DOE PAGES title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Absence of nematic ordering transition in a diamond lattice: Application to FeSc 2 S 4

Abstract

Recent neutron scattering observations by [Plumb et al., Phys. Rev. X 6, 041055 (2016)] reveal that the ground state of FeSc 2 S 4 is magnetic with two distinct Fe environments, instead of a quantum spin liquid as had been previously thought. Starting with the relevant O(N)-symmetric vector model of FeSc 2 S 4 , we study how the discrete (Z2) and continuous rotational symmetries are successively broken, yielding nematic and ordered phases. At high temperatures, we find that the nematic order parameter falls as T–γ (γ > 0), and therefore, FeSc 2 S 4 lacks any distinct nematic ordering temperature. Furthermore, this feature indicates that the three-dimensional diamond lattice of FeSc 2 S 4 is highly susceptible to the breaking of Ising symmetries, and explains the two distinct Fe environments that are present even at high temperatures, as seen by Mössbauer and far-infrared optical spectroscopy.

Authors:
 [1];  [1];  [1];  [1]
  1. Univ. of Illinois, Urbana, IL (United States)
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Emergent Superconductivity (CES)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1388510
Alternate Identifier(s):
OSTI ID: 1338099
Grant/Contract Number:  
AC02-98CH10886; DMR-1461952; AC02-98CH1088
Resource Type:
Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 95; Journal Issue: 2; Related Information: CES partners with Brookhaven National Laboratory (BNL); Argonne National Laboratory; University of Illinois, Urbana-Champaign; Los Alamos National Laboratory; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; phonons; thermal conductivity; energy storage (including batteries and capacitors); superconductivity; defects; spin dynamics

Citation Formats

Setty, Chandan, Leong, Zhidong, Zhang, Shuyi, and Phillips, Philip W. Absence of nematic ordering transition in a diamond lattice: Application to FeSc2S4. United States: N. p., 2017. Web. doi:10.1103/PhysRevB.95.020403.
Setty, Chandan, Leong, Zhidong, Zhang, Shuyi, & Phillips, Philip W. Absence of nematic ordering transition in a diamond lattice: Application to FeSc2S4. United States. https://doi.org/10.1103/PhysRevB.95.020403
Setty, Chandan, Leong, Zhidong, Zhang, Shuyi, and Phillips, Philip W. Tue . "Absence of nematic ordering transition in a diamond lattice: Application to FeSc2S4". United States. https://doi.org/10.1103/PhysRevB.95.020403. https://www.osti.gov/servlets/purl/1388510.
@article{osti_1388510,
title = {Absence of nematic ordering transition in a diamond lattice: Application to FeSc2S4},
author = {Setty, Chandan and Leong, Zhidong and Zhang, Shuyi and Phillips, Philip W.},
abstractNote = {Recent neutron scattering observations by [Plumb et al., Phys. Rev. X 6, 041055 (2016)] reveal that the ground state of FeSc2S4 is magnetic with two distinct Fe environments, instead of a quantum spin liquid as had been previously thought. Starting with the relevant O(N)-symmetric vector model of FeSc2S4, we study how the discrete (Z2) and continuous rotational symmetries are successively broken, yielding nematic and ordered phases. At high temperatures, we find that the nematic order parameter falls as T–γ (γ > 0), and therefore, FeSc2S4 lacks any distinct nematic ordering temperature. Furthermore, this feature indicates that the three-dimensional diamond lattice of FeSc2S4 is highly susceptible to the breaking of Ising symmetries, and explains the two distinct Fe environments that are present even at high temperatures, as seen by Mössbauer and far-infrared optical spectroscopy.},
doi = {10.1103/PhysRevB.95.020403},
journal = {Physical Review B},
number = 2,
volume = 95,
place = {United States},
year = {Tue Jan 03 00:00:00 EST 2017},
month = {Tue Jan 03 00:00:00 EST 2017}
}

Journal Article:

Citation Metrics:
Cited by: 1 work
Citation information provided by
Web of Science

Save / Share:

Works referenced in this record:

Orbital physics in sulfur spinels: ordered, liquid and glassy ground states
journal, January 2004


Singlet-Triplet Excitations and Long-Range Entanglement in the Spin-Orbital Liquid Candidate FeSc 2 S 4
journal, May 2015


Spin liquids in frustrated magnets
journal, March 2010


Vibronic and Magnetic Excitations in the Spin-Orbital Liquid State of FeSc 2 S 4
journal, June 2005


Magnetic ordering in the frustrated system FeSc2S4
journal, October 2008

  • Son, Bae Soon; Kim, Sam Jin; Jo, Younghun
  • Journal of Magnetism and Magnetic Materials, Vol. 320, Issue 20
  • DOI: 10.1016/j.jmmm.2008.04.151

Theory of excitations and dielectric response at a spin-orbital quantum critical point
journal, September 2015


Pressure effects on magnetically driven electronic nematic states in iron pnictide superconductors
journal, March 2012


Spiral order by disorder and lattice nematic order in a frustrated Heisenberg antiferromagnet on the honeycomb lattice
journal, June 2010


Order-by-disorder and spiral spin-liquid in frustrated diamond-lattice antiferromagnets
journal, May 2007

  • Bergman, Doron; Alicea, Jason; Gull, Emanuel
  • Nature Physics, Vol. 3, Issue 7
  • DOI: 10.1038/nphys622

Spin-Orbital Short-Range Order on a Honeycomb-Based Lattice
journal, May 2012


Spin liquid state in ZnFe2O4
journal, September 1999


An orbital-selective spin liquid in a frustrated heavy fermion spinel LiV2O4
journal, January 2012

  • Shimizu, Yasuhiro; Takeda, Hikaru; Tanaka, Moe
  • Nature Communications, Vol. 3, Issue 1
  • DOI: 10.1038/ncomms1979

Orbital Freezing and Orbital Glass State in F e C r 2 S 4
journal, January 2005


Topological Spin Liquid on the Hyperkagome Lattice of Na 4 Ir 3 O 8
journal, June 2008


Magnetic ordering and spin excitations in the frustrated magnet Mn Sc 2 S 4
journal, January 2006


Antiferromagnetic and Orbital Ordering on a Diamond Lattice Near Quantum Criticality
journal, December 2016

  • Plumb, K. W.; Morey, J. R.; Rodriguez-Rivera, J. A.
  • Physical Review X, Vol. 6, Issue 4
  • DOI: 10.1103/PhysRevX.6.041055

Emergent excitations in a geometrically frustrated magnet
journal, August 2002


The Jahn-Teller effect and magnetism: transition metal compounds
journal, April 1982


Ising transition in frustrated Heisenberg models
journal, January 1990


Spin-orbiton and quantum criticality in FeSc 2 S 4
journal, March 2015


Kinetically inhibited order in a diamond-lattice antiferromagnet
journal, September 2011

  • MacDougall, G. J.; Gout, D.; Zarestky, J. L.
  • Proceedings of the National Academy of Sciences, Vol. 108, Issue 38
  • DOI: 10.1073/pnas.1107861108

Spin-Orbital Singlet and Quantum Critical Point on the Diamond Lattice: FeSc 2 S 4
journal, March 2009


Excitation spectrum and magnetic field effects in a quantum critical spin-orbital system: The case of FeSc 2 S 4
journal, December 2009


Spin and Orbital Frustration in MnSc 2 S 4 and FeSc 2 S 4
journal, March 2004


DISTRIBUTION OF STRAINS AT Fe 2+ A SITE IN THE THIOSPINEL FeSc 2 S 4
journal, December 1976


What drives nematic order in iron-based superconductors?
journal, January 2014

  • Fernandes, R. M.; Chubukov, A. V.; Schmalian, J.
  • Nature Physics, Vol. 10, Issue 2
  • DOI: 10.1038/nphys2877

Nematic Order by Disorder in Spin-2 Bose-Einstein Condensates
journal, May 2007


Geometric frustration in the cubic spinels M Al 2 O 4 ( M = Co , Fe, and Mn)
journal, November 2005


Theory of electron nematic order in LaFeAsO
journal, June 2008


Spin excitations in frustrated A -site spinels investigated with inelastic neutron scattering
journal, April 2009


Ordering due to disorder in a frustrated vector antiferromagnet
journal, April 1989


Spin liquid versus spin solid in A-site spinels
journal, May 2006


Magnetic model of the tetragonal-orthorhombic transition in the cuprates
journal, September 2006


Quantum Phase Transitions
book, December 2007


Structural investigations of the compounds ASc2S4 (A=Mn, Fe, Cd)
journal, February 2002


Order as an effect of disorder
journal, January 1980


Large n Expansion for Frustrated and Doped Quantum Antiferromagnets
journal, January 1991