Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal–Organic Framework with Functional Groups
Abstract
A facile preparation of a mesoporous Cr-MOF, PCN-333(Cr) with functional group, has been demonstrated herein through a dual exchange strategy, involving a sequential ligand exchange and metal metathesis process. After optimization of the exchange system, the functionalized PCN-333(Cr), N3–PCN-333(Cr) shows well maintained crystallinity, porosity, as well as much improved chemical stability. Because of the exceptionally large pores (~5.5 nm) in PCN-333(Cr), a secondary functional moiety, Zn-TEPP with a size of 18 Å × 18 Å, has been successfully clicked into the framework. In this article, we have also analyzed kinetics and thermodynamics during dual exchange process, showing our attempts to interpret the exchange event in the PCN-333. Our findings not only provide a highly stable mesoporous Cr-MOF platform for expanding MOF-based applications, but also suggest a route to functionalized Cr-MOF which may have not been achievable through conventional approaches.
- Authors:
-
- Texas A & M Univ., College Station, TX (United States)
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Center for Gas Separations (CGS)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES); The Welch Foundation
- OSTI Identifier:
- 1387387
- Grant/Contract Number:
- SC0001015; A-1725
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the American Chemical Society
- Additional Journal Information:
- Journal Volume: 137; Journal Issue: 36; Related Information: CGS partners with University of California, Berkeley; University of California, Davis; Lawrence Berkeley National Laboratory; University of Minnesota; National Energy Technology Laboratory; Texas A&M University; Journal ID: ISSN 0002-7863
- Publisher:
- American Chemical Society (ACS)
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; membrane; carbon capture; materials and chemistry by design; synthesis (novel materials); synthesis (self-assembly); synthesis (scalable processing); functionalization; ligand exchange; metals; metal organic frameworks; metathesis
Citation Formats
Park, Jihye, Feng, Dawei, and Zhou, Hong-Cai. Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal–Organic Framework with Functional Groups. United States: N. p., 2015.
Web. doi:10.1021/jacs.5b07373.
Park, Jihye, Feng, Dawei, & Zhou, Hong-Cai. Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal–Organic Framework with Functional Groups. United States. https://doi.org/10.1021/jacs.5b07373
Park, Jihye, Feng, Dawei, and Zhou, Hong-Cai. Fri .
"Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal–Organic Framework with Functional Groups". United States. https://doi.org/10.1021/jacs.5b07373. https://www.osti.gov/servlets/purl/1387387.
@article{osti_1387387,
title = {Dual Exchange in PCN-333: A Facile Strategy to Chemically Robust Mesoporous Chromium Metal–Organic Framework with Functional Groups},
author = {Park, Jihye and Feng, Dawei and Zhou, Hong-Cai},
abstractNote = {A facile preparation of a mesoporous Cr-MOF, PCN-333(Cr) with functional group, has been demonstrated herein through a dual exchange strategy, involving a sequential ligand exchange and metal metathesis process. After optimization of the exchange system, the functionalized PCN-333(Cr), N3–PCN-333(Cr) shows well maintained crystallinity, porosity, as well as much improved chemical stability. Because of the exceptionally large pores (~5.5 nm) in PCN-333(Cr), a secondary functional moiety, Zn-TEPP with a size of 18 Å × 18 Å, has been successfully clicked into the framework. In this article, we have also analyzed kinetics and thermodynamics during dual exchange process, showing our attempts to interpret the exchange event in the PCN-333. Our findings not only provide a highly stable mesoporous Cr-MOF platform for expanding MOF-based applications, but also suggest a route to functionalized Cr-MOF which may have not been achievable through conventional approaches.},
doi = {10.1021/jacs.5b07373},
journal = {Journal of the American Chemical Society},
number = 36,
volume = 137,
place = {United States},
year = {Fri Aug 28 00:00:00 EDT 2015},
month = {Fri Aug 28 00:00:00 EDT 2015}
}
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Figures / Tables:
Figure 1: (a) Ligands in MIL-100 (BTC) and PCN-333 (TATB). (b) The largest cage in PCN-333. (c) Supertetrahedron in PCN-333.
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