Heavy ion irradiations on synthetic hollandite-type materials: Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al)
Abstract
The hollandite supergroup of minerals has received considerable attention as a nuclear waste form for immobilization of Cs. Here, the radiation stability of synthetic hollandite-type compounds described generally as Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al) were evaluated by heavy ion (Kr) irradiations on polycrystalline single phase materials and multiphase materials incorporating the hollandite phases. Ion irradiation damage effects on these samples were examined using grazing incidence X-ray diffraction (GIXRD) and transmission electron microscopy (TEM). Single phase compounds possess tetragonal structure with space group I4/m. GIXRD and TEM observations revealed that 600 keV Kr irradiation-induced amorphization on single phase hollandites compounds occurred at a fluence between 2.5×1014 Kr/cm2 and 5×1014 Kr/cm2. The critical amorphization fluence of single phase hollandite compounds obtained by in situ 1 MeV Kr ion irradiation was around 3.25×1014 Kr/cm2. The hollandite phase exhibited similar amorphization susceptibility under Kr ion irradiation when incorporated into a multiphase system.
- Authors:
-
[1];
[1];
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Alfred Univ., NY (United States). Kazuo Inamori School of Engineering and the New York State College of Ceramics
- Savannah River National Lab (SRNL), Aiken, SC (United States). Materials Science and Technology Directorate
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Univ. of New Mexico, Albuquerque, NM (United States). TEM Lab.
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Sandia National Lab. (SNL-NM), Albuquerque, NM (United States); Savannah River National Laboratory (SRNL), Aiken, SC (United States); Argonne National Laboratory (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5); USDOE National Nuclear Security Administration (NNSA); Kyocera Corp., Kyoto (Japan)
- Contributing Org.:
- Idaho National Laboratory (INL), Idaho Falls, ID (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- OSTI Identifier:
- 1458922
- Alternate Identifier(s):
- OSTI ID: 1337199
- Report Number(s):
- LA-UR-15-29651
Journal ID: ISSN 0022-4596; TRN: US1901522
- Grant/Contract Number:
- AC52-06NA25396; AC04-94AL85000; AC02–06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of Solid State Chemistry
- Additional Journal Information:
- Journal Volume: 239; Journal Issue: C; Journal ID: ISSN 0022-4596
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE WASTES FROM NUCLEAR FACILITIES; Hollandite; Amorphization; Radiation damage
Citation Formats
Tang, Ming, Tumurugoti, Priyatham, Clark, Braeden, Sundaram, S. K., Amoroso, Jake, Marra, James, Sun, Cheng, Lu, Ping, Wang, Yongqiang, and Jiang, Ying. -Bing. Heavy ion irradiations on synthetic hollandite-type materials: Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al). United States: N. p., 2016.
Web. doi:10.1016/j.jssc.2016.04.014.
Tang, Ming, Tumurugoti, Priyatham, Clark, Braeden, Sundaram, S. K., Amoroso, Jake, Marra, James, Sun, Cheng, Lu, Ping, Wang, Yongqiang, & Jiang, Ying. -Bing. Heavy ion irradiations on synthetic hollandite-type materials: Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al). United States. https://doi.org/10.1016/j.jssc.2016.04.014
Tang, Ming, Tumurugoti, Priyatham, Clark, Braeden, Sundaram, S. K., Amoroso, Jake, Marra, James, Sun, Cheng, Lu, Ping, Wang, Yongqiang, and Jiang, Ying. -Bing. Tue .
"Heavy ion irradiations on synthetic hollandite-type materials: Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al)". United States. https://doi.org/10.1016/j.jssc.2016.04.014. https://www.osti.gov/servlets/purl/1458922.
@article{osti_1458922,
title = {Heavy ion irradiations on synthetic hollandite-type materials: Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al)},
author = {Tang, Ming and Tumurugoti, Priyatham and Clark, Braeden and Sundaram, S. K. and Amoroso, Jake and Marra, James and Sun, Cheng and Lu, Ping and Wang, Yongqiang and Jiang, Ying. -Bing.},
abstractNote = {The hollandite supergroup of minerals has received considerable attention as a nuclear waste form for immobilization of Cs. Here, the radiation stability of synthetic hollandite-type compounds described generally as Ba1.0Cs0.3A2.3Ti5.7O16 (A=Cr, Fe, Al) were evaluated by heavy ion (Kr) irradiations on polycrystalline single phase materials and multiphase materials incorporating the hollandite phases. Ion irradiation damage effects on these samples were examined using grazing incidence X-ray diffraction (GIXRD) and transmission electron microscopy (TEM). Single phase compounds possess tetragonal structure with space group I4/m. GIXRD and TEM observations revealed that 600 keV Kr irradiation-induced amorphization on single phase hollandites compounds occurred at a fluence between 2.5×1014 Kr/cm2 and 5×1014 Kr/cm2. The critical amorphization fluence of single phase hollandite compounds obtained by in situ 1 MeV Kr ion irradiation was around 3.25×1014 Kr/cm2. The hollandite phase exhibited similar amorphization susceptibility under Kr ion irradiation when incorporated into a multiphase system.},
doi = {10.1016/j.jssc.2016.04.014},
journal = {Journal of Solid State Chemistry},
number = C,
volume = 239,
place = {United States},
year = {Tue Apr 12 00:00:00 EDT 2016},
month = {Tue Apr 12 00:00:00 EDT 2016}
}
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Works referencing / citing this record:
Atomistic scale investigation of cation ordering and phase stability in Cs-substituted Ba1.33Zn1.33Ti6.67O16, Ba1.33Ga2.66Ti5.67O16 and Ba1.33Al2.66Ti5.33O16 hollandite
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