Localized Symmetry Breaking for Tuning Thermal Expansion in ScF3 Nanoscale Frameworks

Hu, Lei; Qin, Feiyu; Sanson, Andrea; Huang, Liang-Feng; Pan, Zhao; Li, Qiang; Sun, Qiang; Wang, Lu; Guo, Fangmin; Aydemir, Umut; Ren, Yang; Sun, Chengjun; Deng, Jinxia; Aquilanti, Giuliana; Rondinelli, James M.; Chen, Jun; Xing, Xianran

doi:10.1021/jacs.8b00885

Title: Localized Symmetry Breaking for Tuning Thermal Expansion in ScF₃ Nanoscale Frameworks

Abstract

The local symmetry, beyond the averaged crystallographic structure, tends to bring unu-sual performances. Negative thermal expansion is a peculiar physical property of solids. Here in this paper, we report the delicate design of the localized symmetry breaking to achieve the controllable thermal expansion in ScF₃ nano-scale frameworks. Intriguingly, an isotropic zero thermal expansion is concurrently engineered by localized symmetry breaking, with a remarkably low coefficient of thermal expansion of about +4.0×10-8/K up to 675K. This mechanism is investigated by the joint analysis of atomic pair dis-tribution function of synchrotron X-ray total scattering and extended X-ray absorption fine structure spectra. A localized rhombohedral distortion presumably plays a critical role in stiffening ScF₃ nano-scale frameworks and concomitantly suppressing transverse thermal vibrations of fluorine atoms. This physical scenario is also theoretically corroborated by the extinction of phonon modes with negative Grüneisen parameters in the rhombohedral ScF₃. The present work opens an untraditional chemical modification to achieve controllable thermal expansion by breaking local symmetries of materials.

Authors:

Hu, Lei ^[1]; Qin, Feiyu ^[2];

^[3];

^[4]; Pan, Zhao ^[2]; Li, Qiang ^[2]; Sun, Qiang ^[5]; Wang, Lu ^[2]; Guo, Fangmin ^[6]; Aydemir, Umut ^[7]; Ren, Yang ^[6]; Sun, Chengjun ^[6]; Deng, Jinxia ^[2]; Aquilanti, Giuliana ^[8];

^[4];

^[2];

^[2]

Univ. of Science and Technology, Beijing (China). Dept. of Physical Chemistry; Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Univ. of Science and Technology, Beijing (China). Dept. of Physical Chemistry
Univ. of Padova, Padova (Italy). Dept. of Phyics and Astronomy
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering
Zhengzhou Univ., Zhengzhou (China). International Lab. for Quantum Functional Materials of Henan, School of Physics and Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). X-Ray Science Division
Northwestern Univ., Evanston, IL (United States). Dept. of Materials Science and Engineering; Koc University, Sariyer, Istanbul (Turkey). Dept. of Chemistry
Elettra Sincrotrone Trieste, Basovizza, Trieste (Italy)

Publication Date:: Tue Mar 20 00:00:00 EDT 2018

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: National Natural Science Foundation of China (NSFC); USDOE Office of Science - Office of Basic Energy Sciences - Scientific User Facilities Division

OSTI Identifier:: 1435043

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the American Chemical Society

Additional Journal Information:: Journal Volume: 140; Journal Issue: 13; Journal ID: ISSN 0002-7863

Publisher:: American Chemical Society (ACS)

Country of Publication:: United States

Language:: English

Subject:: 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS

Citation Formats


                    Hu, Lei, Qin, Feiyu, Sanson, Andrea, Huang, Liang-Feng, Pan, Zhao, Li, Qiang, Sun, Qiang, Wang, Lu, Guo, Fangmin, Aydemir, Umut, Ren, Yang, Sun, Chengjun, Deng, Jinxia, Aquilanti, Giuliana, Rondinelli, James M., Chen, Jun, and Xing, Xianran. Localized Symmetry Breaking for Tuning Thermal Expansion in ScF3 Nanoscale Frameworks.  United States: N. p., 2018. 
Web.  doi:10.1021/jacs.8b00885.

Copy to clipboard


                    Hu, Lei, Qin, Feiyu, Sanson, Andrea, Huang, Liang-Feng, Pan, Zhao, Li, Qiang, Sun, Qiang, Wang, Lu, Guo, Fangmin, Aydemir, Umut, Ren, Yang, Sun, Chengjun, Deng, Jinxia, Aquilanti, Giuliana, Rondinelli, James M., Chen, Jun, & Xing, Xianran. Localized Symmetry Breaking for Tuning Thermal Expansion in ScF3 Nanoscale Frameworks.  United States.  https://doi.org/10.1021/jacs.8b00885

Copy to clipboard


                    Hu, Lei, Qin, Feiyu, Sanson, Andrea, Huang, Liang-Feng, Pan, Zhao, Li, Qiang, Sun, Qiang, Wang, Lu, Guo, Fangmin, Aydemir, Umut, Ren, Yang, Sun, Chengjun, Deng, Jinxia, Aquilanti, Giuliana, Rondinelli, James M., Chen, Jun, and Xing, Xianran. Tue .  
"Localized Symmetry Breaking for Tuning Thermal Expansion in ScF3 Nanoscale Frameworks".  United States.  https://doi.org/10.1021/jacs.8b00885.  https://www.osti.gov/servlets/purl/1435043.

Copy to clipboard


                    
@article{osti_1435043,

  title        = {Localized Symmetry Breaking for Tuning Thermal Expansion in ScF3 Nanoscale Frameworks},

  author       = {Hu, Lei and Qin, Feiyu and Sanson, Andrea and Huang, Liang-Feng and Pan, Zhao and Li, Qiang and Sun, Qiang and Wang, Lu and Guo, Fangmin and Aydemir, Umut and Ren, Yang and Sun, Chengjun and Deng, Jinxia and Aquilanti, Giuliana and Rondinelli, James M. and Chen, Jun and Xing, Xianran},

  abstractNote = {The local symmetry, beyond the averaged crystallographic structure, tends to bring unu-sual performances. Negative thermal expansion is a peculiar physical property of solids. Here in this paper, we report the delicate design of the localized symmetry breaking to achieve the controllable thermal expansion in ScF3 nano-scale frameworks. Intriguingly, an isotropic zero thermal expansion is concurrently engineered by localized symmetry breaking, with a remarkably low coefficient of thermal expansion of about +4.0×10-8/K up to 675K. This mechanism is investigated by the joint analysis of atomic pair dis-tribution function of synchrotron X-ray total scattering and extended X-ray absorption fine structure spectra. A localized rhombohedral distortion presumably plays a critical role in stiffening ScF3 nano-scale frameworks and concomitantly suppressing transverse thermal vibrations of fluorine atoms. This physical scenario is also theoretically corroborated by the extinction of phonon modes with negative Grüneisen parameters in the rhombohedral ScF3. The present work opens an untraditional chemical modification to achieve controllable thermal expansion by breaking local symmetries of materials.},

  doi          = {10.1021/jacs.8b00885},

  journal      = {Journal of the American Chemical Society},

  number       = 13,

  volume       = 140,

  place        = {United States},

  year         = {Tue Mar 20 00:00:00 EDT 2018},

  month        = {Tue Mar 20 00:00:00 EDT 2018}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1021/jacs.8b00885

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 35 works

Citation information provided by
Web of Science

Figures / Tables:

Figure 1: (a) Temperature dependence of relative lattice constant, Δa = a_T – a₀, of ScF₃ crystals. S1 is bulk ScF₃; while S2 (13.2 nm), S3 (8.1 nm), and S4 (6.3 nm) are nanocrystals. (b) Contour plots of (100) peaks of ScF₃ crystals (S1 to S4).

All figures and tables (4 total)

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Entropically Stabilized Local Dipole Formation in Lead Chalcogenides
journal, December 2010

Bozin, E. S.; Malliakas, C. D.; Souvatzis, P.
Science, Vol. 330, Issue 6011
DOI: 10.1126/science.1192759

Local atomic structure of superconducting ${FeSe}_{1 - x} {Te}_{x}$
journal, April 2010

Louca, Despina; Horigane, K.; Llobet, A.
Physical Review B, Vol. 81, Issue 13
DOI: 10.1103/PhysRevB.81.134524

Local Lattice Distortion in the Giant Negative Thermal Expansion Material ${Mn}_{3} {Cu}_{1 - x} {Ge}_{x} N$
journal, November 2008

Iikubo, S.; Kodama, K.; Takenaka, K.
Physical Review Letters, Vol. 101, Issue 20
DOI: 10.1103/PhysRevLett.101.205901

Zero thermal expansion in a pure-form antiperovskite manganese nitride
journal, March 2009

Takenaka, K.; Takagi, H.
Applied Physics Letters, Vol. 94, Issue 13
DOI: 10.1063/1.3110046

Adjustable Zero Thermal Expansion in Antiperovskite Manganese Nitride
journal, September 2011

Song, Xiaoyan; Sun, Zhonghua; Huang, Qingzhen
Advanced Materials, Vol. 23, Issue 40
DOI: 10.1002/adma.201102552

Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8
journal, April 1996

Mary, T. A.; Evans, J. S. O.; Vogt, T.
Science, Vol. 272, Issue 5258
DOI: 10.1126/science.272.5258.90

A century of zero expansion
journal, July 1999

Mohn, Peter
Nature, Vol. 400, Issue 6739
DOI: 10.1038/21778

A fresh twist on shrinking materials
journal, December 2011

Attfield, J. Paul
Nature, Vol. 480, Issue 7378
DOI: 10.1038/480465a

Negative thermal expansion materials †
journal, January 1999

Evans, John S. O.
Journal of the Chemical Society, Dalton Transactions, Issue 19
DOI: 10.1039/a904297k

Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
journal, June 2011

Azuma, Masaki; Chen, Wei-tin; Seki, Hayato
Nature Communications, Vol. 2, Issue 1
DOI: 10.1038/ncomms1361

Colossal negative thermal expansion in reduced layered ruthenate
journal, January 2017

Takenaka, Koshi; Okamoto, Yoshihiko; Shinoda, Tsubasa
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/ncomms14102

Colossal Volume Contraction in Strong Polar Perovskites of Pb(Ti,V)O ₃
journal, October 2017

Pan, Zhao; Chen, Jun; Jiang, Xingxing
Journal of the American Chemical Society, Vol. 139, Issue 42
DOI: 10.1021/jacs.7b08625

Giant Negative Thermal Expansion in NaZn ₁₃ -Type La(Fe, Si, Co) ₁₃ Compounds
journal, July 2013

Huang, Rongjin; Liu, Yanying; Fan, Wei
Journal of the American Chemical Society, Vol. 135, Issue 31
DOI: 10.1021/ja405161z

Zero Thermal Expansion in Magnetic and Metallic Tb(Co,Fe) ₂ Intermetallic Compounds
journal, January 2018

Song, Yuzhu; Chen, Jun; Liu, Xinzhi
Journal of the American Chemical Society, Vol. 140, Issue 2
DOI: 10.1021/jacs.7b12235

Systematic and Controllable Negative, Zero, and Positive Thermal Expansion in Cubic Zr _{1– x} Sn _x Mo ₂ O ₈
journal, August 2013

Tallentire, Sarah E.; Child, Felicity; Fall, Ian
Journal of the American Chemical Society, Vol. 135, Issue 34
DOI: 10.1021/ja4060564

Atomic Linkage Flexibility Tuned Isotropic Negative, Zero, and Positive Thermal Expansion in MZrF ₆ (M = Ca, Mn, Fe, Co, Ni, and Zn)
journal, October 2016

Hu, Lei; Chen, Jun; Xu, Jiale
Journal of the American Chemical Society, Vol. 138, Issue 44
DOI: 10.1021/jacs.6b08746

Zero Thermal Expansion in a Flexible, Stable Framework: Tetramethylammonium Copper(I) Zinc(II) Cyanide
journal, January 2010

Phillips, Anthony E.; Halder, Gregory J.; Chapman, Karena W.
Journal of the American Chemical Society, Vol. 132, Issue 1
DOI: 10.1021/ja906895j

Tunable thermal expansion in framework materials through redox intercalation
journal, February 2017

Chen, Jun; Gao, Qilong; Sanson, Andrea
Nature Communications, Vol. 8, Issue 1
DOI: 10.1038/ncomms14441

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF ₃
journal, November 2010

Greve, Benjamin K.; Martin, Kenneth L.; Lee, Peter L.
Journal of the American Chemical Society, Vol. 132, Issue 44
DOI: 10.1021/ja106711v

Local behaviour of negative thermal expansion materials
journal, May 2006

Fornasini, P.; Dalba, G.; Grisenti, R.
Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 246, Issue 1
DOI: 10.1016/j.nimb.2005.12.062

Negative thermal expansion and local dynamics in ${Cu}_{2} O$ and ${Ag}_{2} O$
journal, June 2006

Sanson, A.; Rocca, F.; Dalba, G.
Physical Review B, Vol. 73, Issue 21
DOI: 10.1103/PhysRevB.73.214305

Negative thermal expansion in crystals with the delafossite structure: An extended x-ray absorption fine structure study of ${CuScO}_{2}$ and ${CuLaO}_{2}$
journal, March 2009

Ahmed, S. I.; Dalba, G.; Fornasini, P.
Physical Review B, Vol. 79, Issue 10
DOI: 10.1103/PhysRevB.79.104302

Toward an Understanding of the Local Origin of Negative Thermal Expansion in ZrW ₂ O ₈ : Limits and Inconsistencies of the Tent and Rigid Unit Mode Models
journal, June 2014

Sanson, Andrea
Chemistry of Materials, Vol. 26, Issue 12
DOI: 10.1021/cm501107w

New Insights into the Negative Thermal Expansion: Direct Experimental Evidence for the “Guitar-String” Effect in Cubic ScF ₃
journal, June 2016

Hu, Lei; Chen, Jun; Sanson, Andrea
Journal of the American Chemical Society, Vol. 138, Issue 27
DOI: 10.1021/jacs.6b02370

Size effects on negative thermal expansion in cubic ScF ₃
journal, July 2016

Yang, C.; Tong, P.; Lin, J. C.
Applied Physics Letters, Vol. 109, Issue 2
DOI: 10.1063/1.4959083

Zero Thermal Expansion and Ferromagnetism in Cubic Sc _{1– x} M _x F ₃ (M = Ga, Fe) over a Wide Temperature Range
journal, September 2014

Hu, Lei; Chen, Jun; Fan, Longlong
Journal of the American Chemical Society, Vol. 136, Issue 39
DOI: 10.1021/ja5077487

High-Curie - Temperature Ferromagnetism in (Sc,Fe)F ₃ Fluorides and its Dependence on Chemical Valence
journal, July 2015

Hu, Lei; Chen, Jun; Fan, Longlong
Advanced Materials, Vol. 27, Issue 31
DOI: 10.1002/adma.201500868

Near-Zero Thermal Expansion and High Ultraviolet Transparency in a Borate Crystal of Zn ₄ B ₆ O ₁₃
journal, July 2016

Jiang, Xingxing; Molokeev, Maxim S.; Gong, Pifu
Advanced Materials, Vol. 28, Issue 36
DOI: 10.1002/adma.201601816

Works referencing / citing this record:

Cone-spiral magnetic ordering dominated lattice distortion and giant negative thermal expansion in Fe-doped MnNiGe compounds
journal, January 2020

Shen, Feiran; Zhou, Houbo; Hu, Fengxia
Materials Horizons, Vol. 7, Issue 3
DOI: 10.1039/c9mh01602c

Perovskite-related ReO3-type structures
journal, January 2020

Evans, Hayden A.; Wu, Yue; Seshadri, Ram
Nature Reviews Materials, Vol. 5, Issue 3
DOI: 10.1038/s41578-019-0160-x

On the switching between negative and positive thermal expansion in framework materials
journal, May 2019

Sanson, Andrea
Materials Research Letters, Vol. 7, Issue 10
DOI: 10.1080/21663831.2019.1621957

On the switching between negative and positive thermal expansion in framework materials
text, January 2019

Sanson, Andrea
Figshare
DOI: 10.6084/m9.figshare.8208539.v1

On the switching between negative and positive thermal expansion in framework materials
text, January 2019

Sanson, Andrea
Taylor & Francis
DOI: 10.6084/m9.figshare.8208539

Figures / Tables found in this record:

Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

Similar Records in DOE PAGES and OSTI.GOV collections:

Size effects on negative thermal expansion in cubic ScF{sub 3}

Journal Article Yang, C. ; Guo, X. G. ; Zhang, K. ; ... - Applied Physics Letters

Scandium trifluoride (ScF{sub 3}), adopting a cubic ReO{sub 3}-type structure at ambient pressure, undergoes a pronounced negative thermal expansion (NTE) over a wide range of temperatures (10 K–1100 K). Here, we report the size effects on the NTE properties of ScF{sub 3}. The magnitude of NTE is reduced with diminishing the crystal size. As revealed by the specific heat measurement, the low-energy phonon vibrations which account for the NTE behavior are stiffened as the crystal size decreases. With decreasing the crystal size, the peaks in high-energy X-ray pair distribution function (PDF) become broad, which cannot be illuminated by local symmetry breaking. Instead,more »« less
https://doi.org/10.1063/1.4959083
Solid solubility, phase transitions, thermal expansion, and compressibility in Sc{sub 1−x}Al{sub x}F{sub 3}

Journal Article Morelock, Cody R. ; Gallington, Leighanne C. ; Wilkinson, Angus P., E-mail: angus.wilkinson@chemistry.gatech.edu ; ... - Journal of Solid State Chemistry

With the goal of thermal expansion control, the synthesis and properties of Sc{sub 1−x}Al{sub x}F{sub 3} were investigated. The solubility limit of AlF{sub 3} in ScF{sub 3} at ∼1340 K is ∼50%. Solid solutions (x≤0.50) were characterized by synchrotron powder diffraction at ambient pressure between 100 and 900 K and at pressures <0.414 GPa while heating from 298 to 523 K. A phase transition from cubic to rhombohedral is observed. The transition temperature increases smoothly with Al{sup 3+} content, approaching 500 K at the solid solubility limit, and also upon compression at fixed Al{sup 3+} content. The slope of themore »« less
https://doi.org/10.1016/J.JSSC.2014.11.007
Pronounced negative thermal expansion from a simple structure : Cubic ScF{sub 3}.

Journal Article Greve, B K ; Martin, K L ; Lee, P L ; ... - J. Am. Chem. Soc.

Scandium trifluoride maintains a cubic ReO{sub 3} type structure down to at least 10 K, although the pressure at which its cubic to rhombohedral phase transition occurs drops from >0.5 GPa at {approx}300 K to 0.1-0.2 GPa at 50 K. At low temperatures it shows strong negative thermal expansion (NTE) (60-110 K, {alpha}{sub l} {approx} -14 ppm K{sup -1}). On heating, its coefficient of thermal expansion (CTE) smoothly increases, leading to a room temperature CTE that is similar to that of ZrW{sub 2}O{sub 8} and positive thermal expansion above {approx}1100 K. While the cubic ReO{sub 3} structure type is oftenmore »« less
https://doi.org/10.1021/ja106711v
Tunable thermal expansion and magnetism in Zr-doped ScF₃

Journal Article Wang, Tao ; Xu, Jiale ; Hu, Lei ; ... - Applied Physics Letters

The negative thermal expansion (NTE) behavior provides us an opportunity to design materials with controllable coefficient of thermal expansion (CTE). In this letter, we report a tunable isotropic thermal expansion in the cubic (Sc_1-xZr_x)F_3+δ over a wide temperature and CTE range (more »« less
Cited by 17
https://doi.org/10.1063/1.4966958

Full Text Available
New insights into the negative thermal expansion: Direct experimental evidence for the “guitar-string” effect in cubic ScF₃

Journal Article Hu, Lei ; Chen, Jun ; Sanson, Andrea ; ... - Journal of the American Chemical Society

The understanding of the negative thermal expansion (NTE) mechanism remains challenging but critical for the development of NTE materials. This study sheds light on NTE of ScF₃, one of the most outstanding materials with NTE. The local dynamics of ScF₃ has been investigated by a combined analysis of synchrotron-based X-ray total scattering, ex-tended X-ray absorption fine structure and neutron powder diffraction. Very interestingly, we observe that i) the Sc-F nearest-neighbor distance strongly expands with increasing temperature while the Sc-Sc next-nearest-neighbor distance contracts, ii) the thermal ellipsoids of relative vibrations be-tween Sc-F nearest-neighbors are highly elongated in the direction perpendicular tomore »« less
Cited by 99
https://doi.org/10.1021/jacs.6b02370

Full Text Available

Similar Records

Title: Localized Symmetry Breaking for Tuning Thermal Expansion in ScF3 Nanoscale Frameworks

Abstract

Citation Formats

Figures / Tables:

Entropically Stabilized Local Dipole Formation in Lead Chalcogenides journal, December 2010

Local atomic structure of superconducting FeSe 1 − x Te x journal, April 2010

Local Lattice Distortion in the Giant Negative Thermal Expansion Material Mn 3 Cu 1 − x Ge x N journal, November 2008

Zero thermal expansion in a pure-form antiperovskite manganese nitride journal, March 2009

Adjustable Zero Thermal Expansion in Antiperovskite Manganese Nitride journal, September 2011

Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8 journal, April 1996

A century of zero expansion journal, July 1999

A fresh twist on shrinking materials journal, December 2011

Negative thermal expansion materials † journal, January 1999

Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer journal, June 2011

Colossal negative thermal expansion in reduced layered ruthenate journal, January 2017

Colossal Volume Contraction in Strong Polar Perovskites of Pb(Ti,V)O 3 journal, October 2017

Giant Negative Thermal Expansion in NaZn 13 -Type La(Fe, Si, Co) 13 Compounds journal, July 2013

Zero Thermal Expansion in Magnetic and Metallic Tb(Co,Fe) 2 Intermetallic Compounds journal, January 2018

Systematic and Controllable Negative, Zero, and Positive Thermal Expansion in Cubic Zr 1– x Sn x Mo 2 O 8 journal, August 2013

Atomic Linkage Flexibility Tuned Isotropic Negative, Zero, and Positive Thermal Expansion in MZrF 6 (M = Ca, Mn, Fe, Co, Ni, and Zn) journal, October 2016

Zero Thermal Expansion in a Flexible, Stable Framework: Tetramethylammonium Copper(I) Zinc(II) Cyanide journal, January 2010

Tunable thermal expansion in framework materials through redox intercalation journal, February 2017

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF 3 journal, November 2010

Local behaviour of negative thermal expansion materials journal, May 2006

Negative thermal expansion and local dynamics in Cu 2 O and Ag 2 O journal, June 2006

Negative thermal expansion in crystals with the delafossite structure: An extended x-ray absorption fine structure study of CuScO 2 and CuLaO 2 journal, March 2009

Toward an Understanding of the Local Origin of Negative Thermal Expansion in ZrW 2 O 8 : Limits and Inconsistencies of the Tent and Rigid Unit Mode Models journal, June 2014

New Insights into the Negative Thermal Expansion: Direct Experimental Evidence for the “Guitar-String” Effect in Cubic ScF 3 journal, June 2016

Size effects on negative thermal expansion in cubic ScF 3 journal, July 2016

Zero Thermal Expansion and Ferromagnetism in Cubic Sc 1– x M x F 3 (M = Ga, Fe) over a Wide Temperature Range journal, September 2014

High-Curie - Temperature Ferromagnetism in (Sc,Fe)F 3 Fluorides and its Dependence on Chemical Valence journal, July 2015

Near-Zero Thermal Expansion and High Ultraviolet Transparency in a Borate Crystal of Zn 4 B 6 O 13 journal, July 2016

Cone-spiral magnetic ordering dominated lattice distortion and giant negative thermal expansion in Fe-doped MnNiGe compounds journal, January 2020

Perovskite-related ReO3-type structures journal, January 2020

On the switching between negative and positive thermal expansion in framework materials journal, May 2019

On the switching between negative and positive thermal expansion in framework materials text, January 2019

On the switching between negative and positive thermal expansion in framework materials text, January 2019

Title: Localized Symmetry Breaking for Tuning Thermal Expansion in ScF₃ Nanoscale Frameworks

Entropically Stabilized Local Dipole Formation in Lead Chalcogenides
journal, December 2010

Local atomic structure of superconducting ${FeSe}_{1 - x} {Te}_{x}$
journal, April 2010

Local Lattice Distortion in the Giant Negative Thermal Expansion Material ${Mn}_{3} {Cu}_{1 - x} {Ge}_{x} N$
journal, November 2008

Zero thermal expansion in a pure-form antiperovskite manganese nitride
journal, March 2009

Adjustable Zero Thermal Expansion in Antiperovskite Manganese Nitride
journal, September 2011

Negative Thermal Expansion from 0.3 to 1050 Kelvin in ZrW2O8
journal, April 1996

A century of zero expansion
journal, July 1999

A fresh twist on shrinking materials
journal, December 2011

Negative thermal expansion materials †
journal, January 1999

Colossal negative thermal expansion in BiNiO3 induced by intermetallic charge transfer
journal, June 2011

Colossal negative thermal expansion in reduced layered ruthenate
journal, January 2017

Colossal Volume Contraction in Strong Polar Perovskites of Pb(Ti,V)O ₃
journal, October 2017

Giant Negative Thermal Expansion in NaZn ₁₃ -Type La(Fe, Si, Co) ₁₃ Compounds
journal, July 2013

Zero Thermal Expansion in Magnetic and Metallic Tb(Co,Fe) ₂ Intermetallic Compounds
journal, January 2018

Systematic and Controllable Negative, Zero, and Positive Thermal Expansion in Cubic Zr _{1– x} Sn _x Mo ₂ O ₈
journal, August 2013

Atomic Linkage Flexibility Tuned Isotropic Negative, Zero, and Positive Thermal Expansion in MZrF ₆ (M = Ca, Mn, Fe, Co, Ni, and Zn)
journal, October 2016

Zero Thermal Expansion in a Flexible, Stable Framework: Tetramethylammonium Copper(I) Zinc(II) Cyanide
journal, January 2010

Tunable thermal expansion in framework materials through redox intercalation
journal, February 2017

Pronounced Negative Thermal Expansion from a Simple Structure: Cubic ScF ₃
journal, November 2010

Local behaviour of negative thermal expansion materials
journal, May 2006

Negative thermal expansion and local dynamics in ${Cu}_{2} O$ and ${Ag}_{2} O$
journal, June 2006

Negative thermal expansion in crystals with the delafossite structure: An extended x-ray absorption fine structure study of ${CuScO}_{2}$ and ${CuLaO}_{2}$
journal, March 2009

Toward an Understanding of the Local Origin of Negative Thermal Expansion in ZrW ₂ O ₈ : Limits and Inconsistencies of the Tent and Rigid Unit Mode Models
journal, June 2014

New Insights into the Negative Thermal Expansion: Direct Experimental Evidence for the “Guitar-String” Effect in Cubic ScF ₃
journal, June 2016

Size effects on negative thermal expansion in cubic ScF ₃
journal, July 2016

Zero Thermal Expansion and Ferromagnetism in Cubic Sc _{1– x} M _x F ₃ (M = Ga, Fe) over a Wide Temperature Range
journal, September 2014

High-Curie - Temperature Ferromagnetism in (Sc,Fe)F ₃ Fluorides and its Dependence on Chemical Valence
journal, July 2015

Near-Zero Thermal Expansion and High Ultraviolet Transparency in a Borate Crystal of Zn ₄ B ₆ O ₁₃
journal, July 2016

Cone-spiral magnetic ordering dominated lattice distortion and giant negative thermal expansion in Fe-doped MnNiGe compounds
journal, January 2020

Perovskite-related ReO3-type structures
journal, January 2020

On the switching between negative and positive thermal expansion in framework materials
journal, May 2019

On the switching between negative and positive thermal expansion in framework materials
text, January 2019

On the switching between negative and positive thermal expansion in framework materials
text, January 2019