Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery

Zhang, Lu; Huang, Jinhua; Youssef, Kyrrilos; Redfern, Paul C.; Curtiss, Larry A.; Amine, Khalil; Zhang, Zhengcheng

doi:10.1149/2.0971414jes

Title: Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery

Abstract

A novel electrolyte additive, 3-oxabicyclo[3.1.0]hexane-2,4-dione (OHD), has been discovered and evaluated in Li-_1.1(Mn_1/3Ni_1/3Co_1/3)_0.9O₂/graphite cells under elevated temperature. When an appropriate amount of OHD is used, the cell capacity retention is improved from 60% (Gen 2 electrolyte alone) to 82% (Gen 2 electrolyte plus OHD) after 200 cycles with no obvious impedance increase. The amount of OHD added is the key to achieving the superior cell performance. In conclusion, the effect of OHD additive was investigated by means of electrochemical analysis, fourier transform infrared spectroscopy, scanning electron microscopy, and density functional theory computation.

Authors:

Zhang, Lu ^[1]; Huang, Jinhua ^[1]; Youssef, Kyrrilos ^[1]; Redfern, Paul C. ^[1]; Curtiss, Larry A. ^[1]; Amine, Khalil ^[1]; Zhang, Zhengcheng ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Fri Oct 31 00:00:00 EDT 2014

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Joint Center for Energy Storage Research (JCESR); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

OSTI Identifier:: 1392637

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of the Electrochemical Society

Additional Journal Information:: Journal Volume: 161; Journal Issue: 14; Journal ID: ISSN 0013-4651

Publisher:: The Electrochemical Society

Country of Publication:: United States

Language:: English

Subject:: 25 ENERGY STORAGE; SEI; electrolyte additive; lithium-ion battery; molecular engineering; surface characterization

Citation Formats


                    Zhang, Lu, Huang, Jinhua, Youssef, Kyrrilos, Redfern, Paul C., Curtiss, Larry A., Amine, Khalil, and Zhang, Zhengcheng. Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery.  United States: N. p., 2014. 
Web.  doi:10.1149/2.0971414jes.

Copy to clipboard


                    Zhang, Lu, Huang, Jinhua, Youssef, Kyrrilos, Redfern, Paul C., Curtiss, Larry A., Amine, Khalil, & Zhang, Zhengcheng. Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery.  United States.  https://doi.org/10.1149/2.0971414jes

Copy to clipboard


                    Zhang, Lu, Huang, Jinhua, Youssef, Kyrrilos, Redfern, Paul C., Curtiss, Larry A., Amine, Khalil, and Zhang, Zhengcheng. Fri .  
"Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery".  United States.  https://doi.org/10.1149/2.0971414jes.  https://www.osti.gov/servlets/purl/1392637.

Copy to clipboard


                    
@article{osti_1392637,

  title        = {Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery},

  author       = {Zhang, Lu and Huang, Jinhua and Youssef, Kyrrilos and Redfern, Paul C. and Curtiss, Larry A. and Amine, Khalil and Zhang, Zhengcheng},

  abstractNote = {A novel electrolyte additive, 3-oxabicyclo[3.1.0]hexane-2,4-dione (OHD), has been discovered and evaluated in Li-1.1(Mn1/3Ni1/3Co1/3)0.9O2/graphite cells under elevated temperature. When an appropriate amount of OHD is used, the cell capacity retention is improved from 60% (Gen 2 electrolyte alone) to 82% (Gen 2 electrolyte plus OHD) after 200 cycles with no obvious impedance increase. The amount of OHD added is the key to achieving the superior cell performance. In conclusion, the effect of OHD additive was investigated by means of electrochemical analysis, fourier transform infrared spectroscopy, scanning electron microscopy, and density functional theory computation.},

  doi          = {10.1149/2.0971414jes},

  journal      = {Journal of the Electrochemical Society},

  number       = 14,

  volume       = 161,

  place        = {United States},

  year         = {Fri Oct 31 00:00:00 EDT 2014},

  month        = {Fri Oct 31 00:00:00 EDT 2014}

}

Copy to clipboard

Journal Article:

Free Publicly Available Full Text

Accepted Manuscript (DOE)

Publisher's Version of Record

https://doi.org/10.1149/2.0971414jes

Other availability

Search WorldCat to find libraries that may hold this journal

Citation Metrics:

Cited by: 9 works

Citation information provided by
Web of Science

Save / Share:

Export Metadata

Save to My Library

Works referenced in this record:

Improved lithium manganese oxide spinel/graphite Li-ion cells for high-power applications
journal, April 2004

Amine, K.; Liu, J.; Kang, S.
Journal of Power Sources, Vol. 129, Issue 1
DOI: 10.1016/j.jpowsour.2003.11.007

Tris(pentafluorophenyl) Borane as an Additive to Improve the Power Capabilities of Lithium-Ion Batteries
journal, January 2006

Chen, Zonghai; Amine, K.
Journal of The Electrochemical Society, Vol. 153, Issue 6
DOI: 10.1149/1.2194633

LiBOB-Based Electrolytes for Li-Ion Batteries for Transportation Applications
journal, January 2004

Jow, T. R.; Xu, K.; Ding, M. S.
Journal of The Electrochemical Society, Vol. 151, Issue 10
DOI: 10.1149/1.1789393

Advanced cathode materials for high-power applications
journal, August 2005

Amine, K.; Liu, J.; Belharouak, I.
Journal of Power Sources, Vol. 146, Issue 1-2
DOI: 10.1016/j.jpowsour.2005.03.227

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

Xu, Kang
Chemical Reviews, Vol. 104, Issue 10, p. 4303-4418
DOI: 10.1021/cr030203g

Electrolytes and Interphasial Chemistry in Li Ion Devices
journal, January 2010

Xu, Kang
Energies, Vol. 3, Issue 1
DOI: 10.3390/en3010135

Origin of Graphite Exfoliation An Investigation of the Important Role of Solvent Cointercalation
journal, January 2000

Chung, Geun-Chang; Kim, Hyung-Jin; Yu, Seung-Il
Journal of The Electrochemical Society, Vol. 147, Issue 12
DOI: 10.1149/1.1394076

New cyclic carbonate solvent for lithium ion batteries: trans-2,3-butylene carbonate
journal, October 1999

Chung, G.
Electrochemistry Communications, Vol. 1, Issue 10
DOI: 10.1016/S1388-2481(99)00101-0

Ultra-thin passivating film induced by vinylene carbonate on highly oriented pyrolytic graphite negative electrode in lithium-ion cell
journal, June 2002

Matsuoka, O.; Hiwara, A.; Omi, T.
Journal of Power Sources, Vol. 108, Issue 1-2
DOI: 10.1016/S0378-7753(02)00012-5

Effects of Some Organic Additives on Lithium Deposition in Propylene Carbonate
journal, January 2002

Mogi, Ryo; Inaba, Minoru; Jeong, Soon-Ki
Journal of The Electrochemical Society, Vol. 149, Issue 12
DOI: 10.1149/1.1516770

Anodic Polymerization of Vinyl Ethylene Carbonate in Li-Ion Battery Electrolyte
journal, January 2005

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.
Electrochemical and Solid-State Letters, Vol. 8, Issue 7
DOI: 10.1149/1.1921127

Effect of Morphology and Current Density on the Electrochemical Behavior of Graphite Electrodes in PC-Based Electrolyte Containing VEC Additive
journal, January 2004

Hu, Yongsheng; Kong, Weihe; Wang, Zhaoxiang
Electrochemical and Solid-State Letters, Vol. 7, Issue 11
DOI: 10.1149/1.1807532

Electrolyte additive to improve performance of MCMB/LiNi1/3Co1/3Mn1/3O2 Li-ion cell
journal, October 2010

Qin, Yan; Chen, Zonghai; Lu, Wenquan
Journal of Power Sources, Vol. 195, Issue 19
DOI: 10.1016/j.jpowsour.2010.04.040

LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation
journal, January 2002

Xu, Kang; Zhang, Shengshui; Jow, T. Richard
Electrochemical and Solid-State Letters, Vol. 5, Issue 1
DOI: 10.1149/1.1426042

Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate
journal, September 2002

Xu, Kang; Zhang, Shengshui; Poese, Bruce A.
Electrochemical and Solid-State Letters, Vol. 5, Issue 11, p. A259-A262
DOI: 10.1149/1.1510322

An unique lithium salt for the improved electrolyte of Li-ion battery
journal, September 2006

Shui Zhang, Sheng
Electrochemistry Communications, Vol. 8, Issue 9
DOI: 10.1016/j.elecom.2006.06.016

Reduction Mechanisms of Ethylene, Propylene, and Vinylethylene Carbonates
journal, January 2004

Vollmer, James M.; Curtiss, Larry A.; Vissers, Donald R.
Journal of The Electrochemical Society, Vol. 151, Issue 1
DOI: 10.1149/1.1633765

Degradation Mechanism and Life Prediction of Lithium-Ion Batteries
journal, January 2006

Yoshida, Toshihiro; Takahashi, Michio; Morikawa, Satoshi
Journal of The Electrochemical Society, Vol. 153, Issue 3
DOI: 10.1149/1.2162467

Effect of electrolyte additives in improving the cycle and calendar life of graphite/Li1.1[Ni1/3Co1/3Mn1/3]0.9O2 Li-ion cells
journal, December 2007

Liu, Jun; Chen, Zonghai; Busking, Sara
Journal of Power Sources, Vol. 174, Issue 2
DOI: 10.1016/j.jpowsour.2007.06.225

Works referencing / citing this record:

Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries
journal, March 2018

Wang, Aiping; Kadam, Sanket; Li, Hong
npj Computational Materials, Vol. 4, Issue 1
DOI: 10.1038/s41524-018-0064-0

An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 V lithium-ion batteries
journal, January 2015

Huang, Jinhua; Azimi, Nasim; Cheng, Lei
Journal of Materials Chemistry A, Vol. 3, Issue 20
DOI: 10.1039/c5ta01326g

Similar Records in DOE PAGES and OSTI.GOV collections:

Effect of electrolyte additives in improving the cycle and calendar life of graphite/Li{sub1.1}[Ni{sub1/3}Co{sub1/3}Mn{sub1/3}]{0.9}O{sub 2} Li-ion cells.

Journal Article Liu, J ; Chen, Z ; Busking, S ; ... - J. Power Sources

Lithium-rich layered metal oxide Li{sub 1.1}[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]{sub 0.9}O{sub 2} was investigated as a potential positive electrode material for high-power batteries for hybrid electric vehicle (HEV) applications. In order to evaluate the power and life characteristics of the graphite/Li{sub 1.1}[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]{sub 0.9}O{sub 2} cell chemistry, hybrid pulse power characterization (HPPC) and accelerated calendar life tests were conducted on several pouch cells containing electrolytes with and without additives. The data show that the cells containing 0.5 wt% lithium bis(oxalate)borate (LiBOB) or vinyl ethyl carbonate (VEC) additives, or the novel lithium difluoro(oxalato)borate (LiDFOB) additive, have much improved cycle andmore » calendar life performance.« less
https://doi.org/10.1016/j.jpowsour.2007.06.225
Lithium tetrafluoro oxalato phosphate as electrolyte additive for lithium-ion cells.

Journal Article Qin, Y ; Chen, Z ; Liu, J ; ... - Electrochem. Solid State Lett.

Lithium tetrafluoro oxalato phosphate (LTFOP) was investigated as an electrolyte additive to improve the life of mesocarbon microbead (MCMB)/Li{sub 1.1}[Ni{sub 1/3}Co{sub 1/3}Mn{sub 1/3}]{sub 0.9}O{sub 2} (NCM) cells for high power applications. With the addition of 1-3 wt % LTFOP to MCMB/NCM cells, the capacity retention after 200 cycles at 55 C significantly improved. Electrochemical impedance spectroscopy showed that the LTFOP addition in the electrolyte increased the initial impedance but lowered the impedance growth rate during cycling. Aging tests at 55 C indicated that the capacity retention of the negative electrode significantly benefited as a result of the LTFOP addition. Differentialmore »« less
https://doi.org/10.1149/1.3261738
The electrochemical reactions of pure In with Li and Na: anomalous electrolyte decomposition, benefits of FEC additive, phase transitions and electrode performance

Journal Article Hawks, Samantha A ; Baggetto, Loic ; Bridges, Craig A ; ... - Journal of Power Sources

Indium thin films are evaluated as an anode material for Li-ion and Na-ion batteries (theoretical capacities of 1012 mAh g-1 for Li and 467 mAh g-1 for Na). The native surface oxides are responsible for the anomalous electrolyte decomposition during the first cycle while oxidized In species are found to be responsible for the electrolyte decomposition during the subsequent cycles. The presence of 5wt% FEC electrolyte additive suppresses the occurrence of the anomalous electrolyte decomposition during the first cycle but is not sufficient to prevent the decomposition upon further cycling from 0 to 2 V. Prevention of the anomalous decompositionmore »« less
Electrolyte additive to improve performance of MCMB LiNi{sub 1/3}Co{sub 1/3}Mn{sub 1/3}O{sub 2} Li-ion cell.

Journal Article Qin, Y ; Chen, Z ; Lu, W ; ... - J. Power Sources

The electrolyte additive, 3,9-divinyl-2,4,8,10-tetraoxaspiro[5,5] undecane (TOS), was investigated as a means to improve the life of mesocarbon microbead (MCMB)/Li1.1[Ni1/3Co1/3Mn1/3]0.9O2 (NCM) cells for high-power applications. With the addition of an appropriate amount of TOS (no more than 1 wt%) to MCMB/NCM cells, the capacity retention was significantly improved at 55 C compared with cells containing pristine electrolyte. Aging tests at 55 C indicated that the capacity retention of the negative electrode had benefited as a result of the formation of a stable passivation film at the surface of the carbon electrode due to TOS reduction. Electrochemical impedance spectroscopy showed that amore »« less
https://doi.org/10.1016/j.jpowsour.2010.04.040
Gel electrolyte for lithium-ion batteries.

Journal Article Chen, Z ; Zhang, L Z ; West, R ; ... - Electrochim. Acta

The electrochemical performance of gel electrolytes based on crosslinked poly[ethyleneoxide-co-2-(2-methoxyethyoxy)ethyl glycidyl ether-co-allyl glycidyl ether] was investigated using graphite/Li{sub 1.1}[Ni{sub 1/3}Mn{sub 1/3}Co{sub 1/3}]{sub 0.9}O{sub 2} lithium-ion cells. It was found that the conductivity of the crosslinked gel electrolytes was as high as 5.9 mS/cm at room temperature, which is very similar to that of the conventional organic carbonate liquid electrolytes. Moreover, the capacity retention of lithium-ion cells comprising gel electrolytes was also similar to that of cells with conventional electrolytes. Despite of the high conductivity of the gel electrolytes, the rate capability of lithium-ion cells comprising gel electrolytes is inferior tomore »« less
https://doi.org/10.1016/j.electacta.2007.10.058

Similar Records

Title: Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery

Abstract

Citation Formats

Improved lithium manganese oxide spinel/graphite Li-ion cells for high-power applications journal, April 2004

Tris(pentafluorophenyl) Borane as an Additive to Improve the Power Capabilities of Lithium-Ion Batteries journal, January 2006

LiBOB-Based Electrolytes for Li-Ion Batteries for Transportation Applications journal, January 2004

Advanced cathode materials for high-power applications journal, August 2005

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries journal, October 2004

Electrolytes and Interphasial Chemistry in Li Ion Devices journal, January 2010

Origin of Graphite Exfoliation An Investigation of the Important Role of Solvent Cointercalation journal, January 2000

New cyclic carbonate solvent for lithium ion batteries: trans-2,3-butylene carbonate journal, October 1999

Ultra-thin passivating film induced by vinylene carbonate on highly oriented pyrolytic graphite negative electrode in lithium-ion cell journal, June 2002

Effects of Some Organic Additives on Lithium Deposition in Propylene Carbonate journal, January 2002

Anodic Polymerization of Vinyl Ethylene Carbonate in Li-Ion Battery Electrolyte journal, January 2005

Effect of Morphology and Current Density on the Electrochemical Behavior of Graphite Electrodes in PC-Based Electrolyte Containing VEC Additive journal, January 2004

Electrolyte additive to improve performance of MCMB/LiNi1/3Co1/3Mn1/3O2 Li-ion cell journal, October 2010

LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation journal, January 2002

Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate journal, September 2002

An unique lithium salt for the improved electrolyte of Li-ion battery journal, September 2006

Reduction Mechanisms of Ethylene, Propylene, and Vinylethylene Carbonates journal, January 2004

Degradation Mechanism and Life Prediction of Lithium-Ion Batteries journal, January 2006

Effect of electrolyte additives in improving the cycle and calendar life of graphite/Li1.1[Ni1/3Co1/3Mn1/3]0.9O2 Li-ion cells journal, December 2007

Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries journal, March 2018

An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 V lithium-ion batteries journal, January 2015

Improved lithium manganese oxide spinel/graphite Li-ion cells for high-power applications
journal, April 2004

Tris(pentafluorophenyl) Borane as an Additive to Improve the Power Capabilities of Lithium-Ion Batteries
journal, January 2006

LiBOB-Based Electrolytes for Li-Ion Batteries for Transportation Applications
journal, January 2004

Advanced cathode materials for high-power applications
journal, August 2005

Nonaqueous Liquid Electrolytes for Lithium-Based Rechargeable Batteries
journal, October 2004

Electrolytes and Interphasial Chemistry in Li Ion Devices
journal, January 2010

Origin of Graphite Exfoliation An Investigation of the Important Role of Solvent Cointercalation
journal, January 2000

New cyclic carbonate solvent for lithium ion batteries: trans-2,3-butylene carbonate
journal, October 1999

Ultra-thin passivating film induced by vinylene carbonate on highly oriented pyrolytic graphite negative electrode in lithium-ion cell
journal, June 2002

Effects of Some Organic Additives on Lithium Deposition in Propylene Carbonate
journal, January 2002

Anodic Polymerization of Vinyl Ethylene Carbonate in Li-Ion Battery Electrolyte
journal, January 2005

Effect of Morphology and Current Density on the Electrochemical Behavior of Graphite Electrodes in PC-Based Electrolyte Containing VEC Additive
journal, January 2004

Electrolyte additive to improve performance of MCMB/LiNi1/3Co1/3Mn1/3O2 Li-ion cell
journal, October 2010

LiBOB as Salt for Lithium-Ion Batteries:A Possible Solution for High Temperature Operation
journal, January 2002

Lithium Bis(oxalato)borate Stabilizes Graphite Anode in Propylene Carbonate
journal, September 2002

An unique lithium salt for the improved electrolyte of Li-ion battery
journal, September 2006

Reduction Mechanisms of Ethylene, Propylene, and Vinylethylene Carbonates
journal, January 2004

Degradation Mechanism and Life Prediction of Lithium-Ion Batteries
journal, January 2006

Effect of electrolyte additives in improving the cycle and calendar life of graphite/Li1.1[Ni1/3Co1/3Mn1/3]0.9O2 Li-ion cells
journal, December 2007

Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries
journal, March 2018

An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 V lithium-ion batteries
journal, January 2015