Thermophysical properties and conduction mechanisms in AsxSe1-x chalcogenide glasses ranging from x = 0.2 to 0.5
Abstract
The arsenic (As) to selenium (Se) ratio in AsxSe1-x glasses ranging from x = 0.2 to 0.5 was varied in order to examine the effect of chemical and topological ordering on the glass' thermal transport behavior. The fundamental thermal properties of glass transition temperature (Tg), thermal conductivity (k), and heat capacity (cp) were experimentally measured using differential scanning calorimetry, transient plane source method, and ultrasonic testing. Based on topological constraint theory, inflections in Tg and k were found at the structural coordination number $$\langle$$r$$\rangle$$ of 2.4, whereas a slight increase in heat capacity (cp) with increasing $$\langle$$r$$\rangle$$ was observed. A maximum in total thermal conductivity of 0.232 W/m·K was measured for the composition with x = 0.4, which corresponds to the stoichiometric As2Se3. Gas kinetic theory was used to derive an expression for the photon (kp) portion of thermal conductivity, which was calculated by measurements of the glass' absorption coefficient (α) and refractive index (n). Models based on Debye theory were then used to derive expressions for specific heat (cv) and the lattice (kl) portion of thermal conductivity. The maximum value for kp was 0.173 W/m·K for the composition with x = 0.2, and a minimum value of 0.144 W/m·K was measured for the composition with x = 0.4. Photonic conduction was found to be the dominant carrier mechanisms in all compositions, comprising 60% to 95% of the measured total thermal conductivity.
- Authors:
-
[1];
- Univ. of Central Florida, Orlando, FL (United States). The College of Optics and Photonics (CREOL)
- Publication Date:
- Research Org.:
- Univ. of Central Florida, Orlando, FL (United States)
- Sponsoring Org.:
- USDOE; Defense Threat Reduction Agency (DTRA)
- OSTI Identifier:
- 1465114
- Alternate Identifier(s):
- OSTI ID: 1328596
- Grant/Contract Number:
- EE0005327; HDTRA1-13-1-0001; NA000278
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Applied Physics
- Additional Journal Information:
- Journal Volume: 120; Journal Issue: 14; Journal ID: ISSN 0021-8979
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS; phonons; photons; thermal conduction; heat capacity; glasses; thermal conductivity; glass transitions; absorption coefficient; refractive index
Citation Formats
Lonergan, Jason, Smith, Charmayne, McClane, Devon, and Richardson, Kathleen. Thermophysical properties and conduction mechanisms in AsxSe1-x chalcogenide glasses ranging from x = 0.2 to 0.5. United States: N. p., 2016.
Web. doi:10.1063/1.4962446.
Lonergan, Jason, Smith, Charmayne, McClane, Devon, & Richardson, Kathleen. Thermophysical properties and conduction mechanisms in AsxSe1-x chalcogenide glasses ranging from x = 0.2 to 0.5. United States. https://doi.org/10.1063/1.4962446
Lonergan, Jason, Smith, Charmayne, McClane, Devon, and Richardson, Kathleen. Tue .
"Thermophysical properties and conduction mechanisms in AsxSe1-x chalcogenide glasses ranging from x = 0.2 to 0.5". United States. https://doi.org/10.1063/1.4962446. https://www.osti.gov/servlets/purl/1465114.
@article{osti_1465114,
title = {Thermophysical properties and conduction mechanisms in AsxSe1-x chalcogenide glasses ranging from x = 0.2 to 0.5},
author = {Lonergan, Jason and Smith, Charmayne and McClane, Devon and Richardson, Kathleen},
abstractNote = {The arsenic (As) to selenium (Se) ratio in AsxSe1-x glasses ranging from x = 0.2 to 0.5 was varied in order to examine the effect of chemical and topological ordering on the glass' thermal transport behavior. The fundamental thermal properties of glass transition temperature (Tg), thermal conductivity (k), and heat capacity (cp) were experimentally measured using differential scanning calorimetry, transient plane source method, and ultrasonic testing. Based on topological constraint theory, inflections in Tg and k were found at the structural coordination number $\langle$r$\rangle$ of 2.4, whereas a slight increase in heat capacity (cp) with increasing $\langle$r$\rangle$ was observed. A maximum in total thermal conductivity of 0.232 W/m·K was measured for the composition with x = 0.4, which corresponds to the stoichiometric As2Se3. Gas kinetic theory was used to derive an expression for the photon (kp) portion of thermal conductivity, which was calculated by measurements of the glass' absorption coefficient (α) and refractive index (n). Models based on Debye theory were then used to derive expressions for specific heat (cv) and the lattice (kl) portion of thermal conductivity. The maximum value for kp was 0.173 W/m·K for the composition with x = 0.2, and a minimum value of 0.144 W/m·K was measured for the composition with x = 0.4. Photonic conduction was found to be the dominant carrier mechanisms in all compositions, comprising 60% to 95% of the measured total thermal conductivity.},
doi = {10.1063/1.4962446},
journal = {Journal of Applied Physics},
number = 14,
volume = 120,
place = {United States},
year = {Tue Oct 11 00:00:00 EDT 2016},
month = {Tue Oct 11 00:00:00 EDT 2016}
}
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Works referenced in this record:
Chemical bond approach to determining conductivity band gaps in amorphous chalcogenides and pnictides
journal, September 1981
- Rao, K. J.; Mohan, R.
- Solid State Communications, Vol. 39, Issue 10
Refractive-Index Behavior of Amorphous Semiconductors and Glasses
journal, April 1973
- Wemple, S. H.
- Physical Review B, Vol. 7, Issue 8
Thermal transport near the glass transition in bulk As-Se glasses
journal, April 1989
- Madhusoodanan, K. N.; Philip, Jacob
- Physical Review B, Vol. 39, Issue 11
Integrated flexible chalcogenide glass photonic devices
journal, June 2014
- Li, Lan; Lin, Hongtao; Qiao, Shutao
- Nature Photonics, Vol. 8, Issue 8
Structure of Se-rich As-Se glasses by high-resolution x-ray photoelectron spectroscopy
journal, September 2007
- Golovchak, R.; Kovalskiy, A.; Miller, A. C.
- Physical Review B, Vol. 76, Issue 12
Thermal Conductivities of As-Se Glasses
journal, July 1975
- Kuriyama, Masaaki
- Journal of the American Ceramic Society, Vol. 58, Issue 7-8
A Comparative Study of Purification Routes for As 2 Se 3 Chalcogenide Glass
journal, December 2012
- Danto, Sylvain; Thompson, Daniel; Wachtel, Peter
- International Journal of Applied Glass Science, Vol. 4, Issue 1
Acoustic and optical Debye temperatures of the vitreous system CoO-Co2O3-P2O5
journal, July 1986
- Bridge, B.; Higazy, A. A.
- Journal of Materials Science, Vol. 21, Issue 7
Composition dependence of the viscosity and other physical properties in the arsenic selenide glass system
journal, September 2011
- Musgraves, J. David; Wachtel, Peter; Novak, Spencer
- Journal of Applied Physics, Vol. 110, Issue 6
Rare-earth doped chalcogenide glass laser
journal, January 1996
- Schweizer, T.; Hewak, D. W.; Payne, D. N.
- Electronics Letters, Vol. 32, Issue 7
Raman spectra of chalcogen chains isolated in zeolite matrixes
journal, April 1985
- Bogomolov, V. N.; Poborchy, V. V.; Romanov, S. G.
- Journal of Physics C: Solid State Physics, Vol. 18, Issue 12
Demonstration of CO_2-laser power delivery through chalcogenide-glass fiber with negative-curvature hollow core
journal, January 2011
- Kosolapov, Alexey F.; Pryamikov, Andrey D.; Biriukov, Alexander S.
- Optics Express, Vol. 19, Issue 25
A general structural model for semiconducting glasses
journal, April 1989
- Liu, J. Z.; Taylor, P. C.
- Solid State Communications, Vol. 70, Issue 1
Densities, microhardnesses and electron microscopic studies of As-Se glasses
journal, February 1981
- Mohan, R.; Panchapagesan, T. S.; Rao, K. J.
- Bulletin of Materials Science, Vol. 3, Issue 1
Optical properties and applications of chalcogenide glasses: a review
journal, November 2003
- Zakery, A.; Elliott, S. R.
- Journal of Non-Crystalline Solids, Vol. 330, Issue 1-3
Theory of Heat Conduction in Rare-Gas Crystals
journal, January 1965
- Julian, Carl L.
- Physical Review, Vol. 137, Issue 1A
Topology of covalent non-crystalline solids I: Short-range order in chalcogenide alloys
journal, October 1979
- Phillips, J. C.
- Journal of Non-Crystalline Solids, Vol. 34, Issue 2
Thermal Conductivity: I, Concepts of Measurement and Factors Affecting Thermal Conductivity of Ceramic Materials
journal, February 1954
- Kingery, W. D.; McQUARRIE, M. C.
- Journal of the American Ceramic Society, Vol. 37, Issue 2
Structural characterizations of vitreous inorganic polymers by thermal studies
journal, July 1967
- Myers, M. B.; Felty, E. J.
- Materials Research Bulletin, Vol. 2, Issue 7
Covalent bond approach to the glass-transition temperature of chalcogenide glasses
journal, August 1995
- Tichý, L.; Tichá, H.
- Journal of Non-Crystalline Solids, Vol. 189, Issue 1-2
Chalcogenide glasses: a review of their preparation, properties and applications
journal, May 1995
- Seddon, A. B.
- Journal of Non-Crystalline Solids, Vol. 184
Refractive index dispersion of chalcogenide glasses for ultra-high numerical-aperture fiber for mid-infrared supercontinuum generation
journal, January 2014
- Dantanarayana, Harshana G.; Abdel-Moneim, Nabil; Tang, Zhuoqi
- Optical Materials Express, Vol. 4, Issue 7
Effect of Te additions on the optical properties of (As–Sb–Se) thin films
journal, February 2007
- Othman, A. A.; Aly, K. A.; Abousehly, A. M.
- Thin Solid Films, Vol. 515, Issue 7-8
Complex structural rearrangements in As-Se glasses
journal, February 2014
- Golovchak, R.; Oelgoetz, J.; Vlcek, M.
- The Journal of Chemical Physics, Vol. 140, Issue 5
Behavior of the Electronic Dielectric Constant in Covalent and Ionic Materials
journal, February 1971
- Wemple, S. H.; DiDomenico, M.
- Physical Review B, Vol. 3, Issue 4
Measurement of the refractive index dispersion of As 2 Se 3 bulk glass and thin films prior to and after laser irradiation and annealing using prism coupling in the near- and mid-infrared spectral range
journal, May 2011
- Carlie, N.; Anheier, N. C.; Qiao, H. A.
- Review of Scientific Instruments, Vol. 82, Issue 5
Mechanical and thermal properties of simultaneously substituted pyrochlore compounds (Ca2Nb2O7) (Gd2Zr2O7)1−
journal, March 2015
- Zhao, Meng; Ren, Xiaorui; Pan, Wei
- Journal of the European Ceramic Society, Vol. 35, Issue 3
Chalcogenide photonics
journal, February 2011
- Eggleton, Benjamin J.; Luther-Davies, Barry; Richardson, Kathleen
- Nature Photonics, Vol. 5, Issue 3
Properties of Dy3+-Doped Ge–As–Ga–Se Chalcogenide Glasses
journal, August 2006
- Jing, Ren; Guang, Yang; Huidan, Zeng
- Journal of the American Ceramic Society, Vol. 89, Issue 8
Photoluminescence in Er-doped Ge-As-Se chalcogenide thin films
journal, January 2012
- Yan, Kunlun; Wang, Rongping; Vu, Khu
- Optical Materials Express, Vol. 2, Issue 9
Multihundred‐watt CO laser power delivery through chalcogenide glass fibers
journal, February 1993
- Sato, Shunichi; Igarashi, Kaoru; Taniwaki, Manabu
- Applied Physics Letters, Vol. 62, Issue 7
Conduction in non-crystalline materials: III. Localized states in a pseudogap and near extremities of conduction and valence bands
journal, April 1969
- Mott, N. F.
- Philosophical Magazine, Vol. 19, Issue 160
Study of mid-infrared laser action in chalcogenide rare earth doped glass with Dy^3+, Pr^3+and Tb^3+
journal, January 2012
- Sójka, Ł.; Tang, Z.; Zhu, H.
- Optical Materials Express, Vol. 2, Issue 11
Remote fiber-optic chemical sensing using evanescent-wave interactions in chalcogenide glass fibers
journal, January 1991
- Heo, Jong; Rodrigues, Monica; Saggese, Steven J.
- Applied Optics, Vol. 30, Issue 27
Thermal Conductivity of Infrared Transparent Chalcogenide Glasses
journal, March 1975
- Hayes, D. J.; Rea, S. N.; Hilton, A. R.
- Journal of the American Ceramic Society, Vol. 58, Issue 3-4
Topological versus chemical ordering in network glasses at intermediate and extended length scales
journal, May 2005
- Salmon, Philip S.; Martin, Richard A.; Mason, Philip E.
- Nature, Vol. 435, Issue 7038
Structural phase transitions in chalcogenide glasses
journal, January 1989
- Tanaka, Keiji
- Physical Review B, Vol. 39, Issue 2
Fabrication of molded chalcogenide-glass lens for thermal imaging applications
journal, January 2012
- Cha, Du Hwan; Kim, Hye-Jeong; Hwang, Yeon
- Applied Optics, Vol. 51, Issue 23
Structure of As2Se3 and AsSe network glasses: Evidence for coordination defects and homopolar bonding
journal, October 2013
- Bauchy, M.; Micoulaut, M.
- Journal of Non-Crystalline Solids, Vol. 377
Low loss Ge-As-Se chalcogenide glass fiber, fabricated using extruded preform, for mid-infrared photonics
journal, January 2015
- Tang, Zhuoqi; Shiryaev, Vladimir S.; Furniss, David
- Optical Materials Express, Vol. 5, Issue 8
The Thermal Conductivity of Nonmetallic Crystals
book, January 1979
- Slack, Glen A.
- Solid State Physics
Carbon monoxide laser power delivery with an As_2S_3 infrared glass fiber
journal, January 1984
- Arai, Tsunenori; Kikuchi, Makoto
- Applied Optics, Vol. 23, Issue 17
Mid-wave IR and long-wave IR laser potential of rare-earth doped chalcogenide glass fiber
journal, January 2001
- Shaw, L. B.; Cole, B.; Thielen, P. A.
- IEEE Journal of Quantum Electronics, Vol. 37, Issue 9
Rigidity transitions in binary Ge–Se glasses and the intermediate phase
journal, November 2001
- Boolchand, P.; Feng, X.; Bresser, W. J.
- Journal of Non-Crystalline Solids, Vol. 293-295
Infrared-transmitting glass-ceramics: a review
conference, June 2013
- McCloy, John S.; Riley, Brian J.; Pierce, David A.
- SPIE Defense, Security, and Sensing, SPIE Proceedings
Optical properties and electronic structure of amorphous Ge and Si
journal, January 1968
- Tauc, J.
- Materials Research Bulletin, Vol. 3, Issue 1
An Introduction to Thermal Physics
journal, August 2000
- Schroeder, Daniel V.; Gould, Harvey
- Physics Today, Vol. 53, Issue 8
Works referencing / citing this record:
Calorimetric and volumetric functions of AsxSe1−x (x = 0.3–0.5) glasses and their model representation
journal, June 2019
- Kut’in, A. M.; Shiryaev, V. S.; Plekhovich, A. D.
- Journal of Thermal Analysis and Calorimetry, Vol. 139, Issue 2