Kinetic and potential sputtering of an anorthite-like glassy thin film

Hijazi, H.; Bannister, M. E.; Meyer, H. M.; Rouleau, C. M.; Meyer, F. W.

doi:10.1002/2017JE005300

Title: Kinetic and potential sputtering of an anorthite-like glassy thin film

Abstract

Abstract In this paper, we present measurements of He ⁺ and He ⁺² ion‐induced sputtering of an anorthite‐like thin film at a fixed solar wind‐relevant impact energy of ~0.5 keV/amu using a quartz crystal microbalance approach (QCM) for determination of total absolute sputtering yields. He ⁺² ions are the most abundant multicharged ions in the solar wind, and increased sputtering by these ions in comparison to equivelocity He ⁺ ions is expected to have the biggest effect on the overall sputtering efficiency of solar wind impact on the Moon. Our measurements indicate an almost 70% increase of the sputtering yield for doubly charged incident He ions compared to that for same velocity He ⁺ impact (14.6 amu/ion for He ⁺² vs. 8.7 amu/ion for He ⁺ ). Using a selective sputtering model, the new QCM results presented here, together with previously published results for Ar ^+q ions and SRIM results for the relevant kinetic‐sputtering yields, the effect due to multicharged‐solar‐wind‐ion impact on local near‐surface modification of lunar anorthite‐like soil is explored. It is shown that the multicharged‐solar‐wind component leads to a more pronounced and significant differentiation of depleted and enriched surface elements as well as a shortening of the timescale overmore »« less

Authors:

Hijazi, H. ^[1]; Bannister, M. E. ^[1]; Meyer, H. M. ^[2]; Rouleau, C. M. ^[3]; Meyer, F. W. ^[1]

Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Physics Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science and Technology Division
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Science

Publication Date:: Fri Jul 28 00:00:00 EDT 2017

Research Org.:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1394230

Alternate Identifier(s):: OSTI ID: 1374763

Grant/Contract Number:: AC05-00OR22725

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Geophysical Research. Planets

Additional Journal Information:: Journal Volume: 122; Journal Issue: 7; Journal ID: ISSN 2169-9097

Publisher:: American Geophysical Union

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Hijazi, H., Bannister, M. E., Meyer, H. M., Rouleau, C. M., and Meyer, F. W. Kinetic and potential sputtering of an anorthite-like glassy thin film.  United States: N. p., 2017. 
Web.  doi:10.1002/2017JE005300.

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                    Hijazi, H., Bannister, M. E., Meyer, H. M., Rouleau, C. M., & Meyer, F. W. Kinetic and potential sputtering of an anorthite-like glassy thin film.  United States.  https://doi.org/10.1002/2017JE005300

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                    Hijazi, H., Bannister, M. E., Meyer, H. M., Rouleau, C. M., and Meyer, F. W. Fri .  
"Kinetic and potential sputtering of an anorthite-like glassy thin film".  United States.  https://doi.org/10.1002/2017JE005300.  https://www.osti.gov/servlets/purl/1394230.

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@article{osti_1394230,

  title        = {Kinetic and potential sputtering of an anorthite-like glassy thin film},

  author       = {Hijazi, H. and Bannister, M. E. and Meyer, H. M. and Rouleau, C. M. and Meyer, F. W.},

  abstractNote = {Abstract In this paper, we present measurements of He + and He +2 ion‐induced sputtering of an anorthite‐like thin film at a fixed solar wind‐relevant impact energy of ~0.5 keV/amu using a quartz crystal microbalance approach (QCM) for determination of total absolute sputtering yields. He +2 ions are the most abundant multicharged ions in the solar wind, and increased sputtering by these ions in comparison to equivelocity He + ions is expected to have the biggest effect on the overall sputtering efficiency of solar wind impact on the Moon. Our measurements indicate an almost 70% increase of the sputtering yield for doubly charged incident He ions compared to that for same velocity He + impact (14.6 amu/ion for He +2 vs. 8.7 amu/ion for He + ). Using a selective sputtering model, the new QCM results presented here, together with previously published results for Ar +q ions and SRIM results for the relevant kinetic‐sputtering yields, the effect due to multicharged‐solar‐wind‐ion impact on local near‐surface modification of lunar anorthite‐like soil is explored. It is shown that the multicharged‐solar‐wind component leads to a more pronounced and significant differentiation of depleted and enriched surface elements as well as a shortening of the timescale over which such surface‐compositional modifications might occur in astrophysical settings. In addition, to validate previous and future determinations of multicharged‐ion‐induced sputtering enhancement for those cases where the QCM approach cannot be used, relative quadrupole mass spectrometry (QMS)‐based measurements are presented for the same anorthite‐like thin film as were investigated by QCM, and their suitability and limitations for charge state‐enhanced yield measurements are discussed.},

  doi          = {10.1002/2017JE005300},

  journal      = {Journal of Geophysical Research. Planets},

  number       = 7,

  volume       = 122,

  place        = {United States},

  year         = {Fri Jul 28 00:00:00 EDT 2017},

  month        = {Fri Jul 28 00:00:00 EDT 2017}

}

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Anorthite sputtering by H ⁺ and Ar ^{q +} ( q = 1-9) at solar wind velocities
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Title: Kinetic and potential sputtering of an anorthite-like glassy thin film

Abstract

Citation Formats

Sputtering of ice by low-energy ions journal, January 2008

Evidence of Coulomb explosion sputtering of ultra-thin Pt films due to impact of multi-charged Ar ions journal, December 2003

Mass fractionation of the lunar surface by solar wind sputtering journal, September 1977

Solar-wind protons and heavy ions sputtering of lunar surface materials journal, June 2011

The lunar exosphere: The sputtering contribution journal, November 2007

Luminescence excitation characteristics of Ca, Na and K-aluminosilicates (feldspars) in the stimulation range 5–40 eV: determination of the band-gap energies journal, April 2004

Potential Sputtering of Clean SiO 2 by Slow Highly Charged Ions journal, August 1997

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Sputtering rates under solar-wind bombardment journal, August 1963

Sputtering and surface topography of oxides journal, March 1990

Angular and charge state distributions of highly charged ions scattered during low energy surface-channeling interactions with Au(110) journal, June 1995

Threshold for Potential Sputtering of LiF journal, November 1999

Characterization of the calcium-fluoroaluminosilicate glass prepared by a non-hydrolytic sol-gel route for future dental application as glass ionomer cement journal, June 2009

The lunar surface-exosphere connection: Measurement of secondary-ions from Apollo soils journal, July 2015

Time Scales for Charge Equilibration of O q + ( 3 ≤ q ≤ 8 ) Ions during Surface-Channeling Interactions with Au(110) journal, March 1995

Potential sputtering: desorption from insulator surfaces by impact of slow multicharged ions journal, September 1999

Coulomb explosion potential sputtering induced by slow highly charged ion impact journal, November 2005

Modification of the lunar surface by the solar-wind bombardment journal, November 1963

Solar wind heavy ion abundances journal, August 1975

Composition of quasi-stationary solar wind flows from Ulysses/Solar Wind Ion Composition Spectrometer journal, December 2000

Srim-2003 journal, June 2004

Sputtering of lunar regolith simulant by protons and singly and multicharged Ar ions at solar wind energies journal, June 2011

Anorthite and CaAl2Si2O8 glass: low frequency Raman spectroscopy and neutron scattering journal, August 2003

Sputtering: survey of observations and derived principles journal, November 2003

Potential sputtering journal, November 2003

Recent advances in pulsed-laser deposition of complex oxides journal, June 2008

Sputtering of Au and Al2O3 surfaces by slow highly charged ions journal, August 2001

Anorthite sputtering by H + and Ar q + ( q = 1-9) at solar wind velocities journal, October 2014

Sputtering of ice by low-energy ions
journal, January 2008

Evidence of Coulomb explosion sputtering of ultra-thin Pt films due to impact of multi-charged Ar ions
journal, December 2003

Mass fractionation of the lunar surface by solar wind sputtering
journal, September 1977

Solar-wind protons and heavy ions sputtering of lunar surface materials
journal, June 2011

The lunar exosphere: The sputtering contribution
journal, November 2007

Luminescence excitation characteristics of Ca, Na and K-aluminosilicates (feldspars) in the stimulation range 5–40 eV: determination of the band-gap energies
journal, April 2004

Potential Sputtering of Clean ${SiO}_{2}$ by Slow Highly Charged Ions
journal, August 1997

Solar-Storm/Lunar Atmosphere Model (SSLAM): An overview of the effort and description of the driving storm environment: SSLAM DESCRIPTION
journal, October 2012

Sputtering rates under solar-wind bombardment
journal, August 1963

Sputtering and surface topography of oxides
journal, March 1990

Angular and charge state distributions of highly charged ions scattered during low energy surface-channeling interactions with Au(110)
journal, June 1995

Threshold for Potential Sputtering of LiF
journal, November 1999

Characterization of the calcium-fluoroaluminosilicate glass prepared by a non-hydrolytic sol-gel route for future dental application as glass ionomer cement
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The lunar surface-exosphere connection: Measurement of secondary-ions from Apollo soils
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journal, March 1995

Potential sputtering: desorption from insulator surfaces by impact of slow multicharged ions
journal, September 1999

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