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Title: Conductive polymer binder for nano-silicon/graphite composite electrode in lithium-ion batteries towards a practical application

Abstract

The state-of-the-art graphite anode containing a small portion of silicon represents a promising way of applying high-capacity alloy anode in the next generation high energy density lithium-ion batteries. The conductive polymeric binders developed for Si anodes proved to be an effective binder for this graphite/nanoSi composite electrode. Without any acetylene black conductive additives in the electrode, a high areal capacity of above 2.5 mAh/cm2 is achieved during long-term cycling over 100 cycles. Finally, this conductive polymer-enabled graphite/nanoSi composite electrode exhibits high specific capacity and high 1st cycle efficiency, which is a significant progress toward commercial application of Si anodes.

Authors:
 [1];  [2];  [1];  [1];  [1]
+ Show Author Affiliations
  1. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Applied Energy Materials Group. Energy Storage and Distributed Resources Division
  2. Univ. of Michigan, Ann Arbor, MI (United States)
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1433094
Alternate Identifier(s):
OSTI ID: 1324353
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Electrochimica Acta
Additional Journal Information:
Journal Volume: 209; Journal ID: ISSN 0013-4686
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
25 ENERGY STORAGE; conductive polymer binder; silicon nanoparticle; graphite; lithium-ion battery; practical application

Citation Formats

Zhao, Hui, Du, Allen, Ling, Min, Battaglia, Vincent, and Liu, Gao. Conductive polymer binder for nano-silicon/graphite composite electrode in lithium-ion batteries towards a practical application. United States: N. p., 2016. Web. doi:10.1016/j.electacta.2016.05.061.
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Zhao, Hui, Du, Allen, Ling, Min, Battaglia, Vincent, & Liu, Gao. Conductive polymer binder for nano-silicon/graphite composite electrode in lithium-ion batteries towards a practical application. United States. https://doi.org/10.1016/j.electacta.2016.05.061
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Zhao, Hui, Du, Allen, Ling, Min, Battaglia, Vincent, and Liu, Gao. Tue . "Conductive polymer binder for nano-silicon/graphite composite electrode in lithium-ion batteries towards a practical application". United States. https://doi.org/10.1016/j.electacta.2016.05.061. https://www.osti.gov/servlets/purl/1433094.
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@article{osti_1433094,
title = {Conductive polymer binder for nano-silicon/graphite composite electrode in lithium-ion batteries towards a practical application},
author = {Zhao, Hui and Du, Allen and Ling, Min and Battaglia, Vincent and Liu, Gao},
abstractNote = {The state-of-the-art graphite anode containing a small portion of silicon represents a promising way of applying high-capacity alloy anode in the next generation high energy density lithium-ion batteries. The conductive polymeric binders developed for Si anodes proved to be an effective binder for this graphite/nanoSi composite electrode. Without any acetylene black conductive additives in the electrode, a high areal capacity of above 2.5 mAh/cm2 is achieved during long-term cycling over 100 cycles. Finally, this conductive polymer-enabled graphite/nanoSi composite electrode exhibits high specific capacity and high 1st cycle efficiency, which is a significant progress toward commercial application of Si anodes.},
doi = {10.1016/j.electacta.2016.05.061},
journal = {Electrochimica Acta},
number = ,
volume = 209,
place = {United States},
year = {Tue May 10 00:00:00 EDT 2016},
month = {Tue May 10 00:00:00 EDT 2016}
}
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Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1016/j.electacta.2016.05.061
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Works referenced in this record:

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    Works referencing / citing this record:

    High capacity silicon anodes enabled by MXene viscous aqueous ink
    journal, February 2019

    • Zhang, Chuanfang; Park, Sang-Hoon; Seral‐Ascaso, Andrés
    • Nature Communications, Vol. 10, Issue 1
    • DOI: 10.1038/s41467-019-08383-y

    Crosslinked Chitosan Networks as Binders for Silicon/Graphite Composite Electrodes in Li-Ion Batteries
    journal, January 2018

    • Zhao, Xiuyun; Yim, Chae-Ho; Du, Naiying
    • Journal of The Electrochemical Society, Vol. 165, Issue 5
    • DOI: 10.1149/2.114805jes

    Challenges and Recent Progress in the Development of Si Anodes for Lithium-Ion Battery
    journal, September 2017

    Preparation and electromagnetic attenuation properties of MoS2–PANI composites: a promising broadband absorbing material
    journal, November 2018

    • Yang, Jiling; Ye, Mingquan; Han, Aijun
    • Journal of Materials Science: Materials in Electronics, Vol. 30, Issue 1
    • DOI: 10.1007/s10854-018-0292-6

    Bi 2 S 3 /C nanorods as efficient anode materials for lithium-ion batteries
    journal, January 2019

    • Chai, Wenwen; Yang, Fan; Yin, Weihao
    • Dalton Transactions, Vol. 48, Issue 5
    • DOI: 10.1039/c8dt04158j

    Investigation into the bending force performance of the Chitosan based electric actuator manufactured by freeze-drying
    journal, December 2018

    High capacity silicon anodes enabled by MXene viscous aqueous ink
    journal, February 2019

    • Zhang, Chuanfang; Park, Sang-Hoon; Seral‐Ascaso, Andrés
    • Nature Communications, Vol. 10, Issue 1
    • DOI: 10.1038/s41467-019-08383-y
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