Ambient-Pressure XPS Studies of Reactions of Alcohols on SrTiO3(100)

Zhang, Yafen; Savara, Aditya Ashi; Mullins, David R.

doi:10.1021/acs.jpcc.7b06319

Title: Ambient-Pressure XPS Studies of Reactions of Alcohols on SrTiO₃(100)

Abstract

Ambient-pressure X-ray photoelectron spectroscopy (APXPS) and temperature-programmed desorption (TPD) have been employed to elucidate the adsorption and reaction of simple alcohols on SrTiO₃(100). TPD experiments indicate molecular desorption of alcohols with a small amount of aldehydes below 100 °C, whereas no gas-phase products are observed above this temperature. APXPS spectra at 0.1 Torr show that alcohols adsorb dissociatively onto SrTiO₃(100) to form alkoxies. Surface methoxides appear to react with each other to produce acetate as a surface intermediate. These surface species are eventually oxidized to gas-phase CO, CO₂, and H₂O. Ethoxide is readily oxidized to acetate species that undergo further reactions to form gas-phase products. CO₂ is the only C-containing product during ethanol oxidation, whereas methanol can also produce the partial oxidation product, CO. When no O₂ is present, alcohol oxidation yields gas-phase CO, CO₂, or H₂O and creates oxygen vacancies on the surface, resulting in the reduction of Ti⁴⁺. Without a source of oxygen replenishment, the availability of surface oxygen would be limited, and thus, the oxidation reactions could not progress indefinitely. At near-ambient pressures, the reactivity of the surface and the distribution of surface species and reaction products were changed by altering the alcohol/O₂ ratio, consistent with anmore »« less

Authors:

^[1];

^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Tue Oct 03 00:00:00 EDT 2017

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1468274

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Physical Chemistry. C

Additional Journal Information:: Journal Volume: 121; Journal Issue: 42; Journal ID: ISSN 1932-7447

Publisher:: American Chemical Society

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Zhang, Yafen, Savara, Aditya Ashi, and Mullins, David R. Ambient-Pressure XPS Studies of Reactions of Alcohols on SrTiO3(100).  United States: N. p., 2017. 
Web.  doi:10.1021/acs.jpcc.7b06319.

Copy to clipboard


                    Zhang, Yafen, Savara, Aditya Ashi, & Mullins, David R. Ambient-Pressure XPS Studies of Reactions of Alcohols on SrTiO3(100).  United States.  https://doi.org/10.1021/acs.jpcc.7b06319

Copy to clipboard


                    Zhang, Yafen, Savara, Aditya Ashi, and Mullins, David R. Tue .  
"Ambient-Pressure XPS Studies of Reactions of Alcohols on SrTiO3(100)".  United States.  https://doi.org/10.1021/acs.jpcc.7b06319.  https://www.osti.gov/servlets/purl/1468274.

Copy to clipboard


                    
@article{osti_1468274,

  title        = {Ambient-Pressure XPS Studies of Reactions of Alcohols on SrTiO3(100)},

  author       = {Zhang, Yafen and Savara, Aditya Ashi and Mullins, David R.},

  abstractNote = {Ambient-pressure X-ray photoelectron spectroscopy (APXPS) and temperature-programmed desorption (TPD) have been employed to elucidate the adsorption and reaction of simple alcohols on SrTiO3(100). TPD experiments indicate molecular desorption of alcohols with a small amount of aldehydes below 100 °C, whereas no gas-phase products are observed above this temperature. APXPS spectra at 0.1 Torr show that alcohols adsorb dissociatively onto SrTiO3(100) to form alkoxies. Surface methoxides appear to react with each other to produce acetate as a surface intermediate. These surface species are eventually oxidized to gas-phase CO, CO2, and H2O. Ethoxide is readily oxidized to acetate species that undergo further reactions to form gas-phase products. CO2 is the only C-containing product during ethanol oxidation, whereas methanol can also produce the partial oxidation product, CO. When no O2 is present, alcohol oxidation yields gas-phase CO, CO2, or H2O and creates oxygen vacancies on the surface, resulting in the reduction of Ti4+. Without a source of oxygen replenishment, the availability of surface oxygen would be limited, and thus, the oxidation reactions could not progress indefinitely. At near-ambient pressures, the reactivity of the surface and the distribution of surface species and reaction products were changed by altering the alcohol/O2 ratio, consistent with an interpretation that surface vacancies are being created and that their concentration is altered when an oxygen source is present. In conclusion, the conversion from acetate to CO2 might be rate-limiting when sufficient O2 gas is present.},

  doi          = {10.1021/acs.jpcc.7b06319},

  journal      = {Journal of Physical Chemistry. C},

  number       = 42,

  volume       = 121,

  place        = {United States},

  year         = {Tue Oct 03 00:00:00 EDT 2017},

  month        = {Tue Oct 03 00:00:00 EDT 2017}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1021/acs.jpcc.7b06319

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 21 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

A Bifunctional Perovskite Catalyst for Oxygen Reduction and Evolution
journal, March 2014

Jung, Jae-Il; Jeong, Hu Young; Lee, Jang-Soo
Angewandte Chemie International Edition, Vol. 53, Issue 18
DOI: 10.1002/anie.201311223

High Performance Au–Pd Supported on 3D Hybrid Strontium-Substituted Lanthanum Manganite Perovskite Catalyst for Methane Combustion
journal, September 2016

Wang, Yuan; Arandiyan, Hamidreza; Scott, Jason
ACS Catalysis, Vol. 6, Issue 10
DOI: 10.1021/acscatal.6b01685

Hydrophobicity of rare-earth oxide ceramics
journal, January 2013

Azimi, Gisele; Dhiman, Rajeev; Kwon, Hyuk-Min
Nature Materials, Vol. 12, Issue 4, p. 315-320
DOI: 10.1038/nmat3545

Compositional engineering of perovskite materials for high-performance solar cells
journal, January 2015

Jeon, Nam Joong; Noh, Jun Hong; Yang, Woon Seok
Nature, Vol. 517, Issue 7535
DOI: 10.1038/nature14133

High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015

Yang, W. S.; Noh, J. H.; Jeon, N. J.
Science, Vol. 348, Issue 6240
DOI: 10.1126/science.aaa9272

Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO _x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation
journal, July 2015

Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru
The Journal of Physical Chemistry C, Vol. 119, Issue 32
DOI: 10.1021/acs.jpcc.5b04310

Adsorption and Reaction of Methanol on Stoichiometric and Defective SrTiO ₃ (100) Surfaces
journal, March 2005

Wang, Li-Qiong; Ferris, Kim F.; Azad, Samina
The Journal of Physical Chemistry B, Vol. 109, Issue 10
DOI: 10.1021/jp048338t

Organic Reactions at Well-Defined Oxide Surfaces
journal, January 1996

Barteau, Mark A.
Chemical Reviews, Vol. 96, Issue 4
DOI: 10.1021/cr950222t

Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide
journal, July 2013

Mullins, David R.; Albrecht, Peter M.; Calaza, Florencia
Topics in Catalysis, Vol. 56, Issue 15-17
DOI: 10.1007/s11244-013-0146-7

The surface chemistry of cerium oxide
journal, March 2015

Mullins, David R.
Surface Science Reports, Vol. 70, Issue 1
DOI: 10.1016/j.surfrep.2014.12.001

Recent Advances of Lanthanum-Based Perovskite Oxides for Catalysis
journal, September 2015

Zhu, Huiyuan; Zhang, Pengfei; Dai, Sheng
ACS Catalysis, Vol. 5, Issue 11
DOI: 10.1021/acscatal.5b01667

Preferential isotopic labeling of lattice oxygen positions on the SnO2(110) surface
journal, March 1990

Cox, David F.; Fryberger, Teresa B.
Surface Science, Vol. 227, Issue 1-2
DOI: 10.1016/0039-6028(90)90380-Q

Oxygen vacancies and defect electronic states on the ${SnO}_{2}$ (110)- 1×1 surface
journal, July 1988

Cox, David F.; Fryberger, Teresa B.; Semancik, Steve
Physical Review B, Vol. 38, Issue 3
DOI: 10.1103/PhysRevB.38.2072

Methanol: A “Smart” Chemical Probe Molecule
journal, September 2001

Badlani, Mohit; Wachs, Israel E.
Catalysis Letters, Vol. 75, Issue 3/4, p. 137-149
DOI: 10.1023/A:1016715520904

Perovskite Oxides: Preparation, Characterizations, and Applications in Heterogeneous Catalysis
journal, August 2014

Zhu, Junjiang; Li, Hailong; Zhong, Linyun
ACS Catalysis, Vol. 4, Issue 9
DOI: 10.1021/cs500606g

Perovskites as Substitutes of Noble Metals for Heterogeneous Catalysis: Dream or Reality
journal, September 2014

Royer, Sébastien; Duprez, Daniel; Can, Fabien
Chemical Reviews, Vol. 114, Issue 20
DOI: 10.1021/cr500032a

Chemical Structures and Performance of Perovskite Oxides
journal, July 2001

Pena, M.; Fierro, J.
Chemical Reviews, Vol. 101, Issue 7, p. 1981-2018
DOI: 10.1021/cr980129f

Synergistic Oxygen Evolving Activity of a TiO ₂ -Rich Reconstructed SrTiO ₃ (001) Surface
journal, February 2015

Martirez, John Mark P.; Kim, Seungchul; Morales, Erie H.
Journal of the American Chemical Society, Vol. 137, Issue 8
DOI: 10.1021/ja511332y

Adsorption and decomposition of methanol on TiO2, SrTiO3 and SrO
journal, January 1994

Aas, Nina; Pringle, Thomas J.; Bowker, Michael
Journal of the Chemical Society, Faraday Transactions, Vol. 90, Issue 7
DOI: 10.1039/ft9949001015

UPS and XPS studies of the chemisorption of O2, H2 AND H2O on reduced and stoichiometric SrTiO3(111) surfaces; The effects of illumination
journal, April 1980

Ferrer, Salvador; Somorjai, G. A.
Surface Science, Vol. 94, Issue 1
DOI: 10.1016/0039-6028(80)90155-7

Different binding sites for methanol dehydrogenation and deoxygenation on stoichiometric and defective TiO2(110) surfaces
journal, October 2003

Farfan-Arribas, Enrique; Madix, Robert J.
Surface Science, Vol. 544, Issue 2-3
DOI: 10.1016/j.susc.2003.08.025

The chemistry of methanol on the TiO2(110) surface: the influence of vacancies and coadsorbed species
journal, January 1999

Henderson, Michael A.; Otero-Tapia, Sary; Castro, Miguel E.
Faraday Discussions, Vol. 114
DOI: 10.1039/a902070e

A laser drilled aperture for use in an ultrahigh vacuum gas doser
journal, November 1989

Hagans, Patrick L.; DeKoven, Benjamin M.; Womack, Joseph L.
Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 7, Issue 6
DOI: 10.1116/1.576346

Oxidation and Reduction under Cover: Chemistry at the Confined Space between Ultrathin Nanoporous Silicates and Ru(0001)
journal, April 2016

Zhong, Jian-Qiang; Kestell, John; Waluyo, Iradwikanari
The Journal of Physical Chemistry C, Vol. 120, Issue 15
DOI: 10.1021/acs.jpcc.6b02851

Structure change of TiO2-terminated SrTiO3(001) surfaces by annealing in O2 atmosphere and ultrahigh vacuum
journal, February 1999

Nishimura, T.; Ikeda, A.; Namba, H.
Surface Science, Vol. 421, Issue 3
DOI: 10.1016/S0039-6028(98)00840-1

Surface phase, morphology, and charge distribution transitions on vacuum and ambient annealed $SrTi O_{3}$ (100)
journal, May 2016

Dagdeviren, Omur E.; Simon, Georg H.; Zou, Ke
Physical Review B, Vol. 93, Issue 19
DOI: 10.1103/PhysRevB.93.195303

Reactions of methanol on W(100) and W(100)-(5 $times; 1)C surfaces
journal, April 1980

Ko, E.
Journal of Catalysis, Vol. 62, Issue 2
DOI: 10.1016/0021-9517(80)90454-6

Adsorption and Reaction of Acetone over CeO _x (111) Thin Films
journal, March 2009

Senanayake, S. D.; Gordon, W. O.; Overbury, S. H.
The Journal of Physical Chemistry C, Vol. 113, Issue 15
DOI: 10.1021/jp810403d

Adsorption and reaction of formaldehyde on thin-film cerium oxide
journal, April 2006

Zhou, J.; Mullins, D. R.
Surface Science, Vol. 600, Issue 7
DOI: 10.1016/j.susc.2006.02.009

Adsorption and Reaction of Acetaldehyde over CeO _X (111) Thin Films
journal, February 2011

Chen, T. -L.; Mullins, D. R.
The Journal of Physical Chemistry C, Vol. 115, Issue 8
DOI: 10.1021/jp110429s

Adsorption and reaction of methanol on thin-film cerium oxide
journal, April 2006

Mullins, D. R.; Robbins, M. D.; Zhou, J.
Surface Science, Vol. 600, Issue 7
DOI: 10.1016/j.susc.2006.02.011

Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO ₂ (111) catalysts: an in situ study of C–C and O–H bond scission
journal, January 2016

Liu, Zongyuan; Duchoň, Tomáš; Wang, Huanru
Physical Chemistry Chemical Physics, Vol. 18, Issue 25
DOI: 10.1039/C6CP01212D

Adsorption and interaction of methanol with zinc oxide: Single crystal faces and zinc oxide-copper catalyst surfaces studied by photoelectron spectroscopY (XPS and UPS)
journal, October 1989

Au, C. T.; Hirsch, W.; Hirschwald, W.
Surface Science, Vol. 221, Issue 1-2
DOI: 10.1016/0039-6028(89)90570-0

Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(1 1 1)
journal, September 2015

Calaza, Florencia C.; Chen, Tsung-Liang; Mullins, David R.
Catalysis Today, Vol. 253
DOI: 10.1016/j.cattod.2015.03.033

Acetaldehyde Adsorption and Reaction on CeO ₂ (100) Thin Films
journal, July 2013

Mullins, D. R.; Albrecht, P. M.
The Journal of Physical Chemistry C, Vol. 117, Issue 28
DOI: 10.1021/jp404752m

Adsorption and Reaction of Methanol over CeO _X (100) Thin Films
journal, March 2013

Albrecht, Peter M.; Mullins, David R.
Langmuir, Vol. 29, Issue 14
DOI: 10.1021/la400295f

Water Dissociation on CeO ₂ (100) and CeO ₂ (111) Thin Films
journal, August 2012

Mullins, David R.; Albrecht, Peter M.; Chen, Tsung-Liang
The Journal of Physical Chemistry C, Vol. 116, Issue 36
DOI: 10.1021/jp306444h

Adsorption and Reaction of C ₁ −C ₃ Alcohols over CeO _X (111) Thin Films
journal, July 2010

Mullins, D. R.; Senanayake, S. D.; Chen, T. -L.
The Journal of Physical Chemistry C, Vol. 114, Issue 40
DOI: 10.1021/jp103905e

Works referencing / citing this record:

Surface chemistry of 2-propanol and O ₂ mixtures on SnO ₂ (110) studied with ambient-pressure x-ray photoelectron spectroscopy
journal, February 2020

Diulus, J. Trey; Elzein, Radwan; Addou, Rafik
The Journal of Chemical Physics, Vol. 152, Issue 5
DOI: 10.1063/1.5138923

Water adsorption, dissociation and oxidation on SrTiO ₃ and ferroelectric surfaces revealed by ambient pressure X-ray photoelectron spectroscopy
journal, January 2019

Domingo, Neus; Pach, Elzbieta; Cordero-Edwards, Kumara
Physical Chemistry Chemical Physics, Vol. 21, Issue 9
DOI: 10.1039/c8cp07632d

Similar Records in DOE PAGES and OSTI.GOV collections:

Adsorption and Reaction of NO on Oxidized and Reduced SrTiO{sub 3} (100) Surfaces

Journal Article Azad, Samina ; Szanyi, Janos ; Peden, Charles HF ; ... - Journal of Vacuum Science and Technology, A: Vacuum, Surfaces and Films

Adsorption and reaction of NO on oxidized and reduced SrTiO{sub 3}(100) surfaces have been studied using temperature programmed desorption (TPD). Major desorption peaks for NO from the fully oxidized surface as found at 140 and 260 K, along with a long tail that continues up to 500 K. The desorption features at 140 and 260 K correspond to activation energies of 36 and 66 kJ/mol, respectively, using a simple Redhead analysis. NO reacts non-dissociatively on the fully oxidized surface. Reactivity of reduced SrTiO{sub 3}(100) is relatively higher than that of the fully oxidized surface and is influenced by the adsorptionmore »« less
https://doi.org/10.1116/1.1560718
Identification of adsorbed species during steady-state photocatalytic oxidation of ethanol on TiO{sub 2}

Journal Article Muggli, D S ; Lowery, K H ; Falconer, J L - Journal of Catalysis

The identification and concentrations of species on a TiO{sub 2} surface during photocatalytic oxidation (PCO) of ethanol were determined by combining transient and steady-state PCO with temperature-programmed desorption (TPD) and oxidation (TPO). Ethanol and its partial oxidation intermediates (acetaldehyde, acetic acid, formaldehyde, and formic acid) are on the catalyst surface, and their concentrations depend on the ethanol, O{sub 2}, and water feed concentrations. The rate of PCO was greater initially than at steady state for all experimental conditions, and this initial deactivation may be due in part to the accumulation of acetaldehyde on the surface. Weakly bound ethanol preferentially formsmore »« less
https://doi.org/10.1006/jcat.1998.2276
Correlating the Reverse Water–Gas Shift Reaction with Surface Chemistry: The Influence of Reactant Gas Exposure to Ni(100)

Journal Article Lee, Kyung-Jae ; Ye, Yifan ; Su, Hongyang ; ... - ACS Catalysis

Using ambient pressure X-ray photoelectron spectroscopy (APXPS) and mass spectrometry (MS) while varying the temperature, we were able to directly understand how the sequence of exposing reactant gases, CO₂ and H₂, influenced the surface species and reverse water–gas shift reaction product formation on Ni(100). When first dosing CO₂ at room temperature (RT), the Ni(100) surface shows a significant amount of surface oxide due to CO₂ spontaneously dissociating into CO and O and this is nearly unchanged upon introducing H₂. However, when H₂ is dosed first to the nickel surface and CO₂ is subsequently introduced, the spontaneous dissociation of CO₂ stillmore »« less
https://doi.org/10.1021/acscatal.3c01517
Adsorption and Reaction of CO and CO{sub 2} on Oxidized and Reduced SrTiO{sub 3} (100) Surfaces

Journal Article Azad, Samina ; Engelhard, Mark H ; Wang, Li Q - Journal of Physical Chemistry B

The adsorption and reaction of CO and CO{sub 2} on oxidized and reduced SrTiO{sub 3}(100) surfaces have been studied using temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy (XPS). XPS results indicate that the fully oxidized and vacuum annealed SrTiO{sub 3}(100) surfaces are nearly defect-free with predominantly Ti{sup 4+} ions whereas the sputter-reduced surfaces contain substantial amounts of defects ({approx} 40% reduced Ti sites). Both CO and CO{sub 2} are found to adsorb weakly on the oxidized SrTiO{sub 3}(100) surfaces. The desorption activation energies of CO and CO{sub 2} from the oxidized SrTiO{sub 3}(100) surfaces are 38 and 32 kJmol{supmore »« less
https://doi.org/10.1021/jp045864b
In Situ Studies of Surface Mobility on Noble Metal Model Catalysts Using STM and XPS at Ambient Pressure

Thesis/Dissertation Butcher, Derek Robert

High Pressure Scanning Tunneling Microscopy (HP-STM) and Ambient Pressure X-ray Photoelectron Spectroscopy were used to study the structural properties and catalytic behavior of noble metal surfaces at high pressure. HP-STM was used to study the structural rearrangement of the top most atomic surface layer of the metal surfaces in response to changes in gas pressure and reactive conditions. AP-XPS was applied to single crystal and nanoparticle systems to monitor changes in the chemical composition of the surface layer in response to changing gas conditions. STM studies on the Pt(100) crystal face showed the lifting of the Pt(100)-hex surface reconstruction inmore »« less
https://doi.org/10.2172/984961

Full Text Available

Similar Records

Title: Ambient-Pressure XPS Studies of Reactions of Alcohols on SrTiO3(100)

Abstract

Citation Formats

A Bifunctional Perovskite Catalyst for Oxygen Reduction and Evolution journal, March 2014

High Performance Au–Pd Supported on 3D Hybrid Strontium-Substituted Lanthanum Manganite Perovskite Catalyst for Methane Combustion journal, September 2016

Hydrophobicity of rare-earth oxide ceramics journal, January 2013

Compositional engineering of perovskite materials for high-performance solar cells journal, January 2015

High-performance photovoltaic perovskite layers fabricated through intramolecular exchange journal, May 2015

Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation journal, July 2015

Adsorption and Reaction of Methanol on Stoichiometric and Defective SrTiO 3 (100) Surfaces journal, March 2005

Organic Reactions at Well-Defined Oxide Surfaces journal, January 1996

Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide journal, July 2013

The surface chemistry of cerium oxide journal, March 2015

Recent Advances of Lanthanum-Based Perovskite Oxides for Catalysis journal, September 2015

Preferential isotopic labeling of lattice oxygen positions on the SnO2(110) surface journal, March 1990

Oxygen vacancies and defect electronic states on the SnO 2 (110)- 1×1 surface journal, July 1988

Methanol: A “Smart” Chemical Probe Molecule journal, September 2001

Perovskite Oxides: Preparation, Characterizations, and Applications in Heterogeneous Catalysis journal, August 2014

Perovskites as Substitutes of Noble Metals for Heterogeneous Catalysis: Dream or Reality journal, September 2014

Chemical Structures and Performance of Perovskite Oxides journal, July 2001

Synergistic Oxygen Evolving Activity of a TiO 2 -Rich Reconstructed SrTiO 3 (001) Surface journal, February 2015

Adsorption and decomposition of methanol on TiO2, SrTiO3 and SrO journal, January 1994

UPS and XPS studies of the chemisorption of O2, H2 AND H2O on reduced and stoichiometric SrTiO3(111) surfaces; The effects of illumination journal, April 1980

Different binding sites for methanol dehydrogenation and deoxygenation on stoichiometric and defective TiO2(110) surfaces journal, October 2003

The chemistry of methanol on the TiO2(110) surface: the influence of vacancies and coadsorbed species journal, January 1999

A laser drilled aperture for use in an ultrahigh vacuum gas doser journal, November 1989

Oxidation and Reduction under Cover: Chemistry at the Confined Space between Ultrathin Nanoporous Silicates and Ru(0001) journal, April 2016

Structure change of TiO2-terminated SrTiO3(001) surfaces by annealing in O2 atmosphere and ultrahigh vacuum journal, February 1999

Surface phase, morphology, and charge distribution transitions on vacuum and ambient annealed SrTi O 3 (100) journal, May 2016

Reactions of methanol on W(100) and W(100)-(5 $times; 1)C surfaces journal, April 1980

Adsorption and Reaction of Acetone over CeO x (111) Thin Films journal, March 2009

Adsorption and reaction of formaldehyde on thin-film cerium oxide journal, April 2006

Adsorption and Reaction of Acetaldehyde over CeO X (111) Thin Films journal, February 2011

Adsorption and reaction of methanol on thin-film cerium oxide journal, April 2006

Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO 2 (111) catalysts: an in situ study of C–C and O–H bond scission journal, January 2016

Adsorption and interaction of methanol with zinc oxide: Single crystal faces and zinc oxide-copper catalyst surfaces studied by photoelectron spectroscopY (XPS and UPS) journal, October 1989

Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(1 1 1) journal, September 2015

Acetaldehyde Adsorption and Reaction on CeO 2 (100) Thin Films journal, July 2013

Adsorption and Reaction of Methanol over CeO X (100) Thin Films journal, March 2013

Water Dissociation on CeO 2 (100) and CeO 2 (111) Thin Films journal, August 2012

Adsorption and Reaction of C 1 −C 3 Alcohols over CeO X (111) Thin Films journal, July 2010

Surface chemistry of 2-propanol and O 2 mixtures on SnO 2 (110) studied with ambient-pressure x-ray photoelectron spectroscopy journal, February 2020

Water adsorption, dissociation and oxidation on SrTiO 3 and ferroelectric surfaces revealed by ambient pressure X-ray photoelectron spectroscopy journal, January 2019

Title: Ambient-Pressure XPS Studies of Reactions of Alcohols on SrTiO₃(100)

A Bifunctional Perovskite Catalyst for Oxygen Reduction and Evolution
journal, March 2014

High Performance Au–Pd Supported on 3D Hybrid Strontium-Substituted Lanthanum Manganite Perovskite Catalyst for Methane Combustion
journal, September 2016

Hydrophobicity of rare-earth oxide ceramics
journal, January 2013

Compositional engineering of perovskite materials for high-performance solar cells
journal, January 2015

High-performance photovoltaic perovskite layers fabricated through intramolecular exchange
journal, May 2015

Mechanistic Insights of Ethanol Steam Reforming over Ni–CeO _x (111): The Importance of Hydroxyl Groups for Suppressing Coke Formation
journal, July 2015

Adsorption and Reaction of Methanol on Stoichiometric and Defective SrTiO ₃ (100) Surfaces
journal, March 2005

Organic Reactions at Well-Defined Oxide Surfaces
journal, January 1996

Variations in Reactivity on Different Crystallographic Orientations of Cerium Oxide
journal, July 2013

The surface chemistry of cerium oxide
journal, March 2015

Recent Advances of Lanthanum-Based Perovskite Oxides for Catalysis
journal, September 2015

Preferential isotopic labeling of lattice oxygen positions on the SnO2(110) surface
journal, March 1990

Oxygen vacancies and defect electronic states on the ${SnO}_{2}$ (110)- 1×1 surface
journal, July 1988

Methanol: A “Smart” Chemical Probe Molecule
journal, September 2001

Perovskite Oxides: Preparation, Characterizations, and Applications in Heterogeneous Catalysis
journal, August 2014

Perovskites as Substitutes of Noble Metals for Heterogeneous Catalysis: Dream or Reality
journal, September 2014

Chemical Structures and Performance of Perovskite Oxides
journal, July 2001

Synergistic Oxygen Evolving Activity of a TiO ₂ -Rich Reconstructed SrTiO ₃ (001) Surface
journal, February 2015

Adsorption and decomposition of methanol on TiO2, SrTiO3 and SrO
journal, January 1994

UPS and XPS studies of the chemisorption of O2, H2 AND H2O on reduced and stoichiometric SrTiO3(111) surfaces; The effects of illumination
journal, April 1980

Different binding sites for methanol dehydrogenation and deoxygenation on stoichiometric and defective TiO2(110) surfaces
journal, October 2003

The chemistry of methanol on the TiO2(110) surface: the influence of vacancies and coadsorbed species
journal, January 1999

A laser drilled aperture for use in an ultrahigh vacuum gas doser
journal, November 1989

Oxidation and Reduction under Cover: Chemistry at the Confined Space between Ultrathin Nanoporous Silicates and Ru(0001)
journal, April 2016

Structure change of TiO2-terminated SrTiO3(001) surfaces by annealing in O2 atmosphere and ultrahigh vacuum
journal, February 1999

Surface phase, morphology, and charge distribution transitions on vacuum and ambient annealed $SrTi O_{3}$ (100)
journal, May 2016

Reactions of methanol on W(100) and W(100)-(5 $times; 1)C surfaces
journal, April 1980

Adsorption and Reaction of Acetone over CeO _x (111) Thin Films
journal, March 2009

Adsorption and reaction of formaldehyde on thin-film cerium oxide
journal, April 2006

Adsorption and Reaction of Acetaldehyde over CeO _X (111) Thin Films
journal, February 2011

Adsorption and reaction of methanol on thin-film cerium oxide
journal, April 2006

Ambient pressure XPS and IRRAS investigation of ethanol steam reforming on Ni–CeO ₂ (111) catalysts: an in situ study of C–C and O–H bond scission
journal, January 2016

Adsorption and interaction of methanol with zinc oxide: Single crystal faces and zinc oxide-copper catalyst surfaces studied by photoelectron spectroscopY (XPS and UPS)
journal, October 1989

Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(1 1 1)
journal, September 2015

Acetaldehyde Adsorption and Reaction on CeO ₂ (100) Thin Films
journal, July 2013

Adsorption and Reaction of Methanol over CeO _X (100) Thin Films
journal, March 2013

Water Dissociation on CeO ₂ (100) and CeO ₂ (111) Thin Films
journal, August 2012

Adsorption and Reaction of C ₁ −C ₃ Alcohols over CeO _X (111) Thin Films
journal, July 2010

Surface chemistry of 2-propanol and O ₂ mixtures on SnO ₂ (110) studied with ambient-pressure x-ray photoelectron spectroscopy
journal, February 2020

Water adsorption, dissociation and oxidation on SrTiO ₃ and ferroelectric surfaces revealed by ambient pressure X-ray photoelectron spectroscopy
journal, January 2019