Aqueous and Template-Free Synthesis of Meso-Macroporous Polymers for Highly Selective Capture and Conversion of Carbon Dioxide
Abstract
Abstract Meso–macroporous polymers possessing nitrogen functionality were innovatively synthesized through an aqueous and template‐free route herein. Specifically, the polymerization of 1‐(4‐vinylbenzyl)‐1,3,5,7‐tetraazaadamantan‐1‐ium chloride in aqueous solution under high temperatures induces the decomposition of the hexamethylenetetramine unit into ammonia and formaldehyde molecules, followed by the cross‐linking of benzene rings through “resol chemistry”. During this process, extended meso–macroporous frameworks were constructed, and active nitrogen species were incorporated. Taking the advantage of the meso–macroporosity and nitrogen functionality, the synthesized polymers offer competitive CO 2 capacities (0.37–1.58 mmol g −1 at 0 °C and 0.15 bar) and outstanding CO 2 /N 2 selectivities (155–324 at 0 °C). Furthermore, after complexed with metal ions, the synthesized polymers show excellent activity for catalyzing the cycloaddition of propylene oxide with CO 2 (yield>98.5 %, turnover frequency: 612.9–761.1 h −1 ).
- Authors:
-
[2];
- Nanchang Univ. (China)
- Fuzhou Univ. (China)
- Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Georgia Inst. of Technology, Atlanta, GA (United States). Energy Frontier Research Center (EFRC) Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1469891
- Alternate Identifier(s):
- OSTI ID: 1399273
- Grant/Contract Number:
- SC0012577
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemSusChem
- Additional Journal Information:
- Journal Volume: 10; Journal Issue: 21; Related Information: UNCAGE-ME partners with Georgia Institute of Technology (lead); Lehigh University; Oak Ridge National Laboratory; University of Alabama; University of Florida; University of Wisconsin; Washington University in St. Louis; Journal ID: ISSN 1864-5631
- Publisher:
- ChemPubSoc Europe
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 54 ENVIRONMENTAL SCIENCES; 36 MATERIALS SCIENCE; carbon dioxide capture; carbon dioxide conversion; meso-macropores; nitrogen functionality; porous organic polymers
Citation Formats
Huang, Kuan, Liu, Fujian, Jiang, Lilong, and Dai, Sheng. Aqueous and Template-Free Synthesis of Meso-Macroporous Polymers for Highly Selective Capture and Conversion of Carbon Dioxide. United States: N. p., 2017.
Web. doi:10.1002/cssc.201701666.
Huang, Kuan, Liu, Fujian, Jiang, Lilong, & Dai, Sheng. Aqueous and Template-Free Synthesis of Meso-Macroporous Polymers for Highly Selective Capture and Conversion of Carbon Dioxide. United States. https://doi.org/10.1002/cssc.201701666
Huang, Kuan, Liu, Fujian, Jiang, Lilong, and Dai, Sheng. Fri .
"Aqueous and Template-Free Synthesis of Meso-Macroporous Polymers for Highly Selective Capture and Conversion of Carbon Dioxide". United States. https://doi.org/10.1002/cssc.201701666. https://www.osti.gov/servlets/purl/1469891.
@article{osti_1469891,
title = {Aqueous and Template-Free Synthesis of Meso-Macroporous Polymers for Highly Selective Capture and Conversion of Carbon Dioxide},
author = {Huang, Kuan and Liu, Fujian and Jiang, Lilong and Dai, Sheng},
abstractNote = {Abstract Meso–macroporous polymers possessing nitrogen functionality were innovatively synthesized through an aqueous and template‐free route herein. Specifically, the polymerization of 1‐(4‐vinylbenzyl)‐1,3,5,7‐tetraazaadamantan‐1‐ium chloride in aqueous solution under high temperatures induces the decomposition of the hexamethylenetetramine unit into ammonia and formaldehyde molecules, followed by the cross‐linking of benzene rings through “resol chemistry”. During this process, extended meso–macroporous frameworks were constructed, and active nitrogen species were incorporated. Taking the advantage of the meso–macroporosity and nitrogen functionality, the synthesized polymers offer competitive CO 2 capacities (0.37–1.58 mmol g −1 at 0 °C and 0.15 bar) and outstanding CO 2 /N 2 selectivities (155–324 at 0 °C). Furthermore, after complexed with metal ions, the synthesized polymers show excellent activity for catalyzing the cycloaddition of propylene oxide with CO 2 (yield>98.5 %, turnover frequency: 612.9–761.1 h −1 ).},
doi = {10.1002/cssc.201701666},
journal = {ChemSusChem},
number = 21,
volume = 10,
place = {United States},
year = {Fri Sep 01 00:00:00 EDT 2017},
month = {Fri Sep 01 00:00:00 EDT 2017}
}
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