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Title: Two-Dimensional Hybrid Organohalide Perovskites from Ultrathin PbS Nanocrystals as Template

Abstract

Direct conversion of preprocessed binary semiconductor NCs as template holds the key toward the shape control of hybrid perovskites. Here we report on an innovative route for realizing shape-controlled hybrid organohalide perovskite NCs from two-dimensional PbS NCs on solid substrates. Rectangular PbI2 NCs are first synthesized by iodination of PbS NCs. Resultant PbI2 NCs are subsequently transformed into the well-defined rectangular hybrid perovskite NCs upon controlled CH3NH3Br exposure. Structural analyses using X-ray absorption fine structure reveal transition of cubic lattice of PbS to hybrid perovskites with a mixture of cubic and tetragonal phases exhibiting a bimodal distribution of shorter Pb–Br and longer Pb–I bonds around an immediate neighboring lead absorber within the first coordination shell. Furthermore, this direct all anion exchange reaction route opens up new strategies for the fabrication of shape-controlled perovskite NCs on flexible substrates from suitable existing binary NCs as template for optoelectronic applications.

Authors:
 [1];  [2];  [1];  [1]; ORCiD logo [3];  [4]; ORCiD logo [5]; ORCiD logo [1]
  1. Indian Association for the Cultivation of Science, Kolkata (India)
  2. Indian Inst. of Science, Bangalore (India)
  3. Saha Inst. of Nuclear Physics, Kolkata (India)
  4. Illinois Inst. of Technology, Chicago, IL (United States)
  5. Indian Association for the Cultivation of Science, Kolkata (India); Indian Inst. of Science, Bangalore (India); Council of Scientific and Industrial Research-Network of Institutes for Solar Energy (CSIR-NISE), New Delhi (India)
Publication Date:
Research Org.:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
OSTI Identifier:
1393646
Grant/Contract Number:  
AC02-06CH11357; DMR-086935
Resource Type:
Accepted Manuscript
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 121; Journal Issue: 11; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
ENGLISH
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; iodine; physical and chemical processes; bromine; perovskites; annealing (metallurgy)

Citation Formats

Pradhan, Jayita, Mukherjee, Soham, Khan, Ali Hossain, Dalui, Amit, Satpati, Biswarup, Segre, Carlo U., Sarma, D. D., and Acharya, Somobrata. Two-Dimensional Hybrid Organohalide Perovskites from Ultrathin PbS Nanocrystals as Template. United States: N. p., 2017. Web. doi:10.1021/acs.jpcc.7b01236.
Pradhan, Jayita, Mukherjee, Soham, Khan, Ali Hossain, Dalui, Amit, Satpati, Biswarup, Segre, Carlo U., Sarma, D. D., & Acharya, Somobrata. Two-Dimensional Hybrid Organohalide Perovskites from Ultrathin PbS Nanocrystals as Template. United States. https://doi.org/10.1021/acs.jpcc.7b01236
Pradhan, Jayita, Mukherjee, Soham, Khan, Ali Hossain, Dalui, Amit, Satpati, Biswarup, Segre, Carlo U., Sarma, D. D., and Acharya, Somobrata. Tue . "Two-Dimensional Hybrid Organohalide Perovskites from Ultrathin PbS Nanocrystals as Template". United States. https://doi.org/10.1021/acs.jpcc.7b01236. https://www.osti.gov/servlets/purl/1393646.
@article{osti_1393646,
title = {Two-Dimensional Hybrid Organohalide Perovskites from Ultrathin PbS Nanocrystals as Template},
author = {Pradhan, Jayita and Mukherjee, Soham and Khan, Ali Hossain and Dalui, Amit and Satpati, Biswarup and Segre, Carlo U. and Sarma, D. D. and Acharya, Somobrata},
abstractNote = {Direct conversion of preprocessed binary semiconductor NCs as template holds the key toward the shape control of hybrid perovskites. Here we report on an innovative route for realizing shape-controlled hybrid organohalide perovskite NCs from two-dimensional PbS NCs on solid substrates. Rectangular PbI2 NCs are first synthesized by iodination of PbS NCs. Resultant PbI2 NCs are subsequently transformed into the well-defined rectangular hybrid perovskite NCs upon controlled CH3NH3Br exposure. Structural analyses using X-ray absorption fine structure reveal transition of cubic lattice of PbS to hybrid perovskites with a mixture of cubic and tetragonal phases exhibiting a bimodal distribution of shorter Pb–Br and longer Pb–I bonds around an immediate neighboring lead absorber within the first coordination shell. Furthermore, this direct all anion exchange reaction route opens up new strategies for the fabrication of shape-controlled perovskite NCs on flexible substrates from suitable existing binary NCs as template for optoelectronic applications.},
doi = {10.1021/acs.jpcc.7b01236},
journal = {Journal of Physical Chemistry. C},
number = 11,
volume = 121,
place = {United States},
year = {Tue Feb 28 00:00:00 EST 2017},
month = {Tue Feb 28 00:00:00 EST 2017}
}

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