Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming

Mayr, Lukas; Shi, Xue -Rong; Kopfle, Norbert; Milligan, Cory A.; Zemlyanov, Dmitry Y.; Knop-Gericke, Axel; Havecker, Michael; Klotzer, Bernhard; Penner, Simon

doi:10.1039/c6cp07197j

Title: Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming

Abstract

An inverse Pd–Zr model catalyst was prepared by chemical vapor deposition (CVD) using zirconium-t-butoxide (ZTB) as an organometallic precursor.

Authors:

Mayr, Lukas ^[1]; Shi, Xue -Rong ^[2]; Kopfle, Norbert ^[2]; Milligan, Cory A. ^[3]; Zemlyanov, Dmitry Y. ^[3]; Knop-Gericke, Axel ^[4]; Havecker, Michael ^[4]; Klotzer, Bernhard ^[2]; Penner, Simon ^[2]

Univ. of Innsbruck, Innsbruck (Austria); Purdue Univ., West Lafayette, IN (United States)
Univ. of Innsbruck, Innsbruck (Austria)
Purdue Univ., West Lafayette, IN (United States)
Fritz-Haber-Institute of the Max-Planck-Society, Berlin (Germany)

Publication Date:: Tue Nov 08 00:00:00 EST 2016

Research Org.:: Purdue Univ., West Lafayette, IN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division

OSTI Identifier:: 1439062

Grant/Contract Number:: FG02-03ER15408

Resource Type:: Accepted Manuscript

Journal Name:: Physical Chemistry Chemical Physics. PCCP

Additional Journal Information:: Journal Volume: 18; Journal Issue: 46; Journal ID: ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Mayr, Lukas, Shi, Xue -Rong, Kopfle, Norbert, Milligan, Cory A., Zemlyanov, Dmitry Y., Knop-Gericke, Axel, Havecker, Michael, Klotzer, Bernhard, and Penner, Simon. Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming.  United States: N. p., 2016. 
Web.  doi:10.1039/c6cp07197j.

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                    Mayr, Lukas, Shi, Xue -Rong, Kopfle, Norbert, Milligan, Cory A., Zemlyanov, Dmitry Y., Knop-Gericke, Axel, Havecker, Michael, Klotzer, Bernhard, & Penner, Simon. Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming.  United States.  https://doi.org/10.1039/c6cp07197j

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                    Mayr, Lukas, Shi, Xue -Rong, Kopfle, Norbert, Milligan, Cory A., Zemlyanov, Dmitry Y., Knop-Gericke, Axel, Havecker, Michael, Klotzer, Bernhard, and Penner, Simon. Tue .  
"Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming".  United States.  https://doi.org/10.1039/c6cp07197j.  https://www.osti.gov/servlets/purl/1439062.

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@article{osti_1439062,

  title        = {Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming},

  author       = {Mayr, Lukas and Shi, Xue -Rong and Kopfle, Norbert and Milligan, Cory A. and Zemlyanov, Dmitry Y. and Knop-Gericke, Axel and Havecker, Michael and Klotzer, Bernhard and Penner, Simon},

  abstractNote = {An inverse Pd–Zr model catalyst was prepared by chemical vapor deposition (CVD) using zirconium-t-butoxide (ZTB) as an organometallic precursor.},

  doi          = {10.1039/c6cp07197j},

  journal      = {Physical Chemistry Chemical Physics. PCCP},

  number       = 46,

  volume       = 18,

  place        = {United States},

  year         = {Tue Nov 08 00:00:00 EST 2016},

  month        = {Tue Nov 08 00:00:00 EST 2016}

}

Copy to clipboard

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https://doi.org/10.1039/c6cp07197j

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Works referencing / citing this record:

Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
journal, September 2018

Köpfle, Norbert; Götsch, Thomas; Grünbacher, Matthias
Angewandte Chemie International Edition, Vol. 57, Issue 44
DOI: 10.1002/anie.201807463

A Comparative Discussion of the Catalytic Activity and CO2-Selectivity of Cu-Zr and Pd-Zr (Intermetallic) Compounds in Methanol Steam Reforming
journal, February 2017

Köpfle, Norbert; Mayr, Lukas; Schmidmair, Daniela
Catalysts, Vol. 7, Issue 12
DOI: 10.3390/catal7020053

Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
journal, September 2018

Köpfle, Norbert; Götsch, Thomas; Grünbacher, Matthias
Angewandte Chemie International Edition, Vol. 57, Issue 44
DOI: 10.1002/anie.201807463

Zirconium-assistierte Aktivierung von Palladium zur Steigerung der Produktion von Synthesegas in der Trockenreformierung von Methan
journal, September 2018

Köpfle, Norbert; Götsch, Thomas; Grünbacher, Matthias
Angewandte Chemie, Vol. 130, Issue 44
DOI: 10.1002/ange.201807463

Metal Clusters Dispersed on Oxide Supports: Preparation Methods and Metal-Support Interactions
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Guo, Yu; Zhang, Ya-Wen
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DOI: 10.1007/s11244-018-0957-7

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Title: Chemical vapor deposition-prepared sub-nanometer Zr clusters on Pd surfaces: promotion of methane dry reforming

Abstract

Citation Formats

X‐ray photoelectron spectroscopic studies on yttria, zirconia, and yttria‐stabilized zirconia journal, July 1991

Surface oxides on Pd(111): STM and density functional calculations journal, July 2007

Liquid-phase Oppenauer oxidation of primary allylic and benzylic alcohols to corresponding aldehydes by solid zirconia catalysts journal, October 2004

Carbon incorporation during ethene oxidation on Pd(111) studied by in situ X-ray photoelectron spectroscopy at 2×10−3 mbar2×10−3 mbar journal, September 2006

Vibrational frequency analysis, FT-IR, DFT and M06-2X studies on tert-Butyl N-(thiophen-2yl)carbamate journal, July 2014

An (ultra) high-vacuum compatible sputter source for oxide thin film growth journal, September 2013

Surface and subsurface oxygen on Pd(111) journal, January 2000

From ultrasoft pseudopotentials to the projector augmented-wave method journal, January 1999

Photocatalytic studies of Ho–Zr–O nano-composite with controllable composition and defects journal, September 2013

Structure/processing relationships in the fabrication of nanoporous gold journal, June 2010

Theoretical studies on chemisorption of oxygen on β-Mo2C catalyst and its surface oxidation journal, August 2012

Theoretical Study of Oxygen Chemisorption on Pd (111), Au (111) and Pd–Au (111) Alloy Surfaces journal, March 2012

Trimethylaluminum and Oxygen Atomic Layer Deposition on Hydroxyl-Free Cu(111) journal, July 2015

Advanced anodes for high-temperature fuel cells journal, January 2004

Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process journal, June 2005

Infrared Spectra of Transition Metal Alkoxides. journal, November 1964

Low temperature dry reforming of methane over Pt–Ni–Mg/ceria–zirconia catalysts journal, December 2015

Subsurface-Controlled CO 2 Selectivity of PdZn Near-Surface Alloys in H 2 Generation by Methanol Steam Reforming journal, April 2010

Effects of zirconia phase on the synthesis of higher alcohols over zirconia and modified zirconia journal, February 2004

An XPS study of hydrogen implanted zirconium journal, September 1987

Steigerung der Wasserstoffproduktion in der Methanol-Dampfreformierung auf Kupfer durch Zink-unterstützte Wasseraktivierung journal, February 2012

Rapid thermal chemical vapor deposition of zirconium oxide for metal-oxide-semiconductor field effect transistor application journal, January 2001

Structure and Reactivity of PdOx/ZrO2Catalysts for Methane Oxidation at Low Temperatures journal, October 1998

Ultrathin zirconium oxide films as alternative gate dielectrics journal, January 2001

Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties journal, September 1998

Coupled calculation of vibrational frequencies and intensities journal, December 1981

Growth and decay of the Pd(111)–Pd5O4 surface oxide: Pressure-dependent kinetics and structural aspects journal, January 2006

Oxygen-induced surface phase transformation of Pd(1 1 1): sticking, adsorption and desorption kinetics journal, June 2001

XPS studies of the thermal behaviour of passivated Zircaloy-4 surfaces journal, July 1988

Carbon Dioxide Reforming of Methane To Produce Synthesis Gas over Metal-Supported Catalysts: State of the Art journal, January 1996

Slab model studies of water adsorption and decomposition on clean and X- (X = C, N and O) contaminated Pd(111) surfaces journal, January 2007

Dry reforming of methane over CeO2 supported Ni, Co and Ni–Co catalysts journal, December 2015

Comparative study at low and medium reaction temperatures of syngas production by methane reforming with carbon dioxide over silica and alumina supported catalysts journal, May 1998

Boosting Hydrogen Production from Methanol and Water by in situ Activation of Bimetallic Cu−Zr Species journal, April 2016

Surface Chemistry of Trimethylaluminum on Pd(111) and Pt(111) journal, August 2015

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal, October 1996

Nano-Au/CeO2 catalysts for CO oxidation: Influence of dopants (Fe, La and Zr) on the physicochemical properties and catalytic activity journal, January 2014

Atomic Layer Deposition of FeO on Pt(111) by Ferrocene Adsorption and Oxidation journal, August 2015

Palladium Nanoparticle Formation on TiO 2 (110) by Thermal Decomposition of Palladium(II) Hexafluoroacetylacetonate journal, August 2014

Surface and interface structures of epitaxial ZrO 2 films on Pt ( 111 ) : Experiment and density-functional theory calculations journal, December 2006

The electronic, elastic and structural properties of Pd–Zr intermetallic journal, January 2012

Coupled calculation of vibrational frequencies and intensities journal, November 1981

Steering of methanol reforming selectivity by zirconia–copper interaction journal, January 2015

Combined UHV/high-pressure catalysis setup for depth-resolved near-surface spectroscopic characterization and catalytic testing of model catalysts journal, May 2014

ZrO 2 film growth by chemical vapor deposition using zirconium tetra- tert- butoxide journal, July 1999

Reactions of unsaturated oxygenates on rhodium(111) as probes of multiple coordination of adsorbates journal, May 1992

Growth of an Ultrathin Zirconia Film on Pt 3 Zr Examined by High-Resolution X-ray Photoelectron Spectroscopy, Temperature-Programmed Desorption, Scanning Tunneling Microscopy, and Density Functional Theory journal, January 2015

Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming journal, September 2018

A Comparative Discussion of the Catalytic Activity and CO2-Selectivity of Cu-Zr and Pd-Zr (Intermetallic) Compounds in Methanol Steam Reforming journal, February 2017

Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming journal, September 2018

Zirconium-assistierte Aktivierung von Palladium zur Steigerung der Produktion von Synthesegas in der Trockenreformierung von Methan journal, September 2018

Metal Clusters Dispersed on Oxide Supports: Preparation Methods and Metal-Support Interactions journal, May 2018

X‐ray photoelectron spectroscopic studies on yttria, zirconia, and yttria‐stabilized zirconia
journal, July 1991

Surface oxides on Pd(111): STM and density functional calculations
journal, July 2007

Liquid-phase Oppenauer oxidation of primary allylic and benzylic alcohols to corresponding aldehydes by solid zirconia catalysts
journal, October 2004

Carbon incorporation during ethene oxidation on Pd(111) studied by in situ X-ray photoelectron spectroscopy at 2×10−3 mbar2×10−3 mbar
journal, September 2006

Vibrational frequency analysis, FT-IR, DFT and M06-2X studies on tert-Butyl N-(thiophen-2yl)carbamate
journal, July 2014

An (ultra) high-vacuum compatible sputter source for oxide thin film growth
journal, September 2013

Surface and subsurface oxygen on Pd(111)
journal, January 2000

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Photocatalytic studies of Ho–Zr–O nano-composite with controllable composition and defects
journal, September 2013

Structure/processing relationships in the fabrication of nanoporous gold
journal, June 2010

Theoretical studies on chemisorption of oxygen on β-Mo2C catalyst and its surface oxidation
journal, August 2012

Theoretical Study of Oxygen Chemisorption on Pd (111), Au (111) and Pd–Au (111) Alloy Surfaces
journal, March 2012

Trimethylaluminum and Oxygen Atomic Layer Deposition on Hydroxyl-Free Cu(111)
journal, July 2015

Advanced anodes for high-temperature fuel cells
journal, January 2004

Surface chemistry of atomic layer deposition: A case study for the trimethylaluminum/water process
journal, June 2005

Infrared Spectra of Transition Metal Alkoxides.
journal, November 1964

Low temperature dry reforming of methane over Pt–Ni–Mg/ceria–zirconia catalysts
journal, December 2015

Subsurface-Controlled CO ₂ Selectivity of PdZn Near-Surface Alloys in H ₂ Generation by Methanol Steam Reforming
journal, April 2010

Effects of zirconia phase on the synthesis of higher alcohols over zirconia and modified zirconia
journal, February 2004

An XPS study of hydrogen implanted zirconium
journal, September 1987

Steigerung der Wasserstoffproduktion in der Methanol-Dampfreformierung auf Kupfer durch Zink-unterstützte Wasseraktivierung
journal, February 2012

Rapid thermal chemical vapor deposition of zirconium oxide for metal-oxide-semiconductor field effect transistor application
journal, January 2001

Structure and Reactivity of PdOx/ZrO2Catalysts for Methane Oxidation at Low Temperatures
journal, October 1998

Ultrathin zirconium oxide films as alternative gate dielectrics
journal, January 2001

Onset of Catalytic Activity of Gold Clusters on Titania with the Appearance of Nonmetallic Properties
journal, September 1998

Coupled calculation of vibrational frequencies and intensities
journal, December 1981

Growth and decay of the Pd(111)–Pd5O4 surface oxide: Pressure-dependent kinetics and structural aspects
journal, January 2006

Oxygen-induced surface phase transformation of Pd(1 1 1): sticking, adsorption and desorption kinetics
journal, June 2001

XPS studies of the thermal behaviour of passivated Zircaloy-4 surfaces
journal, July 1988

Carbon Dioxide Reforming of Methane To Produce Synthesis Gas over Metal-Supported Catalysts: State of the Art
journal, January 1996

Slab model studies of water adsorption and decomposition on clean and X- (X = C, N and O) contaminated Pd(111) surfaces
journal, January 2007

Dry reforming of methane over CeO2 supported Ni, Co and Ni–Co catalysts
journal, December 2015

Comparative study at low and medium reaction temperatures of syngas production by methane reforming with carbon dioxide over silica and alumina supported catalysts
journal, May 1998

Boosting Hydrogen Production from Methanol and Water by in situ Activation of Bimetallic Cu−Zr Species
journal, April 2016

Surface Chemistry of Trimethylaluminum on Pd(111) and Pt(111)
journal, August 2015

Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set
journal, October 1996

Nano-Au/CeO2 catalysts for CO oxidation: Influence of dopants (Fe, La and Zr) on the physicochemical properties and catalytic activity
journal, January 2014

Atomic Layer Deposition of FeO on Pt(111) by Ferrocene Adsorption and Oxidation
journal, August 2015

Palladium Nanoparticle Formation on TiO ₂ (110) by Thermal Decomposition of Palladium(II) Hexafluoroacetylacetonate
journal, August 2014

Surface and interface structures of epitaxial ${ZrO}_{2}$ films on $Pt (111)$ : Experiment and density-functional theory calculations
journal, December 2006

The electronic, elastic and structural properties of Pd–Zr intermetallic
journal, January 2012

Coupled calculation of vibrational frequencies and intensities
journal, November 1981

Steering of methanol reforming selectivity by zirconia–copper interaction
journal, January 2015

Combined UHV/high-pressure catalysis setup for depth-resolved near-surface spectroscopic characterization and catalytic testing of model catalysts
journal, May 2014

ZrO 2 film growth by chemical vapor deposition using zirconium tetra- tert- butoxide
journal, July 1999

Reactions of unsaturated oxygenates on rhodium(111) as probes of multiple coordination of adsorbates
journal, May 1992

Growth of an Ultrathin Zirconia Film on Pt ₃ Zr Examined by High-Resolution X-ray Photoelectron Spectroscopy, Temperature-Programmed Desorption, Scanning Tunneling Microscopy, and Density Functional Theory
journal, January 2015

Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
journal, September 2018

A Comparative Discussion of the Catalytic Activity and CO2-Selectivity of Cu-Zr and Pd-Zr (Intermetallic) Compounds in Methanol Steam Reforming
journal, February 2017

Zirconium-Assisted Activation of Palladium To Boost Syngas Production by Methane Dry Reforming
journal, September 2018

Zirconium-assistierte Aktivierung von Palladium zur Steigerung der Produktion von Synthesegas in der Trockenreformierung von Methan
journal, September 2018

Metal Clusters Dispersed on Oxide Supports: Preparation Methods and Metal-Support Interactions
journal, May 2018