Experimental and theoretical studies of laser-induced breakdown spectroscopy emission from iron oxide: Studies of atmospheric effects
Abstract
In this paper, we report on a comprehensive study of the emission spectra from laser-induced breakdown spectroscopy (LIBS) measurements on iron oxide. Measurements have been made of the emission from Fe2O3 under atmospheres of air, He, and Ar, and at different atmospheric pressures. The effect of varying the time delay of the measurement is also explored. Theoretical calculations were performed to analyze the plasma conditions and find that a reasonably consistent picture of the change in plasma temperature and density for different atmospheric conditions can be reached. We also investigate the sensitivity of the OI 777 nm emission lines to the plasma conditions, something that has not been explored in detail in the previous work. In conclusion, we also show that LIBS can be used to differentiate between FeO and Fe2O3 by examining the ratio of the intensities of selected Fe emission to O emission lines.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); LANL Laboratory Directed Research and Development (LDRD) Program
- OSTI Identifier:
- 1457275
- Alternate Identifier(s):
- OSTI ID: 1430393
- Report Number(s):
- LA-UR-15-29689
Journal ID: ISSN 0584-8547
- Grant/Contract Number:
- AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Spectrochimica Acta. Part B, Atomic Spectroscopy
- Additional Journal Information:
- Journal Volume: 122; Journal ID: ISSN 0584-8547
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; LIBS; matrix effects; atomic physics; LTE modeling
Citation Formats
Colgan, J., Barefield, J. E., Judge, E. J., Campbell, K., Johns, H. M., Kilcrease, D. P., McInroy, R., and Clegg, S. M. Experimental and theoretical studies of laser-induced breakdown spectroscopy emission from iron oxide: Studies of atmospheric effects. United States: N. p., 2016.
Web. doi:10.1016/j.sab.2016.05.016.
Colgan, J., Barefield, J. E., Judge, E. J., Campbell, K., Johns, H. M., Kilcrease, D. P., McInroy, R., & Clegg, S. M. Experimental and theoretical studies of laser-induced breakdown spectroscopy emission from iron oxide: Studies of atmospheric effects. United States. https://doi.org/10.1016/j.sab.2016.05.016
Colgan, J., Barefield, J. E., Judge, E. J., Campbell, K., Johns, H. M., Kilcrease, D. P., McInroy, R., and Clegg, S. M. Thu .
"Experimental and theoretical studies of laser-induced breakdown spectroscopy emission from iron oxide: Studies of atmospheric effects". United States. https://doi.org/10.1016/j.sab.2016.05.016. https://www.osti.gov/servlets/purl/1457275.
@article{osti_1457275,
title = {Experimental and theoretical studies of laser-induced breakdown spectroscopy emission from iron oxide: Studies of atmospheric effects},
author = {Colgan, J. and Barefield, J. E. and Judge, E. J. and Campbell, K. and Johns, H. M. and Kilcrease, D. P. and McInroy, R. and Clegg, S. M.},
abstractNote = {In this paper, we report on a comprehensive study of the emission spectra from laser-induced breakdown spectroscopy (LIBS) measurements on iron oxide. Measurements have been made of the emission from Fe2O3 under atmospheres of air, He, and Ar, and at different atmospheric pressures. The effect of varying the time delay of the measurement is also explored. Theoretical calculations were performed to analyze the plasma conditions and find that a reasonably consistent picture of the change in plasma temperature and density for different atmospheric conditions can be reached. We also investigate the sensitivity of the OI 777 nm emission lines to the plasma conditions, something that has not been explored in detail in the previous work. In conclusion, we also show that LIBS can be used to differentiate between FeO and Fe2O3 by examining the ratio of the intensities of selected Fe emission to O emission lines.},
doi = {10.1016/j.sab.2016.05.016},
journal = {Spectrochimica Acta. Part B, Atomic Spectroscopy},
number = ,
volume = 122,
place = {United States},
year = {Thu Jun 02 00:00:00 EDT 2016},
month = {Thu Jun 02 00:00:00 EDT 2016}
}
Web of Science
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Works referencing / citing this record:
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