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Title: The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice

Abstract

Results of magnetization and neutron diffraction measurements of the manganese vanadate system Mn5(VO4)2(OH)4 are reported. The crystal structure of this compound contains triangular [Mn3O13] building blocks that produce two-dimensional Mn2+ magnetic networks with striped triangular topologies. The Mn sheets are connected through the nonmagnetic vanadate tetrahedra extending along the a-axis. Magnetization measurements performed on single crystals reveal the onset of a long-range antiferromagnetic order below approximately 45 K. The magnetic structure is Néel-type with nearest-neighbor Mn atoms coupled via three or four antiferromagnetic bonds. The magnetic moments are confined within the layers and are oriented parallel to the b direction. In conclusion, the magnitudes of ordered moments are reduced, presumably by geometrical frustration and the low-dimensionality of the lattice structure.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3]; ORCiD logo [1]; ORCiD logo [1];  [4]
+ Show Author Affiliations
  1. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Neutron Scattering Division
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division; Clemson Univ., SC (United States). Dept. of Chemistry and Center for Optical Materials Science and Engineering Technologies (COMSET)
  4. Clemson Univ., SC (United States). Dept. of Chemistry and Center for Optical Materials Science and Engineering Technologies (COMSET)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1468015
Alternate Identifier(s):
OSTI ID: 1467766
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
AIP Advances
Additional Journal Information:
Journal Volume: 8; Journal Issue: 10; Journal ID: ISSN 2158-3226
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE

Citation Formats

Garlea, Vasile O., McGuire, Michael A., Sanjeewa, Liurukara D., Pajerowski, Daniel M., Ye, Feng, and Kolis, Joseph W. The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice. United States: N. p., 2018. Web. doi:10.1063/1.5043124.
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Garlea, Vasile O., McGuire, Michael A., Sanjeewa, Liurukara D., Pajerowski, Daniel M., Ye, Feng, & Kolis, Joseph W. The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice. United States. https://doi.org/10.1063/1.5043124
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Garlea, Vasile O., McGuire, Michael A., Sanjeewa, Liurukara D., Pajerowski, Daniel M., Ye, Feng, and Kolis, Joseph W. Thu . "The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice". United States. https://doi.org/10.1063/1.5043124. https://www.osti.gov/servlets/purl/1468015.
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@article{osti_1468015,
title = {The magnetic order of a manganese vanadate system with two-dimensional striped triangular lattice},
author = {Garlea, Vasile O. and McGuire, Michael A. and Sanjeewa, Liurukara D. and Pajerowski, Daniel M. and Ye, Feng and Kolis, Joseph W.},
abstractNote = {Results of magnetization and neutron diffraction measurements of the manganese vanadate system Mn5(VO4)2(OH)4 are reported. The crystal structure of this compound contains triangular [Mn3O13] building blocks that produce two-dimensional Mn2+ magnetic networks with striped triangular topologies. The Mn sheets are connected through the nonmagnetic vanadate tetrahedra extending along the a-axis. Magnetization measurements performed on single crystals reveal the onset of a long-range antiferromagnetic order below approximately 45 K. The magnetic structure is Néel-type with nearest-neighbor Mn atoms coupled via three or four antiferromagnetic bonds. The magnetic moments are confined within the layers and are oriented parallel to the b direction. In conclusion, the magnitudes of ordered moments are reduced, presumably by geometrical frustration and the low-dimensionality of the lattice structure.},
doi = {10.1063/1.5043124},
journal = {AIP Advances},
number = 10,
volume = 8,
place = {United States},
year = {Thu Aug 30 00:00:00 EDT 2018},
month = {Thu Aug 30 00:00:00 EDT 2018}
}
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Journal Article:
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Publisher's Version of Record
https://doi.org/10.1063/1.5043124
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Works referenced in this record:

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Unusual ordered phases of highly frustrated magnets: a review
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    Works referencing / citing this record:

    Single crystal neutron and magnetic measurements of Rb 2 Mn 3 (VO 4 ) 2 CO 3 and K 2 Co 3 (VO 4 ) 2 CO 3 with mixed honeycomb and triangular magnetic lattices
    journal, January 2020

    • Smith Pellizzeri, Tiffany M.; Sanjeewa, Liurukara D.; Pellizzeri, Steven
    • Dalton Transactions, Vol. 49, Issue 14
    • DOI: 10.1039/c9dt03389k
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