Silicon Composite Electrodes with Dynamic Ionic Bonding
Abstract
Silicon (Si) composite electrodes are developed with increased cycle lifetimes and reliability through dynamic ionic bonding between active Si nanoparticles and a polymer binder. Amine groups are covalently attached to Si nanoparticles via surface functionalization. Si composite electrodes are fabricated by combining the Si nanoparticles with a poly(acrylic acid) (PAA) binder. The formation of ionic bonds between amine groups on Si particles and carboxylic acid groups on the PAA binder is characterized by X‐ray photoelectron spectroscopy and Raman spectroscopy. Si composite anodes with ionic bonding demonstrate long term cycling stability with capacity retention of 80% at 400 cycles at a current density of 2.1 A g −1 and good rate capability. The dynamic ionic bonds effectively mitigate the deterioration of electrical interfaces in the composite anodes as suggested by stable impedance over 300 cycles.
- Authors:
-
- Univ. of Illinois at Urbana-Champaign, IL (United States). Beckman Inst. for Advanced Science and Technology; Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Materials Science and Engineering
- Univ. of Illinois at Urbana-Champaign, IL (United States). Beckman Inst. for Advanced Science and Technology; Univ. of Illinois at Urbana-Champaign, IL (United States). Dept. of Aerospace Engineering
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States). Energy Frontier Research Center (EFRC) Center for Electrical Energy Storage (CEES)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1469920
- Alternate Identifier(s):
- OSTI ID: 1378805
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 17; Related Information: CEES partners with Argonne National Laboratory (lead); University of Illinois, Urbana-Champaign; Northwest University; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; ionic bonding; Li‐ion batteries; restoration of electrical interfaces; Si composite anodes
Citation Formats
Kang, Sen, Yang, Ke, White, Scott R., and Sottos, Nancy R. Silicon Composite Electrodes with Dynamic Ionic Bonding. United States: N. p., 2017.
Web. doi:10.1002/aenm.201700045.
Kang, Sen, Yang, Ke, White, Scott R., & Sottos, Nancy R. Silicon Composite Electrodes with Dynamic Ionic Bonding. United States. https://doi.org/10.1002/aenm.201700045
Kang, Sen, Yang, Ke, White, Scott R., and Sottos, Nancy R. Fri .
"Silicon Composite Electrodes with Dynamic Ionic Bonding". United States. https://doi.org/10.1002/aenm.201700045. https://www.osti.gov/servlets/purl/1469920.
@article{osti_1469920,
title = {Silicon Composite Electrodes with Dynamic Ionic Bonding},
author = {Kang, Sen and Yang, Ke and White, Scott R. and Sottos, Nancy R.},
abstractNote = {Silicon (Si) composite electrodes are developed with increased cycle lifetimes and reliability through dynamic ionic bonding between active Si nanoparticles and a polymer binder. Amine groups are covalently attached to Si nanoparticles via surface functionalization. Si composite electrodes are fabricated by combining the Si nanoparticles with a poly(acrylic acid) (PAA) binder. The formation of ionic bonds between amine groups on Si particles and carboxylic acid groups on the PAA binder is characterized by X‐ray photoelectron spectroscopy and Raman spectroscopy. Si composite anodes with ionic bonding demonstrate long term cycling stability with capacity retention of 80% at 400 cycles at a current density of 2.1 A g −1 and good rate capability. The dynamic ionic bonds effectively mitigate the deterioration of electrical interfaces in the composite anodes as suggested by stable impedance over 300 cycles.},
doi = {10.1002/aenm.201700045},
journal = {Advanced Energy Materials},
number = 17,
volume = 7,
place = {United States},
year = {Fri May 12 00:00:00 EDT 2017},
month = {Fri May 12 00:00:00 EDT 2017}
}
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