Correction to Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers

An, Litao; Wang, Hao; Teat, Simon J.; Xu, Feng; Wang, Xin-Long; Wang, Fangming; Li, Jing

doi:10.1021/acs.inorgchem.6b02919

Title: Correction to Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers

Abstract

In the present work we report the design, synthesis, crystal structure determination, and adsorption properties of two new cadmium-based porous coordination polymers, [Cd(pda)0.5(spiro-4-py)0.5(HCOO)]•2H2O•DMF (compound 1, pda = p-phenylenediacetate, spiro- 4-py = (2,2’,7,7’-tetra(pyridin-4-yl)-9,9’-spirobi[fluorene], DMF = N,N’-dimethylformamide) and [Cd2(pda)(spiro-4-py)(CH3COO)2]•DMA (compound 2, DMA = N,N’-dimethylacetamide) with similar structures. The coordination between cadmium and two organic linkers, pda and spiro-4-py, has yielded two-dimensional frameworks with rhombic openings. Stacking of these two-dimensional networks does not block the openings but rather results in permanent porosity with one-dimensional channels in the final structures. The permanent porosity of these compounds is confirmed by gas adsorption measurements. Compounds 1 and 2 have BET (Brunauer-Emmett-Teller) surface areas of 687 and 584 m²/g, respectively. Both compounds show favorable adsorption towards carbon dioxide over other light gases such as nitrogen, oxygen, and carbon monoxide. IAST (Ideal adsorbed solution theory) is employed to predict the adsorption selectivity of binary gas mixtures. Though compounds 1 and 2 possess similar structures, differences are observed in their gas adsorption behaviors, which can be attributed to their different terminal ligands of formate and acetate, respectively. Strikingly, both compounds show exceptionally high stability in aqueous media with a wide pH range, a characteristic that is highly desirable formore »« less

Authors:

An, Litao ^[1]; Wang, Hao ^[2]; Teat, Simon J. ^[3]; Xu, Feng ^[2]; Wang, Xin-Long ^[2]; Wang, Fangming ^[2];

^[2]

Huaiyin Normal Univ., Huaian (China). Jiangsu Key Lab. for Chemistry of Low-Dimensional Materials, College of Chemistry and Chemical Engineering; Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology
Rutgers Univ., Piscataway, NJ (United States). Dept. of Chemistry and Chemical Biology
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source (ALS)

Publication Date:: Wed Dec 14 00:00:00 EST 2016

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1459381

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Inorganic Chemistry

Additional Journal Information:: Journal Volume: 56; Journal Issue: 1; Journal ID: ISSN 0020-1669

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    An, Litao, Wang, Hao, Teat, Simon J., Xu, Feng, Wang, Xin-Long, Wang, Fangming, and Li, Jing. Correction to Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers.  United States: N. p., 2016. 
Web.  doi:10.1021/acs.inorgchem.6b02919.

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                    An, Litao, Wang, Hao, Teat, Simon J., Xu, Feng, Wang, Xin-Long, Wang, Fangming, & Li, Jing. Correction to Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers.  United States.  https://doi.org/10.1021/acs.inorgchem.6b02919

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                    An, Litao, Wang, Hao, Teat, Simon J., Xu, Feng, Wang, Xin-Long, Wang, Fangming, and Li, Jing. Wed .  
"Correction to Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers".  United States.  https://doi.org/10.1021/acs.inorgchem.6b02919.  https://www.osti.gov/servlets/purl/1459381.

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@article{osti_1459381,

  title        = {Correction to Selective Carbon Dioxide Adsorption by Two Robust Microporous Coordination Polymers},

  author       = {An, Litao and Wang, Hao and Teat, Simon J. and Xu, Feng and Wang, Xin-Long and Wang, Fangming and Li, Jing},

  abstractNote = {In the present work we report the design, synthesis, crystal structure determination, and adsorption properties of two new cadmium-based porous coordination polymers, [Cd(pda)0.5(spiro-4-py)0.5(HCOO)]•2H2O•DMF (compound 1, pda = p-phenylenediacetate, spiro- 4-py = (2,2’,7,7’-tetra(pyridin-4-yl)-9,9’-spirobi[fluorene], DMF = N,N’-dimethylformamide) and [Cd2(pda)(spiro-4-py)(CH3COO)2]•DMA (compound 2, DMA = N,N’-dimethylacetamide) with similar structures. The coordination between cadmium and two organic linkers, pda and spiro-4-py, has yielded two-dimensional frameworks with rhombic openings. Stacking of these two-dimensional networks does not block the openings but rather results in permanent porosity with one-dimensional channels in the final structures. The permanent porosity of these compounds is confirmed by gas adsorption measurements. Compounds 1 and 2 have BET (Brunauer-Emmett-Teller) surface areas of 687 and 584 m2/g, respectively. Both compounds show favorable adsorption towards carbon dioxide over other light gases such as nitrogen, oxygen, and carbon monoxide. IAST (Ideal adsorbed solution theory) is employed to predict the adsorption selectivity of binary gas mixtures. Though compounds 1 and 2 possess similar structures, differences are observed in their gas adsorption behaviors, which can be attributed to their different terminal ligands of formate and acetate, respectively. Strikingly, both compounds show exceptionally high stability in aqueous media with a wide pH range, a characteristic that is highly desirable for gas separation-related applications. The robustness of these structures suggests that the use of hydrophobic spiro based multipyridine ligands can lead to water stable frameworks built on late-transition metals that are otherwise sensitive to moisture.},

  doi          = {10.1021/acs.inorgchem.6b02919},

  journal      = {Inorganic Chemistry},

  number       = 1,

  volume       = 56,

  place        = {United States},

  year         = {Wed Dec 14 00:00:00 EST 2016},

  month        = {Wed Dec 14 00:00:00 EST 2016}

}

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https://doi.org/10.1021/acs.inorgchem.6b02919

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Table 1: Crystal Data for compounds 1 and 2

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