Combining Electronic and Geometric Effects of ZnO-Promoted Pt Nanocatalysts for Aqueous Phase Reforming of 1-Propanol
Abstract
Compared with Pt/Al2O3, sintering-resistant Pt nanoparticle catalysts promoted by ZnO significantly improved the reactivity and selectivity toward hydrogen formation in the aqueous phase reforming (APR) of 1-propanol. The improved performance was found to benefit from both the electronic and geometric effects of ZnO thin films. In situ small-angle X-ray scattering and scanning transmission electron microscopy showed that ZnO-promoted Pt possessed promising thermal stability under APR reaction conditions. In situ X-ray absorption spectroscopy showed clear charge transfer between ZnO and Pt nanoparticles. The improved reactivity and selectivity seemed to benefit from having both Pt-ZnO and Pt-Al2O3 interfaces.
- Authors:
-
- Argonne National Lab. (ANL), Lemont, IL (United States); Univ. of Alabama in Huntsville, Huntsville, AL (United States)
- Argonne National Lab. (ANL), Lemont, IL (United States)
- Univ. of Illinois at Chicago, Chicago, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Laboratory (ANL), Argonne, IL (United States); Energy Frontier Research Centers (EFRC) (United States). Institute for Atom-efficient Chemical Transformations (IACT)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1390898
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Catalysis
- Additional Journal Information:
- Journal Volume: 6; Journal Issue: 6; Journal ID: ISSN 2155-5435
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Lei, Yu, Lee, Sungsik, Low, Ke -Bin, Marshall, Christopher L., and Elam, Jeffrey W. Combining Electronic and Geometric Effects of ZnO-Promoted Pt Nanocatalysts for Aqueous Phase Reforming of 1-Propanol. United States: N. p., 2016.
Web. doi:10.1021/acscatal.6b00963.
Lei, Yu, Lee, Sungsik, Low, Ke -Bin, Marshall, Christopher L., & Elam, Jeffrey W. Combining Electronic and Geometric Effects of ZnO-Promoted Pt Nanocatalysts for Aqueous Phase Reforming of 1-Propanol. United States. https://doi.org/10.1021/acscatal.6b00963
Lei, Yu, Lee, Sungsik, Low, Ke -Bin, Marshall, Christopher L., and Elam, Jeffrey W. Tue .
"Combining Electronic and Geometric Effects of ZnO-Promoted Pt Nanocatalysts for Aqueous Phase Reforming of 1-Propanol". United States. https://doi.org/10.1021/acscatal.6b00963. https://www.osti.gov/servlets/purl/1390898.
@article{osti_1390898,
title = {Combining Electronic and Geometric Effects of ZnO-Promoted Pt Nanocatalysts for Aqueous Phase Reforming of 1-Propanol},
author = {Lei, Yu and Lee, Sungsik and Low, Ke -Bin and Marshall, Christopher L. and Elam, Jeffrey W.},
abstractNote = {Compared with Pt/Al2O3, sintering-resistant Pt nanoparticle catalysts promoted by ZnO significantly improved the reactivity and selectivity toward hydrogen formation in the aqueous phase reforming (APR) of 1-propanol. The improved performance was found to benefit from both the electronic and geometric effects of ZnO thin films. In situ small-angle X-ray scattering and scanning transmission electron microscopy showed that ZnO-promoted Pt possessed promising thermal stability under APR reaction conditions. In situ X-ray absorption spectroscopy showed clear charge transfer between ZnO and Pt nanoparticles. The improved reactivity and selectivity seemed to benefit from having both Pt-ZnO and Pt-Al2O3 interfaces.},
doi = {10.1021/acscatal.6b00963},
journal = {ACS Catalysis},
number = 6,
volume = 6,
place = {United States},
year = {Tue Apr 26 00:00:00 EDT 2016},
month = {Tue Apr 26 00:00:00 EDT 2016}
}
Web of Science
Works referenced in this record:
Synthesis of Transportation Fuels from Biomass: Chemistry, Catalysts, and Engineering
journal, September 2006
- Huber, George W.; Iborra, Sara; Corma, Avelino
- Chemical Reviews, Vol. 106, Issue 9, p. 4044-4098
Hydrogen from biomass-production by steam reforming of biomass pyrolysis oil☆
journal, December 2007
- Czernik, S.; Evans, R.; French, R.
- Catalysis Today, Vol. 129, Issue 3-4
Raney Ni-Sn Catalyst for H2 Production from Biomass-Derived Hydrocarbons
journal, June 2003
- Huber, G. W.
- Science, Vol. 300, Issue 5628
Understanding the Chemistry of H 2 Production for 1-Propanol Reforming: Pathway and Support Modification Effects
journal, September 2012
- Lobo, Rodrigo; Marshall, Christopher L.; Dietrich, Paul J.
- ACS Catalysis, Vol. 2, Issue 11
A “Smart” Catalyst: Sinter-Resistant Supported Iridium Clusters Visualized with Electron Microscopy
journal, April 2012
- Aydin, Ceren; Lu, Jing; Browning, Nigel D.
- Angewandte Chemie International Edition, Vol. 51, Issue 24
Stabilizing gold clusters by heterostructured transition-metal oxide–mesoporous silica supports for enhanced catalytic activities for CO oxidation
journal, January 2012
- Ma, Guicen; Binder, Andrew; Chi, Miaofang
- Chemical Communications, Vol. 48, Issue 93
Thermally stable Pt/mesoporous silica core–shell nanocatalysts for high-temperature reactions
journal, November 2008
- Joo, Sang Hoon; Park, Jeong Young; Tsung, Chia-Kuang
- Nature Materials, Vol. 8, Issue 2
A Sinter-Resistant Catalytic System Based on Platinum Nanoparticles Supported on TiO2 Nanofibers and Covered by Porous Silica
journal, September 2010
- Dai, Yunqian; Lim, Byungkwon; Yang, Yong
- Angewandte Chemie International Edition, Vol. 49, Issue 44
Coking- and Sintering-Resistant Palladium Catalysts Achieved Through Atomic Layer Deposition
journal, March 2012
- Lu, Junling; Fu, Baosong; Kung, Mayfair C.
- Science, Vol. 335, Issue 6073
Stabilization of Copper Catalysts for Liquid-Phase Reactions by Atomic Layer Deposition
journal, November 2013
- O'Neill, Brandon J.; Jackson, David H. K.; Crisci, Anthony J.
- Angewandte Chemie International Edition, Vol. 52, Issue 51
Stabilizing Ni Catalysts by Molecular Layer Deposition for Harsh, Dry Reforming Conditions
journal, July 2014
- Gould, Troy D.; Izar, Alan; Weimer, Alan W.
- ACS Catalysis, Vol. 4, Issue 8
Porous Alumina Protective Coatings on Palladium Nanoparticles by Self-Poisoned Atomic Layer Deposition
journal, May 2012
- Lu, Junling; Liu, Bin; Greeley, Jeffrey P.
- Chemistry of Materials, Vol. 24, Issue 11
A nanostructured cathode architecture for low charge overpotential in lithium-oxygen batteries
journal, August 2013
- Lu, Jun; Lei, Yu; Lau, Kah Chun
- Nature Communications, Vol. 4, Issue 1
Ultralow Loading Pt Nanocatalysts Prepared by Atomic Layer Deposition on Carbon Aerogels
journal, August 2008
- King, Jeffrey S.; Wittstock, Arne; Biener, Juergen
- Nano Letters, Vol. 8, Issue 8, p. 2405-2409
Synthesis of Pt–Pd Core–Shell Nanostructures by Atomic Layer Deposition: Application in Propane Oxidative Dehydrogenation to Propylene
journal, September 2012
- Lei, Yu; Liu, Bin; Lu, Junling
- Chemistry of Materials, Vol. 24, Issue 18
Growth of ZnO/Al2O3 Alloy Films Using Atomic Layer Deposition Techniques
journal, February 2003
- Elam, J. W.; George, S. M.
- Chemistry of Materials, Vol. 15, Issue 4
Atomic Layer Deposition of Platinum Thin Films
journal, May 2003
- Aaltonen, Titta; Ritala, Mikko; Sajavaara, Timo
- Chemistry of Materials, Vol. 15, Issue 9, p. 1924-1928
Adsorbate-Induced Structural Changes in 1–3 nm Platinum Nanoparticles
journal, June 2014
- Lei, Yu; Zhao, Haiyan; Rivas, Rosa Diaz
- Journal of the American Chemical Society, Vol. 136, Issue 26
Atomic Layer Deposition of Platinum Catalysts on Nanowire Surfaces for Photoelectrochemical Water Reduction
journal, August 2013
- Dasgupta, Neil P.; Liu, Chong; Andrews, Sean
- Journal of the American Chemical Society, Vol. 135, Issue 35
Aqueous-Phase Reforming of Ethylene Glycol Over Supported Platinum Catalysts
journal, May 2003
- Shabaker, J. W.; Huber, G. W.; Davda, R. R.
- Catalysis Letters, Vol. 88, Issue 1/2, p. 1-8
Steam reforming and dehydrogenation of methanol: Difference in the catalytic functions of copper and group VIII metals
journal, April 1997
- Takezawa, N.; Iwasa, N.
- Catalysis Today, Vol. 36, Issue 1
CO oxidation over ZnO films on Pt(111) at near-atmospheric pressures
journal, May 2013
- Martynova, Y.; Liu, B. -H.; McBriarty, M. E.
- Journal of Catalysis, Vol. 301
Works referencing / citing this record:
Elucidating the restructuring-induced highly active bimetallic Pt–Co/KL catalyst for the aromatization of n -heptane
journal, January 2020
- Wang, Shuyuan; Xu, Dan; Zhu, Di
- Chemical Communications, Vol. 56, Issue 6
Oxide-Nanotrap-Anchored Platinum Nanoparticles with High Activity and Sintering Resistance by Area-Selective Atomic Layer Deposition
journal, January 2017
- Liu, Xiao; Zhu, Qianqian; Lang, Yun
- Angewandte Chemie, Vol. 129, Issue 6
Synergetic effect on catalytic activity and charge transfer in Pt-Pd bimetallic model catalysts prepared by atomic layer deposition
journal, January 2020
- Jang, Moon-Hyung; Kizilkaya, Orhan; Kropf, A. Jeremy
- The Journal of Chemical Physics, Vol. 152, Issue 2
Oxide‐Nanotrap‐Anchored Platinum Nanoparticles with High Activity and Sintering Resistance by Area‐Selective Atomic Layer Deposition
journal, February 2017
- Liu, Xiao; Zhu, Qianqian; Lang, Yun
- Angewandte Chemie International Edition, Vol. 56, Issue 6