In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation
Abstract
In operando XRD and TXM-XANES approaches demonstrate that structure evolution in NaNi1/3Fe1/3Mn1/3O2 during cycling follows a continuous change, and the formation of a nonequilibrium solid solution phase in the existence of two phases. Here, an O3' and P3' monoclinic phase occur, and redox couples of Ni3+/Ni4+ and Fe3+/Fe4+ are mainly responsible in the charge voltage range from 4.0 to 4.3 V.
- Authors:
-
- Shanghai Jiao Tong Univ. (China). Dept. of Chemical Engineering; Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Shanghai Jiao Tong Univ. (China). Dept. of Chemical Engineering
- Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Sciences and Engineering Division
- Brookhaven National Lab. (BNL), Upton, NY (United States). Photon Sciences Directorate
- Argonne National Lab. (ANL), Argonne, IL (United States). Electron Microscopy Center-Center for Nanoscale Materials
- Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); National Natural Science Foundation of China (NSFC)
- OSTI Identifier:
- 1436248
- Report Number(s):
- BNL-203469-2018-JAAM
Journal ID: ISSN 1614-6832
- Grant/Contract Number:
- SC0012704; AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Advanced Energy Materials
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 24; Journal ID: ISSN 1614-6832
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, and Ma, Zi-Feng. In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation. United States: N. p., 2016.
Web. doi:10.1002/aenm.201601306.
Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, & Ma, Zi-Feng. In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation. United States. https://doi.org/10.1002/aenm.201601306
Xie, Yingying, Wang, Hong, Xu, Guiliang, Wang, Jiajun, Sheng, Huaping, Chen, Zonghai, Ren, Yang, Sun, Cheng-Jun, Wen, Jianguo, Wang, Jun, Miller, Dean J., Lu, Jun, Amine, Khalil, and Ma, Zi-Feng. Fri .
"In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation". United States. https://doi.org/10.1002/aenm.201601306. https://www.osti.gov/servlets/purl/1436248.
@article{osti_1436248,
title = {In Operando XRD and TXM Study on the Metastable Structure Change of NaNi1/3Fe1/3Mn1/3O2 under Electrochemical Sodium-Ion Intercalation},
author = {Xie, Yingying and Wang, Hong and Xu, Guiliang and Wang, Jiajun and Sheng, Huaping and Chen, Zonghai and Ren, Yang and Sun, Cheng-Jun and Wen, Jianguo and Wang, Jun and Miller, Dean J. and Lu, Jun and Amine, Khalil and Ma, Zi-Feng},
abstractNote = {In operando XRD and TXM-XANES approaches demonstrate that structure evolution in NaNi1/3Fe1/3Mn1/3O2 during cycling follows a continuous change, and the formation of a nonequilibrium solid solution phase in the existence of two phases. Here, an O3' and P3' monoclinic phase occur, and redox couples of Ni3+/Ni4+ and Fe3+/Fe4+ are mainly responsible in the charge voltage range from 4.0 to 4.3 V.},
doi = {10.1002/aenm.201601306},
journal = {Advanced Energy Materials},
number = 24,
volume = 6,
place = {United States},
year = {Fri Sep 02 00:00:00 EDT 2016},
month = {Fri Sep 02 00:00:00 EDT 2016}
}
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Works referenced in this record:
Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012
- Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo
- Nature Materials, Vol. 11, Issue 11
Probing three-dimensional sodiation–desodiation equilibrium in sodium-ion batteries by in situ hard X-ray nanotomography
journal, June 2015
- Wang, Jiajun; Eng, Christopher; Chen-Wiegart, Yu-chen Karen
- Nature Communications, Vol. 6, Issue 1
Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010
- Berthelot, R.; Carlier, D.; Delmas, C.
- Nature Materials, Vol. 10, Issue 1
Electrochemical Na Insertion and Solid Electrolyte Interphase for Hard-Carbon Electrodes and Application to Na-Ion Batteries
journal, August 2011
- Komaba, Shinichi; Murata, Wataru; Ishikawa, Toru
- Advanced Functional Materials, Vol. 21, Issue 20
Prototype Sodium-Ion Batteries Using an Air-Stable and Co/Ni-Free O3-Layered Metal Oxide Cathode
journal, October 2015
- Mu, Linqin; Xu, Shuyin; Li, Yunming
- Advanced Materials, Vol. 27, Issue 43
Electrochemical properties of P2-Na2/3[Ni1/3Mn2/3]O2 cathode material for sodium ion batteries when cycled in different voltage ranges
journal, December 2013
- Wang, Hong; Yang, Bingjian; Liao, Xiao-Zhen
- Electrochimica Acta, Vol. 113
The P2-Na2/3Co2/3Mn1/3O2 phase: structure, physical properties and electrochemical behavior as positive electrode in sodium battery
journal, January 2011
- Carlier, D.; Cheng, J. H.; Berthelot, R.
- Dalton Transactions, Vol. 40, Issue 36
Electrochemical intercalation of sodium in NaxCoO2 bronzes
journal, August 1981
- Delmas, C.; Braconnier, J.; Fouassier, C.
- Solid State Ionics, Vol. 3-4
Reversible Sodium Ion Insertion in Single Crystalline Manganese Oxide Nanowires with Long Cycle Life
journal, June 2011
- Cao, Yuliang; Xiao, Lifen; Wang, Wei
- Advanced Materials, Vol. 23, Issue 28, p. 3155-3160
Prussian blue without coordinated water as a superior cathode for sodium-ion batteries
journal, January 2015
- Yang, Dezhi; Xu, Jing; Liao, Xiao-Zhen
- Chemical Communications, Vol. 51, Issue 38
Capturing metastable structures during high-rate cycling of LiFePO4 nanoparticle electrodes
journal, June 2014
- Liu, H.; Strobridge, F. C.; Borkiewicz, O. J.
- Science, Vol. 344, Issue 6191
Large-Scale Synthesis of NaNi 1/3 Fe 1/3 Mn 1/3 O 2 as High Performance Cathode Materials for Sodium Ion Batteries
journal, January 2016
- Wang, Hong; Liao, Xiao-Zhen; Yang, Yang
- Journal of The Electrochemical Society, Vol. 163, Issue 3
O3–Na x Mn 1/3 Fe 2/3 O 2 as a positive electrode material for Na-ion batteries: structural evolutions and redox mechanisms upon Na + (de)intercalation
journal, January 2015
- Mortemard de Boisse, B.; Cheng, J. -H.; Carlier, D.
- Journal of Materials Chemistry A, Vol. 3, Issue 20
Room-temperature stationary sodium-ion batteries for large-scale electric energy storage
journal, January 2013
- Pan, Huilin; Hu, Yong-Sheng; Chen, Liquan
- Energy & Environmental Science, Vol. 6, Issue 8
Prussian blue: a new framework of electrode materials for sodium batteries
journal, January 2012
- Lu, Yuhao; Wang, Long; Cheng, Jinguang
- Chemical Communications, Vol. 48, Issue 52, p. 6544-6546
Enabling Sodium Batteries Using Lithium-Substituted Sodium Layered Transition Metal Oxide Cathodes
journal, February 2011
- Kim, Donghan; Kang, Sun-Ho; Slater, Michael
- Advanced Energy Materials, Vol. 1, Issue 3, p. 333-336
Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application
journal, January 2012
- Kim, Donghan; Lee, Eungje; Slater, Michael
- Electrochemistry Communications, Vol. 18
P2-type Nax[Fe1/2Mn1/2]O2 made from earth-abundant elements for rechargeable Na batteries
journal, April 2012
- Yabuuchi, Naoaki; Kajiyama, Masataka; Iwatate, Junichi
- Nature Materials, Vol. 11, Issue 6
Synthesis, Structure, and Electrochemical Properties of the Layered Sodium Insertion Cathode Material: NaNi 1 / 3 Mn 1 / 3 Co 1 / 3 O 2
journal, April 2012
- Sathiya, M.; Hemalatha, K.; Ramesha, K.
- Chemistry of Materials, Vol. 24, Issue 10
A thermodynamic study of sodium-intercalated TaS2 and TiS2
journal, September 1979
- Nagelberg, Alan S.; Worrell, Wayne L.
- Journal of Solid State Chemistry, Vol. 29, Issue 3
O3-type Na(Mn0.25Fe0.25Co0.25Ni0.25)O2: A quaternary layered cathode compound for rechargeable Na ion batteries
journal, December 2014
- Li, Xin; Wu, Di; Zhou, Yong-Ning
- Electrochemistry Communications, Vol. 49
First-principles investigation on crystal, electronic structures and Diffusion barriers of NaNi1/3Co1/3Mn1/3O2 for advanced rechargeable Na-ion batteries
journal, February 2015
- Su, Jingcang; Pei, Yong; Yang, Zhenhua
- Computational Materials Science, Vol. 98
New Insights into the Performance Degradation of Fe-Based Layered Oxides in Sodium-Ion Batteries: Instability of Fe 3+ /Fe 4+ Redox in α-NaFeO 2
journal, September 2015
- Lee, Eungje; Brown, Dennis E.; Alp, Esen E.
- Chemistry of Materials, Vol. 27, Issue 19
Advanced Na[Ni 0.25 Fe 0.5 Mn 0.25 ]O 2 /C–Fe 3 O 4 Sodium-Ion Batteries Using EMS Electrolyte for Energy Storage
journal, February 2014
- Oh, Seung-Min; Myung, Seung-Taek; Yoon, Chong Seung
- Nano Letters, Vol. 14, Issue 3
Study of Thermal Decomposition of Li 1-x (Ni 1/3 Mn 1/3 Co 1/3 ) 0.9 O 2 Using In-Situ High-Energy X-Ray Diffraction
journal, March 2013
- Chen, Zonghai; Ren, Yang; Lee, Eungje
- Advanced Energy Materials, Vol. 3, Issue 6
In operando tracking phase transformation evolution of lithium iron phosphate with hard X-ray microscopy
journal, August 2014
- Wang, Jiajun; Chen-Wiegart, Yu-chen Karen; Wang, Jun
- Nature Communications, Vol. 5, Issue 1
Works referencing / citing this record:
Ti-Substituted NaNi 0.5 Mn 0.5- x Ti x O 2 Cathodes with Reversible O3−P3 Phase Transition for High-Performance Sodium-Ion Batteries
journal, March 2017
- Wang, Peng-Fei; Yao, Hu-Rong; Liu, Xin-Yu
- Advanced Materials, Vol. 29, Issue 19
Exposing {010} Active Facets by Multiple-Layer Oriented Stacking Nanosheets for High-Performance Capacitive Sodium-Ion Oxide Cathode
journal, August 2018
- Xiao, Yao; Wang, Peng-Fei; Yin, Ya-Xia
- Advanced Materials, Vol. 30, Issue 40
Layered Oxide Cathodes for Sodium-Ion Batteries: Phase Transition, Air Stability, and Performance
journal, November 2017
- Wang, Peng-Fei; You, Ya; Yin, Ya-Xia
- Advanced Energy Materials, Vol. 8, Issue 8
Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries
journal, February 2018
- Xu, Gui-Liang; Amine, Rachid; Abouimrane, Ali
- Advanced Energy Materials, Vol. 8, Issue 14
Electrochemistry and Solid‐State Chemistry of NaMeO 2 (Me = 3d Transition Metals)
journal, June 2018
- Kubota, Kei; Kumakura, Shinichi; Yoda, Yusuke
- Advanced Energy Materials, Vol. 8, Issue 17
Deciphering the Cathode-Electrolyte Interfacial Chemistry in Sodium Layered Cathode Materials
journal, October 2018
- Mu, Linqin; Feng, Xu; Kou, Ronghui
- Advanced Energy Materials, Vol. 8, Issue 34
High‐Abundance and Low‐Cost Metal‐Based Cathode Materials for Sodium‐Ion Batteries: Problems, Progress, and Key Technologies
journal, February 2019
- Chen, Mingzhe; Liu, Qiannan; Wang, Shi‐Wen
- Advanced Energy Materials, Vol. 9, Issue 14
A Stable Layered Oxide Cathode Material for High‐Performance Sodium‐Ion Battery
journal, March 2019
- Xiao, Yao; Zhu, Yan‐Fang; Yao, Hu‐Rong
- Advanced Energy Materials, Vol. 9, Issue 19
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode
journal, December 2019
- Xiao, Yao; Zhu, Yan‐Fang; Xiang, Wei
- Angewandte Chemie, Vol. 132, Issue 4
Understanding Challenges of Cathode Materials for Sodium‐Ion Batteries using Synchrotron‐Based X‐Ray Absorption Spectroscopy
journal, July 2019
- Chen, Mingzhe; Chou, Shu‐Lei; Dou, Shi‐Xue
- Batteries & Supercaps, Vol. 2, Issue 10
The effect of Na content on the electrochemical performance of the O3-type NaxFe0.5Mn0.5O2 for sodium-ion batteries
journal, January 2019
- Zhou, Dengmei; Huang, Wanxia; Zhao, Fenglin
- Journal of Materials Science, Vol. 54, Issue 9
Ni-based cathode materials for Na-ion batteries
journal, June 2019
- Zhao, Chenglong; Lu, Yaxiang; Chen, Liquan
- Nano Research, Vol. 12, Issue 9
Synthesis, structure, and electrochemical properties of O′3-type monoclinic NaNi 0.8 Co 0.15 Al 0.05 O 2 cathode materials for sodium-ion batteries
journal, January 2019
- Zhou, Pengfei; Liu, Xiaolan; Weng, Junying
- Journal of Materials Chemistry A, Vol. 7, Issue 2
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures
journal, January 2019
- Wang, Shenghan; Sun, Chenglin; Wang, Ning
- Journal of Materials Chemistry A, Vol. 7, Issue 17
Deciphering an Abnormal Layered‐Tunnel Heterostructure Induced by Chemical Substitution for the Sodium Oxide Cathode
journal, January 2020
- Xiao, Yao; Zhu, Yan‐Fang; Xiang, Wei
- Angewandte Chemie International Edition, Vol. 59, Issue 4