Toward a Four-Electron Redox Quinone Polymer for High Capacity Lithium Ion Storage
Abstract
Abstract Despite recent advances, current polymeric organic cathode materials have failed to incorporate a high degree of lithium storage in a small molecular framework, resulting in low capacities relative to monomers. This report discloses the development of a lithium salt polymer of dihydroxyanthraquinone (LiDHAQS) capable of storing four Li + per monomer. The combination of storing four Li + per monomer and a low molecular weight monomer results in a capacity of 330 mA h g −1 , a record for this class of material. The additional redox events responsible for added Li + storage occur between 3.0 and 3.6 V versus Li/Li + resulting in an average discharge potential of 2.5 V versus Li/Li + . These metrics combined yield a high energy density of 825 W h kg −1 which is a 55% improvement over commercial lithium cobalt oxide. The high performance of LiDHAQS makes it a promising material for next generation Li + cathodes.
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States). Energy Frontier Research Center (EFRC) Center for Electrical Energy Storage (CEES)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1469964
- Alternate Identifier(s):
- OSTI ID: 1396416
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 8; Journal Issue: 5; Related Information: CEES partners with Argonne National Laboratory (lead); University of Illinois, Urbana-Champaign; Northwest University; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; batteries; cathodes; lithium; polymer; quinone
Citation Formats
Petronico, Aaron, Bassett, Kimberly L., Nicolau, Bruno G., Gewirth, Andrew A., and Nuzzo, Ralph G. Toward a Four-Electron Redox Quinone Polymer for High Capacity Lithium Ion Storage. United States: N. p., 2017.
Web. doi:10.1002/aenm.201700960.
Petronico, Aaron, Bassett, Kimberly L., Nicolau, Bruno G., Gewirth, Andrew A., & Nuzzo, Ralph G. Toward a Four-Electron Redox Quinone Polymer for High Capacity Lithium Ion Storage. United States. https://doi.org/10.1002/aenm.201700960
Petronico, Aaron, Bassett, Kimberly L., Nicolau, Bruno G., Gewirth, Andrew A., and Nuzzo, Ralph G. Wed .
"Toward a Four-Electron Redox Quinone Polymer for High Capacity Lithium Ion Storage". United States. https://doi.org/10.1002/aenm.201700960. https://www.osti.gov/servlets/purl/1469964.
@article{osti_1469964,
title = {Toward a Four-Electron Redox Quinone Polymer for High Capacity Lithium Ion Storage},
author = {Petronico, Aaron and Bassett, Kimberly L. and Nicolau, Bruno G. and Gewirth, Andrew A. and Nuzzo, Ralph G.},
abstractNote = {Abstract Despite recent advances, current polymeric organic cathode materials have failed to incorporate a high degree of lithium storage in a small molecular framework, resulting in low capacities relative to monomers. This report discloses the development of a lithium salt polymer of dihydroxyanthraquinone (LiDHAQS) capable of storing four Li + per monomer. The combination of storing four Li + per monomer and a low molecular weight monomer results in a capacity of 330 mA h g −1 , a record for this class of material. The additional redox events responsible for added Li + storage occur between 3.0 and 3.6 V versus Li/Li + resulting in an average discharge potential of 2.5 V versus Li/Li + . These metrics combined yield a high energy density of 825 W h kg −1 which is a 55% improvement over commercial lithium cobalt oxide. The high performance of LiDHAQS makes it a promising material for next generation Li + cathodes.},
doi = {10.1002/aenm.201700960},
journal = {Advanced Energy Materials},
number = 5,
volume = 8,
place = {United States},
year = {Wed Oct 04 00:00:00 EDT 2017},
month = {Wed Oct 04 00:00:00 EDT 2017}
}
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