Reversible Electrochemical Lithium-Ion Insertion into the Rhenium Cluster Chalcogenide–Halide Re6Se8Cl2

Bruck, Andrea M.; Yin, Jiefu; Tong, Xiao; Takeuchi, Esther S.; Takeuchi, Kenneth J.; Szczepura, Lisa F.; Marschilok, Amy C.

doi:10.1021/acs.inorgchem.8b00499

Title: Reversible Electrochemical Lithium-Ion Insertion into the Rhenium Cluster Chalcogenide–Halide Re₆Se₈Cl₂

Full Record
Other Related Research

Abstract

The cluster-based material Re₆Se₈Cl₂ is a two-dimensional ternary material with cluster–cluster bonding across the a and b axes capable of multiple electron transfer accompanied by ion insertion across the c axis. The Li/Re₆Se₈Cl₂ system showed reversible electron transfer from 1 to 3 electron equivalents (ee) at high current densities (88 mA/g). Upon cycling to 4 ee, there was evidence of capacity degradation over 50 cycles associated with the formation of an organic solid–electrolyte interface (between 1.45 and 1 V vs Li/Li⁺). Furthermore, this investigation highlights the ability of cluster-based materials with two-dimensional cluster bonding to be used in applications such as energy storage, showing structural stability and high rate capability.

Authors:

Bruck, Andrea M. ^[1]; Yin, Jiefu ^[1]; Tong, Xiao ^[2];

^[3];

^[1]; Szczepura, Lisa F. ^[4];

^[1]

Stony Brook Univ., Stony Brook, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)
Stony Brook Univ., Stony Brook, NY (United States); Brookhaven National Lab. (BNL), Upton, NY (United States)
Illinois State Univ., Normal, IL (United States)

Publication Date:: Thu Apr 26 00:00:00 EDT 2018

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2mt); Brookhaven National Lab. (BNL), Upton, NY (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1460824

Report Number(s):: BNL-207856-2018-JAAM
Journal ID: ISSN 0020-1669

Grant/Contract Number:: SC0012704

Resource Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Volume: 57; Journal Issue: 9; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Bruck, Andrea M., Yin, Jiefu, Tong, Xiao, Takeuchi, Esther S., Takeuchi, Kenneth J., Szczepura, Lisa F., and Marschilok, Amy C. Reversible Electrochemical Lithium-Ion Insertion into the Rhenium Cluster Chalcogenide–Halide Re6Se8Cl2.  United States: N. p., 2018. 
Web.  doi:10.1021/acs.inorgchem.8b00499.

Copy to clipboard


                    Bruck, Andrea M., Yin, Jiefu, Tong, Xiao, Takeuchi, Esther S., Takeuchi, Kenneth J., Szczepura, Lisa F., & Marschilok, Amy C. Reversible Electrochemical Lithium-Ion Insertion into the Rhenium Cluster Chalcogenide–Halide Re6Se8Cl2.  United States.  https://doi.org/10.1021/acs.inorgchem.8b00499

Copy to clipboard


                    Bruck, Andrea M., Yin, Jiefu, Tong, Xiao, Takeuchi, Esther S., Takeuchi, Kenneth J., Szczepura, Lisa F., and Marschilok, Amy C. Thu .  
"Reversible Electrochemical Lithium-Ion Insertion into the Rhenium Cluster Chalcogenide–Halide Re6Se8Cl2".  United States.  https://doi.org/10.1021/acs.inorgchem.8b00499.  https://www.osti.gov/servlets/purl/1460824.

Copy to clipboard


                    
@article{osti_1460824,

  title        = {Reversible Electrochemical Lithium-Ion Insertion into the Rhenium Cluster Chalcogenide–Halide Re6Se8Cl2},

  author       = {Bruck, Andrea M. and Yin, Jiefu and Tong, Xiao and Takeuchi, Esther S. and Takeuchi, Kenneth J. and Szczepura, Lisa F. and Marschilok, Amy C.},

  abstractNote = {The cluster-based material Re6Se8Cl2 is a two-dimensional ternary material with cluster–cluster bonding across the a and b axes capable of multiple electron transfer accompanied by ion insertion across the c axis. The Li/Re6Se8Cl2 system showed reversible electron transfer from 1 to 3 electron equivalents (ee) at high current densities (88 mA/g). Upon cycling to 4 ee, there was evidence of capacity degradation over 50 cycles associated with the formation of an organic solid–electrolyte interface (between 1.45 and 1 V vs Li/Li+). Furthermore, this investigation highlights the ability of cluster-based materials with two-dimensional cluster bonding to be used in applications such as energy storage, showing structural stability and high rate capability.},

  doi          = {10.1021/acs.inorgchem.8b00499},

  journal      = {Inorganic Chemistry},

  number       = 9,

  volume       = 57,

  place        = {United States},

  year         = {Thu Apr 26 00:00:00 EDT 2018},

  month        = {Thu Apr 26 00:00:00 EDT 2018}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1021/acs.inorgchem.8b00499

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 6 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Similar Records in DOE PAGES and OSTI.GOV collections:

X-ray diffraction investigation and vibrational spectra of the cluster (Re/sub 6/(micro/sub 3/-Se)/sub 4/ (micro/sub 3/-Cl)/sub 4/)Cl/sub 6/

Journal Article Fedorov, V E ; Gubin, S P ; Kolesov, B A ; ... - Sov. J. Coordinat. Chem.; (United States)

An x-ray diffraction investigation has been carried out, and the vibrational spectra have been obtained for the rhenium chloride selenide with the formula Re/sub 3/Se/sub 2/C1/sub 5/ (I), which was synthesized by a gas-transport reaction. The crystals of compound I are triclinic, and at -120/sup 0/C, a = 8.829, b = 8.928, c = 12.591 A, ..cap alpha.. = 83.30, ..beta.. = 84.59, ..gamma.. = 82.10/sup 0/, the space group is P1, and Z = 2 (diffractometer), ..gamma..Mo, 3219 reflections, R = 0.084). The structure of compound I corresponds to the doubled formula Re/sub 6/(..mu../sub 3/-Se)/sub 4/(..mu../sub 3/-Cl)/sub 4/Cl/sub 6/,more »« less
Oxygen atom transfer between rhenium, sulfur, and phosphorus. Characterization and reactivity of Re(O)Cl/sub 3/(Me/sub 2/S)(OPPh/sub 3/) and Re(O)Cl/sub 3/(CNCMe/sub 3/)/sub 2/

Journal Article Bryan, J C ; Stenkamp, R E ; Tulip, T H ; ... - Inorg. Chem.; (United States)

Re(O)Cl/sub 3/(PPh/sub 3/)/sub 2/ (I) reacts with Me/sub 2/SO to form OPPh/sub 3/ and Re(O)Cl/sub 3/(Me/sub 2/S)(OPPh/sub 3/) (II), not Re(O)Cl/sub 3/(Me/sub 2/SO)(PPh/sub 3/) as had been previously reported. Compounds I and II are catalysts for oxygen atom transfer from Me/sub 2/SO to PPh/sub 3/. The mechanism of these oxygen atom transfer reactions has been studied with oxygen-18 labeling experiments. The rhenium oxo group does not appear to be involved; rather, the rhenium center acts as a Lewis acid activator for a Me/sub 2/SO ligand. The rhenium oxo group does, however, exchange oxygen atoms with Me/sub 2/S/sup 18/O, probably bymore »« less
https://doi.org/10.1021/ic00261a024
Synthesis and characterization of rhenium thiolate complexes. Crystal and molecular structures of [NBu{sub 4}][ReO(H{sub 2}O)Br{sub 4}]{center_dot}2H{sub 2}O, [Bu{sub 4}N][ReOBr{sub 4}(OPPh{sub 3})], [ReO(SC{sub 5}H{sub 4}N){sub 3}], [ReO(SC{sub 4}H{sub 3}N{sub 2}){sub 3}][ReO(OH)(SC{sub 5}H{sub 4}N-3,6-(SiMe{sub 2}Bu{sup t}){sub 2}){sub 2}], [Re(N{sub 2}COC{sub 6}H{sub 5})(SC{sub 5}H{sub 4}N)Cl(PPh{sub 3}){sub 2}], and [Re(PPh{sub 3})(SC{sub 4}H{sub 3}N{sub 2}){sub 3}]

Journal Article Rose, D J ; Maresca, K P ; Kettler, P B - Inorganic Chemistry

The syntheses and characterization of six monomeric rhenium thiolate complexes and the structural characterization of two useful rhenium starting materials are presented. Pyridine-2-thiol (2), 3,6-bis(dimethyl-tert-butylsilyl)pyridine-2-thiol (3), and pyrimidine-2-thiol (4) were reacted with [Bu{sub 4}N][ReOBr{sub 4}(H{sub 2}O)]{center_dot}2H{sub 2}O (5), [Bu{sub 4}N][ReOBr{sub 4}(OPPh{sub 3})] (6), [ReO{sub 2}(C{sub 5}H{sub 5}N){sub 4}], and [Re(N{sub 2}CO(C{sub 6}H{sub 5}))Cl{sub 2}(PPh{sub 3}){sub 2}] to give [ReO(C{sub 5}H{sub 4}NS){sub 3}] (7), [ReO(C{sub 8}H{sub 12}NSiS){sub 3}] (8), [ReO(OH)(C{sub 11}H{sub 20}NSi{sub 2}S){sub 2}] (9), [Re(N{sub 2}-CO(C{sub 6}H{sub 5}))Cl(PPh{sub 3}){sub 2}(C{sub 5}H{sub 4}NS)] (10), [ReO(C{sub 4}H{sub 3}N{sub 2}S){sub 3}] (11), and [Re(P(C{sub 6}H{sub 5}){sub 3})(C{sub 4}H{sub 3}N{sub 2}S){sub 3}] (12). Crystalmore »« less
https://doi.org/10.1021/ic950881o
Spectroscopic and theoretical studies of metal cluster complexes. 1. The He(I)photoelectron spectrum of Re/sub 3/Cl/sub 9/. Calculations by the SCC DV X. cap alpha. method of Re/sub 3/Cl/sub 9/ and Re/sub 2/Cl/sub 8//sup 2 -/

Journal Article Trogler, W C ; Ellis, D E ; Berkowitz, J - J. Am. Chem. Soc.; (United States)

The gas-phase photoelectron spectrum of Re/sub 3/Cl/sub 9/ has been measured at ca. 800/sup 0/K. The first vertical ionization potential occurs at 8.85 eV. Results of a discrete variational Hartree-Fock-Slater calculation suggest that this ionization be attributed to a /sup 2/E'' state. Spin-orbit splitting of the first ionization band also supports this assignment. Charge density contributions to this orbital are distributed over the Re 5d, bridging Cl 3p, and axial Cl 3p orbitals in a 5:2:3 ratio. Remaining features in the photoelectron spectrum and the proposed orbital assignments are as follows: 9.80 eV, 22e''; 9.90 eV, 18a/sub 2/'', 12a/sub 2/',more »« less
https://doi.org/10.1021/ja00514a005
Structural studies of single crystals of Chevrel phase selenides REMo{sub 6}Se{sub 8} (RE = La, Ce, Pr, Nd, or Sm) at 298 K

Journal Article Berre, F Le ; Hamard, C ; Pena, O ; ... - Inorganic Chemistry

The authors report on structural studies at room temperature of rare-earth based Chevrel phase selenides of the formula RE{sub x}Mo{sub 6}Se{sub 8}, where RE stands for a light rare-earth La (1), Ce (2), Pr (3), Nd (4), or Sm (5). The single crystals were grown at 1,650 C < T < 1,690 C from off-stoichiometric starting compositions, with the exception of 3, which was grown at 1,710 C from a stoichiometric charge (congruently melting material). The crystal structures were solved in space group R{bar 3} (No. 148; Z = 1) and found to be isostructural with the well-known Chevrel phasesmore »« less
https://doi.org/10.1021/ic990762z

Similar Records

Title: Reversible Electrochemical Lithium-Ion Insertion into the Rhenium Cluster Chalcogenide–Halide Re6Se8Cl2

Abstract

Citation Formats

Title: Reversible Electrochemical Lithium-Ion Insertion into the Rhenium Cluster Chalcogenide–Halide Re₆Se₈Cl₂