Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: Thermocatalytic analysis of CO2-CO selective chemisorption mechanism on lithium cuprate (Li2CuO2) and oxygen addition effect

Abstract

In the present paper, thermogravimetric and catalytic analyses were performed in order to evidence the chemisorption selective mechanism followed during the CO and CO2 chemisorption processes on Li2CuO2 under different atmosphere conditions. Results were contrasted with some thermodynamic data. According to TG results, when the gas flow was composed by one gas (CO or CO2), chemisorption occurred through a superficial reaction followed by a volumetric capture. In the CO case, a double process was produced; CO oxidation and subsequent CO2 chemisorption. Here, Li2CuO2, initially, catalyzed the CO oxidation and then it sorbed CO2. However, as Li2CuO2 structure and composition evolves, it could not be strictly considered as a catalyst. On the other hand, when both gases were present (CO-CO2), a chemisorption competition was observed as a function of temperature, where CO was always selectively chemisorbed. Finally and furthermore, O2 presence modified positively the chemisorption abilities in binary (CO-O2 and CO2-O2) and ternary (CO-CO2-O2) gas systems, in comparison with analogous tests performed in absence of O2.

Authors:
 [1];  [1];  [1];  [2];  [1]
+ Show Author Affiliations
  1. National Autonomous Univ. of Mexico, Mexico City (Mexico). Inst. of Materials Research. Surface Physics and Reactivity Lab. (LaFReS)
  2. National Energy Technology Lab. (NETL), Pittsburgh, PA (United States)
Publication Date:
Research Org.:
National Energy Technology Lab. (NETL), Pittsburgh, PA (United States); National Autonomous Univ. of Mexico, Mexico City (Mexico)
Sponsoring Org.:
USDOE; National Council of Science and Technology (CONACYT) (Mexico); UNAM Support Program for Research Projects and Technological Innovation (PAPIIT) (Mexico)
OSTI Identifier:
1461405
Grant/Contract Number:  
251801; IN-101916
Resource Type:
Accepted Manuscript
Journal Name:
Thermochimica Acta
Additional Journal Information:
Journal Volume: 660; Journal ID: ISSN 0040-6031
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; CO2 chemisorption; CO oxidation; selective sorption process; lithium cuprate

Citation Formats

Yanez-Aulestia, Ana, Gomez-Garcia, J. Francisco, Mendoza-Nieto, J. Arturo, Duan, Yuhua, and Pfeiffer, Heriberto. Thermocatalytic analysis of CO2-CO selective chemisorption mechanism on lithium cuprate (Li2CuO2) and oxygen addition effect. United States: N. p., 2018. Web. doi:10.1016/j.tca.2017.12.027.
Copy to clipboard
Yanez-Aulestia, Ana, Gomez-Garcia, J. Francisco, Mendoza-Nieto, J. Arturo, Duan, Yuhua, & Pfeiffer, Heriberto. Thermocatalytic analysis of CO2-CO selective chemisorption mechanism on lithium cuprate (Li2CuO2) and oxygen addition effect. United States. https://doi.org/10.1016/j.tca.2017.12.027
Copy to clipboard
Yanez-Aulestia, Ana, Gomez-Garcia, J. Francisco, Mendoza-Nieto, J. Arturo, Duan, Yuhua, and Pfeiffer, Heriberto. Fri . "Thermocatalytic analysis of CO2-CO selective chemisorption mechanism on lithium cuprate (Li2CuO2) and oxygen addition effect". United States. https://doi.org/10.1016/j.tca.2017.12.027. https://www.osti.gov/servlets/purl/1461405.
Copy to clipboard
@article{osti_1461405,
title = {Thermocatalytic analysis of CO2-CO selective chemisorption mechanism on lithium cuprate (Li2CuO2) and oxygen addition effect},
author = {Yanez-Aulestia, Ana and Gomez-Garcia, J. Francisco and Mendoza-Nieto, J. Arturo and Duan, Yuhua and Pfeiffer, Heriberto},
abstractNote = {In the present paper, thermogravimetric and catalytic analyses were performed in order to evidence the chemisorption selective mechanism followed during the CO and CO2 chemisorption processes on Li2CuO2 under different atmosphere conditions. Results were contrasted with some thermodynamic data. According to TG results, when the gas flow was composed by one gas (CO or CO2), chemisorption occurred through a superficial reaction followed by a volumetric capture. In the CO case, a double process was produced; CO oxidation and subsequent CO2 chemisorption. Here, Li2CuO2, initially, catalyzed the CO oxidation and then it sorbed CO2. However, as Li2CuO2 structure and composition evolves, it could not be strictly considered as a catalyst. On the other hand, when both gases were present (CO-CO2), a chemisorption competition was observed as a function of temperature, where CO was always selectively chemisorbed. Finally and furthermore, O2 presence modified positively the chemisorption abilities in binary (CO-O2 and CO2-O2) and ternary (CO-CO2-O2) gas systems, in comparison with analogous tests performed in absence of O2.},
doi = {10.1016/j.tca.2017.12.027},
journal = {Thermochimica Acta},
number = ,
volume = 660,
place = {United States},
year = {Fri Jan 05 00:00:00 EST 2018},
month = {Fri Jan 05 00:00:00 EST 2018}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.tca.2017.12.027
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 19 works
Citation information provided by
Web of Science

Figures / Tables:

Fig. 1 Fig. 1: Thermograms of Li2CuO2 sample treated under different carbon oxide atmospheres: (A) CO2 and CO2-O2, (B) CO and CO-O2.
All figures and tables (9 total)
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Adsorbent Materials for Carbon Dioxide Capture from Large Anthropogenic Point Sources
journal, September 2009

  • Choi, Sunho; Drese, Jeffrey H.; Jones, Christopher W.
  • ChemSusChem, Vol. 2, Issue 9, p. 796-854
  • DOI: 10.1002/cssc.200900036

A review on solid adsorbents for carbon dioxide capture
journal, March 2015

Novel lithium-based sorbents from fly ashes for CO2 capture at high temperatures
journal, July 2010

  • Olivares-Marín, M.; Drage, T. C.; Maroto-Valer, M. Mercedes
  • International Journal of Greenhouse Gas Control, Vol. 4, Issue 4
  • DOI: 10.1016/j.ijggc.2009.12.015

CO2 capture by solid adsorbents and their applications: current status and new trends
journal, January 2011

  • Wang, Qiang; Luo, Jizhong; Zhong, Ziyi
  • Energy Environ. Sci., Vol. 4, Issue 1
  • DOI: 10.1039/C0EE00064G

High CO 2 Chemisorption in α-Li 5 AlO 4 at Low Temperatures (30–80 °C): Effect of the Water Vapor Addition
journal, December 2011

  • Ávalos-Rendón, Tatiana L.; Pfeiffer, Heriberto
  • Energy & Fuels, Vol. 26, Issue 5
  • DOI: 10.1021/ef3004416

Preparation and CO2 capture properties of nanocrystalline Li2ZrO3 via an epoxide-mediated sol–gel process
journal, October 2016

  • Guo, Xingzhong; Ding, Li; Ren, Jing
  • Journal of Sol-Gel Science and Technology, Vol. 81, Issue 3
  • DOI: 10.1007/s10971-016-4233-7

Effects of porous carbon additives on the CO2 absorption performance of lithium orthosilicate
journal, August 2016

Experimental study on CO2 capture mechanisms using Na2ZrO3 sorbents synthesized by soft chemistry method
journal, April 2017

Enhanced Sorption Cycle Stability and Kinetics of CO 2 on Lithium Silicates Using the Lithium Ion Channeling Effect of TiO 2 Nanotubes
journal, March 2017

  • Lee, Joo Sung; Yavuz, Cafer T.
  • Industrial & Engineering Chemistry Research, Vol. 56, Issue 12
  • DOI: 10.1021/acs.iecr.6b04918

High-Capacity Li 4 SiO 4 -Based CO 2 Sorbents via a Facile Hydration–NaCl Doping Technique
journal, May 2017

Ultrafast Carbon Dioxide Sorption Kinetics Using Lithium Silicate Nanowires
journal, May 2017

Alkali promoted lithium orthosilicate for CO2 capture at high temperature and low concentration
journal, September 2013

CO 2 Absorption Studies on Mixed Alkali Orthosilicates Containing Rare-Earth Second-Phase Additives
journal, February 2015

  • Subha, P. V.; Nair, Balagopal N.; Hareesh, P.
  • The Journal of Physical Chemistry C, Vol. 119, Issue 10
  • DOI: 10.1021/jp511908t

High Temperature CO 2 Sorption on Li 2 ZrO 3 Based Sorbents
journal, July 2014

  • Wang, Chao; Dou, Binlin; Song, Yongchen
  • Industrial & Engineering Chemistry Research, Vol. 53, Issue 32
  • DOI: 10.1021/ie502042p

Alkali-Doped Lithium Orthosilicate Sorbents for Carbon Dioxide Capture
journal, August 2016

Behaviors and kinetic models analysis of Li 4 SiO 4 under various CO 2 partial pressures
journal, January 2017

  • Zhang, Qi; Peng, Dong; Zhang, Sai
  • AIChE Journal, Vol. 63, Issue 6
  • DOI: 10.1002/aic.15627

Molten K2CO3-promoted high-performance Li4SiO4 sorbents at low CO2 concentrations
journal, September 2017

Analysis and perspectives concerning CO2 chemisorption on lithium ceramics using thermal analysis
journal, November 2011

  • Ortiz-Landeros, José; Ávalos-Rendón, Tatiana L.; Gómez-Yáñez, Carlos
  • Journal of Thermal Analysis and Calorimetry, Vol. 108, Issue 2
  • DOI: 10.1007/s10973-011-2063-y

The Acidic and Basic Properties of Oxides.
journal, January 1947

Analysis of the CO 2 Chemisorption in Li 5 FeO 4 , a New High Temperature CO 2 Captor Material. Effect of the CO 2 and O 2 Partial Pressures
journal, February 2017

  • Lara-García, Hugo A.; Sanchez-Camacho, Pedro; Duan, Yuhua
  • The Journal of Physical Chemistry C, Vol. 121, Issue 6
  • DOI: 10.1021/acs.jpcc.6b12431

High and efficient Li2CuO2-CO2 chemisorption using different partial pressures and enhancement produced by the oxygen addition
journal, April 2017

Effect of Oxygen Addition on the Thermokinetic Properties of CO 2 Chemisorption on Li 2 ZrO 3
journal, October 2010

  • Martínez-dlCruz, Lorena; Pfeiffer, Heriberto
  • Industrial & Engineering Chemistry Research, Vol. 49, Issue 19
  • DOI: 10.1021/ie1005417

CO Oxidation and Subsequent CO 2 Chemisorption on Alkaline Zirconates: Li 2 ZrO 3 and Na 2 ZrO 3
journal, September 2016

  • Alcántar-Vázquez, Brenda; Duan, Yuhua; Pfeiffer, Heriberto
  • Industrial & Engineering Chemistry Research, Vol. 55, Issue 37
  • DOI: 10.1021/acs.iecr.6b02257

CO Chemical Capture on Lithium Cuprate, Through a Consecutive CO Oxidation and Chemisorption Bifunctional Process
journal, February 2016

  • Lara-Garcia, Hugo; Alcántar-Vázquez, Brenda; Duan, Yuhua
  • The Journal of Physical Chemistry C, Vol. 120, Issue 7
  • DOI: 10.1021/acs.jpcc.5b11147

Bifunctional application of sodium cobaltate as a catalyst and captor through CO oxidation and subsequent CO 2 chemisorption processes
journal, January 2016

  • Vera, Elizabeth; Alcántar-Vázquez, Brenda; Duan, Yuhua
  • RSC Advances, Vol. 6, Issue 3
  • DOI: 10.1039/C5RA22749F

Biomass conversion to H 2 with substantially suppressed CO 2 formation in the presence of Group I & Group II hydroxides and a Ni/ZrO 2 catalyst
journal, January 2015

  • Stonor, Maxim R.; Ferguson, Thomas E.; Chen, Jingguang G.
  • Energy & Environmental Science, Vol. 8, Issue 6
  • DOI: 10.1039/C4EE04103H

Water steam effect during high CO 2 chemisorption in lithium cuprate (Li 2 CuO 2 ) at moderate temperatures: experimental and theoretical evidence
journal, January 2015

  • Lara-García, Hugo A.; Alcántar-Vázquez, Brenda; Duan, Yuhua
  • RSC Advances, Vol. 5, Issue 43
  • DOI: 10.1039/C5RA03580E

CO 2 chemisorption in Li 2 CuO 2 microstructurally modified by ball milling: study performed with different physicochemical CO 2 capture conditions
journal, January 2016

  • Lara-García, Hugo A.; Ramírez-Moreno, Margarita J.; Ortiz-Landeros, José
  • RSC Advances, Vol. 6, Issue 63
  • DOI: 10.1039/C6RA06895B

Synthesis and CO 2 Absorption Properties of Single-phase Li 2 CuO 2 as a CO 2 Absorbent
journal, September 2010

  • Matsukura, Yusuke; Okumura, Takeshi; Kobayashi, Ryota
  • Chemistry Letters, Vol. 39, Issue 9
  • DOI: 10.1246/cl.2010.966

Fundamental research on gas–solid reaction between CO2 and Li2CuO2 linking application for solid CO2 absorbent
journal, March 2014

  • Oh-ishi, Katsuyoshi; Matsukura, Yusuke; Okumura, Takeshi
  • Journal of Solid State Chemistry, Vol. 211
  • DOI: 10.1016/j.jssc.2013.12.018

Lithium Cuprate (Li 2 CuO 2 ): A New Possible Ceramic Material for CO 2 Chemisorption
journal, August 2008

  • Palacios-Romero, Luis M.; Pfeiffer, Heriberto
  • Chemistry Letters, Vol. 37, Issue 8
  • DOI: 10.1246/cl.2008.862

Structural Analysis and CO 2 Chemisorption Study on Nonstoichiometric Lithium Cuprates (Li 2+ x CuO 2+ x /2 )
journal, December 2008

  • Palacios-Romero, Luis M.; Lima, Enrique; Pfeiffer, Heriberto
  • The Journal of Physical Chemistry A, Vol. 113, Issue 1
  • DOI: 10.1021/jp808521f

Crystal and magnetic structure of Li2CuO2
journal, May 1990

Thermal and carbothermic decomposition of Na2CO3 and Li2CO3
journal, February 2001

Decomposition of Li2CO3 by Interaction with SiO2 in Mold Flux of Steel Continuous Casting
journal, January 2004

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Enhancing CO 2 chemisorption on lithium cuprate (Li 2 CuO 2 ) at moderate temperatures and different pressures by alkaline nitrate addition
    journal, January 2020

    • Yañez-Aulestia, Ana; Wang, Qiang; Pfeiffer, Heriberto
    • Physical Chemistry Chemical Physics, Vol. 22, Issue 5
    • DOI: 10.1039/c9cp05512f

    CO2–CO capture and kinetic analyses of sodium cobaltate under various partial pressures
    journal, September 2019

    Pentalithium Ferrite (Li5FeO4) as Highly Active Material for Hydrogen Production in the Chemical Looping Partial Oxidation of Methane
    journal, May 2019

    • Hernández-Fontes, Carlos; Mendoza-Nieto, J. Arturo; Lara-García, Hugo A.
    • Topics in Catalysis, Vol. 62, Issue 12-16
    • DOI: 10.1007/s11244-019-01175-0
      Sort by:
      [ × clear filter / sort ]

      Figures / Tables found in this record:

      Fig. 1 (p. 7)figure
      Fig. 2 (p. 9)figure
      Fig. 3 (p. 11)figure
      Fig. 4 (p. 13)figure
      Fig. 5 (p. 14)figure
      Fig. 6 (p. 16)figure
      Fig. 7 (p. 17)figure
      Fig. 8 (p. 18)figure
      Fig. 9 (p. 19)figure
        [ × clear filter / sort ]
        Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

        Similar Records in DOE PAGES and OSTI.GOV collections: