Synthesis, Crystal and Electronic Structures, and Optical Properties of (CH3NH3)2CdX4 (X = Cl, Br, I)
Abstract
Here, we report the synthesis, crystal and electronic structures, as well as optical properties of the hybrid organic–inorganic compounds MA2CdX4 (MA = CH3NH3; X = Cl, Br, I). MA2CdI4 is a new compound, whereas, for MA2CdCl4 and MA2CdBr4, structural investigations have already been conducted but electronic structures and optical properties are reported here for the first time. Single crystals were grown through slow evaporation of MA2CdX4 solutions with optimized conditions yielding mm-sized colorless (X = Cl, Br) and pale yellow (X = I) crystals. Single crystal and variable temperature powder X-ray diffraction measurements suggest that MA2CdCl4 forms a 2D layered perovskite structure and has two structural transitions at 283 and 173 K. In contrast, MA2CdBr4 and MA2CdI4 adopt 0D K2SO4-derived crystal structures based on isolated CdX4 tetrahedra and show no phase transitions down to 20 K. The contrasting crystal structures and chemical compositions in the MA2CdX4 family impact their air stabilities, investigated for the first time in this work; MA2CdCl4 is air-stable, whereas MA2CdBr4 and MA2CdI4 partially decompose when left in air. Optical absorption measurements suggest that MA2CdX4 have large optical band gaps above 3.9 eV. Room temperature photoluminescence spectra of MA2CdX4 yield broad peaks in the 375–955 nm rangemore »
- Authors:
-
[2];
[2];
[2];
[1]
- Univ. of Oklahoma, Norman, OK (United States)
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Publication Date:
- Research Org.:
- Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1410200
- Grant/Contract Number:
- AC05-00OR22725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Inorganic Chemistry
- Additional Journal Information:
- Journal Volume: 56; Journal Issue: 22; Journal ID: ISSN 0020-1669
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Roccanova, Rachel, Ming, Wenmei, Whiteside, Vincent R., McGuire, Michael A., Sellers, Ian R., Du, Mao -Hua, and Saparov, Bayrammurad. Synthesis, Crystal and Electronic Structures, and Optical Properties of (CH3NH3)2CdX4 (X = Cl, Br, I). United States: N. p., 2017.
Web. doi:10.1021/acs.inorgchem.7b01986.
Roccanova, Rachel, Ming, Wenmei, Whiteside, Vincent R., McGuire, Michael A., Sellers, Ian R., Du, Mao -Hua, & Saparov, Bayrammurad. Synthesis, Crystal and Electronic Structures, and Optical Properties of (CH3NH3)2CdX4 (X = Cl, Br, I). United States. https://doi.org/10.1021/acs.inorgchem.7b01986
Roccanova, Rachel, Ming, Wenmei, Whiteside, Vincent R., McGuire, Michael A., Sellers, Ian R., Du, Mao -Hua, and Saparov, Bayrammurad. Thu .
"Synthesis, Crystal and Electronic Structures, and Optical Properties of (CH3NH3)2CdX4 (X = Cl, Br, I)". United States. https://doi.org/10.1021/acs.inorgchem.7b01986. https://www.osti.gov/servlets/purl/1410200.
@article{osti_1410200,
title = {Synthesis, Crystal and Electronic Structures, and Optical Properties of (CH3NH3)2CdX4 (X = Cl, Br, I)},
author = {Roccanova, Rachel and Ming, Wenmei and Whiteside, Vincent R. and McGuire, Michael A. and Sellers, Ian R. and Du, Mao -Hua and Saparov, Bayrammurad},
abstractNote = {Here, we report the synthesis, crystal and electronic structures, as well as optical properties of the hybrid organic–inorganic compounds MA2CdX4 (MA = CH3NH3; X = Cl, Br, I). MA2CdI4 is a new compound, whereas, for MA2CdCl4 and MA2CdBr4, structural investigations have already been conducted but electronic structures and optical properties are reported here for the first time. Single crystals were grown through slow evaporation of MA2CdX4 solutions with optimized conditions yielding mm-sized colorless (X = Cl, Br) and pale yellow (X = I) crystals. Single crystal and variable temperature powder X-ray diffraction measurements suggest that MA2CdCl4 forms a 2D layered perovskite structure and has two structural transitions at 283 and 173 K. In contrast, MA2CdBr4 and MA2CdI4 adopt 0D K2SO4-derived crystal structures based on isolated CdX4 tetrahedra and show no phase transitions down to 20 K. The contrasting crystal structures and chemical compositions in the MA2CdX4 family impact their air stabilities, investigated for the first time in this work; MA2CdCl4 is air-stable, whereas MA2CdBr4 and MA2CdI4 partially decompose when left in air. Optical absorption measurements suggest that MA2CdX4 have large optical band gaps above 3.9 eV. Room temperature photoluminescence spectra of MA2CdX4 yield broad peaks in the 375–955 nm range with full width at half-maximum values up to 208 nm. These PL peaks are tentatively assigned to self-trapped excitons in MA2CdX4 following the crystal and electronic structure considerations. The bands around the Fermi level have small dispersions, which is indicative of high charge localization with significant exciton binding energies in MA2CdX4. On the basis of our combined experimental and computational results, MA2CdX4 and related compounds may be of interest for white-light-emitting phosphors and scintillator applications.},
doi = {10.1021/acs.inorgchem.7b01986},
journal = {Inorganic Chemistry},
number = 22,
volume = 56,
place = {United States},
year = {Thu Nov 02 00:00:00 EDT 2017},
month = {Thu Nov 02 00:00:00 EDT 2017}
}
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Works referenced in this record:
Efficient luminescent solar cells based on tailored mixed-cation perovskites
journal, January 2016
- Bi, Dongqin; Tress, Wolfgang; Dar, M. Ibrahim
- Science Advances, Vol. 2, Issue 1
Perovskite Materials for Light-Emitting Diodes and Lasers
journal, May 2016
- Veldhuis, Sjoerd A.; Boix, Pablo P.; Yantara, Natalia
- Advanced Materials, Vol. 28, Issue 32
Solution-processed hybrid perovskite photodetectors with high detectivity
journal, November 2014
- Dou, Letian; Yang, Yang (Micheal); You, Jingbi
- Nature Communications, Vol. 5, Issue 1
Intriguing Optoelectronic Properties of Metal Halide Perovskites
journal, June 2016
- Manser, Joseph S.; Christians, Jeffrey A.; Kamat, Prashant V.
- Chemical Reviews, Vol. 116, Issue 21
Organic–Inorganic Perovskites: Structural Versatility for Functional Materials Design
journal, March 2016
- Saparov, Bayrammurad; Mitzi, David B.
- Chemical Reviews, Vol. 116, Issue 7
Metal-halide perovskites for photovoltaic and light-emitting devices
journal, May 2015
- Stranks, Samuel D.; Snaith, Henry J.
- Nature Nanotechnology, Vol. 10, Issue 5
Chemical Approaches to Addressing the Instability and Toxicity of Lead–Halide Perovskite Absorbers
journal, August 2016
- Slavney, Adam H.; Smaha, Rebecca W.; Smith, Ian C.
- Inorganic Chemistry, Vol. 56, Issue 1
Designing indirect–direct bandgap transitions in double perovskites
journal, January 2017
- Tran, T. Thao; Panella, Jessica R.; Chamorro, Juan R.
- Materials Horizons, Vol. 4, Issue 4
Strong Electron–Phonon Coupling and Self-Trapped Excitons in the Defect Halide Perovskites A 3 M 2 I 9 (A = Cs, Rb; M = Bi, Sb)
journal, April 2017
- McCall, Kyle M.; Stoumpos, Constantinos C.; Kostina, Svetlana S.
- Chemistry of Materials, Vol. 29, Issue 9
Thin-Film Preparation and Characterization of Cs 3 Sb 2 I 9 : A Lead-Free Layered Perovskite Semiconductor
journal, August 2015
- Saparov, Bayrammurad; Hong, Feng; Sun, Jon-Paul
- Chemistry of Materials, Vol. 27, Issue 16
Efficient inorganic–organic hybrid heterojunction solar cells containing perovskite compound and polymeric hole conductors
journal, May 2013
- Heo, Jin Hyuck; Im, Sang Hyuk; Noh, Jun Hong
- Nature Photonics, Vol. 7, Issue 6, p. 486-491
Detection of X-ray photons by solution-processed lead halide perovskites
journal, May 2015
- Yakunin, Sergii; Sytnyk, Mykhailo; Kriegner, Dominik
- Nature Photonics, Vol. 9, Issue 7
Crystal Growth of the Perovskite Semiconductor CsPbBr 3 : A New Material for High-Energy Radiation Detection
journal, June 2013
- Stoumpos, Constantinos C.; Malliakas, Christos D.; Peters, John A.
- Crystal Growth & Design, Vol. 13, Issue 7
Effects of Organic Moieties on Luminescence Properties of Organic–Inorganic Layered Perovskite-Type Compounds
journal, April 2014
- Kawano, Naoki; Koshimizu, Masanori; Sun, Yan
- The Journal of Physical Chemistry C, Vol. 118, Issue 17
Single-crystal CeCl3(CH3OH)4: A new metal-organic cerium chloride methanol adduct for scintillator applications
journal, December 2008
- Boatner, L. A.; Wisniewski, D.; Neal, J. S.
- Applied Physics Letters, Vol. 93, Issue 24
New Family of Cerium Halide Based Materials: CeX 3 ·ROH Compounds Containing Planes, Chains, and Tetradecanuclear Rings
journal, September 2012
- Vaughn, Shae Anne; Chakoumakos, Bryan C.; Custelcean, Radu
- Inorganic Chemistry, Vol. 51, Issue 20
Discrete Electronic Bands in Semiconductors and Insulators: Potential High-Light-Yield Scintillators
journal, May 2015
- Shi, Hongliang; Du, Mao-Hua
- Physical Review Applied, Vol. 3, Issue 5
Photochemistry on nonreactive and reactive (semiconductor) surfaces
journal, January 1993
- Kamat, Prashant V.
- Chemical Reviews, Vol. 93, Issue 1
Electronegativity values from thermochemical data
journal, June 1961
- Allred, A. L.
- Journal of Inorganic and Nuclear Chemistry, Vol. 17, Issue 3-4
Band gaps and electronic structure of transition-metal compounds
journal, July 1985
- Zaanen, J.; Sawatzky, G. A.; Allen, J. W.
- Physical Review Letters, Vol. 55, Issue 4
X-Ray study of the structural first-order phase transition (Cmca-P42/ncm) in (CH3NH3)2CdCl4
journal, October 1975
- Chapuis, G.; Arend, H.; Kind, R.
- Physica Status Solidi (a), Vol. 31, Issue 2
X-ray study of structural phase transitions in the perovskite-type layer compound (CH3NH3)2CdCl4
journal, July 1976
- Chapuis, G.; Kind, R.; Arend, H.
- Physica Status Solidi (a), Vol. 36, Issue 1
New tetrahedrally coordinated A2CdBr4 compounds (A = Cs, CH3NH3)
journal, November 1979
- Altermatt, D.; Arend, H.; Niggli, A.
- Materials Research Bulletin, Vol. 14, Issue 11
Solvent engineering for high-performance inorganic–organic hybrid perovskite solar cells
journal, July 2014
- Jeon, Nam Joong; Noh, Jun Hong; Kim, Young Chan
- Nature Materials, Vol. 13, Issue 9, p. 897-903
Chemistry and structure in Acta Crystallographica Section C
journal, January 2015
- Linden, Anthony
- Acta Crystallographica Section C Structural Chemistry, Vol. 71, Issue 1
SHELXT – Integrated space-group and crystal-structure determination
journal, January 2015
- Sheldrick, George M.
- Acta Crystallographica Section A Foundations and Advances, Vol. 71, Issue 1, p. 3-8
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996
- Kresse, G.; Furthmüller, J.
- Computational Materials Science, Vol. 6, Issue 1, p. 15-50
From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999
- Kresse, G.; Joubert, D.
- Physical Review B, Vol. 59, Issue 3, p. 1758-1775
Die Krystallstruktur von NH 4 CdCl 3 und RbCdCl 3
journal, January 1939
- Mac Gillavry, C. H.; Nijveld, H.; Dierdorp, S.
- Recueil des Travaux Chimiques des Pays-Bas, Vol. 58, Issue 3
Die Kristallstruktur von K(CdCl3)
journal, April 1947
- Brandenberger, E.
- Experientia, Vol. 3, Issue 4
Structural Phase Transitions in CsPbCl 3 and RbCdCl 3
journal, August 1978
- Plesko, S.; Kind, R.; Roos, J.
- Journal of the Physical Society of Japan, Vol. 45, Issue 2
Synthesis, Crystal Structure, and Electronic Structure of InCdBr3
journal, April 1995
- Dronskowski, Richard
- Journal of Solid State Chemistry, Vol. 116, Issue 1
Solid-state principles applied to organic–inorganic perovskites: new tricks for an old dog
journal, January 2014
- Kieslich, Gregor; Sun, Shijing; Cheetham, Anthony K.
- Chem. Sci., Vol. 5, Issue 12
An extended Tolerance Factor approach for organic–inorganic perovskites
journal, January 2015
- Kieslich, Gregor; Sun, Shijing; Cheetham, Anthony K.
- Chemical Science, Vol. 6, Issue 6
Formability of ABX 3 ( X = F, Cl, Br, I) halide perovskites
journal, November 2008
- Li, Chonghea; Lu, Xionggang; Ding, Weizhong
- Acta Crystallographica Section B Structural Science, Vol. 64, Issue 6
The crystal structure of Rb 2 CdCl 4 in para- and ferroelastic phases
journal, March 1989
- Kruglik, A. I.; Vasilyev, A. D.; Aleksandrov, K. S.
- Phase Transitions, Vol. 15, Issue 1
The structures of hexagonal CsCdCl 3 and tetragonal Cs 2 CdCl 4
journal, June 1964
- Siegel, S.; Gebert, E.
- Acta Crystallographica, Vol. 17, Issue 6
Le tétrabromomercurate(II) de monométhylammonium
journal, February 1983
- Ben Salah, A.
- Journal of Applied Crystallography, Vol. 16, Issue 1
Struktur und Eigenschaften von Doppelhalogeniden von substituiertem Ammonium und Quecksilber(II). VI [1]. Die Kristallstruktur von (CH3NH3)2HgBr4 und (CH3NH3)2HgI4
journal, December 1986
- K�rfer, M.; Fuess, H.; Bats, J. W.
- Zeitschrift f�r anorganische und allgemeine Chemie, Vol. 543, Issue 12
Birefringence, X-ray and neutron diffraction measurements on the structural phase transitions of (CH3NH3)2 MnCl4 and (CH3NH3)2FeCl4
journal, July 1974
- Knorr, K.; Jahn, I. R.; Heger, G.
- Solid State Communications, Vol. 15, Issue 2
Infrared studies of the phase transitions of alkylammonium halides, RNH3X, and bis-(alkylammonium) tetrahalogenometallates(II), (RNH3)2MX4, (R = alkyl, M = metal, X = Cl or Br)
journal, January 1981
- Rao, C. N. R.; Ganguly, Somnath; Swamy, H. Ramachandra
- Journal of the Chemical Society, Faraday Transactions 2, Vol. 77, Issue 10
Molecular reorientation in solid (CH3NH3)2CdBR4 as studied by 79Br and 81Br nuclear quadrupole resonance and 1H nuclear magnetic resonance
journal, January 1992
- Nakayama, Hirokazu; Eguchi, Taro; Nakamura, Nobuo
- Journal of the Chemical Society, Faraday Transactions, Vol. 88, Issue 20
A Highly Disordered New Solid Phase Containing Isotropically Reorienting Cations in (CH 3 NH 3 )2CdBr 4 Studied by 1 H NMR and Thermal Measurements
journal, October 1990
- Ishida, Hiroyuki; Takagi, Kentaro; Terashima, Mifune
- Zeitschrift für Naturforschung A, Vol. 45, Issue 9-10
Massive Anisotropic Thermal Expansion and Thermo-Responsive Breathing in Metal-Organic Frameworks Modulated by Linker Functionalization
journal, July 2013
- Henke, Sebastian; Schneemann, Andreas; Fischer, Roland A.
- Advanced Functional Materials, Vol. 23, Issue 48
Uniaxial Negative Thermal Expansion and Mechanical Properties of a Zinc-Formate Framework
journal, February 2017
- Gao, Hongqiang; Wei, Wenjuan; Li, Yizhang
- Materials, Vol. 10, Issue 2
High Chloride Doping Levels Stabilize the Perovskite Phase of Cesium Lead Iodide
journal, May 2016
- Dastidar, Subham; Egger, David A.; Tan, Liang Z.
- Nano Letters, Vol. 16, Issue 6
A Layered Hybrid Perovskite Solar-Cell Absorber with Enhanced Moisture Stability
journal, September 2014
- Smith, Ian C.; Hoke, Eric T.; Solis-Ibarra, Diego
- Angewandte Chemie International Edition, Vol. 53, Issue 42
Optical reflectivity and electronic structure of layered cadmium halides
journal, April 1986
- Pollini, I.; Thomas, J.; Coehoorn, R.
- Physical Review B, Vol. 33, Issue 8
Synthesis, structural and optical properties of a novel bilayered organic–inorganic perovskite C5Pb2I5
journal, April 2010
- Elleuch, S.; Dammak, T.; Abid, Y.
- Journal of Luminescence, Vol. 130, Issue 4
Two-Dimensional Excitons and Photoluminescence Properties of the Organic/Inorganic (4-FC 6 H 4 C 2 H 4 NH 3 ) 2 [PbI 4 ] Nanomaterial
journal, October 2009
- Dammak, T.; Koubaa, M.; Boukheddaden, K.
- The Journal of Physical Chemistry C, Vol. 113, Issue 44
Optical, electrical properties and characterization of (C2H5NH3)2CdCl4 compound
journal, July 2016
- Lefi, Ramzi; Ben Nasr, Férid; Hrichi, Haikel
- Optik, Vol. 127, Issue 13
Structural, optical properties and characterization of (C2H5NH3)2CdCl4, (C2H5NH3)2CuCl4 and (C2H5NH3)2Cd0.5Cu0.5Cl4 compounds
journal, March 2017
- Lefi, Ramzi; Ben Naser, Ferid; Guermazi, Hajer
- Journal of Alloys and Compounds, Vol. 696
Optical Spectra of Inorganic-Organic Compounds (C 2 H 5 NH 3 ) 2 CdCl 4 in 3–30 eV Range
journal, November 2001
- Ohnishi, Akimasa; Tanaka, Ken-ichi; Kitaura, Mamoru
- Journal of the Physical Society of Japan, Vol. 70, Issue 11
Luminescence Study of Thermally-Oxidized Porous Si under Subgap or Overgap Excitation
journal, April 1998
- Shiba, Kazutoshi; Miyazaki, Seiichi; Hirose, Masataka
- Japanese Journal of Applied Physics, Vol. 37, Issue Part 1, No. 4A
Material parameters for electrostriction
journal, October 1996
- Shkel, Yuri M.; Klingenberg, Daniel J.
- Journal of Applied Physics, Vol. 80, Issue 8
Sub-Gap Excited Photoluminescence in III-V Compound Semiconductor Heterostructures
journal, September 2000
- Kalem, S.; Curtis, A.; Hartmann, Q.
- physica status solidi (b), Vol. 221, Issue 1
White-Light Emission and Structural Distortion in New Corrugated Two-Dimensional Lead Bromide Perovskites
journal, March 2017
- Mao, Lingling; Wu, Yilei; Stoumpos, Constantinos C.
- Journal of the American Chemical Society, Vol. 139, Issue 14
Self-Assembly of Broadband White-Light Emitters
journal, January 2014
- Dohner, Emma R.; Hoke, Eric T.; Karunadasa, Hemamala I.
- Journal of the American Chemical Society, Vol. 136, Issue 5
Intrinsic White-Light Emission from Layered Hybrid Perovskites
journal, September 2014
- Dohner, Emma R.; Jaffe, Adam; Bradshaw, Liam R.
- Journal of the American Chemical Society, Vol. 136, Issue 38
Luminescence of CdCl 2 -CdBr 2 Solid Solutions
journal, November 1977
- Nakagawa, Hideyuki; Hayashi, Keiji; Matsumoto, Hiroaki
- Journal of the Physical Society of Japan, Vol. 43, Issue 5
Relaxed excitonic states in CdI2 crystals
journal, January 1979
- Matsumoto, Hiroaki; Nakagawa, Hideyuki
- Journal of Luminescence, Vol. 18-19
Indirect exciton luminescense and Raman scattering in CdI2
journal, June 1981
- Hayashi, T.; Ohata, T.; Koshino, S.
- Solid State Communications, Vol. 38, Issue 9
Determination of Optical Gain of Self-Trapped Exciton Luminescence in CdI 2
journal, December 1994
- Ohnishi, Akimasa; Kitaura, Mamoru; Nakagawa, Hideyuki
- Journal of the Physical Society of Japan, Vol. 63, Issue 12
Life-time resolved emission spectra in CdCl2 crystals
journal, January 2005
- Kawabata, S.; Kitaura, M.; Nakagawa, H.
- physica status solidi (c), Vol. 2, Issue 1
Decay Time Studies on UV-Luminescence in CdBr2CdCl2 Mixed Crystals
journal, May 1996
- Kitaura, M.; Nakagawa, H.; Fukui, K.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 79
Emission spectra and decay characteristics in photo-stimulated (CnH2n+1NH3)2CdCl4 : n=1, 2, 3
journal, May 1996
- Ohnishi, A.; Yamada, T.; Yoshinari, T.
- Journal of Electron Spectroscopy and Related Phenomena, Vol. 79
Energy transport and scintillation of cerium-doped elpasolite Cs LiYCl : Hybrid density functional calculations
journal, July 2012
- Biswas, Koushik; Du, Mao-Hua
- Physical Review B, Vol. 86, Issue 1
Electronic structure engineering of elpasolites: Case of Cs2AgYCl6
journal, November 2013
- Du, Mao-Hua; Biswas, Koushik
- Journal of Luminescence, Vol. 143
Predicting and Screening Dielectric Transitions in a Series of Hybrid Organic-Inorganic Double Perovskites via an Extended Tolerance Factor Approach
journal, April 2016
- Shi, Chao; Yu, Chun-Hua; Zhang, Wen
- Angewandte Chemie International Edition, Vol. 55, Issue 19
Scintillation Properties and Electronic Structures of the Intrinsic and Extrinsic Mixed Elpasolites ( , Y)
journal, February 2016
- Wei, Hua; Du, Mao-Hua; Stand, Luis
- Physical Review Applied, Vol. 5, Issue 2
Mechanism for Broadband White-Light Emission from Two-Dimensional (110) Hybrid Perovskites
journal, May 2016
- Hu, Te; Smith, Matthew D.; Dohner, Emma R.
- The Journal of Physical Chemistry Letters, Vol. 7, Issue 12
Excitonic and Polaronic Properties of 2D Hybrid Organic–Inorganic Perovskites
journal, January 2017
- Yin, Jun; Li, Hong; Cortecchia, Daniele
- ACS Energy Letters, Vol. 2, Issue 2
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Dielectric phase transition triggered by the order–disorder transformation of cyclopropylamine in a layered organic–inorganic halide perovskite
journal, January 2018
- Han, Shiguo; Liu, Xitao; Zhang, Jing
- Journal of Materials Chemistry C, Vol. 6, Issue 38
High-throughput computational design of organic–inorganic hybrid halide semiconductors beyond perovskites for optoelectronics
journal, January 2019
- Li, Yuheng; Yang, Kesong
- Energy & Environmental Science, Vol. 12, Issue 7
Air-stable all-inorganic perovskite quantum dot inks for multicolor patterns and white LEDs
journal, January 2019
- Zhihai, Wu; Jiao, Wei; Yanni, Sun
- Journal of Materials Science, Vol. 54, Issue 9
(1,4-Butyldiammonium)CdBr 4 : a layered organic–inorganic hybrid perovskite with a visible-blind ultraviolet photoelectric response
journal, January 2018
- Wang, Yuyin; Ji, Chengmin; Liu, Xitao
- Inorganic Chemistry Frontiers, Vol. 5, Issue 10
Rb 2 CuX 3 (X = Cl, Br): 1D All‐Inorganic Copper Halides with Ultrabright Blue Emission and Up‐Conversion Photoluminescence
journal, November 2019
- Creason, Tielyr D.; Yangui, Aymen; Roccanova, Rachel
- Advanced Optical Materials, Vol. 8, Issue 2
(CH 3 NH 3 )AuX 4 ⋅H 2 O (X=Cl, Br) and (CH 3 NH 3 )AuCl 4 : Low‐Band Gap Lead‐Free Layered Gold Halide Perovskite Materials
journal, July 2019
- Worley, Chris; Yangui, Aymen; Roccanova, Rachel
- Chemistry – A European Journal, Vol. 25, Issue 42
Additive-assisted synthesis and optoelectronic properties of (CH 3 NH 3 ) 4 Bi 6 I 22
journal, January 2020
- Sharma, Manila; Yangui, Aymen; Lusson, Alain
- Inorganic Chemistry Frontiers, Vol. 7, Issue 7
Exploring Organic Metal Halides with Reversible Temperature‐Responsive Dual‐Emissive Photoluminescence
journal, October 2019
- Jiang, Xiaomei; Xia, Shengqing; Zhang, Jian
- ChemSusChem, Vol. 12, Issue 24