul 11 00:00:00 EDT 2018}

}

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Works referencing / citing this record:

Progress and Outlook on few Component Composite Solid State Electrolytes
journal, January 2019

Stackhouse, Chavis A.; Abraham, Alyson; Takeuchi, Kenneth J.
MRS Advances, Vol. 4, Issue 49
DOI: 10.1557/adv.2019.264

Interface effects on self-forming rechargeable Li/I2-based solid state batteries
journal, April 2019

Abraham, Alyson; Dunkin, Mikaela R.; Huang, Jianping
MRS Communications, Vol. 9, Issue 02
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Similar Records

Title: Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)2 Based Li/I2 Battery

Abstract

Citation Formats

Batteries used to power implantable biomedical devices journal, December 2012

Electrode Development in a Novel Self-Assembled Lithium Iodide Battery conference, January 2010

An all solid-state rechargeable lithium-iodine thin film battery using LiI(3-hydroxypropionitrile)2 as an I− ion electrolyte journal, January 2011

Iodine ion transport in solid electrolyte LiI(C3H5NO)2: a first-principles identification journal, December 2006

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Electrochemical Impedance Spectroscopy of Electrochemically Self-Assembled Lithium–Iodine Batteries journal, January 2008

Li[sub 9]SiAlO[sub 8]: A Lithium Ion Electrolyte for Voltages above 5.4 V journal, January 1996

Challenges and prospects of the role of solid electrolytes in the revitalization of lithium metal batteries journal, January 2016

Pathways to enabling solid state electrolytically formed batteries: The solid electrolyte interphase journal, April 2012

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Electrolytes and Interphases in Li-Ion Batteries and Beyond journal, October 2014

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Solid-State Composite Electrolyte LiI/3-Hydroxypropionitrile/SiO 2 for Dye-Sensitized Solar Cells journal, May 2005

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Ion transport in small-molecule electrolytes based on LiI/3-hydroxypropionitrile with high salt contents journal, January 2007

Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems journal, January 2016

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface journal, April 2017

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Progress and Outlook on few Component Composite Solid State Electrolytes journal, January 2019

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Title: Communication—Demonstration and Electrochemistry of a Self-Forming Solid State Rechargeable LiI(HPN)₂ Based Li/I₂ Battery

Batteries used to power implantable biomedical devices
journal, December 2012

Electrode Development in a Novel Self-Assembled Lithium Iodide Battery
conference, January 2010

An all solid-state rechargeable lithium-iodine thin film battery using LiI(3-hydroxypropionitrile)2 as an I− ion electrolyte
journal, January 2011

Iodine ion transport in solid electrolyte LiI(C3H5NO)2: a first-principles identification
journal, December 2006

High-power all-solid-state batteries using sulfide superionic conductors
journal, March 2016

Electrical Conductivity of the LiI-H[sub 2]O-Al[sub 2]O[sub 3] System
journal, January 1980

Electrochemical Impedance Spectroscopy of Electrochemically Self-Assembled Lithium–Iodine Batteries
journal, January 2008

Li[sub 9]SiAlO[sub 8]: A Lithium Ion Electrolyte for Voltages above 5.4 V
journal, January 1996

Challenges and prospects of the role of solid electrolytes in the revitalization of lithium metal batteries
journal, January 2016

Pathways to enabling solid state electrolytically formed batteries: The solid electrolyte interphase
journal, April 2012

Garnet-type solid-state fast Li ion conductors for Li batteries: critical review
journal, January 2014

Electrolytes and Interphases in Li-Ion Batteries and Beyond
journal, October 2014

Preferential orientation of I2-LiI(HPN)2 film for a flexible all-solid-state rechargeable lithium–iodine paper battery
journal, January 2015

Solid-State Composite Electrolyte LiI/3-Hydroxypropionitrile/SiO ₂ for Dye-Sensitized Solar Cells
journal, May 2005

Ionic conductivity of solid lithium iodide and its monohydrate
journal, February 1981

Ion transport in small-molecule electrolytes based on LiI/3-hydroxypropionitrile with high salt contents
journal, January 2007

Interfacial behaviours between lithium ion conductors and electrode materials in various battery systems
journal, January 2016

Toward garnet electrolyte–based Li metal batteries: An ultrathin, highly effective, artificial solid-state electrolyte/metallic Li interface
journal, April 2017

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journal, June 2017

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journal, February 2010

Progress and Outlook on few Component Composite Solid State Electrolytes
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Interface effects on self-forming rechargeable Li/I2-based solid state batteries
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