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Title: Unraveling luminescence mechanisms in zero-dimensional halide perovskites

Abstract

Zero-dimensional (0D) halides perovskites, in which anionic metal-halide octahedra (MX 6 ) 4− are separated by organic or inorganic countercations, have recently shown promise as excellent luminescent materials.

Authors:
ORCiD logo [1]; ORCiD logo [2];  [3];  [4]; ORCiD logo [4];  [5]; ORCiD logo [3]; ORCiD logo [6]; ORCiD logo [3]
  1. East China Normal Univ., Shanghai (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  2. Beihang Univ., Beijing (China)
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
  4. FAMU-FSU College of Engineering, Tallahassee, FL (United States)
  5. Univ. of Oklahoma, Norman, OK (United States)
  6. East China Normal Univ., Shanghai (China)
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1456807
Alternate Identifier(s):
OSTI ID: 1439358
Grant/Contract Number:  
AC05-00OR22725
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Materials Chemistry C
Additional Journal Information:
Journal Volume: 6; Journal Issue: 24; Journal ID: ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; Halide perovskite; Luminescence; DFT calculations

Citation Formats

Han, Dan, Shi, Hongliang, Ming, Wenmei, Zhou, Chenkun, Ma, Biwu, Saparov, Bayrammurad, Ma, Ying -Zhong, Chen, Shiyou, and Du, Mao -Hua. Unraveling luminescence mechanisms in zero-dimensional halide perovskites. United States: N. p., 2018. Web. doi:10.1039/C8TC01291A.
Han, Dan, Shi, Hongliang, Ming, Wenmei, Zhou, Chenkun, Ma, Biwu, Saparov, Bayrammurad, Ma, Ying -Zhong, Chen, Shiyou, & Du, Mao -Hua. Unraveling luminescence mechanisms in zero-dimensional halide perovskites. United States. https://doi.org/10.1039/C8TC01291A
Han, Dan, Shi, Hongliang, Ming, Wenmei, Zhou, Chenkun, Ma, Biwu, Saparov, Bayrammurad, Ma, Ying -Zhong, Chen, Shiyou, and Du, Mao -Hua. Fri . "Unraveling luminescence mechanisms in zero-dimensional halide perovskites". United States. https://doi.org/10.1039/C8TC01291A. https://www.osti.gov/servlets/purl/1456807.
@article{osti_1456807,
title = {Unraveling luminescence mechanisms in zero-dimensional halide perovskites},
author = {Han, Dan and Shi, Hongliang and Ming, Wenmei and Zhou, Chenkun and Ma, Biwu and Saparov, Bayrammurad and Ma, Ying -Zhong and Chen, Shiyou and Du, Mao -Hua},
abstractNote = {Zero-dimensional (0D) halides perovskites, in which anionic metal-halide octahedra (MX 6 ) 4− are separated by organic or inorganic countercations, have recently shown promise as excellent luminescent materials.},
doi = {10.1039/C8TC01291A},
journal = {Journal of Materials Chemistry C},
number = 24,
volume = 6,
place = {United States},
year = {Fri May 18 00:00:00 EDT 2018},
month = {Fri May 18 00:00:00 EDT 2018}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 129 works
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Figures / Tables:

Figure 1 Figure 1: Structures of (a) (C4N2H14Br)4SnBr6, (b) (C4N2H14I)4SnI6, and (c) Cs4PbBr6.

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Works referenced in this record:

One-dimensional organic lead halide perovskites with efficient bluish white-light emission
journal, January 2017

  • Yuan, Zhao; Zhou, Chenkun; Tian, Yu
  • Nature Communications, Vol. 8, Issue 1
  • DOI: 10.1038/ncomms14051

Generalized Gradient Approximation Made Simple
journal, October 1996

  • Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
  • Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
  • DOI: 10.1103/PhysRevLett.77.3865

Molecular behavior of zero-dimensional perovskites
journal, December 2017

  • Yin, Jun; Maity, Partha; De Bastiani, Michele
  • Science Advances, Vol. 3, Issue 12
  • DOI: 10.1126/sciadv.1701793

Exploring Polaronic, Excitonic Structures and Luminescence in Cs 4 PbBr 6 /CsPbBr 3
journal, February 2018


Excitonic emissions and above-band-gap luminescence in the single-crystal perovskite semiconductors CsPbB r 3 and CsPbC l 3
journal, December 2015


The emergence of perovskite solar cells
journal, July 2014

  • Green, Martin A.; Ho-Baillie, Anita; Snaith, Henry J.
  • Nature Photonics, Vol. 8, Issue 7, p. 506-514
  • DOI: 10.1038/nphoton.2014.134

Low trap-state density and long carrier diffusion in organolead trihalide perovskite single crystals
journal, January 2015


Zero-Dimensional Cs 4 PbBr 6 Perovskite Nanocrystals
journal, February 2017

  • Zhang, Yuhai; Saidaminov, Makhsud I.; Dursun, Ibrahim
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 5
  • DOI: 10.1021/acs.jpclett.7b00105

Pure zero-dimensional Cs 4 PbBr 6 single crystal rhombohedral microdisks with high luminescence and stability
journal, January 2017

  • Zhang, Haihua; Liao, Qing; Wu, Yishi
  • Physical Chemistry Chemical Physics, Vol. 19, Issue 43
  • DOI: 10.1039/C7CP06097A

Two-Dimensional CH 3 NH 3 PbI 3 Perovskite Nanosheets for Ultrafast Pulsed Fiber Lasers
journal, March 2017

  • Li, Pengfei; Chen, Yao; Yang, Tieshan
  • ACS Applied Materials & Interfaces, Vol. 9, Issue 14
  • DOI: 10.1021/acsami.7b01709

A facile one-pot synthesis of deep blue luminescent lead bromide perovskite microdisks
journal, January 2015

  • Yuan, Zhao; Shu, Yu; Tian, Yu
  • Chemical Communications, Vol. 51, Issue 91
  • DOI: 10.1039/C5CC06750B

All-in-One: Achieving Robust, Strongly Luminescent and Highly Dispersible Hybrid Materials by Combining Ionic and Coordinate Bonds in Molecular Crystals
journal, June 2017

  • Liu, Wei; Zhu, Kun; Teat, Simon J.
  • Journal of the American Chemical Society, Vol. 139, Issue 27
  • DOI: 10.1021/jacs.7b04550

Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
journal, March 2016


Advances in Perovskite Solar Cells
journal, January 2016


Self-Assembly of Broadband White-Light Emitters
journal, January 2014

  • Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I.
  • Journal of the American Chemical Society, Vol. 136, Issue 5
  • DOI: 10.1021/ja411045r

Large-scale room-temperature synthesis and optical properties of perovskite-related Cs 4 PbBr 6 fluorophores
journal, January 2016

  • Chen, Daqin; Wan, Zhongyi; Chen, Xiao
  • Journal of Materials Chemistry C, Vol. 4, Issue 45
  • DOI: 10.1039/C6TC04036E

Photoresponse of CsPbBr 3 and Cs 4 PbBr 6 Perovskite Single Crystals
journal, January 2017

  • Cha, Ji-Hyun; Han, Jae Hoon; Yin, Wenping
  • The Journal of Physical Chemistry Letters, Vol. 8, Issue 3
  • DOI: 10.1021/acs.jpclett.6b02763

A Theory of Sensitized Luminescence in Solids
journal, May 1953

  • Dexter, D. L.
  • The Journal of Chemical Physics, Vol. 21, Issue 5, p. 836-850
  • DOI: 10.1063/1.1699044

Inside Perovskites: Quantum Luminescence from Bulk Cs 4 PbBr 6 Single Crystals
journal, August 2017


Sensitive X-ray detectors made of methylammonium lead tribromide perovskite single crystals
journal, March 2016


Electron-hole diffusion lengths > 175 μm in solution-grown CH 3 NH 3 PbI 3 single crystals
journal, January 2015


Shallow halogen vacancies in halide optoelectronic materials
journal, November 2014


Perovskite Materials for Light-Emitting Diodes and Lasers
journal, May 2016

  • Veldhuis, Sjoerd A.; Boix, Pablo P.; Yantara, Natalia
  • Advanced Materials, Vol. 28, Issue 32
  • DOI: 10.1002/adma.201600669

Enhanced Born charges in III-VII, IV-VII 2 , and V-VII 3 compounds
journal, July 2010


Self-Regulation Mechanism for Charged Point Defects in Hybrid Halide Perovskites
journal, December 2014

  • Walsh, Aron; Scanlon, David O.; Chen, Shiyou
  • Angewandte Chemie International Edition, Vol. 54, Issue 6
  • DOI: 10.1002/anie.201409740

Fluorescent Phase-Pure Zero-Dimensional Perovskite-Related Cs 4 PbBr 6 Microdisks: Synthesis and Single-Particle Imaging Study
journal, September 2017


Intrinsic Lead Ion Emissions in Zero-Dimensional Cs 4 PbBr 6 Nanocrystals
journal, November 2017


Zero-Dimensional Cesium Lead Halides: History, Properties, and Challenges
journal, April 2018

  • Akkerman, Quinten A.; Abdelhady, Ahmed L.; Manna, Liberato
  • The Journal of Physical Chemistry Letters, Vol. 9, Issue 9
  • DOI: 10.1021/acs.jpclett.8b00572

Intrinsic White-Light Emission from Layered Hybrid Perovskites
journal, September 2014

  • Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R.
  • Journal of the American Chemical Society, Vol. 136, Issue 38
  • DOI: 10.1021/ja507086b

Low-Dimensional Organometal Halide Perovskites
journal, November 2017


Enhanced Born charge and proximity to ferroelectricity in thallium halides
journal, April 2010


Electron-Hole Diffusion Lengths Exceeding 1 Micrometer in an Organometal Trihalide Perovskite Absorber
journal, October 2013

  • Stranks, S. D.; Eperon, G. E.; Grancini, G.
  • Science, Vol. 342, Issue 6156, p. 341-344
  • DOI: 10.1126/science.1243982

Long-Range Balanced Electron- and Hole-Transport Lengths in Organic-Inorganic CH3NH3PbI3
journal, October 2013


A Zero-Dimensional Organic Seesaw-Shaped Tin Bromide with Highly Efficient Strongly Stokes-Shifted Deep-Red Emission
journal, December 2017

  • Zhou, Chenkun; Lin, Haoran; Shi, Hongliang
  • Angewandte Chemie International Edition, Vol. 57, Issue 4
  • DOI: 10.1002/anie.201710383

Importance of Spin–Orbit Coupling in Hybrid Organic/Inorganic Perovskites for Photovoltaic Applications
journal, August 2013

  • Even, Jacky; Pedesseau, Laurent; Jancu, Jean-Marc
  • The Journal of Physical Chemistry Letters, Vol. 4, Issue 17
  • DOI: 10.1021/jz401532q

Strongly emissive perovskite nanocrystal inks for high-voltage solar cells
journal, December 2016

  • Akkerman, Quinten A.; Gandini, Marina; Di Stasio, Francesco
  • Nature Energy, Vol. 2, Issue 2
  • DOI: 10.1038/nenergy.2016.194

Pure Cs 4 PbBr 6 : Highly Luminescent Zero-Dimensional Perovskite Solids
journal, September 2016


Photoluminescence of Cs4PbBr6 crystals and thin films
journal, June 1999


Rationale for mixing exact exchange with density functional approximations
journal, December 1996

  • Perdew, John P.; Ernzerhof, Matthias; Burke, Kieron
  • The Journal of Chemical Physics, Vol. 105, Issue 22, p. 9982-9985
  • DOI: 10.1063/1.472933

Highly luminescent nanoscale quasi-2D layered lead bromide perovskites with tunable emissions
journal, January 2016

  • Yuan, Zhao; Shu, Yu; Xin, Yan
  • Chemical Communications, Vol. 52, Issue 20
  • DOI: 10.1039/C5CC09762B

Hybrid Organic-Inorganic Perovskites (HOIPs): Opportunities and Challenges
journal, July 2015

  • Berry, Joseph; Buonassisi, Tonio; Egger, David A.
  • Advanced Materials, Vol. 27, Issue 35
  • DOI: 10.1002/adma.201502294

A Zero-Dimensional Organic Seesaw-Shaped Tin Bromide with Highly Efficient Strongly Stokes-Shifted Deep-Red Emission
journal, December 2017


Self-Regulation Mechanism for Charged Point Defects in Hybrid Halide Perovskites
journal, December 2014

  • Walsh, Aron; Scanlon, David O.; Chen, Shiyou
  • Angewandte Chemie, Vol. 127, Issue 6
  • DOI: 10.1002/ange.201409740

Luminescent Materials
journal, July 1939

  • Leverenz, Humboldt W.; Seitz, Frederick
  • Journal of Applied Physics, Vol. 10, Issue 7
  • DOI: 10.1063/1.1707331

Works referencing / citing this record:

Bulk Assembly of Corrugated 1D Metal Halides with Broadband Yellow Emission
journal, December 2018

  • Lin, Haoran; Zhou, Chenkun; Neu, Jennifer
  • Advanced Optical Materials, Vol. 7, Issue 6
  • DOI: 10.1002/adom.201801474

Rb 2 CuX 3 (X = Cl, Br): 1D All‐Inorganic Copper Halides with Ultrabright Blue Emission and Up‐Conversion Photoluminescence
journal, November 2019

  • Creason, Tielyr D.; Yangui, Aymen; Roccanova, Rachel
  • Advanced Optical Materials, Vol. 8, Issue 2
  • DOI: 10.1002/adom.201901338

Single‐Solvent, Ligand‐Free, Gram‐Scale Synthesis of Cs 4 PbBr 6 Perovskite Solids with Robust Green Photoluminescence
journal, December 2019


Pressure-induced emission of cesium lead halide perovskite nanocrystals
journal, October 2018


Locally collective hydrogen bonding isolates lead octahedra for white emission improvement
journal, November 2019


Structure and optical properties of perovskite-embedded dual-phase microcrystals synthesized by sonochemistry
journal, February 2020


[DMEDA]PbCl 4 : a one-dimensional organic lead halide perovskite with efficient yellow emission
journal, January 2020

  • Sun, Chen; Yue, Yun-Di; Zhang, Wei-Feng
  • CrystEngComm, Vol. 22, Issue 8
  • DOI: 10.1039/c9ce01816f

The optical properties of Cs 4 PbBr 6 –CsPbBr 3 perovskite composites
journal, January 2019

  • Gan, Zhixing; Zheng, Fei; Mao, Wenxin
  • Nanoscale, Vol. 11, Issue 31
  • DOI: 10.1039/c9nr04787e

Highly stable hetero-structured green-emitting cesium lead bromide nanocrystals via ligand-mediated phase control
journal, January 2019

  • Grandhi, G. Krishnamurthy; Viswanath, N. S. M.; Cho, Han Bin
  • Nanoscale, Vol. 11, Issue 44
  • DOI: 10.1039/c9nr07126a

Organic cation directed hybrid lead halides of zero-dimensional to two-dimensional structures with tunable photoluminescence properties
journal, January 2019

  • Yue, Cheng-Yang; Sun, Hai-Xiao; Liu, Quan-Xiu
  • Inorganic Chemistry Frontiers, Vol. 6, Issue 10
  • DOI: 10.1039/c9qi00684b

Intrinsic doping limit and defect-assisted luminescence in Cs 4 PbBr 6
journal, January 2019

  • Jung, Young-Kwang; Calbo, Joaquín; Park, Ji-Sang
  • Journal of Materials Chemistry A, Vol. 7, Issue 35
  • DOI: 10.1039/c9ta06874k

Electronic shell structures, self-trapped excitons, and defect-bound excitons in Li 2 B 12 H 12
journal, January 2019

  • Du, Mao-Hua; Shi, Hongliang; Zhang, S. B.
  • Journal of Materials Chemistry C, Vol. 7, Issue 45
  • DOI: 10.1039/c9tc04150h

Microscopic origin of multiple exciton emission in low-dimensional lead halide perovskites
journal, November 2019

  • Du, Mao-Hua
  • The Journal of Chemical Physics, Vol. 151, Issue 18
  • DOI: 10.1063/1.5127933

Optically pumped white light-emitting diodes based on metal halide perovskites and perovskite-related materials
journal, January 2020

  • Worku, Michael; Xu, Liang-Jin; Chaaban, Maya
  • APL Materials, Vol. 8, Issue 1
  • DOI: 10.1063/1.5140441

Optical Characterization of Cesium Lead Bromide Perovskites
journal, May 2019

  • De Matteis, Fabio; Vitale, Francesco; Privitera, Simone
  • Crystals, Vol. 9, Issue 6
  • DOI: 10.3390/cryst9060280

Pressure-induced emission of cesium lead halide perovskite nanocrystals.
text, January 2018

  • Ma, Zhiwei; Liu, Zhun; Lu, Siyu
  • Apollo - University of Cambridge Repository
  • DOI: 10.17863/cam.33885

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.