Effect of silicon and oxygen dopants on the stability of hydrogenated amorphous carbon under harsh environmental conditions
Abstract
Harsh environments pose materials durability challenges across the automotive, aerospace, and manufacturing sectors, and beyond. While amorphous carbon materials have been used as coatings in many environmentally-demanding applications owing to their unique mechanical, electrical, and optical properties, their limited thermal stability and high reactivity in oxidizing environments have impeded their use in many technologies. Silicon- and oxygen-containing hydrogenated amorphous carbon (a-C:H:Si:O) films are promising for several applications because of their higher thermal stability and lower residual stress compared to hydrogenated amorphous carbon (a-C:H). However, an understanding of their superior thermo-oxidative stability compared to a-C:H is lacking, as it has been inhibited by the intrinsic challenge of characterizing an amorphous, multi-component material. Here, we show that introducing silicon and oxygen in a-C:H slightly enhances the thermal stability in vacuum, but tremendously increases the thermo-oxidative stability and the resistance to degradation upon exposure to the harsh conditions of low Earth orbit (LEO). The latter is demonstrated by having mounted samples of a-C:H:Si:O on the exterior of the International Space Station via the Materials International Space Station (MISSE) mission 7b. Exposing lightly-doped a-C:H:Si:O to elevated temperatures under aerobic conditions or to LEO causes carbon volatilization in the near-surface region, producing a silica surfacemore »
- Authors:
-
- Univ. of Texas, Austin, TX (United States)
- Lehigh Univ., Bethlehem, PA (United States)
- Univ. of Pittsburgh, PA (United States)
- Univ. of Pennsylvania, Philadelphia, PA (United States)
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Univ. of North Texas, Denton, TX (United States)
- Univ. of Florida, Gainesville, FL (United States)
- Publication Date:
- Research Org.:
- Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
- Sponsoring Org.:
- USDOE National Nuclear Security Administration (NNSA); USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1429674
- Alternate Identifier(s):
- OSTI ID: 1525499
- Report Number(s):
- SAND-2017-11747J
Journal ID: ISSN 0008-6223; 658425
- Grant/Contract Number:
- AC04-94AL85000; AC02-98CH10886
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Carbon
- Additional Journal Information:
- Journal Volume: 130; Journal Issue: C; Journal ID: ISSN 0008-6223
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Mangolini, Filippo, Krick, Brandon A., Jacobs, Tevis D. B., Khanal, Subarna R., Streller, Frank, McClimon, J. Brandon, Hilbert, James, Prasad, Somuri V., Scharf, Thomas W., Ohlhausen, James A., Lukes, Jennifer R., Sawyer, W. Gregory, and Carpick, Robert W. Effect of silicon and oxygen dopants on the stability of hydrogenated amorphous carbon under harsh environmental conditions. United States: N. p., 2017.
Web. doi:10.1016/j.carbon.2017.12.096.
Mangolini, Filippo, Krick, Brandon A., Jacobs, Tevis D. B., Khanal, Subarna R., Streller, Frank, McClimon, J. Brandon, Hilbert, James, Prasad, Somuri V., Scharf, Thomas W., Ohlhausen, James A., Lukes, Jennifer R., Sawyer, W. Gregory, & Carpick, Robert W. Effect of silicon and oxygen dopants on the stability of hydrogenated amorphous carbon under harsh environmental conditions. United States. https://doi.org/10.1016/j.carbon.2017.12.096
Mangolini, Filippo, Krick, Brandon A., Jacobs, Tevis D. B., Khanal, Subarna R., Streller, Frank, McClimon, J. Brandon, Hilbert, James, Prasad, Somuri V., Scharf, Thomas W., Ohlhausen, James A., Lukes, Jennifer R., Sawyer, W. Gregory, and Carpick, Robert W. Wed .
"Effect of silicon and oxygen dopants on the stability of hydrogenated amorphous carbon under harsh environmental conditions". United States. https://doi.org/10.1016/j.carbon.2017.12.096. https://www.osti.gov/servlets/purl/1429674.
@article{osti_1429674,
title = {Effect of silicon and oxygen dopants on the stability of hydrogenated amorphous carbon under harsh environmental conditions},
author = {Mangolini, Filippo and Krick, Brandon A. and Jacobs, Tevis D. B. and Khanal, Subarna R. and Streller, Frank and McClimon, J. Brandon and Hilbert, James and Prasad, Somuri V. and Scharf, Thomas W. and Ohlhausen, James A. and Lukes, Jennifer R. and Sawyer, W. Gregory and Carpick, Robert W.},
abstractNote = {Harsh environments pose materials durability challenges across the automotive, aerospace, and manufacturing sectors, and beyond. While amorphous carbon materials have been used as coatings in many environmentally-demanding applications owing to their unique mechanical, electrical, and optical properties, their limited thermal stability and high reactivity in oxidizing environments have impeded their use in many technologies. Silicon- and oxygen-containing hydrogenated amorphous carbon (a-C:H:Si:O) films are promising for several applications because of their higher thermal stability and lower residual stress compared to hydrogenated amorphous carbon (a-C:H). However, an understanding of their superior thermo-oxidative stability compared to a-C:H is lacking, as it has been inhibited by the intrinsic challenge of characterizing an amorphous, multi-component material. Here, we show that introducing silicon and oxygen in a-C:H slightly enhances the thermal stability in vacuum, but tremendously increases the thermo-oxidative stability and the resistance to degradation upon exposure to the harsh conditions of low Earth orbit (LEO). The latter is demonstrated by having mounted samples of a-C:H:Si:O on the exterior of the International Space Station via the Materials International Space Station (MISSE) mission 7b. Exposing lightly-doped a-C:H:Si:O to elevated temperatures under aerobic conditions or to LEO causes carbon volatilization in the near-surface region, producing a silica surface layer that protects the underlying carbon from further removal. In conclusion, these findings provide a novel physically-based understanding of the superior stability of a-C:H:Si:O in harsh environments compared to a-C:H.},
doi = {10.1016/j.carbon.2017.12.096},
journal = {Carbon},
number = C,
volume = 130,
place = {United States},
year = {Wed Dec 27 00:00:00 EST 2017},
month = {Wed Dec 27 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Diamond coatings for micro end mills: Enabling the dry machining of aluminum at the micro-scale
journal, March 2008
- Heaney, Patrick J.; Sumant, Anirudha V.; Torres, Christopher D.
- Diamond and Related Materials, Vol. 17, Issue 3
CVD diamond coating: a technology for tools of future
journal, January 2007
- Palnitkar, Umesh; Lin, I. Nan
- International Journal of Surface Science and Engineering, Vol. 1, Issue 4
Novel Ultrananocrystalline Diamond Probes for High-Resolution Low-Wear Nanolithographic Techniques
journal, August 2005
- Kim, Keun-Ho; Moldovan, Nicolaie; Ke, Changhong
- Small, Vol. 1, Issue 8-9
Preventing Nanoscale Wear of Atomic Force Microscopy Tips Through the Use of Monolithic Ultrananocrystalline Diamond Probes
journal, May 2010
- Liu, J.; Grierson, D. S.; Moldovan, N.
- Small, Vol. 6, Issue 10
Diamond-like carbon for magnetic storage disks
journal, March 2004
- Ferrari, Andrea Carlo
- Surface and Coatings Technology, Vol. 180-181
Head/disk tribology: Toward 10 Gb/in.2 (invited) (abstract)
journal, January 1996
- Marchon, B.
- Journal of Applied Physics, Vol. 79, Issue 8
Automotive tribology overview of current advances and challenges for the future
journal, July 2004
- Tung, Simon C.; McMillan, Michael L.
- Tribology International, Vol. 37, Issue 7
Global energy consumption due to friction in passenger cars
journal, March 2012
- Holmberg, Kenneth; Andersson, Peter; Erdemir, Ali
- Tribology International, Vol. 47
Towards the use of diamond-like carbon solid lubricant coatings in vacuum and space environments
journal, August 2008
- Fontaine, J.
- Proceedings of the Institution of Mechanical Engineers, Part J: Journal of Engineering Tribology, Vol. 222, Issue 8
Thermally induced evolution of hydrogenated amorphous carbon
journal, October 2013
- Mangolini, Filippo; Rose, Franck; Hilbert, James
- Applied Physics Letters, Vol. 103, Issue 16
Heat Assisted Magnetic Recording
journal, November 2008
- Kryder, M. H.; Gage, E. C.; McDaniel, T. W.
- Proceedings of the IEEE, Vol. 96, Issue 11
An electron spectroscopy study of a-C:H under thermal annealing
journal, January 2006
- Calliari, L.; Filippi, M.; Gottardi, G.
- Surface and Interface Analysis, Vol. 38, Issue 4
Diamond-like amorphous carbon
journal, May 2002
- Robertson, J.
- Materials Science and Engineering: R: Reports, Vol. 37, Issue 4-6
Structural stability of hydrogenated amorphous carbon overcoats used in heat-assisted magnetic recording investigated by rapid thermal annealing
journal, February 2013
- Wang, N.; Komvopoulos, K.; Rose, F.
- Journal of Applied Physics, Vol. 113, Issue 8
Thermo‐oxidative erosion of amorphous hydrogenated carbon films
journal, January 1996
- Haasz, A. A.; Chiu, S.; Pierre, J. E.
- Journal of Vacuum Science & Technology A: Vacuum, Surfaces, and Films, Vol. 14, Issue 1
Carbon Overcoat Oxidation in Heat-Assisted Magnetic Recording
journal, July 2013
- Pathem, B. K.; Guo, X. -C.; Rose, F.
- IEEE Transactions on Magnetics, Vol. 49, Issue 7
Thermal stability and oxidation properties of magnetron sputtered diamond-like carbon and its nanocomposite coatings
journal, April 2006
- Zhang, Sam; Bui, Xuan Lam; Li, Xiaomin
- Diamond and Related Materials, Vol. 15, Issue 4-8
Thermal stability in oxidative and protective environments of a-C:H cap layer on a functional gradient coating
journal, February 2011
- Louro, C.; Moura, C. Wagner; Carvalho, N.
- Diamond and Related Materials, Vol. 20, Issue 2
Synchrotron radiation photoelectron spectroscopy and near-edge X-ray absorption fine structure study on oxidative etching of diamond-like carbon films by hyperthermal atomic oxygen
journal, October 2010
- Tagawa, Masahito; Yokota, Kumiko; Kitamura, Akira
- Applied Surface Science, Vol. 256, Issue 24
Space environmental effects on MoS2 and diamond-like carbon lubricating films: Atomic oxygen-induced erosion and its effect on tribological properties
journal, December 2007
- Tagawa, M.; Yokota, K.; Matsumoto, K.
- Surface and Coatings Technology, Vol. 202, Issue 4-7
Thermal stability evaluation of diamond-like nanocomposite coatings
journal, June 2003
- Yang, Won Jae; Choa, Yong-Ho; Sekino, Tohru
- Thin Solid Films, Vol. 434, Issue 1-2
Mechanisms of friction in diamondlike nanocomposite coatings
journal, March 2007
- Scharf, T. W.; Ohlhausen, J. A.; Tallant, D. R.
- Journal of Applied Physics, Vol. 101, Issue 6
Diamond-like nanocomposites (DLN)
journal, May 1992
- Dorfman, V. F.
- Thin Solid Films, Vol. 212, Issue 1-2
Diamond-like nanocomposite coatings (a-C:H/a-Si:O) for tribological applications
journal, February 1998
- Neerinck, D.; Persoone, P.; Sercu, M.
- Diamond and Related Materials, Vol. 7, Issue 2-5
Small amplitude reciprocating wear performance of diamond-like carbon films: dependence of film composition and counterface material
journal, April 2007
- Bares, Jason A.; Sumant, Anirudha V.; Grierson, David S.
- Tribology Letters, Vol. 27, Issue 1
Characterization of diamond-like nanocomposite thin films grown by plasma enhanced chemical vapor deposition
journal, June 2010
- Santra, T. S.; Liu, C. H.; Bhattacharyya, T. K.
- Journal of Applied Physics, Vol. 107, Issue 12
Influence of silicon on the physical properties of diamond-like films
journal, January 1992
- Demichelis, F.; Pirri, C. F.; Tagliaferro, A.
- Materials Science and Engineering: B, Vol. 11, Issue 1-4
Temperature dependent properties of silicon containing diamondlike carbon films prepared by plasma source ion implantation
journal, April 2010
- Hatada, R.; Flege, S.; Baba, K.
- Journal of Applied Physics, Vol. 107, Issue 8
Characteristics and surface energy of silicon-doped diamond-like carbon films fabricated by plasma immersion ion implantation and deposition
journal, September 2006
- Wan, G. J.; Yang, P.; Fu, Ricky K. Y.
- Diamond and Related Materials, Vol. 15, Issue 9
Thermal stability of diamond-like carbon films with added silicon
journal, January 1999
- Wu, Weng-Jin; Hon, Min-Hsiung
- Surface and Coatings Technology, Vol. 111, Issue 2-3
Sliding wear behavior of diamond-like nanocomposite coatings
journal, March 1999
- Kester, D. J.; Brodbeck, C. L.; Singer, I. L.
- Surface and Coatings Technology, Vol. 113, Issue 3
Diamond-like nanocomposite coatings for low-wear and low-friction applications in humid environments
journal, April 1998
- Neerinck, D.; Persoone, P.; Sercu, M.
- Thin Solid Films, Vol. 317, Issue 1-2
LIGA Microsystems: Surface Interactions, Tribology, and Coatings
journal, January 2004
- Prasad, Somuri V.; Dugger, Michael T.; Christenson, Todd R.
- Journal of Manufacturing Processes, Vol. 6, Issue 1
Tribological properties of diamond-like nanocomposite coatings at high temperatures
journal, July 1999
- Venkatraman, C.; Brodbeck, C.; Lei, R.
- Surface and Coatings Technology, Vol. 115, Issue 2-3
Electrical properties of diamond-like nanocomposite coatings
journal, October 1997
- Venkatraman, C.; Goel, A.; Lei, R.
- Thin Solid Films, Vol. 308-309
Space Tribometers: Design for Exposed Experiments on Orbit
journal, September 2010
- Krick, Brandon A.; Sawyer, W. Gregory
- Tribology Letters, Vol. 41, Issue 1
Angle-resolved environmental X-ray photoelectron spectroscopy: A new laboratory setup for photoemission studies at pressures up to 0.4 Torr
journal, September 2012
- Mangolini, F.; Åhlund, J.; Wabiszewski, G. E.
- Review of Scientific Instruments, Vol. 83, Issue 9
Chemical Reactivity of Triphenyl Phosphorothionate (TPPT) with Iron: An ATR/FT-IR and XPS Investigation
journal, September 2010
- Mangolini, Filippo; Rossi, Antonella; Spencer, Nicholas D.
- The Journal of Physical Chemistry C, Vol. 115, Issue 4
Accounting for Nanometer-Thick Adventitious Carbon Contamination in X-ray Absorption Spectra of Carbon-Based Materials
journal, November 2014
- Mangolini, Filippo; McClimon, J. Brandon; Rose, Franck
- Analytical Chemistry, Vol. 86, Issue 24
Quantitative Evaluation of the Carbon Hybridization State by Near Edge X-ray Absorption Fine Structure Spectroscopy
journal, February 2016
- Mangolini, Filippo; McClimon, J. Brandon; Carpick, Robert W.
- Analytical Chemistry, Vol. 88, Issue 5
Why Can’t We See Hydrogen in X-ray Photoelectron Spectroscopy?
journal, July 2012
- Stojilovic, Nenad
- Journal of Chemical Education, Vol. 89, Issue 10
Understanding the hydrogen and oxygen gas pressure dependence of the tribological properties of silicon oxide–doped hydrogenated amorphous carbon coatings
journal, November 2015
- Koshigan, K. D.; Mangolini, F.; McClimon, J. B.
- Carbon, Vol. 93
Solid state magnetic resonance investigation of the thermally-induced structural evolution of silicon oxide-doped hydrogenated amorphous carbon
journal, August 2016
- Peng, Jing; Sergiienko, Anastasiia; Mangolini, Filippo
- Carbon, Vol. 105
Structural studies of argon-sputtered amorphous carbon films by means of extended x-ray-absorption fine structure
journal, October 1988
- Comelli, G.; Stöhr, J.; Robinson, C. J.
- Physical Review B, Vol. 38, Issue 11
Thermal stability and rehybridization of carbon bonding in tetrahedral amorphous carbon
journal, February 2010
- Grierson, D. S.; Sumant, A. V.; Konicek, A. R.
- Journal of Applied Physics, Vol. 107, Issue 3, Article No. 033523
Surface composition, bonding, and morphology in the nucleation and growth of ultra-thin, high quality nanocrystalline diamond films
journal, April 2007
- Sumant, Anirudha V.; Gilbert, P. U. P. A.; Grierson, David S.
- Diamond and Related Materials, Vol. 16, Issue 4-7
Local structural analysis of a-SiCx:H films formed by decomposition of tetramethylsilane in microwave discharge flow of Ar
journal, March 2011
- Wada, Akira; Ogaki, Takeshi; Niibe, Masahito
- Diamond and Related Materials, Vol. 20, Issue 3
Stress relaxation and thermal evolution of film properties in amorphous carbon
journal, September 1997
- Sullivan, J. P.; Friedmann, T. A.; Baca, A. G.
- Journal of Electronic Materials, Vol. 26, Issue 9
Is stress necessary to stabilise sp3 bonding in diamond-like carbon?
journal, March 2002
- Ferrari, A. C.; Rodil, S. E.; Robertson, J.
- Diamond and Related Materials, Vol. 11, Issue 3-6
Thickness of diamond-like carbon coatings quantified with Raman spectroscopy
journal, September 2003
- Scharf, T. W.; Singer, I. L.
- Thin Solid Films, Vol. 440, Issue 1-2
Hyperthermal atomic oxygen interaction with MoS2 lubricants and relevance to space environmental effects in low earth orbit – effects on friction coefficient and wear-life
journal, April 2005
- Tagawa, M.; Muromoto, M.; Hachiue, S.
- Tribology Letters, Vol. 18, Issue 4
Space tribology: its role in spacecraft mechanisms
journal, November 2012
- Roberts, E. W.
- Journal of Physics D: Applied Physics, Vol. 45, Issue 50
Lessons Learned from Atomic Oxygen Interaction with Spacecraft Materials in Low Earth Orbit
conference, January 2009
- Banks, Bruce A.; de Groh, Kim K.; Miller, Sharon K.
- PROTECTION OF MATERIALS AND STRUCTURES FROM SPACE ENVIRONMENT: Proceedings of the 9th International Conference: Protection of Materials and Structures From Space Environment, AIP Conference Proceedings
Comparison of Macro and Microtribological Property of Molybdenum Disulfide Film Exposed to LEO Space Environment
journal, November 2011
- Tagawa, Masahito; Yokota, Kumiko; Ochi, Kunitaka
- Tribology Letters, Vol. 45, Issue 2
High-temperature oxidation behaviour of carbon materials in air
journal, January 1993
- Shemet, V. Zh.; Pomytkin, A. P.; Neshpor, V. S.
- Carbon, Vol. 31, Issue 1
Degradation of Spacecraft Materials in the Space Environment
journal, January 2010
- Miller, Sharon K. R.; Banks, Bruce
- MRS Bulletin, Vol. 35, Issue 1
Works referencing / citing this record:
Silicon Oxide-Rich Diamond-Like Carbon: A Conformal, Ultrasmooth Thin Film Material with High Thermo-Oxidative Stability
journal, November 2018
- Mangolini, Filippo; McClimon, J. Brandon; Segersten, Justin
- Advanced Materials Interfaces, Vol. 6, Issue 2
Mechanism of contact pressure-induced friction at the amorphous carbon/alpha olefin interface
journal, September 2018
- Li, Xiaowei; Wang, Aiying; Lee, Kwang-Ryeol
- npj Computational Materials, Vol. 4, Issue 1
Tribological properties of Ti-doped diamond-like carbon coatings under dry friction and PAO oil lubrication
journal, November 2018
- Guo, Youzhi; Guo, Peng; Sun, Lili
- Surface and Interface Analysis, Vol. 51, Issue 3