Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes

Garrick, Taylor R.; Higa, Kenneth; Wu, Shao-Ling; Dai, Yiling; Huang, Xinyu; Srinivasan, Venkat; Weidner, John W.

doi:10.1149/2.0621711jes

Title: Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes

Abstract

Simulations are presented that result from incorporating dimensional and porosity changes in porous electrodes caused by volume changes in the active material during intercalation into a detailed lithium-ion battery model. Porosity and dimensional changes in an electrode can significantly affect the resistance of the battery during cycling, which in turn alters the reaction distributions in the porous electrodes. In addition, volume changes generate stresses in the electrode which can lead to premature failure of the battery. Material conservation equations are coupled with the mechanical properties of porous electrodes to link dimensional and porosity changes to stresses and the resulting resistances that occur during the intercalation processes. Through the use of porous rock mechanics, porosity and strain gradients can be predicted based on state of discharge and discharge rate. Several different battery casings and discharge rates are examined and operating curves are predicted.

Authors:

Garrick, Taylor R. ^[1]; Higa, Kenneth ^[2]; Wu, Shao-Ling ^[2]; Dai, Yiling ^[2]; Huang, Xinyu ^[3]; Srinivasan, Venkat ^[4]; Weidner, John W. ^[5]

Univ. of South Carolina, Columbia, SC (United States). Hydrogen and Fuel Cell Center; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Electrochemical Technologies Group
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Electrochemical Technologies Group
Univ. of South Carolina, Columbia, SC (United States). Dept. of Mechanical Engineering
Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Electrochemical Technologies Group; Argonne National Lab. (ANL), Argonne, IL (United States). Argonne Collaborative Center for Energy Storage Science
Univ. of South Carolina, Columbia, SC (United States). Hydrogen and Fuel Cell Center

Publication Date:: Fri Jul 21 00:00:00 EDT 2017

Research Org.:: Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

OSTI Identifier:: 1459379

Grant/Contract Number:: AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Volume: 164; Journal Issue: 11; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; battery; intercalation; modeling; porous electrodes; volume change

Citation Formats


                    Garrick, Taylor R., Higa, Kenneth, Wu, Shao-Ling, Dai, Yiling, Huang, Xinyu, Srinivasan, Venkat, and Weidner, John W. Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes.  United States: N. p., 2017. 
Web.  doi:10.1149/2.0621711jes.

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                    Garrick, Taylor R., Higa, Kenneth, Wu, Shao-Ling, Dai, Yiling, Huang, Xinyu, Srinivasan, Venkat, & Weidner, John W. Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes.  United States.  https://doi.org/10.1149/2.0621711jes

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                    Garrick, Taylor R., Higa, Kenneth, Wu, Shao-Ling, Dai, Yiling, Huang, Xinyu, Srinivasan, Venkat, and Weidner, John W. Fri .  
"Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes".  United States.  https://doi.org/10.1149/2.0621711jes.  https://www.osti.gov/servlets/purl/1459379.

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@article{osti_1459379,

  title        = {Modeling Battery Performance Due to Intercalation Driven Volume Change in Porous Electrodes},

  author       = {Garrick, Taylor R. and Higa, Kenneth and Wu, Shao-Ling and Dai, Yiling and Huang, Xinyu and Srinivasan, Venkat and Weidner, John W.},

  abstractNote = {Simulations are presented that result from incorporating dimensional and porosity changes in porous electrodes caused by volume changes in the active material during intercalation into a detailed lithium-ion battery model. Porosity and dimensional changes in an electrode can significantly affect the resistance of the battery during cycling, which in turn alters the reaction distributions in the porous electrodes. In addition, volume changes generate stresses in the electrode which can lead to premature failure of the battery. Material conservation equations are coupled with the mechanical properties of porous electrodes to link dimensional and porosity changes to stresses and the resulting resistances that occur during the intercalation processes. Through the use of porous rock mechanics, porosity and strain gradients can be predicted based on state of discharge and discharge rate. Several different battery casings and discharge rates are examined and operating curves are predicted.},

  doi          = {10.1149/2.0621711jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 11,

  volume       = 164,

  place        = {United States},

  year         = {Fri Jul 21 00:00:00 EDT 2017},

  month        = {Fri Jul 21 00:00:00 EDT 2017}

}

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https://doi.org/10.1149/2.0621711jes

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Electric Motor Design of General Motors’ Chevrolet Bolt Electric Vehicle
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Momen, Faizul; Rahman, Khwaja M.; Son, Yochan
SAE International Journal of Alternative Powertrains, Vol. 5, Issue 2
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Stress and Strain in Silicon Electrode Models
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Higa, Kenneth; Srinivasan, Venkat
Journal of The Electrochemical Society, Vol. 162, Issue 6
DOI: 10.1149/2.0091507jes