Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions

Moore, Samuel L.; Samudrala, Gopi K.; Catledge, Shane A.; Vohra, Yogesh K.

doi:10.1038/s41598-018-19915-9

Title: Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions

Abstract

Early stage nucleation morphologies of spatially localized nanocrystalline diamond (NCD) micro-anvils grown on (100)-oriented single crystal diamond (SCD) anvil surfaces were analyzed and investigated for applications in high pressure studies on materials. NCD was grown on SCD using Microwave Plasma Chemical Vapor Deposition (MPCVD) for brief time intervals ranging from 1-15 minutes. Early stage film morphologies were characterized using scanning electron microscopy (SEM) and Raman spectroscopy and were compared to films grown for several hours. Rapid nucleation and growth of NCD on SCD is demonstrated without any pre-growth seeding of the substrate surface. As grown NCD diamond micro-anvils on SCD were used to generate static pressure of 0.5 Terapascal (TPa) on a tungsten sample as measured by synchrotron x-ray diffraction in a diamond anvil cell. Atomic force microscopy (AFM) analysis after decompression from ultrahigh pressures showed that the detachment of the NCD stage occurred in the bulk of the SCD and not at the interface, suggesting significant adhesive bond strength between nanocrystalline and single crystal diamond.

Authors:

Moore, Samuel L. ^[1]; Samudrala, Gopi K. ^[1]; Catledge, Shane A. ^[1]; Vohra, Yogesh K. ^[1]

Univ.of Alabama, Birmingham, AL (United States). Dept. of Physics

Publication Date:: Tue Jan 23 00:00:00 EST 2018

Research Org.:: Univ.of Alabama, Birmingham, AL (United States)

Sponsoring Org.:: USDOE National Nuclear Security Administration (NNSA), Office of Defense Science (NA-113); USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1417745

Grant/Contract Number:: NA0002928; NA002006; NA0001974; FG02-99ER45775; AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Scientific Reports

Additional Journal Information:: Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2045-2322

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; High Pressure; Nanotechnology; Extreme Conditions; Chemical Vapor Deposition; Synthetic Diamond

Citation Formats


                    Moore, Samuel L., Samudrala, Gopi K., Catledge, Shane A., and Vohra, Yogesh K. Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions.  United States: N. p., 2018. 
Web.  doi:10.1038/s41598-018-19915-9.

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                    Moore, Samuel L., Samudrala, Gopi K., Catledge, Shane A., & Vohra, Yogesh K. Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions.  United States.  https://doi.org/10.1038/s41598-018-19915-9

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                    Moore, Samuel L., Samudrala, Gopi K., Catledge, Shane A., and Vohra, Yogesh K. Tue .  
"Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions".  United States.  https://doi.org/10.1038/s41598-018-19915-9.  https://www.osti.gov/servlets/purl/1417745.

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@article{osti_1417745,

  title        = {Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions},

  author       = {Moore, Samuel L. and Samudrala, Gopi K. and Catledge, Shane A. and Vohra, Yogesh K.},

  abstractNote = {Early stage nucleation morphologies of spatially localized nanocrystalline diamond (NCD) micro-anvils grown on (100)-oriented single crystal diamond (SCD) anvil surfaces were analyzed and investigated for applications in high pressure studies on materials. NCD was grown on SCD using Microwave Plasma Chemical Vapor Deposition (MPCVD) for brief time intervals ranging from 1-15 minutes. Early stage film morphologies were characterized using scanning electron microscopy (SEM) and Raman spectroscopy and were compared to films grown for several hours. Rapid nucleation and growth of NCD on SCD is demonstrated without any pre-growth seeding of the substrate surface. As grown NCD diamond micro-anvils on SCD were used to generate static pressure of 0.5 Terapascal (TPa) on a tungsten sample as measured by synchrotron x-ray diffraction in a diamond anvil cell. Atomic force microscopy (AFM) analysis after decompression from ultrahigh pressures showed that the detachment of the NCD stage occurred in the bulk of the SCD and not at the interface, suggesting significant adhesive bond strength between nanocrystalline and single crystal diamond.},

  doi          = {10.1038/s41598-018-19915-9},

  journal      = {Scientific Reports},

  number       = 1,

  volume       = 8,

  place        = {United States},

  year         = {Tue Jan 23 00:00:00 EST 2018},

  month        = {Tue Jan 23 00:00:00 EST 2018}

}

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Epitaxial diamond encapsulation of metal microprobes for high pressure experiments
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Diamond nanoseeding on silicon: Stability under H2 MPCVD exposures and early stages of growth
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Arnault, J. C.; Saada, S.; Nesladek, M.
Diamond and Related Materials, Vol. 17, Issue 7-10
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Title: Rapid Growth of Nanocrystalline Diamond on Single Crystal Diamond for Studies on Materials under Extreme Conditions

Abstract

Citation Formats

Diamond nanoseeding on silicon: Stability under H2 MPCVD exposures and early stages of growth journal, July 2008

Reevaluation of the mechanism for ultrananocrystalline diamond deposition from Ar∕CH4∕H2 gas mixtures journal, May 2006

High pressure studies using two-stage diamond micro-anvils grown by chemical vapor deposition journal, May 2015

Electrical measurements on praseodymium metal to 179 GPa using designer diamond anvils journal, February 2004

The most incompressible metal osmium at static pressures above 750 gigapascals journal, August 2015

Terapascal static pressure generation with ultrahigh yield strength nanodiamond text, January 2016

The most incompressible metal osmium at static pressures above 750 gigapascals journal, August 2015

The valuable role of renucleation rate in ultrananocrystalline diamond growth journal, March 2012

Nucleation and growth of nanocrystalline diamond on NaCl substrate by RF-PECVD journal, April 2013

Finite Elastic Strain of Cubic Crystals journal, June 1947

Comparison of the growth and properties of ultrananocrystalline diamond and nanocrystalline diamond journal, April 2006

High pressure studies using two-stage diamond micro-anvils grown by chemical vapor deposition journal, May 2015

Epitaxial diamond encapsulation of metal microprobes for high pressure experiments journal, November 2000

Reevaluation of the mechanism for ultrananocrystalline diamond deposition from Ar∕CH4∕H2 gas mixtures journal, May 2006

Terapascal static pressure generation with ultrahigh yield strength nanodiamond journal, July 2016

Theoretical Strength and Cleavage of Diamond journal, May 2000

Shock compression of tungsten and molybdenum journal, February 1992

Shock compression of tungsten and molybdenum journal, February 1992

Incorporation of nitrogen in chemical vapor deposition diamond journal, November 1995

Enhanced diamond nucleation on monodispersed nanocrystalline diamond journal, September 2007

Raman spectroscopy of amorphous, nanostructured, diamond–like carbon, and nanodiamond journal, September 2004

Fabrication of Diamond Based Sensors for Use in Extreme Environments journal, April 2015

From Mott Insulators to Quantum Metals preprint, January 2020

Incorporation of nitrogen in chemical vapor deposition diamond journal, November 1995

Terapascal static pressure generation with ultrahigh yield strength nanodiamond journal, July 2016

Comparison of the growth and properties of ultrananocrystalline diamond and nanocrystalline diamond journal, April 2006

Epitaxial diamond encapsulation of metal microprobes for high pressure experiments journal, November 2000

Diamond nanoseeding on silicon: Stability under H2 MPCVD exposures and early stages of growth journal, July 2008

Pressure, stress, and strain distribution in the double-stage diamond anvil cell journal, July 2015

Nanocrystalline diamond micro-anvil grown on single crystal diamond as a generator of ultra-high pressures journal, September 2016

Diamond sculpting pushes extremes journal, September 2018

Fly scan apparatus for high pressure research using diamond anvil cells journal, January 2019

Single crystal toroidal diamond anvils for high pressure experiments beyond 5 megabar journal, September 2018

Diamond nanoseeding on silicon: Stability under H2 MPCVD exposures and early stages of growth
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Reevaluation of the mechanism for ultrananocrystalline diamond deposition from Ar∕CH4∕H2 gas mixtures
journal, May 2006

High pressure studies using two-stage diamond micro-anvils grown by chemical vapor deposition
journal, May 2015

Electrical measurements on praseodymium metal to 179 GPa using designer diamond anvils
journal, February 2004

The most incompressible metal osmium at static pressures above 750 gigapascals
journal, August 2015

Terapascal static pressure generation with ultrahigh yield strength nanodiamond
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The most incompressible metal osmium at static pressures above 750 gigapascals
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The valuable role of renucleation rate in ultrananocrystalline diamond growth
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Nucleation and growth of nanocrystalline diamond on NaCl substrate by RF-PECVD
journal, April 2013

Finite Elastic Strain of Cubic Crystals
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Comparison of the growth and properties of ultrananocrystalline diamond and nanocrystalline diamond
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High pressure studies using two-stage diamond micro-anvils grown by chemical vapor deposition
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Epitaxial diamond encapsulation of metal microprobes for high pressure experiments
journal, November 2000

Reevaluation of the mechanism for ultrananocrystalline diamond deposition from Ar∕CH4∕H2 gas mixtures
journal, May 2006

Terapascal static pressure generation with ultrahigh yield strength nanodiamond
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Theoretical Strength and Cleavage of Diamond
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Shock compression of tungsten and molybdenum
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Enhanced diamond nucleation on monodispersed nanocrystalline diamond
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Terapascal static pressure generation with ultrahigh yield strength nanodiamond
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Comparison of the growth and properties of ultrananocrystalline diamond and nanocrystalline diamond
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Epitaxial diamond encapsulation of metal microprobes for high pressure experiments
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Diamond nanoseeding on silicon: Stability under H2 MPCVD exposures and early stages of growth
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Pressure, stress, and strain distribution in the double-stage diamond anvil cell
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Nanocrystalline diamond micro-anvil grown on single crystal diamond as a generator of ultra-high pressures
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Diamond sculpting pushes extremes
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Fly scan apparatus for high pressure research using diamond anvil cells
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Single crystal toroidal diamond anvils for high pressure experiments beyond 5 megabar
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