DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Chemically stable artificial SEI for Li-ion battery electrodes

Abstract

Here, the importance of coating’s chemical stability in lithium-ion batteries has been demonstrated by this study. It is well known that the mechanical properties determine the cycle life, and chemical stability or chemical degradation rate determines the calendar life. In this study, we used HfO2 coatings prepared by atomic layer deposition as an example to show the chemical stability of the coatings for lithium ion battery electrodes.

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1]
  1. Univ. of Kentucky, Lexington, KY (United States)
Publication Date:
Research Org.:
General Motors, LLC, Detroit, MI (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1466029
Alternate Identifier(s):
OSTI ID: 1361796
Grant/Contract Number:  
EE0007787; AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Applied Physics Letters
Additional Journal Information:
Journal Volume: 110; Journal Issue: 13; Journal ID: ISSN 0003-6951
Publisher:
American Institute of Physics (AIP)
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE

Citation Formats

Zhang, Qinglin, Han, Lei, Pan, Jie, Chen, Zhi, and Cheng, Yang -Tse. Chemically stable artificial SEI for Li-ion battery electrodes. United States: N. p., 2017. Web. doi:10.1063/1.4979108.
Zhang, Qinglin, Han, Lei, Pan, Jie, Chen, Zhi, & Cheng, Yang -Tse. Chemically stable artificial SEI for Li-ion battery electrodes. United States. https://doi.org/10.1063/1.4979108
Zhang, Qinglin, Han, Lei, Pan, Jie, Chen, Zhi, and Cheng, Yang -Tse. Mon . "Chemically stable artificial SEI for Li-ion battery electrodes". United States. https://doi.org/10.1063/1.4979108. https://www.osti.gov/servlets/purl/1466029.
@article{osti_1466029,
title = {Chemically stable artificial SEI for Li-ion battery electrodes},
author = {Zhang, Qinglin and Han, Lei and Pan, Jie and Chen, Zhi and Cheng, Yang -Tse},
abstractNote = {Here, the importance of coating’s chemical stability in lithium-ion batteries has been demonstrated by this study. It is well known that the mechanical properties determine the cycle life, and chemical stability or chemical degradation rate determines the calendar life. In this study, we used HfO2 coatings prepared by atomic layer deposition as an example to show the chemical stability of the coatings for lithium ion battery electrodes.},
doi = {10.1063/1.4979108},
journal = {Applied Physics Letters},
number = 13,
volume = 110,
place = {United States},
year = {Mon Mar 27 00:00:00 EDT 2017},
month = {Mon Mar 27 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record

Citation Metrics:
Cited by: 17 works
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Tetrakis(dimethylamido)hafnium Adsorption and Reaction on Hydrogen Terminated Si(100) Surfaces
journal, July 2010

  • Li, Kejing; Li, Shenggang; Li, Ning
  • The Journal of Physical Chemistry C, Vol. 114, Issue 33
  • DOI: 10.1021/jp101363r

XPS and depth resolved SXES study of HfO2/Si interlayers
journal, August 2010

  • Filatova, E. O.; Sokolov, A. A.; Ovchinnikov, A. A.
  • Journal of Electron Spectroscopy and Related Phenomena, Vol. 181, Issue 2-3
  • DOI: 10.1016/j.elspec.2010.04.005

Electrode Side Reactions, Capacity Loss and Mechanical Degradation in Lithium-Ion Batteries
journal, January 2015

  • Xu, Jiagang; Deshpande, Rutooj D.; Pan, Jie
  • Journal of The Electrochemical Society, Vol. 162, Issue 10
  • DOI: 10.1149/2.0291510jes

Toward High Cycle Efficiency of Silicon-Based Negative Electrodes by Designing the Solid Electrolyte Interphase
journal, November 2014

  • Zhang, Qinglin; Xiao, Xingcheng; Zhou, Weidong
  • Advanced Energy Materials, Vol. 5, Issue 5
  • DOI: 10.1002/aenm.201401398

(Invited) Atomic Layer Deposition of HfO2 Using HF Etched Thermal and RTP SiO2 as Interfacial Layers
journal, March 2014


Growth and interface of HfO2 films on H-terminated Si from a TDMAH and H2O atomic layer deposition process
journal, September 2008

  • Hackley, Justin C.; Demaree, J. Derek; Gougousi, Theodosia
  • Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 26, Issue 5
  • DOI: 10.1116/1.2965813

Effect of Fluoroethylene Carbonate (FEC) on the Performance and Surface Chemistry of Si-Nanowire Li-Ion Battery Anodes
journal, December 2011

  • Etacheri, Vinodkumar; Haik, Ortal; Goffer, Yossi
  • Langmuir, Vol. 28, Issue 1
  • DOI: 10.1021/la203712s

Binder-free lithium ion battery electrodes made of silicon and pyrolized lignin
journal, January 2016

  • Chen, Tao; Zhang, Qinglin; Xu, Jiagang
  • RSC Advances, Vol. 6, Issue 35
  • DOI: 10.1039/C6RA03001G

Ultrathin SiO2 Films Grown by Atomic Layer Deposition Using Tris(dimethylamino)silane (TDMAS) and Ozone
journal, August 2013


Atomic Layer Deposition of High Quality HfO 2 Using In-Situ Formed Hydrophilic Oxide as an Interfacial Layer
journal, January 2014

  • Han, Lei; Pan, Jie; Zhang, Qinglin
  • ECS Journal of Solid State Science and Technology, Vol. 3, Issue 12
  • DOI: 10.1149/2.0041412jss

Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction
journal, December 2012

  • Pinson, Matthew B.; Bazant, Martin Z.
  • Journal of The Electrochemical Society, Vol. 160, Issue 2
  • DOI: 10.1149/2.044302jes

Role of Surface Oxides in the Formation of Solid–Electrolyte Interphases at Silicon Electrodes for Lithium-Ion Batteries
journal, November 2014

  • Schroder, Kjell W.; Dylla, Anthony G.; Harris, Stephen J.
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 23
  • DOI: 10.1021/am506517j

Ultrathin Multifunctional Oxide Coatings for Lithium Ion Batteries
journal, July 2011


Effects of stress on lithium transport in amorphous silicon electrodes for lithium-ion batteries
journal, April 2015


General method to predict voltage-dependent ionic conduction in a solid electrolyte coating on electrodes
journal, April 2015


Design of Nanostructured Heterogeneous Solid Ionic Coatings through a Multiscale Defect Model
journal, February 2016

  • Pan, Jie; Zhang, Qinglin; Xiao, Xingcheng
  • ACS Applied Materials & Interfaces, Vol. 8, Issue 8
  • DOI: 10.1021/acsami.5b12030

Cathode materials modified by surface coating for lithium ion batteries
journal, May 2006


Analysis of Lithium Insertion/Deinsertion in a Silicon Electrode Particle at Room Temperature
journal, January 2010

  • Chandrasekaran, Rajeswari; Magasinski, Alexandre; Yushin, Gleb
  • Journal of The Electrochemical Society, Vol. 157, Issue 10
  • DOI: 10.1149/1.3474225

The effects of LiBOB additive for stable SEI formation of PP13TFSI-organic mixed electrolyte in lithium ion batteries
journal, May 2011


Solid–Electrolyte Interphase Formation and Electrolyte Reduction at Li-Ion Battery Graphite Anodes: Insights from First-Principles Molecular Dynamics
journal, November 2012

  • Ganesh, P.; Kent, P. R. C.; Jiang, De-en
  • The Journal of Physical Chemistry C, Vol. 116, Issue 46
  • DOI: 10.1021/jp3086304

Atomic Layer Deposition: An Overview
journal, January 2010

  • George, Steven M.
  • Chemical Reviews, Vol. 110, Issue 1, p. 111-131
  • DOI: 10.1021/cr900056b

High-Quality Thin SiO 2 Films Grown by Atomic Layer Deposition Using Tris(dimethylamino)silane (TDMAS) and Ozone
journal, January 2013

  • Han, Lei; Chen, Zhi
  • ECS Journal of Solid State Science and Technology, Vol. 2, Issue 11
  • DOI: 10.1149/2.001312jss

Direct Determination of Solid-Electrolyte Interphase Thickness and Composition as a Function of State of Charge on a Silicon Anode
journal, August 2015

  • Veith, Gabriel M.; Doucet, Mathieu; Baldwin, J. Kevin
  • The Journal of Physical Chemistry C, Vol. 119, Issue 35
  • DOI: 10.1021/acs.jpcc.5b06817

Atomic Layered Coating Enabling Ultrafast Surface Kinetics at Silicon Electrodes in Lithium Ion Batteries
journal, September 2013

  • Li, Juchuan; Xiao, Xingcheng; Cheng, Yang-Tse
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 20
  • DOI: 10.1021/jz4018255

Experimental and Theoretical Characterization of Electrode Materials that Undergo Large Volume Changes and Application to the Lithium–Silicon System
journal, February 2015

  • Verbrugge, Mark W.; Baker, Daniel R.; Xiao, Xingcheng
  • The Journal of Physical Chemistry C, Vol. 119, Issue 10
  • DOI: 10.1021/jp512585z

Voltage hysteresis of lithium ion batteries caused by mechanical stress
journal, January 2016

  • Lu, Bo; Song, Yicheng; Zhang, Qinglin
  • Physical Chemistry Chemical Physics, Vol. 18, Issue 6
  • DOI: 10.1039/C5CP06179B

The Interfacial Quality of HfO[sub 2] on Silicon with Different Thicknesses of the Chemical Oxide Interfacial Layer
journal, January 2010

  • Li, Shibin; Han, Lei; Chen, Zhi
  • Journal of The Electrochemical Society, Vol. 157, Issue 11
  • DOI: 10.1149/1.3483789

Effect of Anode Film Resistance on the Charge/Discharge Capacity of a Lithium-Ion Battery
journal, January 2003

  • Christensen, J.; Newman, J.
  • Journal of The Electrochemical Society, Vol. 150, Issue 11
  • DOI: 10.1149/1.1612501

Functional electrolytes: Synergetic effect of electrolyte additives for lithium-ion battery
journal, October 2008


EIS study on the formation of solid electrolyte interface in Li-ion battery
journal, January 2006


Thermal stability and electrical characteristics of ultrathin hafnium oxide gate dielectric reoxidized with rapid thermal annealing
journal, April 2000

  • Lee, Byoung Hun; Kang, Laegu; Nieh, Renee
  • Applied Physics Letters, Vol. 76, Issue 14
  • DOI: 10.1063/1.126214

A non-destructive method for measuring the mechanical properties of ultrathin films prepared by atomic layer deposition
journal, August 2014

  • Zhang, Qinglin; Xiao, Xingcheng; Cheng, Yang-Tse
  • Applied Physics Letters, Vol. 105, Issue 6
  • DOI: 10.1063/1.4892539

Works referencing / citing this record:

Electrode Engineering by Atomic Layer Deposition for Sodium‐Ion Batteries: From Traditional to Advanced Batteries
journal, December 2019


Heat Generation and Thermal Transport in Lithium-Ion Batteries: A Scale-Bridging Perspective
journal, November 2018