30 Years of Lithium-Ion Batteries

Li, Matthew; Lu, Jun; Chen, Zhongwei; Amine, Khalil

doi:10.1002/adma.201800561

Title: 30 Years of Lithium-Ion Batteries

Abstract

Over the past 30 years, significant commercial and academic progress has been made on Li-based battery technologies. From the early Li-metal anode iterations to the current commercial Li-ion batteries (LIBs), the story of the Li-based battery is full of breakthroughs and back tracing steps. This review will discuss the main roles of material science in the development of LIBs. As LIB research progressed and the materials of interest changed, different emphasis on the different sub-disciplines of material science were placed. Early works on LIBs focused more on solid state physics whereas near the end of the 20th century with nanotechnology on the rise, researchers began to focus more on the morphological aspects (surface coating, porosity, size and shape) of electrode materials. While it is easy to point out which specific cathode and anode materials are currently good candidates for the next-generation of batteries, it is difficult to explain exactly why those were chosen. We hope to clearly draw for the reader a complete developmental story of LIB along with an explanation of the reasons responsible for the various technological shifts. In conclusion, this review will end with a statement of caution for the current modern battery research along with amore »« less

Authors:

Li, Matthew ^[1]; Lu, Jun ^[2]; Chen, Zhongwei ^[3];

^[4]

Argonne National Lab. (ANL), Lemont, IL (United States); Univ. of Waterloo, Waterloo, ON (Canada)
Argonne National Lab. (ANL), Lemont, IL (United States)
Univ. of Waterloo, Waterloo, ON (Canada)
Argonne National Lab. (ANL), Lemont, IL (United States); Imam Abdulrahman Bin Faisal Univ., Dammam (Saudi Arabia); Stanford Univ., Stanford, CA (United States)

Publication Date:: Thu Jun 14 00:00:00 EDT 2018

Research Org.:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE

OSTI Identifier:: 1468617

Alternate Identifier(s):: OSTI ID: 1454332

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Advanced Materials

Additional Journal Information:: Journal Volume: 30; Journal Issue: 33; Journal ID: ISSN 0935-9648

Publisher:: Wiley

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; Anode; Cathode; Electrolyte; Li-ion Battery; Lithium metal

Citation Formats


                    Li, Matthew, Lu, Jun, Chen, Zhongwei, and Amine, Khalil. 30 Years of Lithium-Ion Batteries.  United States: N. p., 2018. 
Web.  doi:10.1002/adma.201800561.

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                    Li, Matthew, Lu, Jun, Chen, Zhongwei, & Amine, Khalil. 30 Years of Lithium-Ion Batteries.  United States.  https://doi.org/10.1002/adma.201800561

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                    Li, Matthew, Lu, Jun, Chen, Zhongwei, and Amine, Khalil. Thu .  
"30 Years of Lithium-Ion Batteries".  United States.  https://doi.org/10.1002/adma.201800561.  https://www.osti.gov/servlets/purl/1468617.

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@article{osti_1468617,

  title        = {30 Years of Lithium-Ion Batteries},

  author       = {Li, Matthew and Lu, Jun and Chen, Zhongwei and Amine, Khalil},

  abstractNote = {Over the past 30 years, significant commercial and academic progress has been made on Li-based battery technologies. From the early Li-metal anode iterations to the current commercial Li-ion batteries (LIBs), the story of the Li-based battery is full of breakthroughs and back tracing steps. This review will discuss the main roles of material science in the development of LIBs. As LIB research progressed and the materials of interest changed, different emphasis on the different sub-disciplines of material science were placed. Early works on LIBs focused more on solid state physics whereas near the end of the 20th century with nanotechnology on the rise, researchers began to focus more on the morphological aspects (surface coating, porosity, size and shape) of electrode materials. While it is easy to point out which specific cathode and anode materials are currently good candidates for the next-generation of batteries, it is difficult to explain exactly why those were chosen. We hope to clearly draw for the reader a complete developmental story of LIB along with an explanation of the reasons responsible for the various technological shifts. In conclusion, this review will end with a statement of caution for the current modern battery research along with a brief discussion on beyond lithium-ion battery chemistries.},

  doi          = {10.1002/adma.201800561},

  journal      = {Advanced Materials},

  number       = 33,

  volume       = 30,

  place        = {United States},

  year         = {Thu Jun 14 00:00:00 EDT 2018},

  month        = {Thu Jun 14 00:00:00 EDT 2018}

}

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High-Performance Lithium-Rich Layered Oxide Material: Effects of Preparation Methods on Microstructure and Electrochemical Properties
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journal, November 2019

Mohanta,
Nanomaterials, Vol. 9, Issue 11
DOI: 10.3390/nano9111581

A Facile, One-Step Synthesis of Silicon/Silicon Carbide/Carbon Nanotube Nanocomposite as a Cycling-Stable Anode for Lithium Ion Batteries
journal, November 2019

Zhang, Yi; Hu, Kai; Zhou, Yunlei
Nanomaterials, Vol. 9, Issue 11
DOI: 10.3390/nano9111624

Figures / Tables found in this record:

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Title: 30 Years of Lithium-Ion Batteries

Abstract

Citation Formats

Figures / Tables:

Mechanisms for Lithium Insertion in Carbonaceous Materials journal, October 1995

Lithium ion secondary batteries; past 10 years and the future journal, November 2001

Thermodynamic investigations of ternary lithium-transition metal-oxygen cathode materials journal, May 1980

Research Progress on Negative Electrodes for Practical Li-Ion Batteries: Beyond Carbonaceous Anodes journal, April 2015

The molicel® rechargeable lithium system: Multicell aspects journal, October 1987

Silicon-Based Anodes for Lithium-Ion Batteries: From Fundamentals to Practical Applications journal, January 2018

Heavy metal toxicities: levels of nickel, cobalt and chromium in the soil and plants associated with visual symptoms and variation in growth of an oat crop journal, January 1973

Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni0.2Li0.2Mn0.6]O2 journal, June 2006

The lithium intercalates of the transition metal dichalcogenides journal, May 1975

Topochemical reactions of rutile related structures with lithium journal, December 1978

A review of the electrochemical performance of alloy anodes for lithium-ion batteries journal, January 2011

High-performance lithium battery anodes using silicon nanowires journal, December 2007

Implementing an in-situ carbon network in Si/reduced graphene oxide for high performance lithium-ion battery anodes journal, January 2016

Design of electrolyte solutions for Li and Li-ion batteries: a review journal, November 2004

Separators for Lithium-Ion Batteries: A Review on the Production Processes and Recent Developments journal, April 2015

Suppressing the Phase Transition of the Layered Ni-Rich Oxide Cathode during High-Voltage Cycling by Introducing Low-Content Li 2 MnO 3 journal, January 2016

Olivine LiCoPO[sub 4] as 4.8 V Electrode Material for Lithium Batteries journal, January 1999

Some Observations on Rechargeable Lithium Electrodes in a Propylene Carbonate Electrolyte journal, January 1974

Effect of Carbon Coating on Electrochemical Performance of Treated Natural Graphite as Lithium-Ion Battery Anode Material journal, January 2000

High-Performance Germanium Nanowire-Based Lithium-Ion Battery Anodes Extending over 1000 Cycles Through in Situ Formation of a Continuous Porous Network journal, January 2014

Ethylene carbonate/ether mixed solvents electrolyte for lithium batteries journal, October 1984

Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries journal, October 2015

Synthesis and Characterization of LiAl[sub 1∕4]Ni[sub 3∕4]O[sub 2] (R3m) for Lithium-Ion (Shuttlecock) Batteries journal, January 1995

Role of surface coating on cathode materials for lithium-ion batteries journal, January 2010

Evolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li 1.2 Ni 0.2 Mn 0.6 O 2 Cathode Material for Lithium Ion Batteries journal, December 2014

Structural and Chemical Evolution of Li- and Mn-Rich Layered Cathode Material journal, February 2015

Electrical Energy Storage for the Grid: A Battery of Choices journal, November 2011

Stabilizing the Electrode/Electrolyte Interface of LiNi 0.8 Co 0.15 Al 0.05 O 2 through Tailoring Aluminum Distribution in Microspheres as Long-Life, High-Rate, and Safe Cathode for Lithium-Ion Batteries journal, August 2017

Electrochemical and Thermal Behavior of LiNi[sub 1−z]M[sub z]O[sub 2] (M = Co, Mn, Ti) journal, January 1997

Nanosilicon anodes for high performance rechargeable batteries journal, October 2017

A reversible graphite-lithium negative electrode for electrochemical generators journal, January 1983

High-Capacity Carbons Prepared from Phenolic Resin for Anodes of Lithium-Ion Batteries journal, January 1995

Effect of magnesium doping on properties of lithium-rich layered oxide cathodes based on a one-step co-precipitation strategy journal, January 2016

Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells journal, January 1990

Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries journal, March 2015

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries journal, September 2010

Thermal Stability of a Propylene Carbonate Electrolyte journal, January 1970

A Cyclable Lithium Organic Electrolyte Cell Based on Two Intercalation Electrodes journal, January 1980

Rapidly falling costs of battery packs for electric vehicles journal, March 2015

Hollow LiMn 2 O 4 Nanocones as Superior Cathode Materials for Lithium-Ion Batteries with Enhanced Power and Cycle Performances journal, February 2014

Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization journal, December 2016

Comparative Study of the Capacity and Rate Capability of LiNiyMnyCo1–2yO2 (y = 0.5, 0.45, 0.4, 0.33) journal, January 2011

The Development and Future of Lithium Ion Batteries journal, December 2016

Manganese oxides for lithium batteries journal, January 1997

Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes journal, January 1997

The Spinel Phases LiM[sub y]Mn[sub 2−y]O[sub 4] (M = Co, Cr, Ni) as the Cathode for Rechargeable Lithium Batteries journal, January 1996

Thermal stability of LixCoO2, LixNiO2 and λ-MnO2 and consequences for the safety of Li-ion cells journal, August 1994

Understanding electrochemical potentials of cathode materials in rechargeable batteries journal, March 2016

Alkali Metal-Nickel Oxides of the Type MNiO 2 journal, March 1954

The Electrochemical Decomposition of Propylene Carbonate on Graphite journal, January 1970

Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries journal, February 2006

History of lithium batteries journal, May 2011

Modified natural graphite as anode material for lithium ion batteries journal, September 2002

Potential of lithium-ion batteries in renewable energy journal, April 2015

Nanotechnology for environmentally sustainable electromobility journal, December 2016

Electrical Energy Storage and Intercalation Chemistry journal, June 1976

3D nitrogen-doped graphene foam with encapsulated germanium/nitrogen-doped graphene yolk-shell nanoarchitecture for high-performance flexible Li-ion battery journal, January 2017

Comparison of the chemical stability of the high energy density cathodes of lithium-ion batteries journal, November 2001

Ti-substituted Li[Li 0.26 Mn 0.6−x Ti x Ni 0.07 Co 0.07 ]O 2 layered cathode material with improved structural stability and suppressed voltage fading journal, January 2015

The path towards sustainable energy journal, December 2016

Calendar aging of a 250 kW/500 kWh Li-ion battery deployed for the grid storage application journal, December 2017

Effects of vinylene carbonate on high temperature storage of high voltage Li-ion batteries journal, November 2011

Sodium-Ion Batteries journal, May 2012

High-energy cathode material for long-life and safe lithium batteries journal, March 2009

Layered Li[Ni[sub x]Co[sub 1−2x]Mn[sub x]]O[sub 2] Cathode Materials for Lithium-Ion Batteries journal, January 2001

Preparation of a new crystal form of manganese dioxide: λ-MnO2 journal, September 1981

Preparation of LiCoPO4/C nanocomposite cathode of lithium batteries with high rate performance journal, July 2011

Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries journal, April 2017

Potential for widespread electrification of personal vehicle travel in the United States journal, August 2016

A review of Ni-based layered oxides for rechargeable Li-ion batteries journal, January 2017

Effects of different carbonate precipitators on LiNi1/3Co1/3Mn1/3O2 morphology and electrochemical performance journal, September 2009

Tin-Nanoparticles Encapsulated in Elastic Hollow Carbon Spheres for High-Performance Anode Material in Lithium-Ion Batteries journal, March 2008

Effects of Capacity Ratios between Anode and Cathode on Electrochemical Properties for Lithium Polymer Batteries journal, February 2015

Cathodic decomposition reactions of propylene carbonate journal, December 1976

Thermal stability of LixCoO2 cathode for lithium ion battery journal, June 2002

The cycling properties of the LixNi1−yCoyO2 electrode journal, April 1993

Mechanisms for Lithium Insertion in Carbonaceous Materials
journal, October 1995

Lithium ion secondary batteries; past 10 years and the future
journal, November 2001

Thermodynamic investigations of ternary lithium-transition metal-oxygen cathode materials
journal, May 1980

Research Progress on Negative Electrodes for Practical Li-Ion Batteries: Beyond Carbonaceous Anodes
journal, April 2015

The molicel® rechargeable lithium system: Multicell aspects
journal, October 1987

Silicon-Based Anodes for Lithium-Ion Batteries: From Fundamentals to Practical Applications
journal, January 2018

Heavy metal toxicities: levels of nickel, cobalt and chromium in the soil and plants associated with visual symptoms and variation in growth of an oat crop
journal, January 1973

Demonstrating Oxygen Loss and Associated Structural Reorganization in the Lithium Battery Cathode Li[Ni_0.2Li_0.2Mn_0.6]O₂
journal, June 2006

The lithium intercalates of the transition metal dichalcogenides
journal, May 1975

Topochemical reactions of rutile related structures with lithium
journal, December 1978

A review of the electrochemical performance of alloy anodes for lithium-ion batteries
journal, January 2011

High-performance lithium battery anodes using silicon nanowires
journal, December 2007

Implementing an in-situ carbon network in Si/reduced graphene oxide for high performance lithium-ion battery anodes
journal, January 2016

Design of electrolyte solutions for Li and Li-ion batteries: a review
journal, November 2004

Separators for Lithium-Ion Batteries: A Review on the Production Processes and Recent Developments
journal, April 2015

Suppressing the Phase Transition of the Layered Ni-Rich Oxide Cathode during High-Voltage Cycling by Introducing Low-Content Li ₂ MnO ₃
journal, January 2016

Olivine LiCoPO[sub 4] as 4.8 V Electrode Material for Lithium Batteries
journal, January 1999

Some Observations on Rechargeable Lithium Electrodes in a Propylene Carbonate Electrolyte
journal, January 1974

Effect of Carbon Coating on Electrochemical Performance of Treated Natural Graphite as Lithium-Ion Battery Anode Material
journal, January 2000

High-Performance Germanium Nanowire-Based Lithium-Ion Battery Anodes Extending over 1000 Cycles Through in Situ Formation of a Continuous Porous Network
journal, January 2014

Ethylene carbonate/ether mixed solvents electrolyte for lithium batteries
journal, October 1984

Evidence of covalent synergy in silicon–sulfur–graphene yielding highly efficient and long-life lithium-ion batteries
journal, October 2015

Synthesis and Characterization of LiAl[sub 1∕4]Ni[sub 3∕4]O[sub 2] (R3m) for Lithium-Ion (Shuttlecock) Batteries
journal, January 1995

Role of surface coating on cathode materials for lithium-ion batteries
journal, January 2010

Evolution of Lattice Structure and Chemical Composition of the Surface Reconstruction Layer in Li _1.2 Ni _0.2 Mn _0.6 O ₂ Cathode Material for Lithium Ion Batteries
journal, December 2014

Structural and Chemical Evolution of Li- and Mn-Rich Layered Cathode Material
journal, February 2015

Electrical Energy Storage for the Grid: A Battery of Choices
journal, November 2011

Stabilizing the Electrode/Electrolyte Interface of LiNi _0.8 Co _0.15 Al _0.05 O ₂ through Tailoring Aluminum Distribution in Microspheres as Long-Life, High-Rate, and Safe Cathode for Lithium-Ion Batteries
journal, August 2017

Electrochemical and Thermal Behavior of LiNi[sub 1−z]M[sub z]O[sub 2] (M = Co, Mn, Ti)
journal, January 1997

Nanosilicon anodes for high performance rechargeable batteries
journal, October 2017

A reversible graphite-lithium negative electrode for electrochemical generators
journal, January 1983

High-Capacity Carbons Prepared from Phenolic Resin for Anodes of Lithium-Ion Batteries
journal, January 1995

Effect of magnesium doping on properties of lithium-rich layered oxide cathodes based on a one-step co-precipitation strategy
journal, January 2016

Studies of Lithium Intercalation into Carbons Using Nonaqueous Electrochemical Cells
journal, January 1990

Nickel-Rich Layered Lithium Transition-Metal Oxide for High-Energy Lithium-Ion Batteries
journal, March 2015

A review of the features and analyses of the solid electrolyte interphase in Li-ion batteries
journal, September 2010

Thermal Stability of a Propylene Carbonate Electrolyte
journal, January 1970

A Cyclable Lithium Organic Electrolyte Cell Based on Two Intercalation Electrodes
journal, January 1980

Rapidly falling costs of battery packs for electric vehicles
journal, March 2015

Hollow LiMn ₂ O ₄ Nanocones as Superior Cathode Materials for Lithium-Ion Batteries with Enhanced Power and Cycle Performances
journal, February 2014

Li‐ and Mn‐Rich Cathode Materials: Challenges to Commercialization
journal, December 2016

Comparative Study of the Capacity and Rate Capability of LiNiyMnyCo1–2yO2 (y = 0.5, 0.45, 0.4, 0.33)
journal, January 2011

The Development and Future of Lithium Ion Batteries
journal, December 2016

Manganese oxides for lithium batteries
journal, January 1997

Advanced Model for Solid Electrolyte Interphase Electrodes in Liquid and Polymer Electrolytes
journal, January 1997

The Spinel Phases LiM[sub y]Mn[sub 2−y]O[sub 4] (M = Co, Cr, Ni) as the Cathode for Rechargeable Lithium Batteries
journal, January 1996

Thermal stability of LixCoO2, LixNiO2 and λ-MnO2 and consequences for the safety of Li-ion cells
journal, August 1994

Understanding electrochemical potentials of cathode materials in rechargeable batteries
journal, March 2016

Alkali Metal-Nickel Oxides of the Type MNiO ₂
journal, March 1954

The Electrochemical Decomposition of Propylene Carbonate on Graphite
journal, January 1970

Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
journal, February 2006

History of lithium batteries
journal, May 2011

Modified natural graphite as anode material for lithium ion batteries
journal, September 2002

Potential of lithium-ion batteries in renewable energy
journal, April 2015

Nanotechnology for environmentally sustainable electromobility
journal, December 2016

Electrical Energy Storage and Intercalation Chemistry
journal, June 1976

3D nitrogen-doped graphene foam with encapsulated germanium/nitrogen-doped graphene yolk-shell nanoarchitecture for high-performance flexible Li-ion battery
journal, January 2017

Comparison of the chemical stability of the high energy density cathodes of lithium-ion batteries
journal, November 2001

Ti-substituted Li[Li _0.26 Mn _0.6−x Ti _x Ni _0.07 Co _0.07 ]O ₂ layered cathode material with improved structural stability and suppressed voltage fading
journal, January 2015

The path towards sustainable energy
journal, December 2016

Calendar aging of a 250 kW/500 kWh Li-ion battery deployed for the grid storage application
journal, December 2017

Effects of vinylene carbonate on high temperature storage of high voltage Li-ion batteries
journal, November 2011

Sodium-Ion Batteries
journal, May 2012

High-energy cathode material for long-life and safe lithium batteries
journal, March 2009

Layered Li[Ni[sub x]Co[sub 1−2x]Mn[sub x]]O[sub 2] Cathode Materials for Lithium-Ion Batteries
journal, January 2001

Preparation of a new crystal form of manganese dioxide: λ-MnO₂
journal, September 1981

Preparation of LiCoPO4/C nanocomposite cathode of lithium batteries with high rate performance
journal, July 2011

Dynamic behaviour of interphases and its implication on high-energy-density cathode materials in lithium-ion batteries
journal, April 2017

Potential for widespread electrification of personal vehicle travel in the United States
journal, August 2016

A review of Ni-based layered oxides for rechargeable Li-ion batteries
journal, January 2017

Effects of different carbonate precipitators on LiNi1/3Co1/3Mn1/3O2 morphology and electrochemical performance
journal, September 2009

Tin-Nanoparticles Encapsulated in Elastic Hollow Carbon Spheres for High-Performance Anode Material in Lithium-Ion Batteries
journal, March 2008

Effects of Capacity Ratios between Anode and Cathode on Electrochemical Properties for Lithium Polymer Batteries
journal, February 2015

Cathodic decomposition reactions of propylene carbonate
journal, December 1976

Thermal stability of LixCoO2 cathode for lithium ion battery
journal, June 2002

The cycling properties of the LixNi1−yCoyO2 electrode
journal, April 1993

Structural Changes and Thermal Stability of Charged LiNi _x Mn _y Co _z O ₂ Cathode Materials Studied by Combined In Situ Time-Resolved XRD and Mass Spectroscopy
journal, December 2014

Effects of aluminum on the structural and electrochemical properties of LiNiO2
journal, April 2003

Challenges for Rechargeable Li Batteries
journal, February 2010

The state of the art of electric and hybrid vehicles
journal, January 2002