Roles of Interfacial Tension in Regulating Internal Organization of Low Bandgap Polymer Bulk Heterojunction Solar Cells by Polymer Additives
Abstract
Abstract The role of a tertiary polymer‐based additive is investigated in increasing the efficiency of inverted low bandgap polymer:fullerene bulk heterojunction (BHJ) solar cells. Charge separation in polymer BHJ solar cells relies on the phase separation between electron accepting fullerene derivatives and photoactive polymers. Proper distribution of individual phases of suitable crystallinities within the active layer is a key factor for efficient charge transport/extraction and high photovoltaic performance. Here, it is demonstrated that the minor addition of a tertiary amorphous polymer, polystyrene (PS), with optimized molecular weights can increase the overall photovoltaic efficiency of poly[ N ‐9′‐heptadecanyl‐2,7‐carbazole‐alt‐5,5‐(4′,7′‐di‐2‐thienyl‐2′,1′,3′‐benzothiadiazole)]:phenyl‐C 61 butyric acid methyl ester (PCDTBT:PCBM) inverted BHJ solar cells, through the interfacial‐tension‐driven increase in crystallinities of photoactive phases and redistribution of PCBM molecules away from the top hole‐collecting anode interface. Complementary studies correlating polymer interfacial tension, blend internal structure, charge transport, and photovoltaic characteristics show that tertiary, high molecular‐weight polymers can serve as effective additives for improving the performance of low bandgap polymer solar cells.
- Authors:
-
- Stony Brook Univ., NY (United States). Dept. of Materials Science and Chemical Engineering
- Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- National Science Foundation (NSF); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1467440
- Alternate Identifier(s):
- OSTI ID: 1456288
- Grant/Contract Number:
- AC02-06CH11357; SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 5; Journal Issue: 15
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; low bandgap polymer solar cells; ternary blends; polymer additives; interfacial tension; crystallinity
Citation Formats
Yang, Zhenhua, Guo, Yichen, Li, Hongfei, Zhou, Yuchen, Zuo, Xianghao, Yu, Yingjie, Pan, Cheng, Strzalka, Joseph, Nam, Chang-Yong, and Rafailovich, Miriam H. Roles of Interfacial Tension in Regulating Internal Organization of Low Bandgap Polymer Bulk Heterojunction Solar Cells by Polymer Additives. United States: N. p., 2018.
Web. doi:10.1002/admi.201800435.
Yang, Zhenhua, Guo, Yichen, Li, Hongfei, Zhou, Yuchen, Zuo, Xianghao, Yu, Yingjie, Pan, Cheng, Strzalka, Joseph, Nam, Chang-Yong, & Rafailovich, Miriam H. Roles of Interfacial Tension in Regulating Internal Organization of Low Bandgap Polymer Bulk Heterojunction Solar Cells by Polymer Additives. United States. https://doi.org/10.1002/admi.201800435
Yang, Zhenhua, Guo, Yichen, Li, Hongfei, Zhou, Yuchen, Zuo, Xianghao, Yu, Yingjie, Pan, Cheng, Strzalka, Joseph, Nam, Chang-Yong, and Rafailovich, Miriam H. Thu .
"Roles of Interfacial Tension in Regulating Internal Organization of Low Bandgap Polymer Bulk Heterojunction Solar Cells by Polymer Additives". United States. https://doi.org/10.1002/admi.201800435. https://www.osti.gov/servlets/purl/1467440.
@article{osti_1467440,
title = {Roles of Interfacial Tension in Regulating Internal Organization of Low Bandgap Polymer Bulk Heterojunction Solar Cells by Polymer Additives},
author = {Yang, Zhenhua and Guo, Yichen and Li, Hongfei and Zhou, Yuchen and Zuo, Xianghao and Yu, Yingjie and Pan, Cheng and Strzalka, Joseph and Nam, Chang-Yong and Rafailovich, Miriam H.},
abstractNote = {Abstract The role of a tertiary polymer‐based additive is investigated in increasing the efficiency of inverted low bandgap polymer:fullerene bulk heterojunction (BHJ) solar cells. Charge separation in polymer BHJ solar cells relies on the phase separation between electron accepting fullerene derivatives and photoactive polymers. Proper distribution of individual phases of suitable crystallinities within the active layer is a key factor for efficient charge transport/extraction and high photovoltaic performance. Here, it is demonstrated that the minor addition of a tertiary amorphous polymer, polystyrene (PS), with optimized molecular weights can increase the overall photovoltaic efficiency of poly[ N ‐9′‐heptadecanyl‐2,7‐carbazole‐alt‐5,5‐(4′,7′‐di‐2‐thienyl‐2′,1′,3′‐benzothiadiazole)]:phenyl‐C 61 butyric acid methyl ester (PCDTBT:PCBM) inverted BHJ solar cells, through the interfacial‐tension‐driven increase in crystallinities of photoactive phases and redistribution of PCBM molecules away from the top hole‐collecting anode interface. Complementary studies correlating polymer interfacial tension, blend internal structure, charge transport, and photovoltaic characteristics show that tertiary, high molecular‐weight polymers can serve as effective additives for improving the performance of low bandgap polymer solar cells.},
doi = {10.1002/admi.201800435},
journal = {Advanced Energy Materials},
number = 15,
volume = 5,
place = {United States},
year = {Thu Aug 09 00:00:00 EDT 2018},
month = {Thu Aug 09 00:00:00 EDT 2018}
}
Web of Science
Works referenced in this record:
TiO2 based metal-semiconductor-metal ultraviolet photodetectors
journal, May 2007
- Xue, Hailin; Kong, Xiangzi; Liu, Ziran
- Applied Physics Letters, Vol. 90, Issue 20
Fabrication of Active Surfaces with Metastable Microgel Layers Formed during Breath Figure Templating
journal, January 2017
- Zhou, Yuchen; Huang, Junjie; Sun, Wei
- ACS Applied Materials & Interfaces, Vol. 9, Issue 4
Ternary organic solar cells offer 14% power conversion efficiency
journal, December 2017
- Xiao, Zuo; Jia, Xue; Ding, Liming
- Science Bulletin, Vol. 62, Issue 23
Flexible, highly efficient all-polymer solar cells
journal, October 2015
- Kim, Taesu; Kim, Jae-Han; Kang, Tae Eui
- Nature Communications, Vol. 6, Issue 1
Electrospun Conjugated Polymer/Fullerene Hybrid Fibers: Photoactive Blends, Conductivity through Tunneling-AFM, Light Scattering, and Perspective for Their Use in Bulk-Heterojunction Organic Solar Cells
journal, January 2018
- Yang, Zhenhua; Moffa, Maria; Liu, Ying
- The Journal of Physical Chemistry C, Vol. 122, Issue 5
The Nanoscale Morphology of a PCDTBT:PCBM Photovoltaic Blend
journal, April 2011
- Staniec, Paul A.; Parnell, Andrew J.; Dunbar, Alan D. F.
- Advanced Energy Materials, Vol. 1, Issue 4
Gravure printing for three subsequent solar cell layers of inverted structures on flexible substrates
journal, February 2011
- Voigt, Monika M.; Mackenzie, Roderick C. I.; Yau, Chin P.
- Solar Energy Materials and Solar Cells, Vol. 95, Issue 2
Interfacial tension of immiscible polymer blends: temperature and molecular weight dependence
journal, October 1988
- Anastasiadis, Spiros H.; Gancarz, Irena; Koberstein, Jeffrey T.
- Macromolecules, Vol. 21, Issue 10
Plastic Solar Cells
journal, February 2001
- Brabec, C. J.; Sariciftci, N. S.; Hummelen, J. C.
- Advanced Functional Materials, Vol. 11, Issue 1
Compact model and design considerations of an ion-sensitive floating gate FET
journal, March 2017
- Kaisti, Matti; Zhang, Qi; Levon, Kalle
- Sensors and Actuators B: Chemical, Vol. 241
Organic solar cells based on nanoporous P3HT obtained from self-assembled P3HT:PS templates
journal, January 2012
- Vohra, Varun; Campoy-Quiles, Mariano; Garriga, Miquel
- Journal of Materials Chemistry, Vol. 22, Issue 37
A polyaniline based ultrasensitive potentiometric immunosensor for cardiac troponin complex detection
journal, October 2015
- Zhang, Qi; Prabhu, Alok; San, Avdar
- Biosensors and Bioelectronics, Vol. 72
A Review on the Development of the Inverted Polymer Solar Cell Architecture
journal, October 2010
- Hau, Steven K.; Yip, Hin-Lap; Jen, Alex K. -Y.
- Polymer Reviews, Vol. 50, Issue 4
Measurements of the Flory−Huggins Interaction Parameter for Polystyrene−Poly(4-vinylpyridine) Blends
journal, July 1997
- Clarke, C. J.; Eisenberg, A.; La Scala, J.
- Macromolecules, Vol. 30, Issue 14
Design of a molecular imprinting biosensor with multi-scale roughness for detection across a broad spectrum of biomolecules
journal, January 2016
- Yu, Yingjie; Zhang, Qi; Chang, Chung-Chueh
- The Analyst, Vol. 141, Issue 19
Device Characteristics of Bulk-Heterojunction Polymer Solar Cells are Independent of Interfacial Segregation of Active Layers
journal, April 2011
- Wang, He; Gomez, Enrique D.; Kim, Jongbok
- Chemistry of Materials, Vol. 23, Issue 8
Enhancing the Efficiency of Bulk Heterojunction Solar Cells via Templated Self-Assembly
journal, February 2013
- Pan, Cheng; Li, Hongfei; Akgun, Bulent
- Macromolecules, Vol. 46, Issue 5
Thermostable single-junction organic solar cells with a power conversion efficiency of 14.62%
journal, March 2018
- Li, Hui; Xiao, Zuo; Ding, Liming
- Science Bulletin, Vol. 63, Issue 6
Polymer crystal–melt interfaces and nucleation in polyethylene
journal, January 2011
- Milner, Scott T.
- Soft Matter, Vol. 7, Issue 6
Morphology Development in Amorphous Polymer:Fullerene Photovoltaic Blend Films During Solution Casting
journal, October 2013
- Pearson, Andrew J.; Wang, Tao; Dunbar, Alan D. F.
- Advanced Functional Materials, Vol. 24, Issue 5
Solution-Processed Zinc Oxide Thin Film as a Buffer Layer for Polymer Solar Cells with an Inverted Device Structure
journal, March 2010
- Yang, Tingbin; Cai, Wanzhu; Qin, Donghuan
- The Journal of Physical Chemistry C, Vol. 114, Issue 14
Highly efficient inverted organic photovoltaics using solution based titanium oxide as electron selective contact
journal, December 2006
- Waldauf, C.; Morana, M.; Denk, P.
- Applied Physics Letters, Vol. 89, Issue 23
Highly Efficient Organic Solar Cells with Improved Vertical Donor-Acceptor Compositional Gradient Via an Inverted Off-Center Spinning Method
journal, December 2015
- Huang, Jiang; Carpenter, Joshua H.; Li, Chang-Zhi
- Advanced Materials, Vol. 28, Issue 5
Linking Vertical Bulk-Heterojunction Composition and Transient Photocurrent Dynamics in Organic Solar Cells with Solution-Processed MoO x Contact Layers
journal, October 2013
- Tremolet de Villers, Bertrand J.; MacKenzie, Roderick C. I.; Jasieniak, Jacek J.
- Advanced Energy Materials, Vol. 4, Issue 5
Universal Formation of Compositionally Graded Bulk Heterojunction for Efficiency Enhancement in Organic Photovoltaics
journal, February 2014
- Xiao, Zhengguo; Yuan, Yongbo; Yang, Bin
- Advanced Materials, Vol. 26, Issue 19
A real-time study of the benefits of co-solvents in polymer solar cell processing
journal, February 2015
- van Franeker, Jacobus J.; Turbiez, Mathieu; Li, Weiwei
- Nature Communications, Vol. 6, Issue 1
26 mA cm−2 Jsc from organic solar cells with a low-bandgap nonfullerene acceptor
journal, November 2017
- Xiao, Zuo; Jia, Xue; Li, Dan
- Science Bulletin, Vol. 62, Issue 22
Interface-engineering additives of poly(oxyethylene tridecyl ether) for low-band gap polymer solar cells consisting of PCDTBT:PCBM_70 bulk-heterojunction layers
journal, December 2012
- Huh, Yoon Ho; Park, Byoungchoo
- Optics Express, Vol. 21, Issue S1
Compatibilizing Bulk Polymer Blends by Using Organoclays
journal, June 2006
- Si, Mayu; Araki, Tohru; Ade, Harald
- Macromolecules, Vol. 39, Issue 14
Effects of clay platelets and natural nanotubes on mechanical properties and gas permeability of Poly (lactic acid) nanocomposites
journal, January 2016
- Guo, Yichen; Yang, Kai; Zuo, Xianghao
- Polymer, Vol. 83
Inverted Polymer Solar Cells Integrated with a Low-Temperature-Annealed Sol-Gel-Derived ZnO Film as an Electron Transport Layer
journal, February 2011
- Sun, Yanming; Seo, Jung Hwa; Takacs, Christopher J.
- Advanced Materials, Vol. 23, Issue 14, p. 1679-1683
Efficient inverted polymer solar cells
journal, June 2006
- Li, G.; Chu, C. -W.; Shrotriya, V.
- Applied Physics Letters, Vol. 88, Issue 25
Efficiency of bulk-heterojunction organic solar cells
journal, December 2013
- Scharber, M. C.; Sariciftci, N. S.
- Progress in Polymer Science, Vol. 38, Issue 12
Low Temperature Surface Cleaning of Silicon and Its Application to Silicon MBE
journal, January 1986
- Ishizaka, Akitoshi
- Journal of The Electrochemical Society, Vol. 133, Issue 4
All solution roll-to-roll processed polymer solar cells free from indium-tin-oxide and vacuum coating steps
journal, August 2009
- Krebs, Frederik C.
- Organic Electronics, Vol. 10, Issue 5
Characterization of the morphology of solution-processed bulk heterojunction organic photovoltaics
journal, December 2013
- Liu, Feng; Gu, Yu; Shen, Xiaobo
- Progress in Polymer Science, Vol. 38, Issue 12
Efficient hybrid organic-inorganic light emitting diodes with self-assembled dipole molecule deposited metal oxides
journal, June 2010
- Park, Ji Sun; Lee, Bo Ram; Lee, Ju Min
- Applied Physics Letters, Vol. 96, Issue 24
Quantitative real-time detection of carcinoembryonic antigen (CEA) from pancreatic cyst fluid using 3-D surface molecular imprinting
journal, January 2016
- Yu, Yingjie; Zhang, Qi; Buscaglia, Jonathan
- The Analyst, Vol. 141, Issue 14
Calculation of interfacial tension in polymer systems
journal, January 1971
- Wu, Souheng
- Journal of Polymer Science Part C: Polymer Symposia, Vol. 34, Issue 1
Bilayer order in a polycarbazole-conjugated polymer
journal, January 2012
- Lu, Xinhui; Hlaing, Htay; Germack, David S.
- Nature Communications, Vol. 3, Issue 1
A new strategy to engineer polymer bulk heterojunction solar cells with thick active layers via self-assembly of the tertiary columnar phase
journal, January 2017
- Li, Hongfei; Yang, Zhenhua; Pan, Cheng
- Nanoscale, Vol. 9, Issue 32
Recent Progress in Polymer Solar Cells: Manipulation of Polymer:Fullerene Morphology and the Formation of Efficient Inverted Polymer Solar Cells
journal, April 2009
- Chen, Li-Min; Hong, Ziruo; Li, Gang
- Advanced Materials, Vol. 21, Issue 14-15
Simultaneous Use of Small‐ and Wide‐Angle X‐ray Techniques to Analyze Nanometerscale Phase Separation in Polymer Heterojunction Solar Cells
journal, July 2008
- Chiu, Mao‐Yuan; Jeng, U‐Ser; Su, Chiu‐Hun
- Advanced Materials, Vol. 20, Issue 13
Molecular Miscibility of Polymer−Fullerene Blends
journal, October 2010
- Collins, Brian A.; Gann, Eliot; Guignard, Lewis
- The Journal of Physical Chemistry Letters, Vol. 1, Issue 21
Polymer materials for prevention of postoperative adhesion
journal, October 2017
- Li, Jiannan; Feng, Xiangru; Liu, Baichun
- Acta Biomaterialia, Vol. 61
Theory of the interface between immiscible polymers
journal, October 1971
- Helfand, Eugene; Tagami, Yukiko
- Journal of Polymer Science Part B: Polymer Letters, Vol. 9, Issue 10
Capitalizing on the molybdenum disulfide/graphene synergy to produce mechanical enhanced flame retardant ethylene-vinyl acetate composites with low aluminum hydroxide loading
journal, October 2017
- Guo, Yichen; Xue, Yuan; Zuo, Xianghao
- Polymer Degradation and Stability, Vol. 144
Intramolecular Transport of Charge Carriers in Trimeric Aniline upon a Three-Step Acid Doping Process
journal, July 2012
- Zhang, Qi; Khajo, Abdelahad; Sai, Tsunehiro
- The Journal of Physical Chemistry A, Vol. 116, Issue 29
Immiscible polymer blends of semicrystalline biocompatible components: thermal properties and phase morphology analysis of PLLA/PCL blends
journal, August 2001
- Dell'Erba, Ramiro; Groeninckx, Gabriel; Maglio, Giovanni
- Polymer, Vol. 42, Issue 18
Highly Efficient and Stable Inverted Polymer Solar Cells Integrated with a Cross-Linked Fullerene Material as an Interlayer
journal, April 2010
- Hsieh, Chao-Hsiang; Cheng, Yen-Ju; Li, Pei-Jung
- Journal of the American Chemical Society, Vol. 132, Issue 13
Enhancing the Mechanical Properties of Biodegradable Polymer Blends Using Tubular Nanoparticle Stitching of the Interfaces
journal, June 2016
- Guo, Yichen; He, Shan; Yang, Kai
- ACS Applied Materials & Interfaces, Vol. 8, Issue 27
Fabrication, Optical Modeling, and Color Characterization of Semitransparent Bulk-Heterojunction Organic Solar Cells in an Inverted Structure
journal, May 2010
- Ameri, Tayebeh; Dennler, Gilles; Waldauf, Christoph
- Advanced Functional Materials, Vol. 20, Issue 10
Nanofiber-Based Bulk-Heterojunction Organic Solar Cells Using Coaxial Electrospinning
journal, May 2012
- Bedford, Nicholas M.; Dickerson, Matthew B.; Drummy, Lawrence F.
- Advanced Energy Materials, Vol. 2, Issue 9
PS-b-P3HT Copolymers as P3HT/PCBM Interfacial Compatibilizers for High Efficiency Photovoltaics
journal, November 2011
- Sun, Zhenzhong; Xiao, Kai; Keum, Jong Kahk
- Advanced Materials, Vol. 23, Issue 46
High-Molecular-Weight Insulating Polymers Can Improve the Performance of Molecular Solar Cells
journal, April 2014
- Huang, Ye; Wen, Wen; Mukherjee, Subhrangsu
- Advanced Materials, Vol. 26, Issue 24
Role of Surface Interactions in the Synergizing Polymer/Clay Flame Retardant Properties
journal, June 2010
- Pack, Seongchan; Kashiwagi, Takashi; Cao, Changhong
- Macromolecules, Vol. 43, Issue 12
Critical factors governing vertical phase separation in polymer–PCBM blend films for organic solar cells
journal, January 2016
- Kim, Min; Lee, Jaewon; Jo, Sae Byeok
- Journal of Materials Chemistry A, Vol. 4, Issue 40
A New Model for the Morphology of P3HT/PCBM Organic Photovoltaics from Small-Angle Neutron Scattering: Rivers and Streams
journal, May 2011
- Yin, Wen; Dadmun, Mark
- ACS Nano, Vol. 5, Issue 6, p. 4756-4768
Increasing the Detection Sensitivity for DNA-Morpholino Hybridization in Sub-Nanomolar Regime by Enhancing the Surface Ion Conductance of PEDOT:PSS Membrane in a Microchannel
journal, June 2016
- Wei, Xi; Panindre, Prabodh; Zhang, Qi
- ACS Sensors, Vol. 1, Issue 7