Exceptional enhancement of Raman scattering on silver chlorobromide nanocube photonic crystals: chemical and photonic contributions

Li, Zheng; Gosztola, David J.; Sun, Cheng-Jun; Heald, Steve M.; Sun, Yugang

doi:10.1039/c5tc00077g

Title: Exceptional enhancement of Raman scattering on silver chlorobromide nanocube photonic crystals: chemical and photonic contributions

Abstract

Photonic crystals made from self-assembly of mono-dispersed AgCl_xBr_1-x nanocubes, which are not plasmonically active, have been discovered to exceptionally enhance Raman scattering of molecules chemically adsorbed on their surfaces. Comprehensive control measurements and X-ray absorption near-edge structure spectroscopy indicate that the Raman enhancement on the AgCl_xBr_1-x nanocube photonic crystals is primarily ascribed to the chemical enhancement mechanism associated with the chemical interactions between adsorbing molecules and the AgCl_xBr_1-x surfaces. In addition, the ordering of the AgCl_xBr_1-x nanocubes in the photonic crystals can selectively reflect Raman scattering back to the detector at the bandgap position of the photonic crystals to provide additional enhancement, i.e., photonic mode enhancement. The thiophenol molecules adsorbed on the AgCl_0.44Br_0.56 nanocube photonic crystals exhibit astonishingly strong Raman signals that are on the same order of magnitude as those recorded from the thiophenol molecules adsorbed on the assembled Ag nanocubes.

Authors:

Li, Zheng ^[1]; Gosztola, David J. ^[1]; Sun, Cheng-Jun ^[1]; Heald, Steve M. ^[1]; Sun, Yugang ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

Publication Date:: Mon Feb 02 00:00:00 EST 2015

Research Org.:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1392364

Grant/Contract Number:: AC02-06CH11357

Resource Type:: Accepted Manuscript

Journal Name:: Journal of Materials Chemistry C

Additional Journal Information:: Journal Volume: 3; Journal Issue: 11; Journal ID: ISSN 2050-7526

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE

Citation Formats


                    Li, Zheng, Gosztola, David J., Sun, Cheng-Jun, Heald, Steve M., and Sun, Yugang. Exceptional enhancement of Raman scattering on silver chlorobromide nanocube photonic crystals: chemical and photonic contributions.  United States: N. p., 2015. 
Web.  doi:10.1039/c5tc00077g.

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                    Li, Zheng, Gosztola, David J., Sun, Cheng-Jun, Heald, Steve M., & Sun, Yugang. Exceptional enhancement of Raman scattering on silver chlorobromide nanocube photonic crystals: chemical and photonic contributions.  United States.  https://doi.org/10.1039/c5tc00077g

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                    Li, Zheng, Gosztola, David J., Sun, Cheng-Jun, Heald, Steve M., and Sun, Yugang. Mon .  
"Exceptional enhancement of Raman scattering on silver chlorobromide nanocube photonic crystals: chemical and photonic contributions".  United States.  https://doi.org/10.1039/c5tc00077g.  https://www.osti.gov/servlets/purl/1392364.

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@article{osti_1392364,

  title        = {Exceptional enhancement of Raman scattering on silver chlorobromide nanocube photonic crystals: chemical and photonic contributions},

  author       = {Li, Zheng and Gosztola, David J. and Sun, Cheng-Jun and Heald, Steve M. and Sun, Yugang},

  abstractNote = {Photonic crystals made from self-assembly of mono-dispersed AgClxBr1-x nanocubes, which are not plasmonically active, have been discovered to exceptionally enhance Raman scattering of molecules chemically adsorbed on their surfaces. Comprehensive control measurements and X-ray absorption near-edge structure spectroscopy indicate that the Raman enhancement on the AgClxBr1-x nanocube photonic crystals is primarily ascribed to the chemical enhancement mechanism associated with the chemical interactions between adsorbing molecules and the AgClxBr1-x surfaces. In addition, the ordering of the AgClxBr1-x nanocubes in the photonic crystals can selectively reflect Raman scattering back to the detector at the bandgap position of the photonic crystals to provide additional enhancement, i.e., photonic mode enhancement. The thiophenol molecules adsorbed on the AgCl0.44Br0.56 nanocube photonic crystals exhibit astonishingly strong Raman signals that are on the same order of magnitude as those recorded from the thiophenol molecules adsorbed on the assembled Ag nanocubes.},

  doi          = {10.1039/c5tc00077g},

  journal      = {Journal of Materials Chemistry C},

  number       = 11,

  volume       = 3,

  place        = {United States},

  year         = {Mon Feb 02 00:00:00 EST 2015},

  month        = {Mon Feb 02 00:00:00 EST 2015}

}

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Title: Exceptional enhancement of Raman scattering on silver chlorobromide nanocube photonic crystals: chemical and photonic contributions

Abstract

Citation Formats

Rationally designed nanostructures for surface-enhanced Raman spectroscopy journal, January 2008

Metallo-Dielectric Photonic Crystals for Surface-Enhanced Raman Scattering journal, March 2011

ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT journal, June 2005

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Raman Spectroscopy journal, June 1998

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Generation of Hot Spots with Silver Nanocubes for Single-Molecule Detection by Surface-Enhanced Raman Scattering journal, May 2011

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On the chemical bonding effects in the Raman response: Benzenethiol adsorbed on silver clusters journal, January 2009

Anomalously intense Raman spectra of pyridine at a silver electrode journal, June 1977

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journal, June 2005

Surface raman spectroelectrochemistry: Part I. Heterocyclic, aromatic, and aliphatic amines adsorbed on the anodized silver electrode
journal, November 1977

Nanoparticleassemblies for biological and chemical sensing
journal, January 2010

Superstructures and SERS Properties of Gold Nanocrystals with Different Shapes
journal, January 2011

Raman Spectroscopy
journal, June 1998

Surface-enhanced Raman scattering on tunable plasmonic nanoparticle substrates
journal, December 2004

Application of SERS spectroscopy to the identification of (3,4-methylenedioxy)amphetamine in forensic samples utilizing matrix stabilized silver halides
journal, January 2001

Molecular Self-Assembly at Bare Semiconductor Surfaces: Preparation and Characterization of Highly Organized Octadecanethiolate Monolayers on GaAs(001)
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Controlled Plasmonic Nanostructures for Surface-Enhanced Spectroscopy and Sensing
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journal, January 2007

Surface-Enhanced Raman Spectroscopy Substrates Created via Electron Beam Lithography and Nanotransfer Printing
journal, January 2008

Optical Properties of Pd−Ag and Pt−Ag Nanoboxes Synthesized via Galvanic Replacement Reactions
journal, October 2005

Surface-Enhanced Raman Spectroscopy of Crystal Violet in the Presence of Halide and Halate Ions with Near-Infrared Wavelength Excitation
journal, October 1997

Raman spectra of pyridine adsorbed at a silver electrode
journal, May 1974

Charge‐transfer theory of surface enhanced Raman spectroscopy: Herzberg–Teller contributions
journal, April 1986

Surfactantless Synthesis of Silver Nanoplates and Their Application in SERS
journal, November 2007

The theory of surface-enhanced Raman scattering
journal, April 2012

Surface enhanced Raman spectra (SERS) of pyridine and dye-1555 adsorbed on silver bromide colloids
journal, January 1987

Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS)
journal, March 1997

Doubly resonant surface-enhanced Raman scattering on gold nanorod decorated inverse opal photonic crystals
journal, January 2012

Gold Nanorod@Chiral Mesoporous Silica Core–shell Nanoparticles with Unique Optical Properties
journal, June 2013

Experimental investigation of photonic band gap influence on enhancement of Raman-scattering in metal-dielectric colloidal crystals
journal, October 2012

On the theory of surface-enhanced Raman scattering
journal, September 1981

Nanogap-engineerable Raman-active nanodumbbells for single-molecule detection
journal, December 2009

An accurate electromagnetic theory study of surface enhancement factors for silver, gold, copper, lithium, sodium, aluminum, gallium, indium, zinc, and cadmium
journal, January 1987

Quantifying Resonant Raman Cross Sections with SERS
journal, May 2010

SERS of Semiconducting Nanoparticles (TiO ₂ Hybrid Composites)
journal, May 2009

Antibacterial and surface-enhanced Raman scattering (SERS) activities of AgCl cubes synthesized by pulsed laser ablation in liquid
journal, September 2012

Single-Molecule and Single-Nanoparticle SERS: Examining the Roles of Surface Active Sites and Chemical Enhancement
journal, January 2002

Silver chlorobromide nanoparticles with highly pure phases: synthesis and characterization
journal, January 2013

Silver chlorobromide nanocubes with significantly improved uniformity: synthesis and assembly into photonic crystals
journal, January 2015

Separation of Electromagnetic and Chemical Contributions to Surface-Enhanced Raman Spectra on Nanoengineered Plasmonic Substrates
journal, September 2010

On the chemical bonding effects in the Raman response: Benzenethiol adsorbed on silver clusters
journal, January 2009

Anomalously intense Raman spectra of pyridine at a silver electrode
journal, June 1977

Maximizing the Electromagnetic and Chemical Resonances of Surface-Enhanced Raman Scattering for Nucleic Acids
journal, July 2014

SERS Substrates Fabricated by Island Lithography: The Silver/Pyridine System
journal, November 2003

Axial and azimuthal angle determination with surface-enhanced Raman spectroscopy: thiophenol on copper, silver, and gold metal surfaces
journal, November 1991

Analyzing the Vibrational Signatures of Thiophenol Adsorbed on Small Gold Clusters by DFT Calculations
journal, April 2013

Probing Single Molecules and Single Nanoparticles by Surface-Enhanced Raman Scattering
journal, February 1997

Localized Surface Plasmon Resonance Spectroscopy and Sensing
journal, May 2007

Surface-enhanced Raman scattering of benzenethiol in silver sol
journal, February 1987

UV/Ozone-Oxidized Large-Scale Graphene Platform with Large Chemical Enhancement in Surface-Enhanced Raman Scattering
journal, November 2011

Enhanced optical absorption in semiconductor nanoparticles enabled by nearfield dielectric scattering
journal, January 2017