Structural and magnetic transitions in spinel FeMn2O4 single crystals

Nepal, Roshan; Zhang, Qiang; Dai, Samuel; Tian, Wei; Nagler, Stephen E.; Jin, Rongying

doi:10.1103/PhysRevB.97.024410

Title: Structural and magnetic transitions in spinel $FeM n_{2} O_{4}$ single crystals

Abstract

Materials that form the spinel structure are known to exhibit geometric frustration, which can lead to magnetic frustration as well. Through magnetization and neutron diffraction measurements, we find that FeMn₂O₄ undergoes one structural and two magnetic transitions. The structural transition occurs at T_s ~595K from cubic at high temperatures to tetragonal at low temperatures. Here, two magnetic transitions are ferrimagnetic at T_FI–1 ~373K and T_FI–2 ~50K, respectively. Further investigation of the specific heat, thermal conductivity, and Seebeck coefficient confirms both magnetic transitions. Of particular interest is that there is a significant magnetic contribution to the low-temperature specific heat and thermal conductivity, providing a unique system to study heat transport by magnetic excitations.

Authors:

Nepal, Roshan ^[1]; Zhang, Qiang ^[1]; Dai, Samuel ^[1];

^[2];

^[2]; Jin, Rongying ^[1]

Louisiana State Univ., Baton Rouge, LA (United States)
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Publication Date:: Thu Jan 11 00:00:00 EST 2018

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1440814

Alternate Identifier(s):: OSTI ID: 1416624

Grant/Contract Number:: AC05-00OR22725; SC0016315; SC0012432

Resource Type:: Accepted Manuscript

Journal Name:: Physical Review B

Additional Journal Information:: Journal Volume: 97; Journal Issue: 2; Journal ID: ISSN 2469-9950

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Nepal, Roshan, Zhang, Qiang, Dai, Samuel, Tian, Wei, Nagler, Stephen E., and Jin, Rongying. Structural and magnetic transitions in spinel FeMn2O4 single crystals.  United States: N. p., 2018. 
Web.  doi:10.1103/PhysRevB.97.024410.

Copy to clipboard


                    Nepal, Roshan, Zhang, Qiang, Dai, Samuel, Tian, Wei, Nagler, Stephen E., & Jin, Rongying. Structural and magnetic transitions in spinel FeMn2O4 single crystals.  United States.  https://doi.org/10.1103/PhysRevB.97.024410

Copy to clipboard


                    Nepal, Roshan, Zhang, Qiang, Dai, Samuel, Tian, Wei, Nagler, Stephen E., and Jin, Rongying. Thu .  
"Structural and magnetic transitions in spinel FeMn2O4 single crystals".  United States.  https://doi.org/10.1103/PhysRevB.97.024410.  https://www.osti.gov/servlets/purl/1440814.

Copy to clipboard


                    
@article{osti_1440814,

  title        = {Structural and magnetic transitions in spinel FeMn2O4 single crystals},

  author       = {Nepal, Roshan and Zhang, Qiang and Dai, Samuel and Tian, Wei and Nagler, Stephen E. and Jin, Rongying},

  abstractNote = {Materials that form the spinel structure are known to exhibit geometric frustration, which can lead to magnetic frustration as well. Through magnetization and neutron diffraction measurements, we find that FeMn2O4 undergoes one structural and two magnetic transitions. The structural transition occurs at Ts ~595K from cubic at high temperatures to tetragonal at low temperatures. Here, two magnetic transitions are ferrimagnetic at TFI–1 ~373K and TFI–2 ~50K, respectively. Further investigation of the specific heat, thermal conductivity, and Seebeck coefficient confirms both magnetic transitions. Of particular interest is that there is a significant magnetic contribution to the low-temperature specific heat and thermal conductivity, providing a unique system to study heat transport by magnetic excitations.},

  doi          = {10.1103/PhysRevB.97.024410},

  journal      = {Physical Review B},

  number       = 2,

  volume       = 97,

  place        = {United States},

  year         = {Thu Jan 11 00:00:00 EST 2018},

  month        = {Thu Jan 11 00:00:00 EST 2018}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (Publisher)

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1103/PhysRevB.97.024410

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 25 works

Citation information provided by
Web of Science

Figures / Tables:

FIG. 1: (a) Crystal structure of FeMn₂O₄; (b) Powder x-ray diffraction pattern at room temperature with all peaks indexed in the I41/amd tetragonal symmetry. Inset: an as-grown single crystal with the growth direction indicated by an arrow; (c) (440)C and (404)C nuclear peaks indexed in pseudocubic notation at indicated temperaturesmore »

All figures and tables (4 total)

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Structure of Spinel
journal, December 1999

Sickafus, Kurt E.; Wills, John M.; Grimes, Norman W.
Journal of the American Ceramic Society, Vol. 82, Issue 12
DOI: 10.1111/j.1151-2916.1999.tb02241.x

Magnetic compensation, field-dependent magnetization reversal, and complex magnetic ordering in ${Co}_{2} {TiO}_{4}$
journal, December 2015

Nayak, S.; Thota, S.; Joshi, D. C.
Physical Review B, Vol. 92, Issue 21
DOI: 10.1103/PhysRevB.92.214434

Magnetic properties of MnFe2O4 nanoparticles
journal, April 2002

Balaji, G.; Gajbhiye, N. S.; Wilde, G.
Journal of Magnetism and Magnetic Materials, Vol. 242-245
DOI: 10.1016/S0304-8853(01)01043-5

Propriétés magnétiques des ferrites ; ferrimagnétisme et antiferromagnétisme
journal, January 1948

Néel, M. Louis
Annales de Physique, Vol. 12, Issue 3
DOI: 10.1051/anphys/194812030137

Phonon-Magnon Interaction in Magnetic Crystals
journal, July 1962

Sinha, K. P.; Upadhyaya, U. N.
Physical Review, Vol. 127, Issue 2
DOI: 10.1103/PhysRev.127.432

Influence of Mn by Li substitution on the Jahn–Teller distortion in LiMn2O4
journal, March 2000

Verhoeven, V. W. J.; Mulder, F. M.; de Schepper, I. M.
Physica B: Condensed Matter, Vol. 276-278
DOI: 10.1016/S0921-4526(99)01272-7

Manganites spinelles purs d'elements de transition preparations et structures cristallographiques
journal, April 1969

Buhl, Robert
Journal of Physics and Chemistry of Solids, Vol. 30, Issue 4
DOI: 10.1016/0022-3697(69)90275-3

Orbital Freezing and Orbital Glass State in $F e {C r}_{2} S_{4}$
journal, January 2005

Fichtl, R.; Tsurkan, V.; Lunkenheimer, P.
Physical Review Letters, Vol. 94, Issue 2
DOI: 10.1103/PhysRevLett.94.027601

Lattice expansion and noncollinear to collinear ferrimagnetic order in a $Mn {Cr}_{2} O_{4}$ nanoparticle
journal, April 2006

Bhowmik, R. N.; Ranganathan, R.; Nagarajan, R.
Physical Review B, Vol. 73, Issue 14
DOI: 10.1103/PhysRevB.73.144413

Cation migration, cation valencies and the cubic-tetragonal transition in MnxFe3−xO4
journal, January 1971

Brabers, V. A. M.
Journal of Physics and Chemistry of Solids, Vol. 32, Issue 9
DOI: 10.1016/S0022-3697(71)80396-7

Magnetic and Orbital Ordering in the Spinel ${MnV}_{2} O_{4}$
journal, February 2008

Garlea, V. O.; Jin, R.; Mandrus, D.
Physical Review Letters, Vol. 100, Issue 6
DOI: 10.1103/PhysRevLett.100.066404

Magnetic Spectra of Manganese Ferrites
journal, May 1958

Harrison, S. E.; Kriessman, C. J.; Pollack, S. R.
Physical Review, Vol. 110, Issue 4
DOI: 10.1103/PhysRev.110.844

Heat capacity study of the magnetic phases in a Nd5Ge3 single crystal
journal, May 2016

Villuendas, D.; Tsutaoka, T.; Hernàndez Ferràs, J. M.
Journal of Magnetism and Magnetic Materials, Vol. 405
DOI: 10.1016/j.jmmm.2016.01.005

The preparation of tetragonal single crystals in the MnxFe3−xO4 system
journal, January 1971

Brabers, V. A. M.
Journal of Crystal Growth, Vol. 8, Issue 1
DOI: 10.1016/0022-0248(71)90017-0

Cooperative Jahn–Teller effect and the role of strain in the tetragonal-to-cubic phase transition in Mg_xCu_1 − xCr₂O₄
journal, August 2016

Tarantino, Serena C.; Giannini, Mattia; Carpenter, Michael A.
IUCrJ, Vol. 3, Issue 5, p. 354-366
DOI: 10.1107/S2052252516012574

In-Plane Thermal Conductivity of ${N d}_{2} {C u O}_{4}$ : Evidence for Magnon Heat Transport
journal, October 2003

Jin, R.; Onose, Y.; Tokura, Y.
Physical Review Letters, Vol. 91, Issue 14
DOI: 10.1103/PhysRevLett.91.146601

Theoretical investigation of MnFe2O4
journal, December 2013

Elfalaky, A.; Soliman, S.
Journal of Alloys and Compounds, Vol. 580
DOI: 10.1016/j.jallcom.2013.05.197

Specific Heats at Low Temperatures
book, January 1966

Gopal, E. S. R.
DOI: 10.1007/978-1-4684-9081-7

NiFe2O4: A Versatile Spinel Material Brings New Opportunities for Spintronics
journal, July 2006

Lüders, U.; Barthélémy, A.; Bibes, M.
Advanced Materials, Vol. 18, Issue 13
DOI: 10.1002/adma.200500972

Mössbauer Effect in Mn _x Fe _{3- x} O ₄
journal, July 1963

Tanaka, Midori; Mizoguchi, Tadashi; Aiyama, Yoshimichi
Journal of the Physical Society of Japan, Vol. 18, Issue 7
DOI: 10.1143/JPSJ.18.1091

Electron, spin-wave, hyperfine, and phonon contributions to the low-temperature specific heat of ${La}_{0.65} {Ca}_{0.35} {MnO}_{3} :$ Effects of magnetic fields and $^{16} {O /}^{18} O$ exchange
journal, September 2001

Fisher, R. A.; Bouquet, F.; Phillips, N. E.
Physical Review B, Vol. 64, Issue 13
DOI: 10.1103/PhysRevB.64.134425

Lattice thermal conductivity of antiferromagnetic insulators
journal, April 1980

Dixon, G. S.
Physical Review B, Vol. 21, Issue 7
DOI: 10.1103/PhysRevB.21.2851

Magnetoelasticity in $A$ Cr $_{2}$ O $_{4}$ spinel oxides ( $A =$ Mn, Fe, Co, Ni, and Cu)
journal, February 2013

Kocsis, V.; Bordács, S.; Varjas, D.
Physical Review B, Vol. 87, Issue 6
DOI: 10.1103/PhysRevB.87.064416

Heat capacity measurements of MnxFe3−xO4
journal, January 1981

Naito, Keiji; Inaba, Hideaki; Yagi, Haruyoshi
Journal of Solid State Chemistry, Vol. 36, Issue 1
DOI: 10.1016/0022-4596(81)90188-2

Spin and Orbital Frustration in ${MnSc}_{2} S_{4}$ and ${FeSc}_{2} S_{4}$
journal, March 2004

Fritsch, V.; Hemberger, J.; Büttgen, N.
Physical Review Letters, Vol. 92, Issue 11
DOI: 10.1103/PhysRevLett.92.116401

Valence states and occupation sites in (Fe,Mn) ₃ O ₄ spinel oxides investigated by soft x-ray absorption spectroscopy and magnetic circular dichroism
journal, June 2008

Lee, H. J.; Kim, G.; Kim, D. H.
Journal of Physics: Condensed Matter, Vol. 20, Issue 29
DOI: 10.1088/0953-8984/20/29/295203

Cation valencies and distributions in spinel structures containing manganese
journal, December 1961

O'keeffe, M.
Journal of Physics and Chemistry of Solids, Vol. 21, Issue 3-4
DOI: 10.1016/0022-3697(61)90096-8

Erratum: “Co-existence of ferrimagnetism and spin-glass state in the spinel Co ₂ SnO ₄ ” [J. Appl. Phys. 113 , 203905 (2013)]
journal, September 2015

Thota, Subhash; Seehra, M. S.
Journal of Applied Physics, Vol. 118, Issue 12
DOI: 10.1063/1.4932158

Anomalous electrical properties of Mn _x Fe _{3− x} O ₄
journal, April 1987

Brabers, V. A. M.; Proykova, Y. G.; Salerno, N.
Journal of Applied Physics, Vol. 61, Issue 8
DOI: 10.1063/1.338432

Ordering process and ferroelectricity in a spinel derived from FeV $_{2}$ O $_{4}$
journal, February 2012

Zhang, Q.; Singh, K.; Guillou, F.
Physical Review B, Vol. 85, Issue 5
DOI: 10.1103/PhysRevB.85.054405

Magnetic Structure of Iron Manganite by Neutron Diffraction
journal, March 1969

Boucher, B.; Buhl, R.; Perrin, M.
Journal of Applied Physics, Vol. 40, Issue 3
DOI: 10.1063/1.1657558

Infrared Spectra of Cubic and Tetragonal Manganese Ferrites
journal, January 1969

Brabers, V. A. M.
physica status solidi (b), Vol. 33, Issue 2
DOI: 10.1002/pssb.19690330209

Magnetic properties of ${Mn}_{3}$ $O_{4}$ and a solution of the canted-spin problem
journal, July 1983

Srinivasan, G.; Seehra, Mohindar S.
Physical Review B, Vol. 28, Issue 1
DOI: 10.1103/PhysRevB.28.1

First-principles study of the inversion thermodynamics and electronic structure of $Fe M_{2} X_{4}$ (thio)spinels ( $M = Cr$ , Mn, Co, Ni; $X = O$ , S)
journal, May 2015

Santos-Carballal, David; Roldan, Alberto; Grau-Crespo, Ricardo
Physical Review B, Vol. 91, Issue 19
DOI: 10.1103/PhysRevB.91.195106

An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions
journal, May 2007

Mathew, Daliya S.; Juang, Ruey-Shin
Chemical Engineering Journal, Vol. 129, Issue 1-3
DOI: 10.1016/j.cej.2006.11.001

Manganites spinelles purs d'elements de transition preparations et structures cristallographiques
journal, November 1968

Buhl, R.
Solid State Communications, Vol. 6, Issue 11
DOI: 10.1016/0038-1098(68)90147-6

The Physical Principles of Magnetism
journal, February 1967

Morrish, Allan H.; Weber, Robert L.
Physics Today, Vol. 20, Issue 2
DOI: 10.1063/1.3034167

Works referencing / citing this record:

Structural and magnetic properties of CoMn2O4 synthesized by auto combustion method
journal, November 2018

Kutty, Rajeesh Kumar Narayanan; Kasturi, Palanisamy Rupa; Jaganath, Jaya
Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 2
DOI: 10.1007/s10854-018-0366-5

MnFe _0.5 Ru _0.5 O ₃ : an above-room-temperature antiferromagnetic semiconductor
journal, January 2019

Tan, Xiaoyan; McCabe, Emma E.; Orlandi, Fabio
Journal of Materials Chemistry C, Vol. 7, Issue 3
DOI: 10.1039/c8tc05059g

Nanowires assembled from iron manganite nanoparticles: Synthesis, characterization, and investigation of electrocatalytic properties for water oxidation reaction
journal, July 2019

Cetin, Asude; Önal, Ahmet M.; Esenturk, Emren Nalbant
Journal of Materials Research, Vol. 34, Issue 18
DOI: 10.1557/jmr.2019.215

Figures / Tables found in this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

Similar Records in DOE PAGES and OSTI.GOV collections:

Mixing $A$ -type and $G$ -type $B$ -site antiferromagnetism in $A M n_{1 - x} F e_{x} O_{3} (A = La, Nd)$

Journal Article Pajerowski, Daniel M. - Physical Review B

Using a classical Heisenberg model with anisotropic nearest-neighbor superexchange and uniaxial anisotropy, I investigate the magnetic order of the transition metals on the B sites in AMn_1-xFe_xO₃(A=La, Nd; x=[0,1]) with Monte Carlo methods. Magnetic parameters are extracted from preexisting experimental data when available and otherwise estimated with calculations. Superexchange energies are compared to density functional theory and anisotropy energies to ligand field theory, and the potential for doping-induced strain affecting these parameters is considered. I find coexistence regions of different types of magnetic order (A-type and G-type antiferromagnetism), regions with distinct magnetic transitions for the two order parameters, noncollinear groundmore »« less
Cited by 3
https://doi.org/10.1103/PhysRevB.98.134431

Full Text Available
Consequences of magnetic ordering in chiral $M n_{1 / 3} Nb S_{2}$

Journal Article Karna, Sunil K. ; Womack, F N. ; Chapai, R ; ... - Physical Review B

Wemore »« less
Cited by 19
https://doi.org/10.1103/PhysRevB.100.184413

Full Text Available
Polaronic transport and thermoelectricity in ${Fe}_{1 - x} {Co}_{x} {Sb}_{2} S_{4}$ ( $x = 0$ , 0.1, and 0.2)

Journal Article Liu, Yu ; Kang, Chang -Jong ; Stavitski, Eli ; ... - Physical Review B

Here, we report a study of Co-doped berthierite Fe_1–xCo_xSb₂S₄ (x=0, 0.1, and 0.2). The alloy series of Fe_1–xCo_xSb₂S₄ crystallize in an orthorhombic structure with the Pnma space group, similar to FeSb₂, and show semiconducting behavior. The large discrepancy between activation energy for conductivity, E_ρ (146 ~270meV), and thermopower, E_S (47 ~108 meV), indicates the polaronic transport mechanism. Bulk magnetization and heat-capacity measurements of pure FeSb₂S₄ (x=0) exhibit a broad antiferromagnetic transition (T_N = 46K) followed by an additional weak transition (T* = 50K). Transition temperatures (T_N and T*) slightly decrease with increasing Co content x. This is also reflected inmore »« less
Cited by 3
https://doi.org/10.1103/PhysRevB.97.155202

Full Text Available
Structure-property relationship in layered $BaM n_{2} S b_{2}$ and $B a_{2} M n_{3} S b_{2} O_{2}$

Journal Article Zhang, Qiang ; Diao, Zhenyu ; Cao, Huibo ; ... - Physical Review B

Layered transition-metal compounds have received great attention owing to their physical properties. In this work, we present the structural, electronic, thermal, and magnetic properties of BaMn₂Sb₂ and Ba₂Mn₃Sb₂O₂ single crystals, both with the layered structure analogous to high-temperature Cu- and Fe-based superconductors. While the Mn moment in the MnSb₄ tetrahedral environment forms a long-range G-type antiferromagnetic (AFM) ordering in both BaMn₂Sb₂ (T_N1≈443K) and Ba₂Mn₃Sb₂O₂ (T_N1≈314K), a short-range AFM order is found in the intercalated MnO₂ layer at a much lower temperature (T_N2≈60K) coexisting with long-range G-type order in MnSb₄ layer in Ba₂Mn₃Sb₂O₂. The directions of the ordered moments in thesemore »« less
Cited by 3
https://doi.org/10.1103/PhysRevB.99.184416

Full Text Available
Evolution of magnetic and orbital properties in the magnetically diluted $A$ -site spinel ${Cu}_{1 - x} {Zn}_{x} {Rh}_{2} O_{4}$

Journal Article Zakrzewski, A. V. ; Gangopadhyay, S. ; MacDougall, Gregory J. ; ... - Physical Review B

In frustrated spinel antiferromagnets, dilution with nonmagnetic ions can be a powerful strategy for probing unconventional spin states or uncovering interesting phenomena. Here, we present x-ray, neutron scattering, and thermodynamic studies of the effects of magnetic dilution of the tetragonally distorted A-site spinel antiferromagnet, CuRh₂O₄, with nonmagnetic Zn²⁺ ions. Our data confirm the helical spin order recently identified at low temperatures in this material, and further demonstrate a systematic suppression of the associated Néel temperature with increasing site dilution towards a continuous transition with critical doping of x_spin ~0.44. Interestingly, this critical doping is demonstrably distinct from a second structuralmore »« less
Cited by 7
https://doi.org/10.1103/PhysRevB.97.214411

Full Text Available

Similar Records

Title: Structural and magnetic transitions in spinel FeM n 2 O 4 single crystals

Abstract

Citation Formats

Figures / Tables:

Structure of Spinel journal, December 1999

Magnetic compensation, field-dependent magnetization reversal, and complex magnetic ordering in Co 2 TiO 4 journal, December 2015

Magnetic properties of MnFe2O4 nanoparticles journal, April 2002

Propriétés magnétiques des ferrites ; ferrimagnétisme et antiferromagnétisme journal, January 1948

Phonon-Magnon Interaction in Magnetic Crystals journal, July 1962

Influence of Mn by Li substitution on the Jahn–Teller distortion in LiMn2O4 journal, March 2000

Manganites spinelles purs d'elements de transition preparations et structures cristallographiques journal, April 1969

Orbital Freezing and Orbital Glass State in F e C r 2 S 4 journal, January 2005

Lattice expansion and noncollinear to collinear ferrimagnetic order in a Mn Cr 2 O 4 nanoparticle journal, April 2006

Cation migration, cation valencies and the cubic-tetragonal transition in MnxFe3−xO4 journal, January 1971

Magnetic and Orbital Ordering in the Spinel MnV 2 O 4 journal, February 2008

Magnetic Spectra of Manganese Ferrites journal, May 1958

Heat capacity study of the magnetic phases in a Nd5Ge3 single crystal journal, May 2016

The preparation of tetragonal single crystals in the MnxFe3−xO4 system journal, January 1971

Cooperative Jahn–Teller effect and the role of strain in the tetragonal-to-cubic phase transition in MgxCu1 − xCr2O4 journal, August 2016

In-Plane Thermal Conductivity of N d 2 C u O 4 : Evidence for Magnon Heat Transport journal, October 2003

Theoretical investigation of MnFe2O4 journal, December 2013

Specific Heats at Low Temperatures book, January 1966

NiFe2O4: A Versatile Spinel Material Brings New Opportunities for Spintronics journal, July 2006

Mössbauer Effect in Mn x Fe 3- x O 4 journal, July 1963

Electron, spin-wave, hyperfine, and phonon contributions to the low-temperature specific heat of La 0.65 Ca 0.35 MnO 3 : Effects of magnetic fields and 16 O / 18 O exchange journal, September 2001

Lattice thermal conductivity of antiferromagnetic insulators journal, April 1980

Magnetoelasticity in A Cr 2 O 4 spinel oxides ( A = Mn, Fe, Co, Ni, and Cu) journal, February 2013

Heat capacity measurements of MnxFe3−xO4 journal, January 1981

Spin and Orbital Frustration in MnSc 2 S 4 and FeSc 2 S 4 journal, March 2004

Valence states and occupation sites in (Fe,Mn) 3 O 4 spinel oxides investigated by soft x-ray absorption spectroscopy and magnetic circular dichroism journal, June 2008

Cation valencies and distributions in spinel structures containing manganese journal, December 1961

Erratum: “Co-existence of ferrimagnetism and spin-glass state in the spinel Co 2 SnO 4 ” [J. Appl. Phys. 113 , 203905 (2013)] journal, September 2015

Anomalous electrical properties of Mn x Fe 3− x O 4 journal, April 1987

Ordering process and ferroelectricity in a spinel derived from FeV 2 O 4 journal, February 2012

Magnetic Structure of Iron Manganite by Neutron Diffraction journal, March 1969

Infrared Spectra of Cubic and Tetragonal Manganese Ferrites journal, January 1969

Magnetic properties of Mn 3 O 4 and a solution of the canted-spin problem journal, July 1983

First-principles study of the inversion thermodynamics and electronic structure of Fe M 2 X 4 (thio)spinels ( M = Cr , Mn, Co, Ni; X = O , S) journal, May 2015

An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions journal, May 2007

Manganites spinelles purs d'elements de transition preparations et structures cristallographiques journal, November 1968

The Physical Principles of Magnetism journal, February 1967

Structural and magnetic properties of CoMn2O4 synthesized by auto combustion method journal, November 2018

MnFe 0.5 Ru 0.5 O 3 : an above-room-temperature antiferromagnetic semiconductor journal, January 2019

Nanowires assembled from iron manganite nanoparticles: Synthesis, characterization, and investigation of electrocatalytic properties for water oxidation reaction journal, July 2019

Title: Structural and magnetic transitions in spinel $FeM n_{2} O_{4}$ single crystals

Structure of Spinel
journal, December 1999

Magnetic compensation, field-dependent magnetization reversal, and complex magnetic ordering in ${Co}_{2} {TiO}_{4}$
journal, December 2015

Magnetic properties of MnFe2O4 nanoparticles
journal, April 2002

Propriétés magnétiques des ferrites ; ferrimagnétisme et antiferromagnétisme
journal, January 1948

Phonon-Magnon Interaction in Magnetic Crystals
journal, July 1962

Influence of Mn by Li substitution on the Jahn–Teller distortion in LiMn2O4
journal, March 2000

Manganites spinelles purs d'elements de transition preparations et structures cristallographiques
journal, April 1969

Orbital Freezing and Orbital Glass State in $F e {C r}_{2} S_{4}$
journal, January 2005

Lattice expansion and noncollinear to collinear ferrimagnetic order in a $Mn {Cr}_{2} O_{4}$ nanoparticle
journal, April 2006

Cation migration, cation valencies and the cubic-tetragonal transition in MnxFe3−xO4
journal, January 1971

Magnetic and Orbital Ordering in the Spinel ${MnV}_{2} O_{4}$
journal, February 2008

Magnetic Spectra of Manganese Ferrites
journal, May 1958

Heat capacity study of the magnetic phases in a Nd5Ge3 single crystal
journal, May 2016

The preparation of tetragonal single crystals in the MnxFe3−xO4 system
journal, January 1971

Cooperative Jahn–Teller effect and the role of strain in the tetragonal-to-cubic phase transition in Mg_xCu_1 − xCr₂O₄
journal, August 2016

In-Plane Thermal Conductivity of ${N d}_{2} {C u O}_{4}$ : Evidence for Magnon Heat Transport
journal, October 2003

Theoretical investigation of MnFe2O4
journal, December 2013

Specific Heats at Low Temperatures
book, January 1966

NiFe2O4: A Versatile Spinel Material Brings New Opportunities for Spintronics
journal, July 2006

Mössbauer Effect in Mn _x Fe _{3- x} O ₄
journal, July 1963

Electron, spin-wave, hyperfine, and phonon contributions to the low-temperature specific heat of ${La}_{0.65} {Ca}_{0.35} {MnO}_{3} :$ Effects of magnetic fields and $^{16} {O /}^{18} O$ exchange
journal, September 2001

Lattice thermal conductivity of antiferromagnetic insulators
journal, April 1980

Magnetoelasticity in $A$ Cr $_{2}$ O $_{4}$ spinel oxides ( $A =$ Mn, Fe, Co, Ni, and Cu)
journal, February 2013

Heat capacity measurements of MnxFe3−xO4
journal, January 1981

Spin and Orbital Frustration in ${MnSc}_{2} S_{4}$ and ${FeSc}_{2} S_{4}$
journal, March 2004

Valence states and occupation sites in (Fe,Mn) ₃ O ₄ spinel oxides investigated by soft x-ray absorption spectroscopy and magnetic circular dichroism
journal, June 2008

Cation valencies and distributions in spinel structures containing manganese
journal, December 1961

Erratum: “Co-existence of ferrimagnetism and spin-glass state in the spinel Co ₂ SnO ₄ ” [J. Appl. Phys. 113 , 203905 (2013)]
journal, September 2015

Anomalous electrical properties of Mn _x Fe _{3− x} O ₄
journal, April 1987

Ordering process and ferroelectricity in a spinel derived from FeV $_{2}$ O $_{4}$
journal, February 2012

Magnetic Structure of Iron Manganite by Neutron Diffraction
journal, March 1969

Infrared Spectra of Cubic and Tetragonal Manganese Ferrites
journal, January 1969

Magnetic properties of ${Mn}_{3}$ $O_{4}$ and a solution of the canted-spin problem
journal, July 1983

First-principles study of the inversion thermodynamics and electronic structure of $Fe M_{2} X_{4}$ (thio)spinels ( $M = Cr$ , Mn, Co, Ni; $X = O$ , S)
journal, May 2015

An overview of the structure and magnetism of spinel ferrite nanoparticles and their synthesis in microemulsions
journal, May 2007

Manganites spinelles purs d'elements de transition preparations et structures cristallographiques
journal, November 1968

The Physical Principles of Magnetism
journal, February 1967

Structural and magnetic properties of CoMn2O4 synthesized by auto combustion method
journal, November 2018

MnFe _0.5 Ru _0.5 O ₃ : an above-room-temperature antiferromagnetic semiconductor
journal, January 2019

Nanowires assembled from iron manganite nanoparticles: Synthesis, characterization, and investigation of electrocatalytic properties for water oxidation reaction
journal, July 2019