Search Menu
DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information
Search Scholarly Publications

Title: A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor

Abstract

Selective, robust and cost-effective chemical sensors for detecting small volatile-organic compounds (VOCs) have widespread applications in industry, healthcare and environmental monitoring. Here we design a Pt(II) pincer-Type material with selective absorptive and emissive responses to methanol and water. The yellow anhydrous form converts reversibly on a subsecond timescale to a red hydrate in the presence of parts-per-Thousand levels of atmospheric water vapour. Exposure to methanol induces a similarly-rapid and reversible colour change to a blue methanol solvate. Stable smart coatings on glass demonstrate robust switching over 104 cycles, and flexible microporous polymer membranes incorporating microcrystals of the complex show identical vapochromic behaviour. The rapid vapochromic response can be rationalised from the crystal structure, and in combination with quantum-chemical modelling, we provide a complete microscopic picture of the switching mechanism. We discuss how this multiscale design approach can be used to obtain new compounds with tailored VOC selectivity and spectral responses.

Authors:
ORCiD logo [1];  [2];  [3];  [2];  [2]; ORCiD logo [2];  [2];  [2];  [4]; ORCiD logo [2];  [2]; ORCiD logo [5]; ORCiD logo [5];  [6];  [2]; ORCiD logo [7];  [2];  [2]; ORCiD logo [2];  [8] more »;  [8]; ORCiD logo [8]; ORCiD logo [3] « less
+ Show Author Affiliations
  1. Univ. of Bath, Bath (United Kingdom); The Cambridge Crystallographic Data Centre, Cambridge (United Kingdom)
  2. Univ. of Bath, Bath (United Kingdom)
  3. Univ. of Bath, Bath (United Kingdom); Rutherford Appleton Lab., Oxfordshire (United Kingdom)
  4. Rutherford Appleton Lab., Oxfordshire (United Kingdom)
  5. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  6. Diamond Light Source, Oxfordshire (United Kingdom)
  7. Univ. of Bath, Bath (United Kingdom); Yonsei Univ., Seoul (Korea)
  8. Univ. of Edinburgh, Edinburgh (United Kingdom)
Publication Date:
Research Org.:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1417623
Grant/Contract Number:  
AC02-05CH11231
Resource Type:
Accepted Manuscript
Journal Name:
Nature Communications
Additional Journal Information:
Journal Volume: 8; Journal Issue: 1; Journal ID: ISSN 2041-1723
Publisher:
Nature Publishing Group
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Bryant, M. J., Skelton, J. M., Hatcher, L. E., Stubbs, C., Madrid, E., Pallipurath, A. R., Thomas, L. H., Woodall, C. H., Christensen, J., Fuertes, S., Robinson, T. P., Beavers, C. M., Teat, S. J., Warren, M. R., Pradaux-Caggiano, F., Walsh, A., Marken, F., Carbery, D. R., Parker, S. C., McKeown, N. B., Malpass-Evans, R., Carta, M., and Raithby, P. R. A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor. United States: N. p., 2017. Web. doi:10.1038/s41467-017-01941-2.
Copy to clipboard
Bryant, M. J., Skelton, J. M., Hatcher, L. E., Stubbs, C., Madrid, E., Pallipurath, A. R., Thomas, L. H., Woodall, C. H., Christensen, J., Fuertes, S., Robinson, T. P., Beavers, C. M., Teat, S. J., Warren, M. R., Pradaux-Caggiano, F., Walsh, A., Marken, F., Carbery, D. R., Parker, S. C., McKeown, N. B., Malpass-Evans, R., Carta, M., & Raithby, P. R. A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor. United States. https://doi.org/10.1038/s41467-017-01941-2
Copy to clipboard
Bryant, M. J., Skelton, J. M., Hatcher, L. E., Stubbs, C., Madrid, E., Pallipurath, A. R., Thomas, L. H., Woodall, C. H., Christensen, J., Fuertes, S., Robinson, T. P., Beavers, C. M., Teat, S. J., Warren, M. R., Pradaux-Caggiano, F., Walsh, A., Marken, F., Carbery, D. R., Parker, S. C., McKeown, N. B., Malpass-Evans, R., Carta, M., and Raithby, P. R. Mon . "A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor". United States. https://doi.org/10.1038/s41467-017-01941-2. https://www.osti.gov/servlets/purl/1417623.
Copy to clipboard
@article{osti_1417623,
title = {A rapidly-reversible absorptive and emissive vapochromic Pt(II) pincer-based chemical sensor},
author = {Bryant, M. J. and Skelton, J. M. and Hatcher, L. E. and Stubbs, C. and Madrid, E. and Pallipurath, A. R. and Thomas, L. H. and Woodall, C. H. and Christensen, J. and Fuertes, S. and Robinson, T. P. and Beavers, C. M. and Teat, S. J. and Warren, M. R. and Pradaux-Caggiano, F. and Walsh, A. and Marken, F. and Carbery, D. R. and Parker, S. C. and McKeown, N. B. and Malpass-Evans, R. and Carta, M. and Raithby, P. R.},
abstractNote = {Selective, robust and cost-effective chemical sensors for detecting small volatile-organic compounds (VOCs) have widespread applications in industry, healthcare and environmental monitoring. Here we design a Pt(II) pincer-Type material with selective absorptive and emissive responses to methanol and water. The yellow anhydrous form converts reversibly on a subsecond timescale to a red hydrate in the presence of parts-per-Thousand levels of atmospheric water vapour. Exposure to methanol induces a similarly-rapid and reversible colour change to a blue methanol solvate. Stable smart coatings on glass demonstrate robust switching over 104 cycles, and flexible microporous polymer membranes incorporating microcrystals of the complex show identical vapochromic behaviour. The rapid vapochromic response can be rationalised from the crystal structure, and in combination with quantum-chemical modelling, we provide a complete microscopic picture of the switching mechanism. We discuss how this multiscale design approach can be used to obtain new compounds with tailored VOC selectivity and spectral responses.},
doi = {10.1038/s41467-017-01941-2},
journal = {Nature Communications},
number = 1,
volume = 8,
place = {United States},
year = {Mon Nov 27 00:00:00 EST 2017},
month = {Mon Nov 27 00:00:00 EST 2017}
}
Copy to clipboard
Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record
https://doi.org/10.1038/s41467-017-01941-2
Copyright Statement
Other availability
Search WorldCat Search WorldCat to find libraries that may hold this journal
Citation Metrics:
Cited by: 70 works
Citation information provided by
Web of Science

Figures / Tables:

Fig. 1 Fig. 1: Structure and electronic properties of Pt-pincer complexes. a Structure of general Pt-polypyridine pincer complexes with N^C^N (left), N^N^C (centre) and C^N^C (right) pincer ligands. b The valence Pt dxy and dxz orbitals interact strongly with π-type molecular orbitals on the monodentate ancillary ligand (left), while the $d_{z^{2}}$ orbitalsmore » of adjacent molecules can interact in the stacked geometry typically adopted in the solid state (right). c By adjusting the ancillary ligand, the energy of the $d_{z^{2}}$ orbital relative to the highest-occupied molecular orbital (HOMO) can be manipulated, making the optical properties more sensitive to the solid-state stacking« less
All figures and tables (5 total)
Save / Share:
Export Metadata
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.

Works referenced in this record:

Projector augmented-wave method
journal, December 1994

Shape-Memory Platinum(II) Complexes: Intelligent Vapor-History Sensor with ON-OFF Switching Function
journal, December 2015

  • Shigeta, Yasuhiro; Kobayashi, Atsushi; Ohba, Tadashi
  • Chemistry - A European Journal, Vol. 22, Issue 8
  • DOI: 10.1002/chem.201503247

QUANTUM ESPRESSO: a modular and open-source software project for quantum simulations of materials
journal, September 2009

  • Giannozzi, Paolo; Baroni, Stefano; Bonini, Nicola
  • Journal of Physics: Condensed Matter, Vol. 21, Issue 39, Article No. 395502
  • DOI: 10.1088/0953-8984/21/39/395502

An Alternative Route to Highly Luminescent Platinum(II) Complexes:  Cyclometalation with N∧C∧N-Coordinating Dipyridylbenzene Ligands
journal, November 2003

  • Williams, J. A. Gareth; Beeby, Andrew; Davies, E. Stephen
  • Inorganic Chemistry, Vol. 42, Issue 26
  • DOI: 10.1021/ic035083+

A Vapochromic LED
journal, January 1998

  • Kunugi, Yoshihito; Mann, Kent R.; Miller, Larry L.
  • Journal of the American Chemical Society, Vol. 120, Issue 3
  • DOI: 10.1021/ja973627z

Heteropolynuclear Pt(II)–M(I) Clusters with a C ∧ N ∧ C Biscyclometalated Ligand
journal, May 2012

  • Fuertes, Sara; Woodall, Christopher H.; Raithby, Paul R.
  • Organometallics, Vol. 31, Issue 11
  • DOI: 10.1021/om300170j

Controlling and imaging biomimetic self-assembly
journal, November 2015

  • Aliprandi, Alessandro; Mauro, Matteo; De Cola, Luisa
  • Nature Chemistry, Vol. 8, Issue 1
  • DOI: 10.1038/nchem.2383

Ab initiomolecular dynamics for liquid metals
journal, January 1993

SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053273314026370

Vapochromism and Its Structural Basis in a Luminescent Pt(II) Terpyridine−Nicotinamide Complex
journal, December 2004

  • Wadas, Thaddeus J.; Wang, Quan-Ming; Kim, Yong-joo
  • Journal of the American Chemical Society, Vol. 126, Issue 51
  • DOI: 10.1021/ja047955s

Controlling Emission Energy, Self-Quenching, and Excimer Formation in Highly Luminescent N∧C∧N-Coordinated Platinum(II) Complexes
journal, December 2005

  • Farley, Sarah J.; Rochester, David L.; Thompson, Amber L.
  • Inorganic Chemistry, Vol. 44, Issue 26
  • DOI: 10.1021/ic051049e

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu
journal, April 2010

  • Grimme, Stefan; Antony, Jens; Ehrlich, Stephan
  • The Journal of Chemical Physics, Vol. 132, Issue 15
  • DOI: 10.1063/1.3382344

Effect of the damping function in dispersion corrected density functional theory
journal, March 2011

  • Grimme, Stefan; Ehrlich, Stephan; Goerigk, Lars
  • Journal of Computational Chemistry, Vol. 32, Issue 7
  • DOI: 10.1002/jcc.21759

Can volatile compounds in exhaled breath be used to monitor control in diabetes mellitus?
journal, April 2011

The coordination chemistry of dipyridylbenzene: N-deficient terpyridine or panacea for brightly luminescent metal complexes?
journal, January 2009

  • Williams, J. A. Gareth
  • Chemical Society Reviews, Vol. 38, Issue 6
  • DOI: 10.1039/b804434c

Origin of Polychromism of Cis Square-Planar Platinum(II) Complexes: Comparison of Two Forms of [Pt(2,2'-bpy)(Cl2]
journal, May 1994

  • Herber, R. H.; Croft, M.; Coyer, M. J.
  • Inorganic Chemistry, Vol. 33, Issue 11
  • DOI: 10.1021/ic00089a018

A search for the elusive red form in substituted PtII bipyridine complexes
journal, January 1997

Self-Assembly of Luminescent Alkynylplatinum(II) Terpyridyl Complexes: Modulation of Photophysical Properties through Aggregation Behavior
journal, June 2011

  • Wong, Keith Man-Chung; Yam, Vivian Wing-Wah
  • Accounts of Chemical Research, Vol. 44, Issue 6
  • DOI: 10.1021/ar100130j

Synthesis, Characterization and Photophysics of a New Series of Anionic C,N,C Cyclometalated Platinum Complexes †
journal, November 2007

  • Berenguer, Jesús R.; Lalinde, Elena; Torroba, Javier
  • Inorganic Chemistry, Vol. 46, Issue 23
  • DOI: 10.1021/ic701298z

New P,N Ligands for Asymmetric Ir-Catalyzed Reactions
journal, August 2003

  • Bunlaksananusorn, Tanasri; Polborn, Kurt; Knochel, Paul
  • Angewandte Chemie International Edition, Vol. 42, Issue 33
  • DOI: 10.1002/anie.200351936

Organoplatinum crystals for gas-triggered switches
journal, August 2000

  • Albrecht, Martin; Lutz, Martin; Spek, Anthony L.
  • Nature, Vol. 406, Issue 6799
  • DOI: 10.1038/35023107

Restoring the Density-Gradient Expansion for Exchange in Solids and Surfaces
journal, April 2008

Vapour-Induced Amorphous-Crystalline Transformation of a Luminescent Platinum(II)-Diimine Complex
journal, April 2010

  • Kobayashi, Atsushi; Yonemura, Tsubasa; Kato, Masako
  • European Journal of Inorganic Chemistry, Vol. 2010, Issue 17
  • DOI: 10.1002/ejic.201000289

Photoresponsive Supramolecular Organometallic Nanosheets Induced by PtII⋅⋅⋅PtII and CH⋅⋅⋅π Interactions
journal, December 2009

  • Chen, Yong; Li, Kai; Lu, Wei
  • Angewandte Chemie International Edition, Vol. 48, Issue 52
  • DOI: 10.1002/anie.200905678

Emission Spectroscopic Properties of the Red Form of Dichloro(2,2‘-bipyridine)platinum(II). Role of Intermolecular Stacking Interactions
journal, January 1996

  • Connick, William B.; Henling, Lawrence M.; Marsh, Richard E.
  • Inorganic Chemistry, Vol. 35, Issue 21
  • DOI: 10.1021/ic960511f

Two-step Changes in Luminescence Color of Pt(II) Complex Bearing an Amide Moiety by Mechano- and Vapochromism
journal, January 2012

  • Choi, Seong Jib; Kuwabara, Junpei; Nishimura, Yoshinobu
  • Chemistry Letters, Vol. 41, Issue 1
  • DOI: 10.1246/cl.2012.65

Emissive or Nonemissive? A Theoretical Analysis of the Phosphorescence Efficiencies of Cyclometalated Platinum(II) Complexes
journal, June 2009

  • Tong, Glenna So-Ming; Che, Chi-Ming
  • Chemistry - A European Journal, Vol. 15, Issue 29
  • DOI: 10.1002/chem.200802485

A New Class of Platinum(II) Vapochromic Salts
journal, February 2004

  • Grove, Levi J.; Rennekamp, Jeffrey M.; Jude, Hershel
  • Journal of the American Chemical Society, Vol. 126, Issue 6
  • DOI: 10.1021/ja037783j

Self‐Consistent Molecular‐Orbital Methods. IX. An Extended Gaussian‐Type Basis for Molecular‐Orbital Studies of Organic Molecules
journal, January 1971

  • Ditchfield, R.; Hehre, W. J.; Pople, J. A.
  • The Journal of Chemical Physics, Vol. 54, Issue 2
  • DOI: 10.1063/1.1674902

Luminescent Platinum Complexes Having Sensing Functionalities
journal, January 2007

  • Kato, Masako
  • Bulletin of the Chemical Society of Japan, Vol. 80, Issue 2
  • DOI: 10.1246/bcsj.80.287

Structure of a Crystalline Vapochromic Platinum(II) Salt
journal, March 2008

  • Grove, Levi J.; Oliver, Allen G.; Krause, Jeanette A.
  • Inorganic Chemistry, Vol. 47, Issue 5
  • DOI: 10.1021/ic701523e

An Efficient Polymer Molecular Sieve for Membrane Gas Separations
journal, January 2013

A Submicrometer Wire-to-Wheel Metamorphism of Hybrid Tridentate Cyclometalated Platinum(II) Complexes
journal, June 2008

  • Lu, Wei; Chui, Stephen Sin-Yin; Ng, Kwan-Ming
  • Angewandte Chemie International Edition, Vol. 47, Issue 24
  • DOI: 10.1002/anie.200704450

Structural and Spectroscopic Studies on Pt···Pt and π−π Interactions in Luminescent Multinuclear Cyclometalated Platinum(II) Homologues Tethered by Oligophosphine Auxiliaries
journal, June 2004

  • Lu, Wei; Chan, Michael C. W.; Zhu, Nianyong
  • Journal of the American Chemical Society, Vol. 126, Issue 24
  • DOI: 10.1021/ja039727o

Natural population analysis
journal, July 1985

  • Reed, Alan E.; Weinstock, Robert B.; Weinhold, Frank
  • The Journal of Chemical Physics, Vol. 83, Issue 2
  • DOI: 10.1063/1.449486

Structures, Photoluminescence, and Reversible Vapoluminescence Properties of Neutral Platinum(II) Complexes Containing Extended π-Conjugated Cyclometalated Ligands
journal, June 2006

  • Kui, Steven C. F.; Chui, Stephen Sin-Yin; Che, Chi-Ming
  • Journal of the American Chemical Society, Vol. 128, Issue 25
  • DOI: 10.1021/ja061422x

Organometallic benzylidene anilines: donor–acceptor features in NCN-pincer Pt( ii ) complexes with a 4-(E)-[(4-R-phenyl)imino]methyl substituent
journal, January 2014

  • Batema, Guido D.; Lutz, Martin; Spek, Anthony L.
  • Dalton Trans., Vol. 43, Issue 32
  • DOI: 10.1039/C4DT01023J

“On−Off” Au(I)···Cu(I) Interactions in a Au(NHC) 2 Luminescent Vapochromic Sensor
journal, July 2010

  • Strasser, Christoph E.; Catalano, Vincent J.
  • Journal of the American Chemical Society, Vol. 132, Issue 29
  • DOI: 10.1021/ja104585q

Ab initio effective core potentials for molecular calculations. Potentials for the transition metal atoms Sc to Hg
journal, January 1985

  • Hay, P. Jeffrey; Wadt, Willard R.
  • The Journal of Chemical Physics, Vol. 82, Issue 1
  • DOI: 10.1063/1.448799

Crystal structure refinement with SHELXL
journal, January 2015

  • Sheldrick, George M.
  • Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1, p. 3-8
  • DOI: 10.1107/S2053229614024218

Toward reliable density functional methods without adjustable parameters: The PBE0 model
journal, April 1999

  • Adamo, Carlo; Barone, Vincenzo
  • The Journal of Chemical Physics, Vol. 110, Issue 13
  • DOI: 10.1063/1.478522

Linear optical properties in the projector-augmented wave methodology
journal, January 2006

Vapor- and Mechanical-Grinding-Triggered Color and Luminescence Switches for Bis(σ-fluorophenylacetylide) Platinum(II) Complexes
journal, January 2011

New C ∧ N ∧ C Bis-Cyclometalated Platinum(II) Complexes: Synthesis, Structures, and Photophysical Properties
journal, December 2011

  • Fuertes, Sara; Brayshaw, Simon K.; Raithby, Paul R.
  • Organometallics, Vol. 31, Issue 1
  • DOI: 10.1021/om200589q

Pressure-sensitive absorption spectra of thin films of bis(diphenylglyoximato)platinum(II), Pt(dpg)2: potential application as an indicator of pressure
journal, January 1991

  • Shirotani, Ichimin; Inagaki, Yukio; Utsumi, Wataru
  • Journal of Materials Chemistry, Vol. 1, Issue 6
  • DOI: 10.1039/jm9910101041

Avogadro: an advanced semantic chemical editor, visualization, and analysis platform
journal, August 2012

  • Hanwell, Marcus D.; Curtis, Donald E.; Lonie, David C.
  • Journal of Cheminformatics, Vol. 4, Issue 1
  • DOI: 10.1186/1758-2946-4-17

New P,N Ligands for Asymmetric Ir-Catalyzed Reactions
journal, August 2003

  • Bunlaksananusorn, Tanasri; Polborn, Kurt; Knochel, Paul
  • Angewandte Chemie, Vol. 115, Issue 33
  • DOI: 10.1002/ange.200351936

A Submicrometer Wire-to-Wheel Metamorphism of Hybrid Tridentate Cyclometalated Platinum(II) Complexes
journal, June 2008

  • Lu, Wei; Chui, Stephen Sin-Yin; Ng, Kwan-Ming
  • Angewandte Chemie, Vol. 120, Issue 24
  • DOI: 10.1002/ange.200704450

New P,N Ligands for Asymmetric Ir-Catalyzed Reactions.
journal, December 2003

  • Bunlaksananusorn, Tanasri; Polborn, Kurt; Knochel, Paul
  • ChemInform, Vol. 34, Issue 50
  • DOI: 10.1002/chin.200350040

Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020

Luminescent Platinum Complexes Having Sensing Functionalities
journal, April 2007

    Sort by:
    [ × clear filter / sort ]

    Works referencing / citing this record:

    Multi‐Stimuli‐Responsive Properties of Aggregation‐Enhanced Emission‐Active Unsymmetrical Pt II Metallomesogens through Self‐Assembly
    journal, July 2019

    • Cuerva, Cristián; Campo, José A.; Cano, Mercedes
    • Chemistry – A European Journal, Vol. 25, Issue 52
    • DOI: 10.1002/chem.201901763

    Aurophilicity‐Mediated Construction of Emissive Porous Molecular Crystals as Versatile Hosts for Liquid and Solid Guests
    journal, December 2019

    • Seki, Tomohiro; Ida, Kentaro; Sato, Hiroyasu
    • Chemistry – A European Journal, Vol. 26, Issue 3
    • DOI: 10.1002/chem.201904597

    Luminescent Anion Sensing by Transition‐Metal Dipyridylbenzene Complexes Incorporated into Acyclic, Macrocyclic and Interlocked Hosts
    journal, April 2020

    • Knighton, Richard C.; Dapin, Sophie; Beer, Paul D.
    • Chemistry – A European Journal, Vol. 26, Issue 23
    • DOI: 10.1002/chem.202000661

    Fast and stable vapochromic response induced through nanocrystal formation of a luminescent platinum(II) complex on periodic mesoporous organosilica
    journal, October 2019

    Pt⋯Pt interaction triggered tuning of circularly polarized luminescence activity in chiral dinuclear platinum( ii ) complexes
    journal, January 2018

    • Zhang, Xiao-Peng; Wang, Li-Li; Qi, Xiao-Wei
    • Dalton Transactions, Vol. 47, Issue 30
    • DOI: 10.1039/c8dt02277a

    Solvent-tuned charge-transfer properties of chiral Pt( ii ) complex and TCNQ˙ − anion adducts
    journal, January 2018

    • Zhang, Xiao-Peng; Wang, Li-Li; Zhang, Da-Shuai
    • RSC Advances, Vol. 8, Issue 20
    • DOI: 10.1039/c8ra01330f

    Infinite coordination polymer networks: metallogelation of aminopyridine conjugates and in situ silver nanoparticle formation
    journal, January 2019

    • Tatikonda, Rajendhraprasad; Bulatov, Evgeny; Özdemir, Zülal
    • Soft Matter, Vol. 15, Issue 3
    • DOI: 10.1039/c8sm02006j

    In situ non-invasive Raman spectroscopic characterisation of succinic acid polymorphism during segmented flow crystallisation
    journal, January 2020

    • Pallipurath, Anuradha R.; Flandrin, Pierre-Baptiste; Wayment, Lois E.
    • Molecular Systems Design & Engineering, Vol. 5, Issue 1
    • DOI: 10.1039/c9me00103d

    Self-healing, luminescent metallogelation driven by synergistic metallophilic and fluorine–fluorine interactions
    journal, January 2020

    • Kolari, Kalle; Bulatov, Evgeny; Tatikonda, Rajendhraprasad
    • Soft Matter, Vol. 16, Issue 11
    • DOI: 10.1039/c9sm02186h
      Sort by:
      [ × clear filter / sort ]

      Figures / Tables found in this record:

      Fig. 1 (p. 4)figure
      Fig. 2 (p. 5)figure
      Fig. 3 (p. 6)figure
      Fig. 4 (p. 7)figure
      Fig. 5 (p. 8)figure
        [ × clear filter / sort ]
        Figures/Tables have been extracted from DOE-funded journal article accepted manuscripts.

        Similar Records in DOE PAGES and OSTI.GOV collections:

        Other research related to this record: