Formation of a Crack-Free, Hybrid Skin Layer with Tunable Surface Topography and Improved Gas Permeation Selectivity on Elastomers Using Gel–Liquid Infiltration Polymerization
Abstract
Surface modifications of elastomers and gels are crucial for emerging applications such as soft robotics and flexible electronics, in large part because they provide a platform to control wettability, adhesion, and permeability. Current surface modification methods via ultraviolet-ozone (UVO) and/or O2 plasma, atomic layer deposition (ALD), plasmas deposition, and chemical treatment impart a dense polymer or inorganic layer on the surface that is brittle and easy to fracture at low strain levels. This paper presents a new method, based on gel–liquid infiltration polymerization, to form hybrid skin layers atop elastomers. The method is unique in that it allows for control of the skin layer topography, with tunable feature sizes and aspect ratios as high as 1.8 without fracture. Unlike previous techniques, the skin layer formed here dramatically improves the barrier properties of the elastomer, while preserving skin layer flexibility. Furthermore, the method is versatile and likely applicable to most interfacial polymerization systems and network polymers on flat and patterned surfaces.
- Authors:
-
- Univ. of Colorado, Boulder, CO (United States)
- National Institute of Standards and Technology (NIST), Gaithersburg, MD (United States)
- National Institute of Standards and Technology (NIST), Boulder, CO (United States)
- Univ. at Buffalo, The State Univ. of New York, Buffalo, NY (United States)
- Brookhaven National Lab. (BNL), Upton, NY (United States)
- Publication Date:
- Research Org.:
- Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1405936
- Report Number(s):
- BNL-114445-2017-JA
Journal ID: ISSN 1944-8244; KC0403020
- Grant/Contract Number:
- SC0012704
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 33; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; gas separation membranes; gels and elastomers; skin layers; surface modifications; surface wrinkles; Center for Functional Nanomaterials
Citation Formats
Wang, Mengyuan, Gorham, Justin M., Killgore, Jason P., Omidvar, Maryam, Lin, Haiqing, DelRio, Frank W., Cox, Lewis M., Zhang, Zheng, and Ding, Yifu. Formation of a Crack-Free, Hybrid Skin Layer with Tunable Surface Topography and Improved Gas Permeation Selectivity on Elastomers Using Gel–Liquid Infiltration Polymerization. United States: N. p., 2017.
Web. doi:10.1021/acsami.7b09274.
Wang, Mengyuan, Gorham, Justin M., Killgore, Jason P., Omidvar, Maryam, Lin, Haiqing, DelRio, Frank W., Cox, Lewis M., Zhang, Zheng, & Ding, Yifu. Formation of a Crack-Free, Hybrid Skin Layer with Tunable Surface Topography and Improved Gas Permeation Selectivity on Elastomers Using Gel–Liquid Infiltration Polymerization. United States. https://doi.org/10.1021/acsami.7b09274
Wang, Mengyuan, Gorham, Justin M., Killgore, Jason P., Omidvar, Maryam, Lin, Haiqing, DelRio, Frank W., Cox, Lewis M., Zhang, Zheng, and Ding, Yifu. Mon .
"Formation of a Crack-Free, Hybrid Skin Layer with Tunable Surface Topography and Improved Gas Permeation Selectivity on Elastomers Using Gel–Liquid Infiltration Polymerization". United States. https://doi.org/10.1021/acsami.7b09274. https://www.osti.gov/servlets/purl/1405936.
@article{osti_1405936,
title = {Formation of a Crack-Free, Hybrid Skin Layer with Tunable Surface Topography and Improved Gas Permeation Selectivity on Elastomers Using Gel–Liquid Infiltration Polymerization},
author = {Wang, Mengyuan and Gorham, Justin M. and Killgore, Jason P. and Omidvar, Maryam and Lin, Haiqing and DelRio, Frank W. and Cox, Lewis M. and Zhang, Zheng and Ding, Yifu},
abstractNote = {Surface modifications of elastomers and gels are crucial for emerging applications such as soft robotics and flexible electronics, in large part because they provide a platform to control wettability, adhesion, and permeability. Current surface modification methods via ultraviolet-ozone (UVO) and/or O2 plasma, atomic layer deposition (ALD), plasmas deposition, and chemical treatment impart a dense polymer or inorganic layer on the surface that is brittle and easy to fracture at low strain levels. This paper presents a new method, based on gel–liquid infiltration polymerization, to form hybrid skin layers atop elastomers. The method is unique in that it allows for control of the skin layer topography, with tunable feature sizes and aspect ratios as high as 1.8 without fracture. Unlike previous techniques, the skin layer formed here dramatically improves the barrier properties of the elastomer, while preserving skin layer flexibility. Furthermore, the method is versatile and likely applicable to most interfacial polymerization systems and network polymers on flat and patterned surfaces.},
doi = {10.1021/acsami.7b09274},
journal = {ACS Applied Materials and Interfaces},
number = 33,
volume = 9,
place = {United States},
year = {Mon Jul 31 00:00:00 EDT 2017},
month = {Mon Jul 31 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Stretchable Hydrogel Electronics and Devices
journal, December 2015
- Lin, Shaoting; Yuk, Hyunwoo; Zhang, Teng
- Advanced Materials, Vol. 28, Issue 22
Epidermal mechano-acoustic sensing electronics for cardiovascular diagnostics and human-machine interfaces
journal, November 2016
- Liu, Yuhao; Norton, James J. S.; Qazi, Raza
- Science Advances, Vol. 2, Issue 11
Hydraulic hydrogel actuators and robots optically and sonically camouflaged in water
journal, February 2017
- Yuk, Hyunwoo; Lin, Shaoting; Ma, Chu
- Nature Communications, Vol. 8, Issue 1
Highly Stretchable, Strain Sensing Hydrogel Optical Fibers
journal, October 2016
- Guo, Jingjing; Liu, Xinyue; Jiang, Nan
- Advanced Materials, Vol. 28, Issue 46
A Mechanoluminescent ZnS:Cu/Rhodamine/SiO 2 /PDMS and Piezoresistive CNT/PDMS Hybrid Sensor: Red-Light Emission and a Standardized Strain Quantification
journal, December 2016
- Sohn, Kee-Sun; Timilsina, Suman; Singh, Satendra Pal
- ACS Applied Materials & Interfaces, Vol. 8, Issue 50
Skin-inspired hydrogel–elastomer hybrids with robust interfaces and functional microstructures
journal, June 2016
- Yuk, Hyunwoo; Zhang, Teng; Parada, German Alberto
- Nature Communications, Vol. 7, Issue 1
Nanocrack-regulated self-humidifying membranes
journal, April 2016
- Park, Chi Hoon; Lee, So Young; Hwang, Doo Sung
- Nature, Vol. 532, Issue 7600
Drying-Mediated Assembly of Colloidal Nanoparticles into Large-Scale Microchannels
journal, June 2013
- Han, Wei; Li, Bo; Lin, Zhiqun
- ACS Nano, Vol. 7, Issue 7
Harnessing Colloidal Crack Formation by Flow-Enabled Self-Assembly
journal, March 2017
- Li, Bo; Jiang, Beibei; Han, Wei
- Angewandte Chemie International Edition, Vol. 56, Issue 16
Adhesive Stretchable Printed Conductive Thin Film Patterns on PDMS Surface with an Atmospheric Plasma Treatment
journal, April 2016
- Li, Chun-Yi; Liao, Ying-Chih
- ACS Applied Materials & Interfaces, Vol. 8, Issue 18
Fabricating Microlens Arrays by Surface Wrinkling
journal, December 2006
- Chan, E. P.; Crosby, A. J.
- Advanced Materials, Vol. 18, Issue 24
Complex micropatterning of periodic structures on elastomeric surfaces
journal, January 2008
- Chiche, Arnaud; Stafford, Christopher M.; Cabral, João T.
- Soft Matter, Vol. 4, Issue 12
Nested self-similar wrinkling patterns in skins
journal, March 2005
- Efimenko, Kirill; Rackaitis, Mindaugas; Manias, Evangelos
- Nature Materials, Vol. 4, Issue 4
Biomimetic Microfingerprints for Anti-Counterfeiting Strategies
journal, February 2015
- Bae, Hyung Jong; Bae, Sangwook; Park, Cheolheon
- Advanced Materials, Vol. 27, Issue 12
Sequential Infiltration Synthesis of Doped Polymer Films with Tunable Electrical Properties for Efficient Triboelectric Nanogenerator Development
journal, July 2015
- Yu, Yanhao; Li, Zhaodong; Wang, Yunming
- Advanced Materials, Vol. 27, Issue 33
Kinetics of Film Formation by Interfacial Polycondensation
journal, March 2005
- Freger, Viatcheslav
- Langmuir, Vol. 21, Issue 5
Mathematical model of charge and density distributions in interfacial polymerization of thin films
journal, February 2003
- Freger, V.; Srebnik, S.
- Journal of Applied Polymer Science, Vol. 88, Issue 5
Influence of substrate processing and interfacial polymerization conditions on the surface topography and permselective properties of surface-patterned thin-film composite membranes
journal, August 2016
- Maruf, Sajjad H.; Greenberg, Alan R.; Ding, Yifu
- Journal of Membrane Science, Vol. 512
Fabrication and characterization of a surface-patterned thin film composite membrane
journal, February 2014
- Maruf, Sajjad H.; Greenberg, Alan R.; Pellegrino, John
- Journal of Membrane Science, Vol. 452
Sub-10 nm polyamide nanofilms with ultrafast solvent transport for molecular separation
journal, June 2015
- Karan, S.; Jiang, Z.; Livingston, A. G.
- Science, Vol. 348, Issue 6241
Solvent Compatibility of Poly(dimethylsiloxane)-Based Microfluidic Devices
journal, October 2003
- Lee, Jessamine Ng; Park, Cheolmin; Whitesides, George M.
- Analytical Chemistry, Vol. 75, Issue 23, p. 6544-6554
High aspect ratio wrinkles on a soft polymer
journal, January 2010
- Ahmed, Sk. Faruque; Rho, Geon-Ho; Lee, Kwang-Ryeol
- Soft Matter, Vol. 6, Issue 22
Achieving high aspect ratio wrinkles by modifying material network stress
journal, January 2017
- Chen, Yu-Cheng; Wang, Yan; McCarthy, Thomas J.
- Soft Matter, Vol. 13, Issue 22
Harnessing Localized Ridges for High-Aspect-Ratio Hierarchical Patterns with Dynamic Tunability and Multifunctionality
journal, December 2013
- Cao, Changyong; Chan, Hon Fai; Zang, Jianfeng
- Advanced Materials, Vol. 26, Issue 11
Unique Aspects of a Shape Memory Polymer As the Substrate for Surface Wrinkling
journal, January 2012
- Li, Junjun; An, Yonghao; Huang, Rui
- ACS Applied Materials & Interfaces, Vol. 4, Issue 2
Ridge Localizations and Networks in Thin Films Compressed by the Incremental Release of a Large Equi-biaxial Pre-stretch in the Substrate
journal, March 2014
- Takei, Atsushi; Jin, Lihua; Hutchinson, John W.
- Advanced Materials, Vol. 26, Issue 24
High Aspect Ratio Wrinkles via Substrate Prestretch
journal, May 2014
- Chen, Yu-Cheng; Crosby, Alfred J.
- Advanced Materials, Vol. 26, Issue 32
High-Aspect-Ratio Ridge Structures Induced by Plastic Deformation as a Novel Microfabrication Technique
journal, August 2016
- Takei, Atsushi; Jin, Lihua; Fujita, Hiroyuki
- ACS Applied Materials & Interfaces, Vol. 8, Issue 36
Swelling and Morphology of the Skin Layer of Polyamide Composite Membranes: An Atomic Force Microscopy Study
journal, June 2004
- Freger, Viatcheslav
- Environmental Science & Technology, Vol. 38, Issue 11
Glass transition behaviors of interfacially polymerized polyamide barrier layers on thin film composite membranes via nano-thermal analysis
journal, May 2011
- Maruf, Sajjad H.; Ahn, Dae U.; Greenberg, Alan R.
- Polymer, Vol. 52, Issue 12
Thin film composite polyamide membranes: parametric study on the influence of synthesis conditions
journal, January 2015
- Khorshidi, B.; Thundat, T.; Fleck, B. A.
- RSC Advances, Vol. 5, Issue 68
Air plasma treatment of submicron thick PDMS polymer films: effect of oxidation time and storage conditions
journal, February 2005
- Lawton, Renée A.; Price, Colin R.; Runge, Anne F.
- Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 253, Issue 1-3
Super-Hydrophobic PDMS Surface with Ultra-Low Adhesive Force
journal, November 2005
- Jin, Meihua; Feng, Xinjian; Xi, Jinming
- Macromolecular Rapid Communications, Vol. 26, Issue 22
Bilayer Mass Transport Model for Determining Swelling and Diffusion in Coated, Ultrathin Membranes
journal, February 2015
- Nadermann, Nichole K.; Chan, Edwin P.; Stafford, Christopher M.
- ACS Applied Materials & Interfaces, Vol. 7, Issue 6
Gas sorption, diffusion, and permeation in poly(dimethylsiloxane)
journal, February 2000
- Merkel, T. C.; Bondar, V. I.; Nagai, K.
- Journal of Polymer Science Part B: Polymer Physics, Vol. 38, Issue 3, p. 415-434
Dehydration of natural gas using membranes. Part I: Composite membranes
journal, September 2012
- Lin, Haiqing; Thompson, Scott M.; Serbanescu-Martin, Adrian
- Journal of Membrane Science, Vol. 413-414
Patterned Polymer Films via Reactive Silane Infusion-Induced Wrinkling
journal, March 2013
- Li, Yinyong; Peterson, Joseph J.; Jhaveri, Sarav B.
- Langmuir, Vol. 29, Issue 14
Current trends in interfacial polymerization chemistry
journal, December 2016
- Raaijmakers, Michiel J. T.; Benes, Nieck E.
- Progress in Polymer Science, Vol. 63
Comparing flat and micro-patterned surfaces: Gas permeation and tensile stress measurements
journal, July 2008
- Peters, Alisia M.; Lammertink, Rob G. H.; Wessling, Matthias
- Journal of Membrane Science, Vol. 320, Issue 1-2
Surface patterning of polymeric membranes and its effect on antifouling characteristics
journal, August 2016
- Ding, Yifu; Maruf, Sajjad; Aghajani, Masoud
- Separation Science and Technology, Vol. 52, Issue 2
Nanoscale Pillar-Enhanced Tribological Surfaces as Antifouling Membranes
journal, November 2016
- Choi, Wansuk; Chan, Edwin P.; Park, Jong-Hyun
- ACS Applied Materials & Interfaces, Vol. 8, Issue 45
Impacts of reaction and curing conditions on polyamide composite reverse osmosis membrane properties
journal, March 2008
- Ghosh, Asim K.; Jeong, Byeong-Heon; Huang, Xiaofei
- Journal of Membrane Science, Vol. 311, Issue 1-2
Capillary rupture of suspended polymer concentric rings
journal, January 2015
- Zhang, Zheng; Hilton, G. C.; Yang, Ronggui
- Soft Matter, Vol. 11, Issue 37
Instabilities of PS/PMMA Bilayer Patterns with a Corrugated Surface and Interface
journal, February 2012
- Zhang, Zheng; Ahn, Dae Up; Ding, Yifu
- Macromolecules, Vol. 45, Issue 4
One-step process to create porous structures in cross-linked polymer films via breath-figure formations during in situ cross-linking reactions
journal, October 2011
- Maniglio, Devid; Ding, Yifu; Wang, Liang
- Polymer, Vol. 52, Issue 22
Measurement of Viscoelastic Loss Tangent with Contact Resonance Modes of Atomic Force Microscopy
journal, November 2013
- Hurley, Donna C.; Campbell, Sara E.; Killgore, Jason P.
- Macromolecules, Vol. 46, Issue 23
Viscoelastic Property Mapping with Contact Resonance Force Microscopy
journal, December 2011
- Killgore, J. P.; Yablon, D. G.; Tsou, A. H.
- Langmuir, Vol. 27, Issue 23
High-Throughput Measurements of Thermochromic Behavior in V 1– x Nb x O 2 Combinatorial Thin Film Libraries
journal, September 2014
- Barron, S. C.; Gorham, J. M.; Patel, M. P.
- ACS Combinatorial Science, Vol. 16, Issue 10
Physical aging of glassy perfluoropolymers in thin film composite membranes. Part II. Glass transition temperature and the free volume model
journal, March 2017
- Yavari, Milad; Maruf, Sajjad; Ding, Yifu
- Journal of Membrane Science, Vol. 525
Works referencing / citing this record:
Advanced Soft Materials, Sensor Integrations, and Applications of Wearable Flexible Hybrid Electronics in Healthcare, Energy, and Environment
journal, July 2019
- Lim, Hyo‐Ryoung; Kim, Hee Seok; Qazi, Raza
- Advanced Materials
Controlled Growth of Polyamide Films atop Homogenous and Heterogeneous Hydrogels Using Gel–Liquid Interfacial Polymerization
journal, May 2019
- Wang, Mengyuan; Stafford, Christopher M.; Cox, Lewis M.
- Macromolecular Chemistry and Physics