A cobalt(II) spin-crossover compound with partially charged TCNQ radicals and an anomalous conducting behavior
Abstract
The bifunctional salt [Co(terpy)2](TCNQ)3·CH3CN (terpy = 2,2';6',2"-terpyridine, TCNQ = 7,7,8,8-tetracyanoquino-dimethane) exhibits a high room temperature conductivity of 0.13 S cm-1 and an anomaly in conductivity at ~190 K as evidenced by variable temperature structural, magnetic and conductivity studies. The anomaly in the conductivity at 190 K has been correlated with the temperature dependent structural breathing and Jahn–Teller distortion of the low spin state of the SCO units, as well as the charge fluctuations and supramolecular π-stacking interactions of partially charged TCNQ radicals. Finally, the modular synthetic approach leads to an accessible source of partially charged TCNQ radicals for the facile preparation of bifunctional molecular materials with high electrical conductivity.
- Authors:
-
[1];
[1];
[1]
- Texas A&M Univ., College Station, TX (United States). Dept. of Chemistry
- Shanghai Univ., Shanghai (China). Dept. of Chemistry, Innovative Drug Research Center
- Publication Date:
- Research Org.:
- Texas A&M Univ., College Station, TX (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1467560
- Grant/Contract Number:
- SC0012582
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Chemical Science
- Additional Journal Information:
- Journal Volume: 7; Journal Issue: 2; Journal ID: ISSN 2041-6520
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Zhang, Xuan, Wang, Zhao-Xi, Xie, Haomiao, Li, Ming-Xing, Woods, Toby J., and Dunbar, Kim R. A cobalt(II) spin-crossover compound with partially charged TCNQ radicals and an anomalous conducting behavior. United States: N. p., 2015.
Web. doi:10.1039/c5sc03547c.
Zhang, Xuan, Wang, Zhao-Xi, Xie, Haomiao, Li, Ming-Xing, Woods, Toby J., & Dunbar, Kim R. A cobalt(II) spin-crossover compound with partially charged TCNQ radicals and an anomalous conducting behavior. United States. https://doi.org/10.1039/c5sc03547c
Zhang, Xuan, Wang, Zhao-Xi, Xie, Haomiao, Li, Ming-Xing, Woods, Toby J., and Dunbar, Kim R. Tue .
"A cobalt(II) spin-crossover compound with partially charged TCNQ radicals and an anomalous conducting behavior". United States. https://doi.org/10.1039/c5sc03547c. https://www.osti.gov/servlets/purl/1467560.
@article{osti_1467560,
title = {A cobalt(II) spin-crossover compound with partially charged TCNQ radicals and an anomalous conducting behavior},
author = {Zhang, Xuan and Wang, Zhao-Xi and Xie, Haomiao and Li, Ming-Xing and Woods, Toby J. and Dunbar, Kim R.},
abstractNote = {The bifunctional salt [Co(terpy)2](TCNQ)3·CH3CN (terpy = 2,2';6',2"-terpyridine, TCNQ = 7,7,8,8-tetracyanoquino-dimethane) exhibits a high room temperature conductivity of 0.13 S cm-1 and an anomaly in conductivity at ~190 K as evidenced by variable temperature structural, magnetic and conductivity studies. The anomaly in the conductivity at 190 K has been correlated with the temperature dependent structural breathing and Jahn–Teller distortion of the low spin state of the SCO units, as well as the charge fluctuations and supramolecular π-stacking interactions of partially charged TCNQ radicals. Finally, the modular synthetic approach leads to an accessible source of partially charged TCNQ radicals for the facile preparation of bifunctional molecular materials with high electrical conductivity.},
doi = {10.1039/c5sc03547c},
journal = {Chemical Science},
number = 2,
volume = 7,
place = {United States},
year = {Tue Dec 08 00:00:00 EST 2015},
month = {Tue Dec 08 00:00:00 EST 2015}
}
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Works referenced in this record:
Spin Crossover, Reversible Redox, and Supramolecular Interactions in 3d Complexes of 4-(4-Pyridyl)-2,5-dipyrazyl-pyridine
journal, May 2015
- Miller, Reece G.; Brooker, Sally
- Inorganic Chemistry, Vol. 54, Issue 11
Hybrid organic–inorganic materials: a land of multidisciplinarity
journal, January 1996
- Judeinstein, Patrick; Sanchez, Clément
- J. Mater. Chem., Vol. 6, Issue 4
Design and synthesis of organic metals
journal, July 1974
- Garito, Anthony F.; Heeger, Alan J.
- Accounts of Chemical Research, Vol. 7, Issue 7
Highly Conducting Coordination Polymers Based on Infinite M(4,4′-bpy) Chains Flanked by Regular Stacks of Non-Integer TCNQ Radicals
journal, August 2011
- Ballesteros-Rivas, Maria; Ota, Akira; Reinheimer, Eric
- Angewandte Chemie International Edition, Vol. 50, Issue 41
Synergistic electrical bistability in a conductive spin crossover heterostructure
journal, January 2015
- Chen, Yan-Cong; Meng, Yan; Ni, Zhao-Ping
- Journal of Materials Chemistry C, Vol. 3, Issue 5
Multifunctional molecular materials
journal, June 2003
- Coronado, E.; Forment-Aliaga, A.; Galán-Mascarós, J. R.
- Solid State Sciences, Vol. 5, Issue 6
Electrical properties and phase transitions of trimethylammonium-iodine-tetracyanoquinodimethane (TMA-I-TCNQ)
journal, October 1983
- Ikari, T.; Jandl, S.; Aubin, M.
- Physical Review B, Vol. 28, Issue 7
Modified Chesnut Model for Spin-Crossover Semiconductors [Fe(acpa) 2 ](TCNQ) n
journal, January 2002
- Nakano, Motohiro; Fujita, Naoki; Matsubayashi, Gen-Etsu
- Molecular Crystals and Liquid Crystals, Vol. 379, Issue 1
Electrical conductive coordination polymers
journal, January 2012
- Givaja, Gonzalo; Amo-Ochoa, Pilar; Gómez-García, Carlos J.
- Chem. Soc. Rev., Vol. 41, Issue 1
Complex TCNQ salts with asymmetric donors. I. Transport properties
journal, December 1978
- Holczer, K.; Mihaly, G.; Janossy, A.
- Journal of Physics C: Solid State Physics, Vol. 11, Issue 23
Organic/Inorganic Hybrid Materials: Challenges for ab Initio Methodology
journal, August 2014
- Draxl, Claudia; Nabok, Dmitrii; Hannewald, Karsten
- Accounts of Chemical Research, Vol. 47, Issue 11
An unusual discontinuity in the thermal spin transition in [Co(terpy)2][BF4]2
journal, January 2010
- Kilner, Colin A.; Halcrow, Malcolm A.
- Dalton Transactions, Vol. 39, Issue 38
Structural and Physical Properties of a Series of 7,7,8,8-Tetracyanoquinodimethane Salts with Dications Bearing Two Terminal Pyridinium Rings
journal, September 2014
- Kubota, Hiroyuki; Takahashi, Yukihiro; Harada, Jun
- Crystal Growth & Design, Vol. 14, Issue 11
Photomagnetic Response in Highly Conductive Iron(II) Spin-Crossover Complexes with TCNQ Radicals
journal, November 2014
- Phan, Hoa; Benjamin, Shermane M.; Steven, Eden
- Angewandte Chemie International Edition, Vol. 54, Issue 3
Measurement of Seebeck and Hall effects in compactions of TCNQ salts
journal, January 1971
- Blythe, A. R.; Boon, M. R.; Wright, P. G.
- Discussions of the Faraday Society, Vol. 51
Spin-crossover behavior and electrical conduction property in iron( ii ) complexes with tetrathiafulvalene moieties
journal, January 2011
- Nihei, Masayuki; Takahashi, Nobukazu; Nishikawa, Hiroyuki
- Dalton Trans., Vol. 40, Issue 10
Synthesis and Properties of Cobalt(III) Complexes of 4-Substituted Pyridine-Capped Dioxocyclams
journal, December 2005
- Reiff, Angela L.; Garcia-Frutos, Eva M.; Gil, Jun Mo
- Inorganic Chemistry, Vol. 44, Issue 25
Organic-Inorganic Hybrid Materials as Semiconducting Channels in Thin-Film Field-Effect Transistors
journal, October 1999
- Kagan, C. R.; Mitzi, D. B.; Dimitrakopoulos, C. D.
- Science, Vol. 286, Issue 5441, p. 945-947
Spin Crossover Probes Confer Multistability to Organic Conducting Polymers
journal, September 2014
- Koo, Yong-Sung; Galán-Mascarós, José Ramón
- Advanced Materials, Vol. 26, Issue 39
High-spin-low-spin equilibriums of cobalt(2+) in the terpyridine complexes Co(terpy)2X2.nH2O
journal, August 1982
- Kremer, S.; Henke, W.; Reinen, D.
- Inorganic Chemistry, Vol. 21, Issue 8
Single-Chain Magnetic Behavior in a Hetero-Tri-Spin Complex Mediated by Supramolecular Interactions with TCNQF .− Radicals
journal, September 2014
- Wang, Zhao-Xi; Zhang, Xuan; Zhang, Yuan-Zhu
- Angewandte Chemie International Edition, Vol. 53, Issue 43
A cadmium TCNQ-based semiconductor with versatile binding modes and non-integer redox states
journal, January 2014
- Zhang, Xuan; Zhang, Zhongyue; Zhao, Hanhua
- Chem. Commun., Vol. 50, Issue 12
Iron(II) complexes of 2,6-di(pyrazol-1-yl)pyridines—A versatile system for spin-crossover research
journal, November 2009
- Halcrow, Malcolm A.
- Coordination Chemistry Reviews, Vol. 253, Issue 21-22
Long-range magnetic order in a purely organic 2D layer adsorbed on epitaxial graphene
journal, April 2013
- Garnica, Manuela; Stradi, Daniele; Barja, Sara
- Nature Physics, Vol. 9, Issue 6
Structure of the red, semiconducting form of 4,4',5,5'-tetramethyl-Δ 2,2' -bi-1,3-diselenole-7,7,8,8-tetracyano- p -quinodimethane, TMTSF–TCNQ
journal, April 1982
- Kistenmacher, T. J.; Emge, T. J.; Bloch, A. N.
- Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, Vol. 38, Issue 4
Vanadium 7,7,8,8-Tetracyano- p -quinodimethane (V[TCNQ] 2 )-Based Magnets
journal, October 2004
- Vickers, Elaine B.; Selby, Trent D.; Thorum, Matthew S.
- Inorganic Chemistry, Vol. 43, Issue 20
Characterization of the charge-transfer reaction between decamethylferrocene and 7,7,8,8,-tetracyano-p-quinodimethane (1:1). The iron-57 Moessbauer spectra and structures of the paramagnetic dimeric and the metamagnetic one-dimensional salts and the molecular and electronic structures of (TCNQ)n(n = 0, -1, -2)
journal, July 1987
- Miller, Joel S.; Zhang, Jian H.; Reiff, William M.
- The Journal of Physical Chemistry, Vol. 91, Issue 16
A one-dimensional coordination polymer exhibiting simultaneous spin-crossover and semiconductor behaviour
journal, January 2011
- Xue, Wei; Wang, Bao-Ying; Zhu, Jie
- Chemical Communications, Vol. 47, Issue 37
Superconducting fluctuations and the peierls instability in an organic solid
journal, June 1973
- Coleman, L. B.; Cohen, M. J.; Sandman, D. J.
- Solid State Communications, Vol. 12, Issue 11
Single-chain magnets: beyond the Glauber model
journal, January 2013
- Zhang, Wei-Xiong; Ishikawa, Ryuta; Breedlove, Brian
- RSC Advances, Vol. 3, Issue 12
[Fe(sal2-trien)][Ni(dmit)2]: towards switchable spin crossover molecular conductors
journal, January 2005
- Dorbes, St�phane; Valade, Lydie; Real, Jos� A.
- Chemical Communications, Issue 1
Electrical Conductivity and Spin Crossover: A New Achievement with a Metal Bis Dithiolene Complex
journal, October 2007
- Faulmann, Christophe; Jacob, Kane; Dorbes, Stéphane
- Inorganic Chemistry, Vol. 46, Issue 21
Coexistence of ferromagnetism and metallic conductivity in a molecule-based layered compound
journal, November 2000
- Coronado, Eugenio; Galán-Mascarós, José R.; Gómez-García, Carlos J.
- Nature, Vol. 408, Issue 6811
Electrical Conductivity Modulation Coupled to a High-Spin−Low-Spin Conversion in the Molecular System [Fe III (qsal) 2 ][Ni(dmit) 2 ] 3 ·CH 3 CN·H 2 O
journal, July 2006
- Takahashi, Kazuyuki; Cui, Heng-Bo; Okano, Yoshinori
- Inorganic Chemistry, Vol. 45, Issue 15
Single-Molecule Magnets
journal, November 2000
- Christou, George; Gatteschi, Dante; Hendrickson, David N.
- MRS Bulletin, Vol. 25, Issue 11
Glassy Magnets Composed of Metals Coordinated to 7,7,8,8-tetracyanoquinodimethane: M(TCNQ) 2 (M = Mn, Fe, Co, Ni) †
journal, May 2003
- Clérac, Rodolphe; O'Kane, Shannon; Cowen, Jerry
- Chemistry of Materials, Vol. 15, Issue 9
Spin state switching in iron coordination compounds
journal, January 2013
- Gütlich, Philipp; Gaspar, Ana B.; Garcia, Yann
- Beilstein Journal of Organic Chemistry, Vol. 9
Carrier Concentration Dependent Conduction in Insulator-Doped Donor/Acceptor Chain Compounds
journal, November 2013
- Nishio, Masaki; Hoshino, Norihisa; Kosaka, Wataru
- Journal of the American Chemical Society, Vol. 135, Issue 47
Spin Crossover - Quo Vadis?
journal, February 2013
- Gütlich, Philipp
- European Journal of Inorganic Chemistry, Vol. 2013, Issue 5-6
Structural distortions of the spin-crossover material [Co(pyterpy) 2 ](TCNQ) 2 mediated by supramolecular interactions
journal, January 2015
- Zhang, Xuan; Xie, Haomiao; Ballesteros-Rivas, Maria
- Journal of Materials Chemistry C, Vol. 3, Issue 36
A weak antiferromagnetic interaction between manganese(2+) centers through a TCNQ column: crystal structures and magnetic properties of [MnII(tpa)(TCNQ)(CH3OH)](TCNQ)2.cntdot.CH3CN, [MnII(tpa)(.mu.-O2CCH3)]2(TCNQ)2.cntdot.2CH3CN, and [MnII(tpa)(NCS)2].cntdot.CH3CN (tpa = tris(2-pyridylmethyl)amine)
journal, December 1993
- Oshio, Hiroki; Ino, Etsuo; Mogi, Iwao
- Inorganic Chemistry, Vol. 32, Issue 25
Spontaneous Multielectron Transfer from the Surfaces of PbS Quantum Dots to Tetracyanoquinodimethane
journal, May 2013
- Knowles, Kathryn E.; Malicki, Michał; Parameswaran, Radha
- Journal of the American Chemical Society, Vol. 135, Issue 19
The first coordination compound containing three different types of spin carriers: 2p–3d–4f (TCNQ˙–, Cu2+ and Gd3+)
journal, June 2002
- Madalan, Augustin M.; Roesky, Herbert W.; Andruh, Marius
- Chemical Communications, Issue 15
Organic Conductors with Unusual Band Fillings
journal, November 2004
- Mori, Takehiko
- Chemical Reviews, Vol. 104, Issue 11
Substituted Quinodimethans. II. Anion-radical Derivatives and Complexes of 7,7,8,8-Tetracyanoquinodimethan
journal, September 1962
- Melby, L. R.; Harder, R. J.; Hertler, W. R.
- Journal of the American Chemical Society, Vol. 84, Issue 17
Molecular/Organic Ferromagnets
journal, April 1988
- Miller, J. S.; Epstein, A. J.; Reiff, W. M.
- Science, Vol. 240, Issue 4848
Hybrid CuTCNQ/AgTCNQ Metal-Organic Charge Transfer Complexes via Galvanic Replacement vs Corrosion-Recrystallization
journal, October 2014
- Pearson, Andrew; Ramanathan, Rajesh; O'Mullane, Anthony P.
- Advanced Functional Materials, Vol. 24, Issue 48
A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior
journal, January 2014
- Zhang, Zhongyue; Zhao, Hanhua; Matsushita, Michio M.
- J. Mater. Chem. C, Vol. 2, Issue 2
Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices
journal, December 2013
- Talin, A. Alec; Centrone, Andrea; Ford, Alexandra C.
- Science, Vol. 343, Issue 6166, p. 66-69
Magnetic ordering in TCNQ-based metal–organic frameworks with host–guest interactions
journal, January 2015
- Zhang, Xuan; Saber, Mohamed R.; Prosvirin, Andrey P.
- Inorganic Chemistry Frontiers, Vol. 2, Issue 10
Cooperative phenomena and light-induced bistability in iron(II) spin-crossover compounds
journal, September 1999
- Hauser, Andreas; Jeftić, Jelena; Romstedt, Harald
- Coordination Chemistry Reviews, Vol. 190-192
Evidence of the Chemical Uniaxial Strain Effect on Electrical Conductivity in the Spin-Crossover Conducting Molecular System: [Fe III (qnal) 2 ][Pd(dmit) 2 ] 5 ·Acetone
journal, May 2008
- Takahashi, Kazuyuki; Cui, Heng-Bo; Okano, Yoshinori
- Journal of the American Chemical Society, Vol. 130, Issue 21
Inorganic/Organic Hybrid Materials
journal, October 1998
- Sharp, Kenneth G.
- Advanced Materials, Vol. 10, Issue 15
Magnetically ordered molecule-based materials
journal, January 2011
- Miller, Joel S.
- Chemical Society Reviews, Vol. 40, Issue 6
The foundation of modern spin-crossover
journal, January 2013
- Halcrow, Malcolm A.
- Chemical Communications, Vol. 49, Issue 93
Spin-crossover in cobalt(II) compounds containing terpyridine and its derivatives
journal, September 2011
- Hayami, Shinya; Komatsu, Yasuka; Shimizu, Tetsuya
- Coordination Chemistry Reviews, Vol. 255, Issue 17-18
Soft porous crystal meets TCNQ: charge transfer-type porous coordination polymers
journal, January 2011
- Shimomura, Satoru; Kitagawa, Susumu
- Journal of Materials Chemistry, Vol. 21, Issue 15
Tetracyanoquinodimethanido Derivatives of (Terpyridine)- and (Phenanthroline)metal Complexes − Structural and Magnetic Studies of Radical-Ion Salts: (Terpyridine)- and (Phenanthroline)metal Complexes
journal, December 2004
- Alonso, Cristina; Ballester, Loreto; Gutiérrez, Angel
- European Journal of Inorganic Chemistry, Vol. 2005, Issue 3
Electrochemical and photochemical routes to semiconducting transition metal-tetracyanoquinodimethane coordination polymers
journal, June 2014
- Nafady, Ayman; O’Mullane, Anthony P.; Bond, Alan M.
- Coordination Chemistry Reviews, Vol. 268
Highly Conducting Coordination Polymers Based on Infinite M(4,4′-bpy) Chains Flanked by Regular Stacks of Non-Integer TCNQ Radicals
journal, August 2011
- Ballesteros-Rivas, Maria; Ota, Akira; Reinheimer, Eric
- Angewandte Chemie, Vol. 123, Issue 41
Organic Conductors with Unusual Band Fillings
journal, February 2005
- Mori, Takehiko
- ChemInform, Vol. 36, Issue 6
Magnetically Ordered Molecule-Based Materials
journal, July 2007
- Miller, Joel S.
- MRS Bulletin, Vol. 32, Issue 7
Photomagnetic Response in Highly Conductive Iron(II) Spin-Crossover Complexes with TCNQ Radicals
journal, November 2014
- Phan, Hoa; Benjamin, Shermane M.; Steven, Eden
- Angewandte Chemie, Vol. 127, Issue 3
Single-Molecule Magnets
journal, May 2000
- Ruiz-molina, Daniel; Christou, George; Hendrickson, David N.
- Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, Vol. 343, Issue 1
Superconducting fluctuations and the Peierls instability in an organic solid
journal, December 1993
- Coleman, L. B.; Cohen, M. J.; Sandman, D. J.
- Solid State Communications, Vol. 88, Issue 11-12
Works referencing / citing this record:
Conducting Molecular Nanomagnet of Dy III with Partially Charged TCNQ Radicals
journal, May 2017
- Zhang, Xuan; Xie, Haomiao; Ballesteros-Rivas, Maria
- Chemistry - A European Journal, Vol. 23, Issue 31
Pancake Bonding in π-Stacked Trimers in a Salt of Tetrachloroquinone Anion
journal, May 2018
- Molčanov, Krešimir; Mou, Zhongyu; Kertesz, Miklos
- Chemistry - A European Journal, Vol. 24, Issue 33
Pancake Bonding: An Unusual Pi-Stacking Interaction
journal, November 2018
- Kertesz, Miklos
- Chemistry - A European Journal, Vol. 25, Issue 2
Sliding Polymeric Layers and Anion Displacement Coupled with Spin Crossover in Two-Dimensional Networks of [Fe(hbtz) 2 (CH 3 CN) 2 ](BF 4 ) 2
journal, January 2019
- Książek, Maria; Weselski, Marek; Ilczyszyn, Maria
- Chemistry - A European Journal, Vol. 25, Issue 9
Towards Dual-Functionality Spin-Crossover Complexes
journal, January 2018
- Feltham, Humphrey L. C.; Dankhoff, Katja; Meledandri, Carla J.
- ChemPlusChem, Vol. 83, Issue 7
Use of the TCNQF 4 2− Dianion in the Spontaneous Redox Formation of [Fe III (L − ) 2 ][TCNQF 4 ⋅− ]
journal, March 2018
- Gass, Ian A.; Lu, Jinzhen; Asadi, Mousa
- ChemPlusChem, Vol. 83, Issue 7
Slow Magnetic Relaxation and Spin-Crossover Behavior in a Bicomponent Ion-Pair Cobalt(II) Complex: Slow Magnetic Relaxation and Spin-Crossover Behavior in a Bicomponent Ion-Pair Cobalt(II) Complex
journal, September 2017
- Shao, Dong; Deng, Lin-Dan; Shi, Le
- European Journal of Inorganic Chemistry, Vol. 2017, Issue 33
Reversible Redox, Spin Crossover, and Superexchange Coupling in 3 d Transition-Metal Complexes of Bis -azinyl Analogues of 2,2′:6′,2′′-Terpyridine : Reversible Redox, Spin Crossover, and Superexchange Coupling in 3
journal, March 2018
- Zhang, Yixin; Harriman, Katie L. M.; Brunet, Gabriel
- European Journal of Inorganic Chemistry, Vol. 2018, Issue 10
Structural diversity and magnetic properties of six cobalt coordination polymers based on 2,2′-phosphinico-dibenzoate ligand
journal, January 2016
- Wang, Zhao-Xi; Wu, Lin-Fei; Zhang, Xuan
- Dalton Transactions, Vol. 45, Issue 48
Evidence for a hopping mechanism in metal|single molecule|metal junctions involving conjugated metal–terpyridyl complexes; potential-dependent conductances of complexes [M(pyterpy) 2 ] 2+ (M = Co and Fe; pyterpy = 4′-(pyridin-4-yl)-2,2′:6′,2′′-terpyridine) in ionic liquid
journal, January 2016
- Chappell, Sarah; Brooke, Carly; Nichols, Richard J.
- Faraday Discussions, Vol. 193
Solvent-tuned charge-transfer properties of chiral Pt( ii ) complex and TCNQ˙ − anion adducts
journal, January 2018
- Zhang, Xiao-Peng; Wang, Li-Li; Zhang, Da-Shuai
- RSC Advances, Vol. 8, Issue 20
Reversible on–off switching of both spin crossover and single-molecule magnet behaviours via a crystal-to-crystal transformation
journal, January 2018
- Shao, Dong; Shi, Le; Yin, Lei
- Chemical Science, Vol. 9, Issue 41
Bistable molecular materials with dynamic structures
journal, January 2020
- Yao, Zi-Shuo; Tang, Zheng; Tao, Jun
- Chemical Communications, Vol. 56, Issue 14
Synthesis, structure and magnetic properties of copper( ii ) azide
journal, January 2019
- Shi, Taqing; Xu, Ye; Zou, Ya-Jing
- Dalton Transactions, Vol. 48, Issue 30
Ligand mixed-valence and electrical conductivity in coordination complexes containing a redox-active phenalenol-substituted ligand
journal, January 2019
- Dale, Sarah; Bonanno, Nico M.; Pelaccia, Mark
- Dalton Transactions, Vol. 48, Issue 23
From spin-crossover to single molecule magnetism: tuning magnetic properties of Co( ii ) bis-ferrocenylterpy cations via supramolecular interactions with organocyanide radical anions
journal, January 2020
- Xie, Haomiao; Vignesh, Kuduva R.; Zhang, Xuan
- Journal of Materials Chemistry C
Towards understanding π-stacking interactions between non-aromatic rings
journal, February 2019
- Molčanov, Krešimir; Kojić-Prodić, Biserka
- IUCrJ, Vol. 6, Issue 2
Spin-Singlet Transition in the Magnetic Hybrid Compound from a Spin-Crossover Fe(III) Cation and π-Radical Anion
journal, August 2017
- Takahashi, Kazuyuki; Sakurai, Takahiro; Zhang, Wei-Min
- Inorganics, Vol. 5, Issue 3
The Highly Conducting Spin-Crossover Compound Combining Fe(III) Cation Complex with TCNQ in a Fractional Reduction State. Synthesis, Structure, Electric and Magnetic Properties
journal, February 2017
- Shvachko, Yuri; Starichenko, Denis; Korolyov, Aleksander
- Magnetochemistry, Vol. 3, Issue 1