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Title: Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like 2D Chalcogenide Battery Anode [Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like Two-Dimensional Chalcogenide Battery Anode]

Abstract

Abstract 2D cobalt selenide based on conversion reaction has attracted much attention due to its open layered structure and high specific capacity. However, effectively suppressing the fast capacity fade caused by the irreversible Se dissolution and serious volume change during the cycling process is still a challenge. Herein, the concentration of dispersion liquid under supercritical conditions is tuned to induce the CoSe crystal to grow along the graphene oxide (GO), and finally obtain the Tremella ‐like CoSe–reduced GO (rGO) hybrid. The nature of epitaxial growth leads to the formation of stable CSe bonds, which maintain a favorable conductive connection between CoSe and rGO as well as enhance the mechanical strength of active materials to suppress Se dissolution and volume expansion during Na/Li intercalation and deintercalation. The unique microstructural merits of the hybrid result in superior sodium/lithium storage performance (400.8 mAh g −1 at 1 A g −1 after 100 cycles for sodium‐ion batteries and 769.6 mAh g −1 at 2 A g −1 after 500 cycles for lithium‐ion batteries). Moreover, the transmission X‐ray microscopy technique is first used to directly observe the Se segregation in cobalt selenide and it being suppressed by the CSe bonds.

Authors:
 [1];  [2];  [1];  [1];  [3];  [1];  [1];  [1];  [4];  [2]; ORCiD logo [4]
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  1. Beijing Institute of Technology, Beijing (P. R. China)
  2. SLAC National Accelerator Lab., Menlo Park, CA (United States)
  3. SLAC National Accelerator Lab., Menlo Park, CA (United States); Chinese Academy of Sciences (CAS), Beijing (P. R. China)
  4. Beijing Institute of Technology, Beijing (P. R. China); Collaborative Innovation Center of Electric Vehicles in Beijing, Beijing (P. R. China)
Publication Date:
Research Org.:
SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1470710
Alternate Identifier(s):
OSTI ID: 1456283
Grant/Contract Number:  
AC02-76SF00515; DE‐AC02‐76SF00515
Resource Type:
Accepted Manuscript
Journal Name:
Advanced Energy Materials
Additional Journal Information:
Journal Volume: 8; Journal Issue: 23; Journal ID: ISSN 1614-6832
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE; carbon–selenium bonds; cobalt selenide; lithium‐ion batteries; Se dissolution; sodium-ion batteries

Citation Formats

Li, Yu, Xu, Yahong, Wang, Zhaohua, Bai, Ying, Zhang, Kai, Dong, Ruiqi, Gao, Yaning, Ni, Qiao, Wu, Feng, Liu, Yijin, and Wu, Chuan. Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like 2D Chalcogenide Battery Anode [Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like Two-Dimensional Chalcogenide Battery Anode]. United States: N. p., 2018. Web. doi:10.1002/aenm.201800927.
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Li, Yu, Xu, Yahong, Wang, Zhaohua, Bai, Ying, Zhang, Kai, Dong, Ruiqi, Gao, Yaning, Ni, Qiao, Wu, Feng, Liu, Yijin, & Wu, Chuan. Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like 2D Chalcogenide Battery Anode [Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like Two-Dimensional Chalcogenide Battery Anode]. United States. https://doi.org/10.1002/aenm.201800927
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Li, Yu, Xu, Yahong, Wang, Zhaohua, Bai, Ying, Zhang, Kai, Dong, Ruiqi, Gao, Yaning, Ni, Qiao, Wu, Feng, Liu, Yijin, and Wu, Chuan. Thu . "Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like 2D Chalcogenide Battery Anode [Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like Two-Dimensional Chalcogenide Battery Anode]". United States. https://doi.org/10.1002/aenm.201800927. https://www.osti.gov/servlets/purl/1470710.
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@article{osti_1470710,
title = {Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like 2D Chalcogenide Battery Anode [Stable Carbon-Selenium Bonds for Enhanced Performance in Tremella-Like Two-Dimensional Chalcogenide Battery Anode]},
author = {Li, Yu and Xu, Yahong and Wang, Zhaohua and Bai, Ying and Zhang, Kai and Dong, Ruiqi and Gao, Yaning and Ni, Qiao and Wu, Feng and Liu, Yijin and Wu, Chuan},
abstractNote = {Abstract 2D cobalt selenide based on conversion reaction has attracted much attention due to its open layered structure and high specific capacity. However, effectively suppressing the fast capacity fade caused by the irreversible Se dissolution and serious volume change during the cycling process is still a challenge. Herein, the concentration of dispersion liquid under supercritical conditions is tuned to induce the CoSe crystal to grow along the graphene oxide (GO), and finally obtain the Tremella ‐like CoSe–reduced GO (rGO) hybrid. The nature of epitaxial growth leads to the formation of stable CSe bonds, which maintain a favorable conductive connection between CoSe and rGO as well as enhance the mechanical strength of active materials to suppress Se dissolution and volume expansion during Na/Li intercalation and deintercalation. The unique microstructural merits of the hybrid result in superior sodium/lithium storage performance (400.8 mAh g −1 at 1 A g −1 after 100 cycles for sodium‐ion batteries and 769.6 mAh g −1 at 2 A g −1 after 500 cycles for lithium‐ion batteries). Moreover, the transmission X‐ray microscopy technique is first used to directly observe the Se segregation in cobalt selenide and it being suppressed by the CSe bonds.},
doi = {10.1002/aenm.201800927},
journal = {Advanced Energy Materials},
number = 23,
volume = 8,
place = {United States},
year = {Thu Jun 21 00:00:00 EDT 2018},
month = {Thu Jun 21 00:00:00 EDT 2018}
}
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https://doi.org/10.1002/aenm.201800927
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Cited by: 83 works
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Figures / Tables:

Scheme 1 Scheme 1: Schematic illustration of showing how the C─Se bonds mechanical stretching in hierarchical tremella-like CoSe-rGO hybrid can mitigate Se dissolution and volume expansion.
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    Freestanding N‐Doped Carbon Coated CuO Array Anode for Lithium‐Ion and Sodium‐Ion Batteries
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      Figures / Tables found in this record:

      Scheme 1 (p. 15)figure
      Figure 1 (p. 16)figure
      Figure 2 (p. 17)figure
      Figure 3 (p. 18)figure
      Figure 4 (p. 19)figure
      Figure S1 (p. 23)figure
      Figure S2 (p. 23)figure
      Figure S3 (p. 24)figure
      Figure S4 (p. 24)figure
      Figure S5 (p. 25)figure
      Figure S6 (p. 26)figure
      Table S1 (p. 27)table
      Table S2 (p. 27)table
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