Tuning Porosity and Surface Area in Mesoporous Silicon for Application in Li-Ion Battery Electrodes
Abstract
This work aims to improve the poor cycle lifetime of silicon-based anodes for Li-ion batteries by tuning microstructural parameters such as pore size, pore volume, and specific surface area in chemically synthesized mesoporous silicon. In this paper, we have specifically produced two different mesoporous silicon samples from the magnesiothermic reduction of ordered mesoporous silica in either argon or forming gas. In situ X-ray diffraction studies indicate that samples made in Ar proceed through a Mg2Si intermediate, and this results in samples with larger pores (diameter ≈ 90 nm), modest total porosity (34%), and modest specific surface area (50 m2 g–1). Reduction in forming gas, by contrast, results in direct conversion of silica to silicon, and this produces samples with smaller pores (diameter ≈ 40 nm), higher porosity (41%), and a larger specific surface area (70 m2 g–1). The material with smaller pores outperforms the one with larger pores, delivering a capacity of 1121 mAh g–1 at 10 A g–1 and retains 1292 mAh g–1 at 5 A g–1 after 500 cycles. For comparison, the sample with larger pores delivers a capacity of 731 mAh g–1 at 10 A g–1 and retains 845 mAh g–1 at 5 A g–1 after 500more »
- Authors:
-
[4]
- Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry
- Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering
- Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering, and The California NanoSystems Inst.
- Univ. of California, Los Angeles, CA (United States). Dept. of Chemistry and Biochemistry, Dept. of Materials Science and Engineering, and The California NanoSystems Inst.
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Nanostructures for Electrical Energy Storage (NEES)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1388860
- Grant/Contract Number:
- SC0001160; SC0014213
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ACS Applied Materials and Interfaces
- Additional Journal Information:
- Journal Volume: 9; Journal Issue: 22; Related Information: NEES partners with University of Maryland (lead); University of California, Irvine; University of Florida; Los Alamos National Laboratory; Sandia National Laboratories; Yale University; Journal ID: ISSN 1944-8244
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 42 ENGINEERING; bio-inspired; energy storage (including batteries and capacitors); defects; charge transport; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing); silicon; high power density; high energy density; mesoporous; magnesiothermic reduction; anode; Li ion battery
Citation Formats
Cook, John B., Kim, Hyung-Seok, Lin, Terri C., Robbennolt, Shauna, Detsi, Eric, Dunn, Bruce S., and Tolbert, Sarah H. Tuning Porosity and Surface Area in Mesoporous Silicon for Application in Li-Ion Battery Electrodes. United States: N. p., 2017.
Web. doi:10.1021/acsami.6b16447.
Cook, John B., Kim, Hyung-Seok, Lin, Terri C., Robbennolt, Shauna, Detsi, Eric, Dunn, Bruce S., & Tolbert, Sarah H. Tuning Porosity and Surface Area in Mesoporous Silicon for Application in Li-Ion Battery Electrodes. United States. https://doi.org/10.1021/acsami.6b16447
Cook, John B., Kim, Hyung-Seok, Lin, Terri C., Robbennolt, Shauna, Detsi, Eric, Dunn, Bruce S., and Tolbert, Sarah H. Tue .
"Tuning Porosity and Surface Area in Mesoporous Silicon for Application in Li-Ion Battery Electrodes". United States. https://doi.org/10.1021/acsami.6b16447. https://www.osti.gov/servlets/purl/1388860.
@article{osti_1388860,
title = {Tuning Porosity and Surface Area in Mesoporous Silicon for Application in Li-Ion Battery Electrodes},
author = {Cook, John B. and Kim, Hyung-Seok and Lin, Terri C. and Robbennolt, Shauna and Detsi, Eric and Dunn, Bruce S. and Tolbert, Sarah H.},
abstractNote = {This work aims to improve the poor cycle lifetime of silicon-based anodes for Li-ion batteries by tuning microstructural parameters such as pore size, pore volume, and specific surface area in chemically synthesized mesoporous silicon. In this paper, we have specifically produced two different mesoporous silicon samples from the magnesiothermic reduction of ordered mesoporous silica in either argon or forming gas. In situ X-ray diffraction studies indicate that samples made in Ar proceed through a Mg2Si intermediate, and this results in samples with larger pores (diameter ≈ 90 nm), modest total porosity (34%), and modest specific surface area (50 m2 g–1). Reduction in forming gas, by contrast, results in direct conversion of silica to silicon, and this produces samples with smaller pores (diameter ≈ 40 nm), higher porosity (41%), and a larger specific surface area (70 m2 g–1). The material with smaller pores outperforms the one with larger pores, delivering a capacity of 1121 mAh g–1 at 10 A g–1 and retains 1292 mAh g–1 at 5 A g–1 after 500 cycles. For comparison, the sample with larger pores delivers a capacity of 731 mAh g–1 at 10 A g–1 and retains 845 mAh g–1 at 5 A g–1 after 500 cycles. The dependence of capacity retention and charge storage kinetics on the nanoscale architecture clearly suggests that these microstructural parameters significantly impact the performance of mesoporous alloy type anodes. Our work is therefore expected to contribute to the design and synthesis of optimal mesoporous architectures for advanced Li-ion battery anodes.},
doi = {10.1021/acsami.6b16447},
journal = {ACS Applied Materials and Interfaces},
number = 22,
volume = 9,
place = {United States},
year = {Tue May 09 00:00:00 EDT 2017},
month = {Tue May 09 00:00:00 EDT 2017}
}
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Synthesis of Si NPs from River Sand Using the Mechanochemical Process and its Applications in Metal Oxide Heterojunction Solar Cells
journal, October 2019
- Kuddus, Abdul; Islam, Rounakul; Tabassum, Samia
- Silicon, Vol. 12, Issue 7
The State of Research Regarding Ordered Mesoporous Materials in Batteries
journal, January 2019
- Du, Guangyu; Xu, Yuxia; Zheng, Shasha
- Small, Vol. 15, Issue 11
Large magnetoelectric effects mediated by electric-field-driven nanoscale phase transformations in sputtered (nanoparticulate) and electrochemically dealloyed (nanoporous) Fe–Cu films
journal, January 2018
- Robbennolt, Shauna; Quintana, Alberto; Pellicer, Eva
- Nanoscale, Vol. 10, Issue 30
Porous carbon-coated ball-milled silicon as high-performance anodes for lithium-ion batteries
journal, November 2018
- Nzabahimana, Joseph; Chang, Peng; Hu, Xianluo
- Journal of Materials Science, Vol. 54, Issue 6
In Situ Probing Multiple-Scale Structures of Energy Materials for Li-Ion Batteries
journal, May 2019
- Zhu, He; Huang, Yalan; Zhu, Hekang
- Small Methods
Small-angle X-ray scattering of nanoporous materials
journal, January 2020
- Welborn, Samuel S.; Detsi, Eric
- Nanoscale Horizons, Vol. 5, Issue 1
Silicon Nanoparticles Confined in Thin Carbon Network: The Free-Standing Anode of Lithium Ion Batteries with High Performance and Easy Recyclability
journal, January 2019
- Kong, Junhua; Wei, Yuefan
- Journal of The Electrochemical Society, Vol. 166, Issue 10