Self-organization of helium precipitates into elongated channels within metal nanolayers
Abstract
Material degradation due to precipitation of implanted helium (He) is a key concern in nuclear energy. Decades of research have mapped out the fate of He precipitates in metals, from nucleation and growth of equiaxed bubbles and voids to formation and bursting of surface blisters. By contrast, we show that He precipitates confined within nanoscale metal layers depart from their classical growth trajectories: They self-organize into elongated channels. These channels form via templated nucleation of He precipitates along layer surfaces followed by their growth and spontaneous coalescence into stable precipitate lines. The total line length and connectivity increases with the amount of implanted He, indicating that these channels ultimately interconnect into percolating “vascular” networks. In conclusion, vascularized metal composites promise a transformative solution to He-induced damage by enabling in operando outgassing of He and other impurities while maintaining material integrity.
- Authors:
-
- Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
- Massachusetts Inst. of Technology (MIT), Cambridge, MA (United States)
- Texas A & M Univ., College Station, TX (United States)
- Publication Date:
- Research Org.:
- Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
- Sponsoring Org.:
- USDOE Laboratory Directed Research and Development (LDRD) Program
- OSTI Identifier:
- 1418768
- Report Number(s):
- LA-UR-17-25074
Journal ID: ISSN 2375-2548
- Grant/Contract Number:
- AC52-06NA25396
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Science Advances
- Additional Journal Information:
- Journal Volume: 3; Journal Issue: 11; Journal ID: ISSN 2375-2548
- Publisher:
- AAAS
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Chen, Di, Li, Nan, Yuryev, Dina, Baldwin, Jon Kevin Scott, Wang, Yongqiang, and Demkowicz, Michael J. Self-organization of helium precipitates into elongated channels within metal nanolayers. United States: N. p., 2017.
Web. doi:10.1126/sciadv.aao2710.
Chen, Di, Li, Nan, Yuryev, Dina, Baldwin, Jon Kevin Scott, Wang, Yongqiang, & Demkowicz, Michael J. Self-organization of helium precipitates into elongated channels within metal nanolayers. United States. https://doi.org/10.1126/sciadv.aao2710
Chen, Di, Li, Nan, Yuryev, Dina, Baldwin, Jon Kevin Scott, Wang, Yongqiang, and Demkowicz, Michael J. Fri .
"Self-organization of helium precipitates into elongated channels within metal nanolayers". United States. https://doi.org/10.1126/sciadv.aao2710. https://www.osti.gov/servlets/purl/1418768.
@article{osti_1418768,
title = {Self-organization of helium precipitates into elongated channels within metal nanolayers},
author = {Chen, Di and Li, Nan and Yuryev, Dina and Baldwin, Jon Kevin Scott and Wang, Yongqiang and Demkowicz, Michael J.},
abstractNote = {Material degradation due to precipitation of implanted helium (He) is a key concern in nuclear energy. Decades of research have mapped out the fate of He precipitates in metals, from nucleation and growth of equiaxed bubbles and voids to formation and bursting of surface blisters. By contrast, we show that He precipitates confined within nanoscale metal layers depart from their classical growth trajectories: They self-organize into elongated channels. These channels form via templated nucleation of He precipitates along layer surfaces followed by their growth and spontaneous coalescence into stable precipitate lines. The total line length and connectivity increases with the amount of implanted He, indicating that these channels ultimately interconnect into percolating “vascular” networks. In conclusion, vascularized metal composites promise a transformative solution to He-induced damage by enabling in operando outgassing of He and other impurities while maintaining material integrity.},
doi = {10.1126/sciadv.aao2710},
journal = {Science Advances},
number = 11,
volume = 3,
place = {United States},
year = {Fri Nov 10 00:00:00 EST 2017},
month = {Fri Nov 10 00:00:00 EST 2017}
}
Web of Science
Works referenced in this record:
Intergranular fracture in irradiated Inconel X-750 containing very high concentrations of helium and hydrogen
journal, February 2015
- Judge, Colin D.; Gauquelin, Nicolas; Walters, Lori
- Journal of Nuclear Materials, Vol. 457
Helium accumulation in metals during irradiation – where do we stand?
journal, December 2003
- Trinkaus, H.; Singh, B. N.
- Journal of Nuclear Materials, Vol. 323, Issue 2-3
Energetics and formation kinetics of helium bubbles in metals
journal, January 1983
- Trinkaus, H.
- Radiation Effects, Vol. 78, Issue 1-4
Mechanisms of helium interaction with radiation effects in metals and alloys: A review
journal, November 1983
- Mansur, L. K.; Coghlan, W. A.
- Journal of Nuclear Materials, Vol. 119, Issue 1
The theory of void nucleation in metals
journal, October 1978
- Russell, K. C.
- Acta Metallurgica, Vol. 26, Issue 10
The role of gas pressure and lateral stress on blistering
journal, October 1980
- Wolfer, W. G.
- Journal of Nuclear Materials, Vol. 93-94
Protrusion formation and surface porosity development on thermally annealed helium implanted copper
journal, April 2004
- Escobar Galindo, R.; van Veen, A.; Evans, J. H.
- Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 217, Issue 2
Plasma-wall interaction of advanced materials
journal, August 2017
- Coenen, J. W.; Berger, M.; Demkowicz, M. J.
- Nuclear Materials and Energy, Vol. 12
Morphology of micro-cavities in nickel during Helium bombardment and post-irradiation annealing
journal, April 1988
- Niwase, K.; Ezawa, T.; Fujita, F. E.
- Radiation Effects, Vol. 106, Issue 1-2
On The Instability Of Jets
journal, November 1878
- Rayleigh, Lord
- Proceedings of the London Mathematical Society, Vol. s1-10, Issue 1
Arrest of He bubble growth in Cu–Nb multilayer nanocomposites
journal, April 2008
- Hattar, K.; Demkowicz, M. J.; Misra, A.
- Scripta Materialia, Vol. 58, Issue 7
He implantation of bulk Cu–Nb nanocomposites fabricated by accumulated roll bonding
journal, September 2014
- Han, W. Z.; Mara, N. A.; Wang, Y. Q.
- Journal of Nuclear Materials, Vol. 452, Issue 1-3
Simulations of the breakup of liquid filaments on a partially wetting solid substrate
journal, July 2013
- Ghigliotti, Giovanni; Zhou, Chunfeng; Feng, James J.
- Physics of Fluids, Vol. 25, Issue 7
Tunable helium bubble superlattice ordered by screw dislocation network
journal, August 2011
- Di, Zengfeng; Bai, Xian-Ming; Wei, Qiangmin
- Physical Review B, Vol. 84, Issue 5
Adhesion of voids to bimetal interfaces with non-uniform energies
journal, October 2015
- Zheng, Shijian; Shao, Shuai; Zhang, Jian
- Scientific Reports, Vol. 5, Issue 1
Helium bubble growth at BCC twist grain boundaries
journal, December 2011
- Hetherly, J.; Martinez, E.; Nastasi, M.
- Journal of Nuclear Materials, Vol. 419, Issue 1-3
Imaging the in-plane distribution of helium precipitates at a Cu/V interface
journal, February 2017
- Chen, Di; Li, Nan; Yuryev, Dina
- Materials Research Letters, Vol. 5, Issue 5
The influence of interfaces on the formation of bubbles in He-ion-irradiated Cu/Mo nanolayers
journal, January 2011
- Li, Nan; Carter, J. J.; Misra, A.
- Philosophical Magazine Letters, Vol. 91, Issue 1
The Stopping and Range of Ions in Matter
book, January 1985
- Ziegler, James F.; Biersack, Jochen P.
- Treatise on Heavy-Ion Science
Interface enabled defects reduction in helium ion irradiated Cu/V nanolayers
journal, December 2010
- Fu, E. G.; Misra, A.; Wang, H.
- Journal of Nuclear Materials, Vol. 407, Issue 3
The role of interface structure in controlling high helium concentrations
journal, June 2012
- Demkowicz, M. J.; Misra, A.; Caro, A.
- Current Opinion in Solid State and Materials Science, Vol. 16, Issue 3
Stability and breakup of confined threads
journal, January 2012
- Janssen, P. J. A.; Meijer, H. E. H.; Anderson, P. D.
- Physics of Fluids, Vol. 24, Issue 1
Computational design of solid-state interfaces using O-lattice theory: An application to mitigating helium-induced damage
journal, December 2014
- Yuryev, D. V.; Demkowicz, M. J.
- Applied Physics Letters, Vol. 105, Issue 22
Helium bubble precipitation at dislocation networks
journal, January 2012
- Hetherly, J.; Martinez, E.; Di, Z. F.
- Scripta Materialia, Vol. 66, Issue 1
Microstructure of copper following high dose 14-MeV Cu ion irradiation
journal, March 1986
- Zinkle, S. J.; Kulcinski, G. L.; Knoll, R. W.
- Journal of Nuclear Materials, Vol. 138, Issue 1
Modeling growth, coalescence, and stability of helium precipitates on patterned interfaces
journal, November 2016
- Yuryev, D. V.; Demkowicz, M. J.
- Modelling and Simulation in Materials Science and Engineering, Vol. 25, Issue 1
Mechanisms of He escape during implantation in CuNb multilayer composites
journal, August 2007
- Demkowicz, M. J.; Wang, Y. Q.; Hoagland, R. G.
- Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 261, Issue 1-2
Interfacial trapping mechanism of He in Cu–Nb multilayer materials
journal, June 2013
- McPhie, M. G.; Capolungo, L.; Dunn, A. Y.
- Journal of Nuclear Materials, Vol. 437, Issue 1-3
A rate theory study of helium bubble formation and retention in Cu–Nb nanocomposites
journal, April 2013
- Dunn, A. Y.; McPhie, M. G.; Capolungo, L.
- Journal of Nuclear Materials, Vol. 435, Issue 1-3
Tungsten as material for plasma-facing components in fusion devices
journal, August 2011
- Philipps, V.
- Journal of Nuclear Materials, Vol. 415, Issue 1
Recent advances in modeling and simulation of the exposure and response of tungsten to fusion energy conditions
journal, June 2017
- Marian, Jaime; Becquart, Charlotte S.; Domain, Christophe
- Nuclear Fusion, Vol. 57, Issue 9
Formation process of tungsten nanostructure by the exposure to helium plasma under fusion relevant plasma conditions
journal, August 2009
- Kajita, Shin; Sakaguchi, Wataru; Ohno, Noriyasu
- Nuclear Fusion, Vol. 49, Issue 9
A description of bubble growth and gas release of helium implanted tungsten
journal, April 2009
- Sharafat, S.; Takahashi, A.; Hu, Q.
- Journal of Nuclear Materials, Vol. 386-388
Formation of helium induced nanostructure ‘fuzz’ on various tungsten grades
journal, September 2010
- Baldwin, M. J.; Doerner, R. P.
- Journal of Nuclear Materials, Vol. 404, Issue 3
Influence of helium induced nanostructures on the thermal shock performance of tungsten
journal, December 2016
- Wirtz, M.; Berger, M.; Huber, A.
- Nuclear Materials and Energy, Vol. 9
Deuterium retention in tungsten in dependence of the surface conditions
journal, March 2003
- Ogorodnikova, O. V.; Roth, J.; Mayer, M.
- Journal of Nuclear Materials, Vol. 313-316
Retention behavior in tungsten and molybdenum exposed to high fluences of deuterium ions in TPE
journal, June 2009
- Sharpe, J. P.; Kolasinski, R. D.; Shimada, M.
- Journal of Nuclear Materials, Vol. 390-391
Design of Radiation Tolerant Materials Via Interface Engineering
journal, September 2013
- Han, Weizhong; Demkowicz, Michael J.; Mara, Nathan A.
- Advanced Materials, Vol. 25, Issue 48
Radiation damage tolerant nanomaterials
journal, November 2013
- Beyerlein, I. J.; Caro, A.; Demkowicz, M. J.
- Materials Today, Vol. 16, Issue 11
Kinetics and morphological evolution of liquid metal dealloying
journal, August 2016
- McCue, Ian; Gaskey, Bernard; Geslin, Pierre-Antoine
- Acta Materialia, Vol. 115
Topology-generating interfacial pattern formation during liquid metal dealloying
journal, November 2015
- Geslin, Pierre-Antoine; McCue, Ian; Gaskey, Bernard
- Nature Communications, Vol. 6, Issue 1
Irradiation-induced patterning in dilute Cu–Fe alloys
journal, October 2014
- Stumphy, B.; Chee, S. W.; Vo, N. Q.
- Journal of Nuclear Materials, Vol. 453, Issue 1-3
Dynamic self-organization in Cu alloys under ion irradiation
journal, July 2010
- Chee, S. W.; Stumphy, B.; Vo, N. Q.
- Acta Materialia, Vol. 58, Issue 12
Material testing facilities and programs for plasma-facing component testing
journal, June 2017
- Linsmeier, Ch.; Unterberg, B.; Coenen, J. W.
- Nuclear Fusion, Vol. 57, Issue 9
An object-oriented finite element framework for multiphysics phase field simulations
journal, January 2012
- Tonks, Michael R.; Gaston, Derek; Millett, Paul C.
- Computational Materials Science, Vol. 51, Issue 1
Kinetics and morphological evolution of liquid metal dealloying
journal, August 2016
- McCue, Ian; Gaskey, Bernard; Geslin, Pierre-Antoine
- Acta Materialia, Vol. 115
Interfacial trapping mechanism of He in Cu–Nb multilayer materials
journal, June 2013
- McPhie, M. G.; Capolungo, L.; Dunn, A. Y.
- Journal of Nuclear Materials, Vol. 437, Issue 1-3
Radiation damage tolerant nanomaterials
journal, November 2013
- Beyerlein, I. J.; Caro, A.; Demkowicz, M. J.
- Materials Today, Vol. 16, Issue 11
Topology-generating interfacial pattern formation during liquid metal dealloying
journal, November 2015
- Geslin, Pierre-Antoine; McCue, Ian; Gaskey, Bernard
- Nature Communications, Vol. 6, Issue 1
Adhesion of voids to bimetal interfaces with non-uniform energies
journal, October 2015
- Zheng, Shijian; Shao, Shuai; Zhang, Jian
- Scientific Reports, Vol. 5, Issue 1
Energetics and formation kinetics of helium bubbles in metals
journal, January 1983
- Trinkaus, H.
- Radiation Effects, Vol. 78, Issue 1-4
Morphology of micro-cavities in nickel during Helium bombardment and post-irradiation annealing
journal, April 1988
- Niwase, K.; Ezawa, T.; Fujita, F. E.
- Radiation Effects, Vol. 106, Issue 1-2
Material testing facilities and programs for plasma-facing component testing
journal, June 2017
- Linsmeier, Ch.; Unterberg, B.; Coenen, J. W.
- Nuclear Fusion, Vol. 57, Issue 9
Recent advances in modeling and simulation of the exposure and response of tungsten to fusion energy conditions
journal, June 2017
- Marian, Jaime; Becquart, Charlotte S.; Domain, Christophe
- Nuclear Fusion, Vol. 57, Issue 9
Works referencing / citing this record:
Understanding the release of helium atoms from nanochannel tungsten: a molecular dynamics simulation
journal, June 2019
- Wei, Guo; Ren, Feng; Fang, Jingzhong
- Nuclear Fusion, Vol. 59, Issue 7
Ion beam analysis of fusion plasma-facing materials and components: facilities and research challenges
journal, December 2019
- Mayer, M.; Möller, S.; Rubel, M.
- Nuclear Fusion, Vol. 60, Issue 2
Symmetry breaking during defect self-organization under irradiation
journal, May 2020
- Zhang, Yongfeng; Gao, Yipeng; Sun, Cheng
- Materials Theory, Vol. 4, Issue 1
An in situ study on Kr ion–irradiated crystalline Cu/amorphous-CuNb nanolaminates
journal, March 2019
- Fan, Zhe; Fan, Cuncai; Li, Jin
- Journal of Materials Research, Vol. 34, Issue 13