Large thermopower from dressed quasiparticles in the layered cobaltates and rhodates
Abstract
The origin of the large thermopower in Na x CoO2 is complicated by correlation phenomena. To disentangle the effects from multiple interactions, we use angle-resolved photoemission to study Kx RhO2, an isostructural analogy of NaxCoO2 with large thermopower and weak electron correlation. In using the experimentally measured electronic structure, we demonstrate that the thermopower in KxRhO2 can be quantitatively explained within the quasiparticle framework after including an electron-phonon mass enhancement effect. Extending the analysis to the cobaltate, we find the doubling in thermopower is well accounted for by additional band renormalization from electron correlation. Thus, the large thermopower emerges from the itinerant quasiparticles dressed by hierarchical electron-phonon and electron-electron interactions.
- Authors:
-
- Stanford Univ., CA (United States). Dept. of Applied Physics; SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Sciences (SIMES)
- Stanford Univ., CA (United States). Dept. of Physics
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Sciences (SIMES); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
- SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Synchrotron Radiation Lightsource
- Nanjing Univ. (China). National Lab. of Solid State Microstructure, Dept. of Materials Science and Engineering
- Nanjing Univ. (China). National Lab. of Solid State Microstructure, Dept. of Physics
- Nanjing Univ. (China). National Lab. of Solid State Microstructure, Collaborative Innovation Center of Advanced Microstructures
- Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source
- Stanford Univ., CA (United States). Dept. of Applied Physics, Dept. of Physics; SLAC National Accelerator Lab., Menlo Park, CA (United States). Stanford Institute for Materials and Energy Sciences (SIMES)
- Publication Date:
- Research Org.:
- SLAC National Accelerator Lab., Menlo Park, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); National Science Foundation (NSF)
- OSTI Identifier:
- 1390319
- Alternate Identifier(s):
- OSTI ID: 1375080; OSTI ID: 1417604
- Grant/Contract Number:
- AC02-05CH11231; AC02-76SF00515; 11374149; 11574131; 91622122
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Physical Review B
- Additional Journal Information:
- Journal Volume: 96; Journal Issue: 8; Journal ID: ISSN 2469-9950
- Publisher:
- American Physical Society (APS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY
Citation Formats
Chen, Su-Di, He, Yu, Zong, Alfred, Zhang, Yan, Hashimoto, Makoto, Zhang, Bin-Bin, Yao, Shu-Hua, Chen, Yan-Bin, Zhou, Jian, Chen, Yan-Feng, Mo, Sung-Kwan, Hussain, Zahid, Lu, Donghui, and Shen, Zhi-Xun. Large thermopower from dressed quasiparticles in the layered cobaltates and rhodates. United States: N. p., 2017.
Web. doi:10.1103/PhysRevB.96.081109.
Chen, Su-Di, He, Yu, Zong, Alfred, Zhang, Yan, Hashimoto, Makoto, Zhang, Bin-Bin, Yao, Shu-Hua, Chen, Yan-Bin, Zhou, Jian, Chen, Yan-Feng, Mo, Sung-Kwan, Hussain, Zahid, Lu, Donghui, & Shen, Zhi-Xun. Large thermopower from dressed quasiparticles in the layered cobaltates and rhodates. United States. https://doi.org/10.1103/PhysRevB.96.081109
Chen, Su-Di, He, Yu, Zong, Alfred, Zhang, Yan, Hashimoto, Makoto, Zhang, Bin-Bin, Yao, Shu-Hua, Chen, Yan-Bin, Zhou, Jian, Chen, Yan-Feng, Mo, Sung-Kwan, Hussain, Zahid, Lu, Donghui, and Shen, Zhi-Xun. Tue .
"Large thermopower from dressed quasiparticles in the layered cobaltates and rhodates". United States. https://doi.org/10.1103/PhysRevB.96.081109. https://www.osti.gov/servlets/purl/1390319.
@article{osti_1390319,
title = {Large thermopower from dressed quasiparticles in the layered cobaltates and rhodates},
author = {Chen, Su-Di and He, Yu and Zong, Alfred and Zhang, Yan and Hashimoto, Makoto and Zhang, Bin-Bin and Yao, Shu-Hua and Chen, Yan-Bin and Zhou, Jian and Chen, Yan-Feng and Mo, Sung-Kwan and Hussain, Zahid and Lu, Donghui and Shen, Zhi-Xun},
abstractNote = {The origin of the large thermopower in Na x CoO2 is complicated by correlation phenomena. To disentangle the effects from multiple interactions, we use angle-resolved photoemission to study Kx RhO2, an isostructural analogy of NaxCoO2 with large thermopower and weak electron correlation. In using the experimentally measured electronic structure, we demonstrate that the thermopower in KxRhO2 can be quantitatively explained within the quasiparticle framework after including an electron-phonon mass enhancement effect. Extending the analysis to the cobaltate, we find the doubling in thermopower is well accounted for by additional band renormalization from electron correlation. Thus, the large thermopower emerges from the itinerant quasiparticles dressed by hierarchical electron-phonon and electron-electron interactions.},
doi = {10.1103/PhysRevB.96.081109},
journal = {Physical Review B},
number = 8,
volume = 96,
place = {United States},
year = {Tue Aug 15 00:00:00 EDT 2017},
month = {Tue Aug 15 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Low-Lying Quasiparticle States and Hidden Collective Charge Instabilities in Parent Cobaltate Superconductors
journal, June 2006
- Qian, D.; Hsieh, D.; Wray, L.
- Physical Review Letters, Vol. 96, Issue 21
Angle-resolved photoemission study of the doping evolution of a three-dimensional Fermi surface in Na x CoO 2
journal, April 2011
- Arakane, T.; Sato, T.; Takahashi, T.
- New Journal of Physics, Vol. 13, Issue 4
Suppression of thermopower of by an external magnetic field: Boltzmann transport combined with spin-polarized density functional theory
journal, November 2007
- Xiang, H. J.; Singh, D. J.
- Physical Review B, Vol. 76, Issue 19
Oxide thermoelectrics: The challenges, progress, and outlook
journal, July 2011
- He, Jian; Liu, Yufei; Funahashi, Ryoji
- Journal of Materials Research, Vol. 26, Issue 15
Colossal Thermoelectric Power Factor in K7/8RhO2
journal, April 2012
- Saeed, Yasir; Singh, Nirpendra; Schwingenschlögl, Udo
- Advanced Functional Materials, Vol. 22, Issue 13
Charge Ordering, Commensurability, and Metallicity in the Phase Diagram of the Layered
journal, June 2004
- Foo, Maw Lin; Wang, Yayu; Watauchi, Satoshi
- Physical Review Letters, Vol. 92, Issue 24
Quasiparticle Dynamics in the Vicinity of Metal-Insulator Phase Transition in
journal, February 2006
- Qian, D.; Wray, L.; Hsieh, D.
- Physical Review Letters, Vol. 96, Issue 4
Three-Dimensional Spin Fluctuations in
journal, April 2005
- Helme, L. M.; Boothroyd, A. T.; Coldea, R.
- Physical Review Letters, Vol. 94, Issue 15
Magnetic Ordering and Spin Waves in
journal, April 2005
- Bayrakci, S. P.; Mirebeau, I.; Bourges, P.
- Physical Review Letters, Vol. 94, Issue 15
Anomalous Quasiparticle Renormalization in : Role of Interorbital Interactions and Magnetic Correlations
journal, July 2007
- Geck, J.; Borisenko, S. V.; Berger, H.
- Physical Review Letters, Vol. 99, Issue 4
Transport properties of the layered Rh oxide K 0.49 RhO 2
journal, March 2010
- Shibasaki, S.; Nakano, T.; Terasaki, I.
- Journal of Physics: Condensed Matter, Vol. 22, Issue 11
Novel Electronic Structure Induced by a Highly Strained Oxide Interface with Incommensurate Crystal Fields
journal, January 2009
- Ou, H. W.; Zhao, J. F.; Zhang, Y.
- Physical Review Letters, Vol. 102, Issue 2
Optical study of the electronic structure and correlation effects in K RhO
journal, August 2011
- Okazaki, R.; Nishina, Y.; Yasui, Y.
- Physical Review B, Vol. 84, Issue 7
Can Disorder Alone Destroy the Hole Pockets of ? A Wannier Function Based First-Principles Method for Disordered Systems
journal, February 2011
- Berlijn, Tom; Volja, Dmitri; Ku, Wei
- Physical Review Letters, Vol. 106, Issue 7
Electron-phonon contribution to the thermopower of metals
journal, November 1990
- Jonson, M.; Mahan, G. D.
- Physical Review B, Vol. 42, Issue 15
Experimental Study of the Incoherent Spectral Weight in the Photoemission Spectra of the Misfit Cobaltate
journal, February 2010
- Nicolaou, A.; Brouet, V.; Zacchigna, M.
- Physical Review Letters, Vol. 104, Issue 5
Spin entropy as the likely source of enhanced thermopower in NaxCo2O4
journal, May 2003
- Wang, Yayu; Rogado, Nyrissa S.; Cava, R. J.
- Nature, Vol. 423, Issue 6938
Thermopower in the correlated hopping regime
journal, January 1976
- Chaikin, P. M.; Beni, G.
- Physical Review B, Vol. 13, Issue 2
NMR studies of metallic
journal, April 1999
- Ray, R.; Ghoshray, A.; Ghoshray, K.
- Physical Review B, Vol. 59, Issue 14
Complete -Band Dispersion Relation in Sodium Cobaltates
journal, November 2006
- Qian, D.; Wray, L.; Hsieh, D.
- Physical Review Letters, Vol. 97, Issue 18
Destruction of the Small Fermi Surfaces in by Disorder
journal, July 2006
- Singh, D. J.; Kasinathan, Deepa
- Physical Review Letters, Vol. 97, Issue 1
Large thermoelectric power in single crystals
journal, November 1997
- Terasaki, I.; Sasago, Y.; Uchinokura, K.
- Physical Review B, Vol. 56, Issue 20
Phase Diagram of Studied By Gutzwiller Density-Functional Theory
journal, August 2008
- Wang, Guang-Tao; Dai, Xi; Fang, Zhong
- Physical Review Letters, Vol. 101, Issue 6
Effects of Spin and Orbital Degeneracy on the Thermopower of Strongly Correlated Systems
journal, November 2001
- Koshibae, W.; Maekawa, S.
- Physical Review Letters, Vol. 87, Issue 23
Giant Electron-Electron Scattering in the Fermi-Liquid State of
journal, July 2004
- Li, S. Y.; Taillefer, Louis; Hawthorn, D. G.
- Physical Review Letters, Vol. 93, Issue 5
Dynamical Mean Field Theory of an Effective Three-Band Model for
journal, February 2009
- Bourgeois, A.; Aligia, A. A.; Rozenberg, M. J.
- Physical Review Letters, Vol. 102, Issue 6
Contribution of electronic structure to the large thermoelectric power in layered cobalt oxides
journal, March 2004
- Takeuchi, Tsunehiro; Kondo, Takeshi; Takami, Tsuyoshi
- Physical Review B, Vol. 69, Issue 12
Fermi Surface Evolution and Luttinger Theorem in : A Systematic Photoemission Study
journal, September 2005
- Yang, H. -B.; Pan, Z. -H.; Sekharan, A. K. P.
- Physical Review Letters, Vol. 95, Issue 14
Superconductivity in two-dimensional CoO2 layers
journal, March 2003
- Takada, Kazunori; Sakurai, Hiroya; Takayama-Muromachi, Eiji
- Nature, Vol. 422, Issue 6927
ARPES on : Fermi Surface and Unusual Band Dispersion
journal, June 2004
- Yang, H. -B.; Wang, S. -C.; Sekharan, A. K. P.
- Physical Review Letters, Vol. 92, Issue 24
Fermi Surface and Quasiparticle Dynamics of Investigated by Angle-Resolved Photoemission Spectroscopy
journal, June 2004
- Hasan, M. Z.; Chuang, Y. -D.; Qian, D.
- Physical Review Letters, Vol. 92, Issue 24
Energy Band Structure of Copper
journal, January 1963
- Burdick, Glenn A.
- Physical Review, Vol. 129, Issue 1
Large enhancement of the thermopower in NaxCoO2 at high Na doping
journal, June 2006
- Lee, Minhyea; Viciu, Liliana; Li, Lu
- Nature Materials, Vol. 5, Issue 7
Seebeck coefficient of : Measurements and a narrow-band model
journal, February 2009
- Kaurav, N.; Wu, K. K.; Kuo, Y. K.
- Physical Review B, Vol. 79, Issue 7
Structure and physical properties of K 0.63 RhO 2 single crystals
journal, December 2012
- Yao, S. H.; Zhang, B. B.; Zhou, J.
- AIP Advances, Vol. 2, Issue 4
“Pudding Mold” Band Drives Large Thermopower in Na x CoO 2
journal, August 2007
- Kuroki, Kazuhiko; Arita, Ryotaro
- Journal of the Physical Society of Japan, Vol. 76, Issue 8
Lattice dynamics of K x RhO 2 single crystals
journal, August 2015
- Zhang, Bin-Bin; Zhang, NaNa; Dong, Song-Tao
- AIP Advances, Vol. 5, Issue 8
Electron Correlation and Fermi Surface Topology of
journal, May 2005
- Zhou, Sen; Gao, Meng; Ding, Hong
- Physical Review Letters, Vol. 94, Issue 20
Thermopower in cobalt oxides
journal, September 2000
- Koshibae, W.; Tsutsui, K.; Maekawa, S.
- Physical Review B, Vol. 62, Issue 11
Superconductivity in Two-Dimensional CoO2 Layers.
journal, June 2003
- Takada, Kazunori; Sakurai, Hiroya; Takayama-Muromachi, Eiji
- ChemInform, Vol. 34, Issue 24
Electronic structure of
journal, April 2007
- Jeong, T.
- Physica B: Condensed Matter, Vol. 392, Issue 1-2
Anisotropic quasiparticle renormalization in Na0.73CoO2: role of inter-orbital interactions and magnetic correlations
text, January 2007
- Geck, J.; Borisenko, S. V.; Berger, H.
- arXiv
"Pudding mold" band drives large thermopower in Na$_x$CoO$_2$
text, January 2007
- Kuroki, Kazuhiko; Arita, Ryotaro
- arXiv
Novel electronic structure induced by a highly strained oxide interface with incommensurate crystal fields
text, January 2008
- Ou, H. W.; Zhao, J. F.; Zhang, Y.
- arXiv
Dynamical mean field theory of an effective three-band model for Na$_x$CoO$_2$
text, January 2009
- Bourgeois, A.; Aligia, A. A.; Rozenberg, M. J.
- arXiv
Colossal Thermoelectric Power Factor in K$_{7/8}$RhO$_2$
text, January 2013
- Saeed, Y.; Singh, N.; Schwingenschlögl, U.
- arXiv
Spin entropy as the likely source of enhanced thermopower in $\rm\bf Na_xCo_2O_4
text, January 2004
- Wang, Yayu; Rogado, Nyrissa S.; Cava, R. J.
- arXiv
Three-Dimensional Spin Fluctuations in Na0.75CoO2
text, January 2004
- Helme, L. M.; Boothroyd, A. T.; Coldea, R.
- arXiv
Large enhancement of the thermopower in Na$_x$CoO$_2$ at high Na doping
text, January 2006
- Lee, Minhyea; Viciu, Liliana; Li, Lu
- arXiv
Works referencing / citing this record:
Enhanced Seebeck coefficient by a filling-induced Lifshitz transition in
journal, January 2019
- Ito, Naoko; Ishii, Mayu; Okazaki, Ryuji
- Physical Review B, Vol. 99, Issue 4