Development of a semigraphitic sulfur-doped ordered mesoporous carbon material for electroanalytical applications
Abstract
The modification of traditional electrodes with mesoporous carbons is a promising strategy to produce high performance electrodes for electrochemical sensing. The high surface area of mesoporous carbons provides a large number of electroactive sites for binding analytes. Controlling the pore size and structure of mesoporous carbons and modifying their electronic properties via doping offers additional benefits like maximizing transport and tuning the electrochemical processes associated with analyte detection. This work reports a facile method to produce sulfur-doped ordered mesoporous carbon materials (S-OMC) with uniform pore structure, large pore volume, high surface area and semigraphitic structure. The synthesis used thiophenol as a single source of carbon and sulfur, and iron as a catalyst for low temperature carbonization. The S-OMC material was deposited on a glassy carbon electrode and used as a sensor with high sensitivity (11.7 A L mol-1) and selectivity for chloramphenicol detection in presence of other antibiotics. As a proof-of-concept, the sensor was applied to the direct analysis of the drug in reconstituted powdered milk and in commercial eye drops.
- Authors:
-
- Univ. of Sao Paulo (Brazil)
- Ames Lab., Ames, IA (United States)
- Univ. of Campinas (UNICAMP), Sao Paulo (Brazil)
- Publication Date:
- Research Org.:
- Ames Laboratory (AMES), Ames, IA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1413141
- Alternate Identifier(s):
- OSTI ID: 1496345
- Report Number(s):
- IS-J-9359
Journal ID: ISSN 0925-4005; PII: S0925400517320786
- Grant/Contract Number:
- AC02-07CH11358
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Sensors and Actuators. B, Chemical
- Additional Journal Information:
- Journal Volume: 257; Journal Issue: C; Related Information: Also available at http://lib.dr.iastate.edu/ameslab_manuscripts/69/; Journal ID: ISSN 0925-4005
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE
Citation Formats
Maluta, Jaqueline R., Machado, Sergio A. S., Chaudhary, Umesh, Manzano, J. Sebastián, Kubota, Lauro T., and Slowing, Igor I. Development of a semigraphitic sulfur-doped ordered mesoporous carbon material for electroanalytical applications. United States: N. p., 2017.
Web. doi:10.1016/j.snb.2017.10.164.
Maluta, Jaqueline R., Machado, Sergio A. S., Chaudhary, Umesh, Manzano, J. Sebastián, Kubota, Lauro T., & Slowing, Igor I. Development of a semigraphitic sulfur-doped ordered mesoporous carbon material for electroanalytical applications. United States. https://doi.org/10.1016/j.snb.2017.10.164
Maluta, Jaqueline R., Machado, Sergio A. S., Chaudhary, Umesh, Manzano, J. Sebastián, Kubota, Lauro T., and Slowing, Igor I. Sun .
"Development of a semigraphitic sulfur-doped ordered mesoporous carbon material for electroanalytical applications". United States. https://doi.org/10.1016/j.snb.2017.10.164. https://www.osti.gov/servlets/purl/1413141.
@article{osti_1413141,
title = {Development of a semigraphitic sulfur-doped ordered mesoporous carbon material for electroanalytical applications},
author = {Maluta, Jaqueline R. and Machado, Sergio A. S. and Chaudhary, Umesh and Manzano, J. Sebastián and Kubota, Lauro T. and Slowing, Igor I.},
abstractNote = {The modification of traditional electrodes with mesoporous carbons is a promising strategy to produce high performance electrodes for electrochemical sensing. The high surface area of mesoporous carbons provides a large number of electroactive sites for binding analytes. Controlling the pore size and structure of mesoporous carbons and modifying their electronic properties via doping offers additional benefits like maximizing transport and tuning the electrochemical processes associated with analyte detection. This work reports a facile method to produce sulfur-doped ordered mesoporous carbon materials (S-OMC) with uniform pore structure, large pore volume, high surface area and semigraphitic structure. The synthesis used thiophenol as a single source of carbon and sulfur, and iron as a catalyst for low temperature carbonization. The S-OMC material was deposited on a glassy carbon electrode and used as a sensor with high sensitivity (11.7 A L mol-1) and selectivity for chloramphenicol detection in presence of other antibiotics. As a proof-of-concept, the sensor was applied to the direct analysis of the drug in reconstituted powdered milk and in commercial eye drops.},
doi = {10.1016/j.snb.2017.10.164},
journal = {Sensors and Actuators. B, Chemical},
number = C,
volume = 257,
place = {United States},
year = {Sun Oct 29 00:00:00 EDT 2017},
month = {Sun Oct 29 00:00:00 EDT 2017}
}
Free Publicly Available Full Text
Publisher's Version of Record
Other availability
Search WorldCat to find libraries that may hold this journal
Cited by: 19 works
Citation information provided by
Web of Science
Web of Science
Save to My Library
You must Sign In or Create an Account in order to save documents to your library.
Works referenced in this record:
Ordered mesoporous carbon for electrochemical sensing: A review
journal, October 2012
- Ndamanisha, Jean Chrysostome; Guo, Li-ping
- Analytica Chimica Acta, Vol. 747
Electrocatalysis, sensors and biosensors in analytical chemistry based on ordered mesoporous and macroporous carbon-modified electrodes
journal, September 2012
- Walcarius, Alain
- TrAC Trends in Analytical Chemistry, Vol. 38
Structurally Ordered Mesoporous Carbon Nanoparticles as Transmembrane Delivery Vehicle in Human Cancer Cells
journal, November 2008
- Kim, Tae-Wan; Chung, Po-Wen; Slowing, Igor I.
- Nano Letters, Vol. 8, Issue 11, p. 3724-3727
Mesoporous carbon nitride based biosensor for highly sensitive and selective analysis of phenol and catechol in compost bioremediation
journal, November 2014
- Zhou, Yaoyu; Tang, Lin; Zeng, Guangming
- Biosensors and Bioelectronics, Vol. 61
Electrochemical determination of morphine at ordered mesoporous carbon modified glassy carbon electrode
journal, February 2010
- Li, Fei; Song, Jixia; Shan, Changsheng
- Biosensors and Bioelectronics, Vol. 25, Issue 6
Ordered Mesoporous Carbons
journal, May 2001
- Ryoo, R.; Joo, S. H.; Kruk, M.
- Advanced Materials, Vol. 13, Issue 9, p. 677-681
Synthesis and characterization of mesoporous carbon for fuel cell applications
journal, January 2007
- Chang, Hyuk; Joo, Sang Hoon; Pak, Chanho
- Journal of Materials Chemistry, Vol. 17, Issue 30
Graphitic Mesostructured Carbon Prepared from Aromatic Precursors
journal, June 2004
- Kim, Chy Hyung; Lee, Dong-Keun; Pinnavaia, Thomas J.
- Langmuir, Vol. 20, Issue 13
A Synthetic Route to Ordered Mesoporous Carbon Materials with Graphitic Pore Walls
journal, September 2003
- Kim, Tae-Wan; Park, In-Soo; Ryoo, Ryong
- Angewandte Chemie, Vol. 115, Issue 36
Synthesis of Ordered Mesoporous Carbon and Nitrogen-Doped Carbon Materials with Graphitic Pore Walls via a Simple Chemical Vapor Deposition Method
journal, September 2004
- Xia, Y.; Mokaya, R.
- Advanced Materials, Vol. 16, Issue 17
Synthesis of Partially Graphitic Ordered Mesoporous Carbons with High Surface Areas
journal, December 2010
- Gao, Wenjun; Wan, Ying; Dou, Yuqian
- Advanced Energy Materials, Vol. 1, Issue 1
Synthesis of Ordered Mesoporous Carbon Materials with Semi-Graphitized Walls via Direct In-situ Silica-Confined Thermal Decomposition of CH4 and Their Hydrogen Storage Properties
journal, February 2009
- Wu, Zhangxiong; Yang, Yunxia; Gu, Dong
- Topics in Catalysis, Vol. 52, Issue 1-2
Highly dispersed sulfur in ordered mesoporous carbon sphere as a composite cathode for rechargeable polymer Li/S battery
journal, April 2011
- Liang, Xiao; Wen, Zhaoyin; Liu, Yu
- Journal of Power Sources, Vol. 196, Issue 7
Large-scale synthesis of ordered mesoporous carbon fiber and its application as cathode material for lithium–sulfur batteries
journal, January 2015
- Wang, Hongqiang; Zhang, Chaofeng; Chen, Zhixin
- Carbon, Vol. 81
Ordered mesoporous carbon/sulfur nanocomposite of high performances as cathode for lithium–sulfur battery
journal, November 2011
- Chen, Shu-Ru; Zhai, Yun-Pu; Xu, Gui-Liang
- Electrochimica Acta, Vol. 56, Issue 26, p. 9549-9555
Ultrastable Pt nanoparticles supported on sulfur-containing ordered mesoporous carbon via strong metal-support interaction
journal, January 2009
- Lee, Hyung Ik; Joo, Sang Hoon; Kim, Jin Hoe
- Journal of Materials Chemistry, Vol. 19, Issue 33
Enhancement of electrochemical stability and catalytic activity of Pt nanoparticles via strong metal-support interaction with sulfur-containing ordered mesoporous carbon
journal, April 2011
- Kwon, Kyungjung; Jin, Seon-ah; Pak, Chanho
- Catalysis Today, Vol. 164, Issue 1
Sulfur-doped ordered mesoporous carbon with high electrocatalytic activity for oxygen reduction
journal, October 2013
- Wang, Huan; Bo, Xiangjie; Zhang, Yufan
- Electrochimica Acta, Vol. 108
The influence of activated carbon surface chemical composition on the adsorption of acetaminophen (paracetamol) in vitro
journal, April 2000
- Terzyk, Artur P.; Rychlicki, Gerhard
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 163, Issue 2-3
The influence of activated carbon surface chemical composition on the adsorption of acetaminophen (paracetamol) in vitro
journal, February 2001
- Terzyk, Artur P.
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 177, Issue 1
Sulfur-Doped Carbon Aerogel as a Metal-Free Oxygen Reduction Catalyst
journal, June 2015
- Seredych, Mykola; László, Krisztina; Bandosz, Teresa J.
- ChemCatChem, Vol. 7, Issue 18
Investigation of the enhancing effects of sulfur and/or oxygen functional groups of nanoporous carbons on adsorption of dibenzothiophenes
journal, April 2011
- Seredych, Mykola; Bandosz, Teresa J.
- Carbon, Vol. 49, Issue 4
Enhancement in Dibenzothiophene Reactive Adsorption from Liquid Fuel via Incorporation of Sulfur Heteroatoms into the Nanoporous Carbon Matrix
journal, December 2010
- Seredych, Mykola; Khine, Monmon; Bandosz, Teresa J.
- ChemSusChem, Vol. 4, Issue 1
Approaches for the simultaneous detection of thiamphenicol, florfenicol and florfenicol amine using immunochemical techniques
journal, July 2013
- Fodey, Terence L.; George, Suja E.; Traynor, Imelda M.
- Journal of Immunological Methods, Vol. 393, Issue 1-2
Detection of chloramphenicol and chloramphenicol glucuronide residues in poultry muscle, honey, prawn and milk using a surface plasmon resonance biosensor and Qflex® kit chloramphenicol
journal, January 2005
- Ferguson, Julie; Baxter, Andrew; Young, Paul
- Analytica Chimica Acta, Vol. 529, Issue 1-2
Fatal Aplastic Anemia Following Topical Administration of Ophthalmic Chloramphenicol
journal, March 1982
- Fraunfelder, F. T.; Bagby, Grover C.; Kelly, Daniel J.
- American Journal of Ophthalmology, Vol. 93, Issue 3
Gray Baby Syndrome Revisited
journal, September 1982
- Krasinski, Keith; Perkin, Ron; Rutledge, Joe
- Clinical Pediatrics, Vol. 21, Issue 9
Synergistic Interaction between Oxides of Copper and Iron for Production of Fatty Alcohols from Fatty Acids
journal, October 2015
- Kandel, Kapil; Chaudhary, Umesh; Nelson, Nicholas C.
- ACS Catalysis, Vol. 5, Issue 11
Large-Scale Synthesis of Aligned Carbon Nanotubes
journal, December 1996
- Li, W. Z.; Xie, S. S.; Qian, L. X.
- Science, Vol. 274, Issue 5293
Structure and Site Evolution of Iron Oxide Catalyst Precursors during the Fischer−Tropsch Synthesis
journal, June 2001
- Li, Senzi; Meitzner, George D.; Iglesia, Enrique
- The Journal of Physical Chemistry B, Vol. 105, Issue 24
A Reliable Synthesis of Cubic Mesoporous MCM-48 Molecular Sieve
journal, November 1998
- Xu, Jie; Luan, Zhaohua; He, Heyong
- Chemistry of Materials, Vol. 10, Issue 11
Carbonization and graphitization of poly-p-phenylene sulphide (PPS) film
journal, September 1994
- Oya, A.; Arai, K.; Fujita, K.
- Journal of Materials Science, Vol. 29, Issue 17
The interlayer spacing of graphite
journal, November 1951
- Bacon, G. E.
- Acta Crystallographica, Vol. 4, Issue 6
Synthesis and Magnetic Properties of Mesostructured γ-Fe 2 O 3 /Carbon Composites by a Co-casting Method
journal, June 2007
- Dong, Xiaoping; Chen, Hangrong; Zhao, Wenru
- Chemistry of Materials, Vol. 19, Issue 14
Preparation and Characterization of Highly Ordered Graphitic Mesoporous Carbon as a Pt Catalyst Support for Direct Methanol Fuel Cells
journal, June 2005
- Su, Fabing; Zeng, Jianhuang; Bao, Xiaoying
- Chemistry of Materials, Vol. 17, Issue 15
Voltammetric behaviour of nitrofurazone, furazolidone and other nitro derivatives of biological importance
journal, January 1987
- Morales, Alfonso; Richter, Pablo; Toral, M. In�s
- The Analyst, Vol. 112, Issue 7
Electrochemical modification of a carbon electrode using aromatic diazonium salts. 2. Electrochemistry of 4-nitrophenyl modified glassy carbon electrodes in aqueous media
journal, September 1998
- Ortiz, Bertha; Saby, Coralie; Champagne, G. Y.
- Journal of Electroanalytical Chemistry, Vol. 455, Issue 1-2
Electrochemical Behavior of a 4-Nitrothiophenol Modified Electrode Prepared by the Self-Assembly Method
journal, May 1995
- Tsutsumi, Hiromori; Furumoto, Shozo; Morita, Masayuki
- Journal of Colloid and Interface Science, Vol. 171, Issue 2
Parallel incident spectroelectrochemistry study of chloramphenicol
journal, May 1998
- Feng, Min; Long, Dajun; Fang, Yuzhi
- Analytica Chimica Acta, Vol. 363, Issue 1
Cathodic stripping voltammetry of clothianidin: Application to environmental studies
journal, January 2011
- Guziejewski, Dariusz; Skrzypek, Sławomira; Łuczak, Adam
- Collection of Czechoslovak Chemical Communications, Vol. 76, Issue 2
Synthesis of nitrogen-doped graphene nanosheets decorated with gold nanoparticles as an improved sensor for electrochemical determination of chloramphenicol
journal, June 2013
- Borowiec, Joanna; Wang, Rui; Zhu, Lihua
- Electrochimica Acta, Vol. 99
Erratum: On the Surface Chemistry of LiMO 2 Cathode Materials (M = [MnNi] and [MnNiCo]): Electrochemical, Spectroscopic, and Calorimetric Studies [J. Electrochem. Soc., 157, A1099 (2010)]
journal, January 2012
- Haik, Ortal; Leifer, Nicole; Sclar, Hadar
- Journal of The Electrochemical Society, Vol. 159, Issue 3
Differential pulse anodic voltammetric determination of pantoprazole in pharmaceutical dosage forms and human plasma using glassy carbon electrode
journal, December 2003
- Erk, Nevin
- Analytical Biochemistry, Vol. 323, Issue 1
Simultaneous determination of dopamine, ascorbic acid and uric acid on ordered mesoporous carbon/Nafion composite film
journal, January 2009
- Zheng, Dan; Ye, Jianshan; Zhou, Liang
- Journal of Electroanalytical Chemistry, Vol. 625, Issue 1
Electrochemical detection of ultratrace nitroaromatic explosives using ordered mesoporous carbon
journal, January 2011
- Zang, Jianfeng; Guo, Chun Xian; Hu, Fengping
- Analytica Chimica Acta, Vol. 683, Issue 2
The reduction mechanism of aromatic nitro compounds in aqueous medium
journal, December 1994
- Laviron, E.; Vallat, A.; Meunier-Prest, R.
- Journal of Electroanalytical Chemistry, Vol. 379, Issue 1-2
The reduction mechanism of aromatic nitro compounds in aqueous medium
journal, August 1990
- Laviron, E.; Roullier, L.
- Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 288, Issue 1-2
Electrochemical behavior of a nitrobenzenesulfonyl derivative of aniline in aqueous solution
journal, January 1997
- Zanoni, M. V. Boldrin; Rosa, I. L. V.; Pesquero, C. R.
- Journal of the Brazilian Chemical Society, Vol. 8, Issue 3
Works referencing / citing this record:
Prediction of Carbon Dioxide Adsorption via Deep Learning
journal, December 2018
- Zhang, Zihao; Schott, Jennifer A.; Liu, Miaomiao
- Angewandte Chemie, Vol. 131, Issue 1
Highly Sensitive and Selective Dopamine Detection Utilizing Nitrogen‐Doped Mesoporous Carbon Prepared by a Molten Glucose‐Assisted Hard‐Template Approach
journal, June 2019
- Liu, Sen; Gao, Shang; Fei, Teng
- ChemPlusChem, Vol. 84, Issue 7
Prediction of Carbon Dioxide Adsorption via Deep Learning
journal, December 2018
- Zhang, Zihao; Schott, Jennifer A.; Liu, Miaomiao
- Angewandte Chemie International Edition, Vol. 58, Issue 1
Nitrogen-Dopped Ordered Mesoporous Carbon Anchored Pd Nanoparticles for Solvent Free Selective Oxidation of Benzyl Alcohol to Benzaldehyde by Using O2
journal, June 2019
- Song, Hongbing; Liu, Zong; Gai, Hengjun
- Frontiers in Chemistry, Vol. 7