DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: The impact of radical loading and oxidation on the conformation of organic radical polymers by small angle neutron scattering

Abstract

SANS provides, for the first time, unique insight into the correlation between organic radical polymer molecular structure and their assembly.

Authors:
ORCiD logo [1];  [2]; ORCiD logo [2];  [3]; ORCiD logo [4]
  1. Univ. of Tennessee, Knoxville, TN (United States)
  2. National Renewable Energy Lab. (NREL), Golden, CO (United States)
  3. National Renewable Energy Lab. (NREL), Golden, CO (United States); Colorado School of Mines, Golden, CO (United States)
  4. Univ. of Tennessee, Knoxville, TN (United States); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Publication Date:
Research Org.:
National Renewable Energy Laboratory (NREL), Golden, CO (United States); Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1468737
Alternate Identifier(s):
OSTI ID: 1462136; OSTI ID: 1511945
Report Number(s):
NREL/JA-5900-71704
Journal ID: ISSN 2050-7488; JMCAET
Grant/Contract Number:  
AC36-08GO28308; AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 6; Journal Issue: 32; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; metal ions; organic polymers; oxidation; secondary batteries; transition metal compounds; transition metals

Citation Formats

Martin, Halie J., Hughes, Barbara K., Braunecker, Wade A., Gennett, Thomas, and Dadmun, Mark D. The impact of radical loading and oxidation on the conformation of organic radical polymers by small angle neutron scattering. United States: N. p., 2018. Web. doi:10.1039/C8TA04583F.
Martin, Halie J., Hughes, Barbara K., Braunecker, Wade A., Gennett, Thomas, & Dadmun, Mark D. The impact of radical loading and oxidation on the conformation of organic radical polymers by small angle neutron scattering. United States. https://doi.org/10.1039/C8TA04583F
Martin, Halie J., Hughes, Barbara K., Braunecker, Wade A., Gennett, Thomas, and Dadmun, Mark D. Mon . "The impact of radical loading and oxidation on the conformation of organic radical polymers by small angle neutron scattering". United States. https://doi.org/10.1039/C8TA04583F. https://www.osti.gov/servlets/purl/1468737.
@article{osti_1468737,
title = {The impact of radical loading and oxidation on the conformation of organic radical polymers by small angle neutron scattering},
author = {Martin, Halie J. and Hughes, Barbara K. and Braunecker, Wade A. and Gennett, Thomas and Dadmun, Mark D.},
abstractNote = {SANS provides, for the first time, unique insight into the correlation between organic radical polymer molecular structure and their assembly.},
doi = {10.1039/C8TA04583F},
journal = {Journal of Materials Chemistry. A},
number = 32,
volume = 6,
place = {United States},
year = {Mon Jul 16 00:00:00 EDT 2018},
month = {Mon Jul 16 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 12 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Charge transport in solid polymer matrixes with redox centers
journal, September 2001


Rechargeable batteries with organic radical cathodes
journal, June 2002


Simplified tube form factor for analysis of small-angle scattering data from carbon nanotube filled systems
journal, February 2007

  • Justice, Ryan S.; Wang, David H.; Tan, Loon-Seng
  • Journal of Applied Crystallography, Vol. 40, Issue s1
  • DOI: 10.1107/S0021889807004153

Challenges for Rechargeable Li Batteries
journal, February 2010

  • Goodenough, John B.; Kim, Youngsik
  • Chemistry of Materials, Vol. 22, Issue 3, p. 587-603
  • DOI: 10.1021/cm901452z

Mantid—Data analysis and visualization package for neutron scattering and μ SR experiments
journal, November 2014

  • Arnold, O.; Bilheux, J. C.; Borreguero, J. M.
  • Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 764
  • DOI: 10.1016/j.nima.2014.07.029

Powering up the Future: Radical Polymers for Battery Applications
journal, December 2012

  • Janoschka, Tobias; Hager, Martin D.; Schubert, Ulrich S.
  • Advanced Materials, Vol. 24, Issue 48
  • DOI: 10.1002/adma.201203119

Superior radical polymer cathode material with a two-electron process redox reaction promoted by graphene
journal, January 2012

  • Guo, Wei; Yin, Ya-Xia; Xin, Sen
  • Energy Environ. Sci., Vol. 5, Issue 1
  • DOI: 10.1039/C1EE02148F

Electrolyte anion-assisted charge transportation in poly(oxoammonium cation/nitroxyl radical) redox gels
journal, January 2012

  • Nakahara, Kentaro; Oyaizu, Kenichi; Nishide, Hiroyuki
  • Journal of Materials Chemistry, Vol. 22, Issue 27
  • DOI: 10.1039/c2jm31907a

Scattering Functions of Semiflexible Polymers with and without Excluded Volume Effects
journal, January 1996

  • Pedersen, Jan Skov; Schurtenberger, Peter
  • Macromolecules, Vol. 29, Issue 23
  • DOI: 10.1021/ma9607630

Close Packing of Nitroxide Radicals in Stable Organic Radical Polymeric Materials
journal, April 2015

  • Bobela, David C.; Hughes, Barbara K.; Braunecker, Wade A.
  • The Journal of Physical Chemistry Letters, Vol. 6, Issue 8
  • DOI: 10.1021/acs.jpclett.5b00259

Incorporating Intermicellar Interactions in the Fitting of SANS Data from Cationic Wormlike Micelles
journal, July 2006

  • Chen, Wei-Ren; Butler, Paul D.; Magid, Linda J.
  • Langmuir, Vol. 22, Issue 15
  • DOI: 10.1021/la0530440

Progress in electrical energy storage system: A critical review
journal, March 2009


Quenching of the Perylene Fluorophore by Stable Nitroxide Radical-Containing Macromolecules
journal, October 2014

  • Hughes, Barbara K.; Braunecker, Wade A.; Ferguson, Andrew J.
  • The Journal of Physical Chemistry B, Vol. 118, Issue 43
  • DOI: 10.1021/jp506240j

Synthesis of electrically conducting organic polymers: halogen derivatives of polyacetylene, (CH) x
journal, January 1977

  • Shirakawa, Hideki; Louis, Edwin J.; MacDiarmid, Alan G.
  • Journal of the Chemical Society, Chemical Communications, Issue 16
  • DOI: 10.1039/c39770000578

Organic radical battery with PTMA cathode: Effect of PTMA content on electrochemical properties
journal, May 2008

  • Kim, Jae-Kwang; Cheruvally, Gouri; Ahn, Jou-Hyeon
  • Journal of Industrial and Engineering Chemistry, Vol. 14, Issue 3
  • DOI: 10.1016/j.jiec.2007.12.002

Synthesis of Poly(4-methacryloyloxy-TEMPO) via Group-Transfer Polymerization and Its Evaluation in Organic Radical Battery
journal, May 2007

  • Bugnon, Lucienne; Morton, Colin J. H.; Novak, Petr
  • Chemistry of Materials, Vol. 19, Issue 11
  • DOI: 10.1021/cm063052h

Relationship between Molecular Structure and Electron Transfer in a Polymeric Nitroxyl-Radical Energy Storage Material
journal, July 2014

  • Kemper, Travis W.; Larsen, Ross E.; Gennett, Thomas
  • The Journal of Physical Chemistry C, Vol. 118, Issue 31
  • DOI: 10.1021/jp501628z

Small-Angle Neutron Scattering Analysis of Bottlebrush Polymers Prepared via Grafting-Through Polymerization
journal, August 2013

  • Pesek, Stacy L.; Li, Xianyu; Hammouda, Boualem
  • Macromolecules, Vol. 46, Issue 17
  • DOI: 10.1021/ma401246b

Organic Electrode Materials for Rechargeable Lithium Batteries
journal, May 2012

  • Liang, Yanliang; Tao, Zhanliang; Chen, Jun
  • Advanced Energy Materials, Vol. 2, Issue 7
  • DOI: 10.1002/aenm.201100795

Organic Radical Battery Approaching Practical Use
journal, March 2011

  • Nakahara, Kentaro; Oyaizu, Kenichi; Nishide, Hiroyuki
  • Chemistry Letters, Vol. 40, Issue 3
  • DOI: 10.1246/cl.2011.222

Polyacetylene and Polynorbornene Derivatives Carrying TEMPO. Synthesis and Properties as Organic Radical Battery Materials
journal, August 2006

  • Katsumata, Toru; Satoh, Masaharu; Wada, Jun
  • Macromolecular Rapid Communications, Vol. 27, Issue 15
  • DOI: 10.1002/marc.200600286

TEMPO-Based Catholyte for High-Energy Density Nonaqueous Redox Flow Batteries
journal, October 2014

  • Wei, Xiaoliang; Xu, Wu; Vijayakumar, Murugesan
  • Advanced Materials, Vol. 26, Issue 45
  • DOI: 10.1002/adma.201403746

Radical Polymers for Organic Electronic Devices: A Radical Departure from Conjugated Polymers?
journal, June 2009


Synthesis and Properties of DNA Complexes Containing 2,2,6,6-Tetramethyl-1-piperidinoxy (TEMPO) Moieties as Organic Radical Battery Materials
journal, April 2008

  • Qu, Jinqing; Morita, Ryuhei; Satoh, Masaharu
  • Chemistry - A European Journal, Vol. 14, Issue 11
  • DOI: 10.1002/chem.200800021

Effect of radical polymer cathode thickness on the electrochemical performance of organic radical battery
journal, November 2007


Works referencing / citing this record:

Redox polymers incorporating pendant 6‐oxoverdazyl and nitronyl nitroxide radicals
journal, January 2020

  • Anghel, Michael; Magnan, François; Catingan, Sara D.
  • Journal of Polymer Science, Vol. 58, Issue 2
  • DOI: 10.1002/pol.20190082