Structure-property relationships in NOx sensor materials composed of arrays of vanadium oxide nanoclusters
Abstract
Here, the mixed-valent vanadium oxide based three-dimensional framework structure species [Cd3(H2O)12V16IVV2VO36(OH)6(AO4)]∙24H2O, (A=V,S) (Cd3(VO)o) represents a rare example of an interesting sensor material which exhibits NOx {NO+NO2} semiconducting gas sensor properties under ambient conditions. The electrical resistance of the sensor material Cd3(VO)o decreases in air. Combined characterization studies revealed that the building block, {V18O42(AO4)} cluster, of 3-D framework undergoes oxidation and remains intact for at least 2 months. The decrease in resistance is attributable to the reactivity of molecular oxygen towards vanadium which results in an increase in the oxidation state as well as the coordination number of vanadium center and decrease in band gap of Cd3(VO)o. Based on these results we propose that the changes in semiconducting properties of Cd3(VO)o under ambient conditions are due to the greater overlap between the O 2p and V 3d orbitals occurring during the oxidation.
- Authors:
-
[1];
[1];
- Illinois Inst. of Technology, Chicago, IL (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Chicago, Chicago, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1429402
- Alternate Identifier(s):
- OSTI ID: 1549490
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Solid State Sciences
- Additional Journal Information:
- Journal Volume: 74; Journal Issue: C; Journal ID: ISSN 1293-2558
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; vanadium oxide nanoclusters; NOx sensing; oxidation; XAFS
Citation Formats
Putrevu, Naga Ravikanth, Darling, Seth B., Segre, Carlo U., Ganegoda, Hasitha, and Khan, M. Ishaque. Structure-property relationships in NOx sensor materials composed of arrays of vanadium oxide nanoclusters. United States: N. p., 2017.
Web. doi:10.1016/j.solidstatesciences.2017.09.008.
Putrevu, Naga Ravikanth, Darling, Seth B., Segre, Carlo U., Ganegoda, Hasitha, & Khan, M. Ishaque. Structure-property relationships in NOx sensor materials composed of arrays of vanadium oxide nanoclusters. United States. https://doi.org/10.1016/j.solidstatesciences.2017.09.008
Putrevu, Naga Ravikanth, Darling, Seth B., Segre, Carlo U., Ganegoda, Hasitha, and Khan, M. Ishaque. Wed .
"Structure-property relationships in NOx sensor materials composed of arrays of vanadium oxide nanoclusters". United States. https://doi.org/10.1016/j.solidstatesciences.2017.09.008. https://www.osti.gov/servlets/purl/1429402.
@article{osti_1429402,
title = {Structure-property relationships in NOx sensor materials composed of arrays of vanadium oxide nanoclusters},
author = {Putrevu, Naga Ravikanth and Darling, Seth B. and Segre, Carlo U. and Ganegoda, Hasitha and Khan, M. Ishaque},
abstractNote = {Here, the mixed-valent vanadium oxide based three-dimensional framework structure species [Cd3(H2O)12V16IVV2VO36(OH)6(AO4)]∙24H2O, (A=V,S) (Cd3(VO)o) represents a rare example of an interesting sensor material which exhibits NOx {NO+NO2} semiconducting gas sensor properties under ambient conditions. The electrical resistance of the sensor material Cd3(VO)o decreases in air. Combined characterization studies revealed that the building block, {V18O42(AO4)} cluster, of 3-D framework undergoes oxidation and remains intact for at least 2 months. The decrease in resistance is attributable to the reactivity of molecular oxygen towards vanadium which results in an increase in the oxidation state as well as the coordination number of vanadium center and decrease in band gap of Cd3(VO)o. Based on these results we propose that the changes in semiconducting properties of Cd3(VO)o under ambient conditions are due to the greater overlap between the O 2p and V 3d orbitals occurring during the oxidation.},
doi = {10.1016/j.solidstatesciences.2017.09.008},
journal = {Solid State Sciences},
number = C,
volume = 74,
place = {United States},
year = {Wed Oct 04 00:00:00 EDT 2017},
month = {Wed Oct 04 00:00:00 EDT 2017}
}
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