Moving towards the magnetoelectric graphene transistor
Abstract
Here, the interfacial charge transfer between mechanically exfoliated few-layer graphene and Cr2O3 (0001) surfaces has been investigated. Electrostatic force microscopy and Kelvin probe force microscopy studies point to hole doping of few-layer graphene, with up to a 150 meV shift in the Fermi level, an aspect that is confirmed by Raman spectroscopy. Density functional theory calculations furthermore confirm the p-type nature of the graphene/chromia interface and suggest that the chromia is able to induce a significant carrier spin polarization in the graphene layer. A large magnetoelectrically controlled magneto-resistance can therefore be anticipated in transistor structures based on this system, a finding important for developing graphene-based spintronic applications.
- Authors:
-
- Univ. of Nebraksa-Lincoln, Lincoln, NE (United States)
- Univ. at Buffalo, The State Uni. of New York, Buffalo, NY (United States)
- Univ. of Science and Technology of China, Anhui (China)
- Univ. at Buffalo, The State Univ. of New York, Buffalo, NY (United States)
- Univ. of Nebraska at Omaha, Omaha, NE (United States)
- Publication Date:
- Research Org.:
- Univ. of Nebraksa-Lincoln, Lincoln, NE (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1406295
- Alternate Identifier(s):
- OSTI ID: 1406386
- Grant/Contract Number:
- SC0016153
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Applied Physics Letters
- Additional Journal Information:
- Journal Volume: 111; Journal Issue: 18; Related Information: http://cdn.scitation.org/journals/content/apl/2017/apl.2017.111.issue-18/1.4999643/20171101/suppl/supplementary%20marterialsv2.pdf?b92b4ad1b4f274c70877518610abb28bd756756a6161842cd52fd8f52e9eae516dc5ee147b8bce65758738b212fba58380ff0f8a9d6c7531ed9e0a54fbc248f7f7604325d1c3e31b8c2ffec948b4aab1951645fa835584d08a19fdb68f38427c9cddcd0c898ac29899234e4f5d1575cc584dfec97383ae628335601020a6ce1b4f518a63b14f4d965b517f5ee119d6383fbd0af0e5b5c60ca58b; Journal ID: ISSN 0003-6951
- Publisher:
- American Institute of Physics (AIP)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; 77 NANOSCIENCE AND NANOTECHNOLOGY; graphene; Cr2O3; magnetoelectric; interfacial charge transfer; scanning probe microscopy
Citation Formats
Cao, Shi, Xiao, Zhiyong, Kwan, Chun -Pui, Zhang, Kai, Bird, Jonathan P., Wang, Lu, Mei, Wai -Ning, Hong, Xia, and Dowben, P. A. Moving towards the magnetoelectric graphene transistor. United States: N. p., 2017.
Web. doi:10.1063/1.4999643.
Cao, Shi, Xiao, Zhiyong, Kwan, Chun -Pui, Zhang, Kai, Bird, Jonathan P., Wang, Lu, Mei, Wai -Ning, Hong, Xia, & Dowben, P. A. Moving towards the magnetoelectric graphene transistor. United States. https://doi.org/10.1063/1.4999643
Cao, Shi, Xiao, Zhiyong, Kwan, Chun -Pui, Zhang, Kai, Bird, Jonathan P., Wang, Lu, Mei, Wai -Ning, Hong, Xia, and Dowben, P. A. Mon .
"Moving towards the magnetoelectric graphene transistor". United States. https://doi.org/10.1063/1.4999643. https://www.osti.gov/servlets/purl/1406295.
@article{osti_1406295,
title = {Moving towards the magnetoelectric graphene transistor},
author = {Cao, Shi and Xiao, Zhiyong and Kwan, Chun -Pui and Zhang, Kai and Bird, Jonathan P. and Wang, Lu and Mei, Wai -Ning and Hong, Xia and Dowben, P. A.},
abstractNote = {Here, the interfacial charge transfer between mechanically exfoliated few-layer graphene and Cr2O3 (0001) surfaces has been investigated. Electrostatic force microscopy and Kelvin probe force microscopy studies point to hole doping of few-layer graphene, with up to a 150 meV shift in the Fermi level, an aspect that is confirmed by Raman spectroscopy. Density functional theory calculations furthermore confirm the p-type nature of the graphene/chromia interface and suggest that the chromia is able to induce a significant carrier spin polarization in the graphene layer. A large magnetoelectrically controlled magneto-resistance can therefore be anticipated in transistor structures based on this system, a finding important for developing graphene-based spintronic applications.},
doi = {10.1063/1.4999643},
journal = {Applied Physics Letters},
number = 18,
volume = 111,
place = {United States},
year = {Mon Oct 30 00:00:00 EDT 2017},
month = {Mon Oct 30 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Raman spectroscopy of graphene on different substrates and influence of defects
journal, June 2008
- Das, Anindya; Chakraborty, Biswanath; Sood, A. K.
- Bulletin of Materials Science, Vol. 31, Issue 3
Generalized Gradient Approximation Made Simple
journal, October 1996
- Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias
- Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868
Robust isothermal electric control of exchange bias at room temperature
journal, June 2010
- He, Xi; Wang, Yi; Wu, Ning
- Nature Materials, Vol. 9, Issue 7
Materials for Spintronics: Magnetic and Transport Properties of Ultrathin (Monolayer Graphene)/MnO(001) and MnO(001) Films
journal, January 2011
- Ilyasov, Victor; Meshi, Besarion; Ryzhkin, Anatoly
- Journal of Modern Physics, Vol. 02, Issue 10
Increasing the Néel temperature of magnetoelectric chromia for voltage-controlled spintronics
journal, June 2014
- Street, M.; Echtenkamp, W.; Komesu, Takashi
- Applied Physics Letters, Vol. 104, Issue 22
Accurate thickness measurement of graphene
journal, February 2016
- Shearer, Cameron J.; Slattery, Ashley D.; Stapleton, Andrew J.
- Nanotechnology, Vol. 27, Issue 12
Evidence for Spin-Flip Scattering and Local Moments in Dilute Fluorinated Graphene
journal, June 2012
- Hong, X.; Zou, K.; Wang, B.
- Physical Review Letters, Vol. 108, Issue 22
Van der Waals density functionals applied to solids
journal, May 2011
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- Physical Review B, Vol. 83, Issue 19
Spin field effect transistor with a graphene channel
journal, October 2007
- Semenov, Y. G.; Kim, K. W.; Zavada, J. M.
- Applied Physics Letters, Vol. 91, Issue 15
Are Al2O3 and MgO tunnel barriers suitable for spin injection in graphene?
journal, August 2010
- Dlubak, B.; Seneor, P.; Anane, A.
- Applied Physics Letters, Vol. 97, Issue 9
Special points for Brillouin-zone integrations
journal, June 1976
- Monkhorst, Hendrik J.; Pack, James D.
- Physical Review B, Vol. 13, Issue 12, p. 5188-5192
Adsorption of potassium on at ionic and metallic coverages and uv-laser-induced desorption
journal, May 1999
- Wilde, M.; Beauport, I.; Stuhl, F.
- Physical Review B, Vol. 59, Issue 20
Molecular adsorption on graphene
journal, October 2014
- Kong, Lingmei; Enders, Axel; Rahman, Talat S.
- Journal of Physics: Condensed Matter, Vol. 26, Issue 44
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium
journal, May 1994
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 49, Issue 20, p. 14251-14269
Chemical accuracy for the van der Waals density functional
journal, December 2009
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- Journal of Physics: Condensed Matter, Vol. 22, Issue 2
Periodic boundary conditions in ab initio calculations
journal, February 1995
- Makov, G.; Payne, M. C.
- Physical Review B, Vol. 51, Issue 7
Imaging and Control of Surface Magnetization Domains in a Magnetoelectric Antiferromagnet
journal, February 2011
- Wu, Ning; He, Xi; Wysocki, Aleksander L.
- Physical Review Letters, Vol. 106, Issue 8
Magnetization at the interface of Cr 2 O 3 and paramagnets with large stoner susceptibility
journal, February 2017
- Cao, Shi; Street, M.; Wang, Junlei
- Journal of Physics: Condensed Matter, Vol. 29, Issue 10
Tuning the Graphene Work Function by Electric Field Effect
journal, October 2009
- Yu, Young-Jun; Zhao, Yue; Ryu, Sunmin
- Nano Letters, Vol. 9, Issue 10, p. 3430-3434
High-Mobility Few-Layer Graphene Field Effect Transistors Fabricated on Epitaxial Ferroelectric Gate Oxides
journal, April 2009
- Hong, X.; Posadas, A.; Zou, K.
- Physical Review Letters, Vol. 102, Issue 13
Equilibrium Magnetization at the Boundary of a Magnetoelectric Antiferromagnet
journal, October 2010
- Belashchenko, K. D.
- Physical Review Letters, Vol. 105, Issue 14
Ab initiomolecular dynamics for liquid metals
journal, January 1993
- Kresse, G.; Hafner, J.
- Physical Review B, Vol. 47, Issue 1, p. 558-561
Proximity Effects Induced in Graphene by Magnetic Insulators: First-Principles Calculations on Spin Filtering and Exchange-Splitting Gaps
journal, January 2013
- Yang, H. X.; Hallal, A.; Terrade, D.
- Physical Review Letters, Vol. 110, Issue 4
Spin polarization asymmetry at the surface of chromia
journal, July 2014
- Cao, Shi; Zhang, Xin; Wu, Ning
- New Journal of Physics, Vol. 16, Issue 7
Adsorbate-substrate and adsorbate-adsorbate interactions of Na and K adlayers on Al(111)
journal, December 1992
- Neugebauer, Jörg; Scheffler, Matthias
- Physical Review B, Vol. 46, Issue 24
Observation of Anomalous Phonon Softening in Bilayer Graphene
journal, September 2008
- Yan, Jun; Henriksen, Erik A.; Kim, Philip
- Physical Review Letters, Vol. 101, Issue 13
Raman Spectrum of Graphene and Graphene Layers
journal, October 2006
- Ferrari, A. C.; Meyer, J. C.; Scardaci, V.
- Physical Review Letters, Vol. 97, Issue 18, Article No. 187401
Spin transport in proximity-induced ferromagnetic graphene
journal, March 2008
- Haugen, Håvard; Huertas-Hernando, Daniel; Brataas, Arne
- Physical Review B, Vol. 77, Issue 11
Magnetoelectric oxide films for spin manipulation in graphene
journal, January 2016
- Stuart, S. C.; Gray, B.; Nevola, D.
- physica status solidi (RRL) - Rapid Research Letters, Vol. 10, Issue 3
Accurate band structures and effective masses for InP, InAs, and InSb using hybrid functionals
journal, July 2009
- Kim, Yoon-Suk; Hummer, Kerstin; Kresse, Georg
- Physical Review B, Vol. 80, Issue 3
Atmospheric Oxygen Binding and Hole Doping in Deformed Graphene on a SiO2 Substrate
journal, December 2010
- Ryu, Sunmin; Liu, Li; Berciaud, Stephane
- Nano Letters, Vol. 10, Issue 12, p. 4944-4951
Interface-Induced Spin Polarization in Graphene on Chromia
journal, January 2016
- Choudhary, Renu; Kumar, Pankaj; Manchanda, Priyanka
- IEEE Magnetics Letters, Vol. 7
Raman Studies of Monolayer Graphene: The Substrate Effect
journal, June 2008
- Wang, Ying ying; Ni, Zhen hua; Yu, Ting
- The Journal of Physical Chemistry C, Vol. 112, Issue 29
Parallel Nanoimprint Forming of One-Dimensional Chiral Semiconductor for Strain-Engineered Optical Properties
journal, August 2020
- Wang, Yixiu; Jin, Shengyu; Wang, Qingxiao
- Nano-Micro Letters, Vol. 12, Issue 1
Raman spectroscopy of graphene on different substrates and influence of defects
preprint, January 2007
- Das, Anindya; Chakraborty, Biswanath; Sood, A. K.
- arXiv
High-Mobility Few-Layer Graphene Field Effect Transistors Fabricated on Epitaxial Ferroelectric Gate Oxides
text, January 2008
- Hong, X.; Posadas, A.; Zou, K.
- arXiv
Chemical accuracy for the van der Waals density functional
preprint, January 2009
- Klimes, J.; Bowler, D. R.; Michaelides, A.
- arXiv
Van der Waals density functionals applied to solids
text, January 2011
- Klimeš, Jiří; Bowler, David R.; Michaelides, Angelos
- arXiv
Works referencing / citing this record:
Manipulation of Antiferromagnetic Spin Using Tunable Parasitic Magnetization in Magnetoelectric Antiferromagnet
journal, October 2018
- Nozaki, Tomohiro; Al‐Mahdawi, Muftah; Shiokawa, Yohei
- physica status solidi (RRL) – Rapid Research Letters, Vol. 12, Issue 12
Tuning the electronic and magnetic properties of InSe nanosheets by transition metal doping
journal, January 2018
- Wang, Tao; Li, Jianwei; Jin, Hao
- Physical Chemistry Chemical Physics, Vol. 20, Issue 11
Spin polarization and tunable valley degeneracy in a MoS 2 monolayer via proximity coupling to a Cr 2 O 3 substrate
journal, January 2019
- Zhang, Kai; Wang, Lu; Wu, Xiaojun
- Nanoscale, Vol. 11, Issue 41
Magnetoelectric control of topological phases in graphene
journal, September 2019
- Takenaka, Hiroyuki; Sandhoefner, Shane; Kovalev, Alexey A.
- Physical Review B, Vol. 100, Issue 12
Reconfigurable characteristics of graphene plates
journal, January 2019
- Moradi, Khatereh; Pourziad, Ali; Nikmehr, Saeid
- Applied Optics, Vol. 58, Issue 20