Synthetic Control of Crystallite Size of Silver Vanadium Phosphorous Oxide (Ag0.50VOPO4·1.9H2O): Impact on Electrochemistry
Abstract
Here, this report describes a synthetic approach to control the crystallite size of silver vanadium phosphorous oxide, Ag0.50VOPO4·1.9H2O, and the impact on electrochemistry in lithium based batteries. Ag0.50VOPO4·1.9H2O was synthesized using a stirred hydrothermal method over a range of temperatures. X-ray diffraction (XRD) was used to confirm the crystalline phase and the crystallite size sizes of 11, 22, 38, 40, 49, and 120 nm. Particle shape was plate-like with edges <1 micron to >10 microns. Under galvanostatic reduction the samples with 22 nm crystallites and 880 nm particles produced the highest capacity, ~25% more capacity than the 120 nm sample. Notably, the 11 nm sample resulted in reduced delivered capacity and higher resistance consistent with increased grain boundaries contributing to resistance. Under intermittent pulsing ohmic resistance decreased with increasing crystallite size from 11 nm to 120 nm implying that electrical conduction within a crystal is more facile than between crystallites and across grain boundaries. Finally, this systematic study of material dimension shows that crystallite size impacts deliverable capacity as well as cell resistance where both interparticle and intraparticle transport are important.
- Authors:
-
- Stony Brook Univ., NY (United States). Department of Materials Science and Engineering
- Stony Brook Univ., NY (United States). Department of Materials Science and Engineering and Department of Chemistry
- Stony Brook Univ., NY (United States). Department of Materials Science and Engineering and Department of Chemistry; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
- Publication Date:
- Research Org.:
- Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1376156
- Report Number(s):
- BNL-114109-2017-JA
Journal ID: ISSN 0013-4651
- Grant/Contract Number:
- SC0012704; SC0012673
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Journal of the Electrochemical Society
- Additional Journal Information:
- Journal Volume: 164; Journal Issue: 6; Journal ID: ISSN 0013-4651
- Publisher:
- The Electrochemical Society
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 25 ENERGY STORAGE; 36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; battery; crystallite size; electrochemistry; synthesis
Citation Formats
Huie, Matthew M., Marschilok, Amy C., Takeuchi, Esther S., and Takeuchi, Kenneth J. Synthetic Control of Crystallite Size of Silver Vanadium Phosphorous Oxide (Ag0.50VOPO4·1.9H2O): Impact on Electrochemistry. United States: N. p., 2017.
Web. doi:10.1149/2.1331706jes.
Huie, Matthew M., Marschilok, Amy C., Takeuchi, Esther S., & Takeuchi, Kenneth J. Synthetic Control of Crystallite Size of Silver Vanadium Phosphorous Oxide (Ag0.50VOPO4·1.9H2O): Impact on Electrochemistry. United States. https://doi.org/10.1149/2.1331706jes
Huie, Matthew M., Marschilok, Amy C., Takeuchi, Esther S., and Takeuchi, Kenneth J. Wed .
"Synthetic Control of Crystallite Size of Silver Vanadium Phosphorous Oxide (Ag0.50VOPO4·1.9H2O): Impact on Electrochemistry". United States. https://doi.org/10.1149/2.1331706jes. https://www.osti.gov/servlets/purl/1376156.
@article{osti_1376156,
title = {Synthetic Control of Crystallite Size of Silver Vanadium Phosphorous Oxide (Ag0.50VOPO4·1.9H2O): Impact on Electrochemistry},
author = {Huie, Matthew M. and Marschilok, Amy C. and Takeuchi, Esther S. and Takeuchi, Kenneth J.},
abstractNote = {Here, this report describes a synthetic approach to control the crystallite size of silver vanadium phosphorous oxide, Ag0.50VOPO4·1.9H2O, and the impact on electrochemistry in lithium based batteries. Ag0.50VOPO4·1.9H2O was synthesized using a stirred hydrothermal method over a range of temperatures. X-ray diffraction (XRD) was used to confirm the crystalline phase and the crystallite size sizes of 11, 22, 38, 40, 49, and 120 nm. Particle shape was plate-like with edges <1 micron to >10 microns. Under galvanostatic reduction the samples with 22 nm crystallites and 880 nm particles produced the highest capacity, ~25% more capacity than the 120 nm sample. Notably, the 11 nm sample resulted in reduced delivered capacity and higher resistance consistent with increased grain boundaries contributing to resistance. Under intermittent pulsing ohmic resistance decreased with increasing crystallite size from 11 nm to 120 nm implying that electrical conduction within a crystal is more facile than between crystallites and across grain boundaries. Finally, this systematic study of material dimension shows that crystallite size impacts deliverable capacity as well as cell resistance where both interparticle and intraparticle transport are important.},
doi = {10.1149/2.1331706jes},
journal = {Journal of the Electrochemical Society},
number = 6,
volume = 164,
place = {United States},
year = {Wed Apr 12 00:00:00 EDT 2017},
month = {Wed Apr 12 00:00:00 EDT 2017}
}
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Works referenced in this record:
Electrochemical Reduction of Silver Vanadium Phosphorus Oxide, Ag 2 VO 2 PO 4 : The Formation of Electrically Conductive Metallic Silver Nanoparticles
journal, October 2009
- Takeuchi, Esther S.; Marschilok, Amy C.; Tanzil, Kevin
- Chemistry of Materials, Vol. 21, Issue 20
Electrochemical Reduction of Ag 0.48 VOPO 4 : A Mechanistic Study Employing X-Ray Absorption Spectroscopy and X-Ray Powder Diffraction
journal, January 2015
- Kirshenbaum, Kevin C.; Menard, Melissa C.; Kim, Young Jin
- Journal of The Electrochemical Society, Vol. 162, Issue 8
New Metal-Intercalated Layered Vanadyl Phosphates, M x VOPO 4 ·yH 2 O (M = Ag, Cu, Zn)
journal, July 1998
- Ayyappan, P.; Ramanan, A.; Torardi, C. C.
- Inorganic Chemistry, Vol. 37, Issue 14
The Scherrer equation versus the 'Debye-Scherrer equation'
journal, August 2011
- Holzwarth, Uwe; Gibson, Neil
- Nature Nanotechnology, Vol. 6, Issue 9
Silver vanadium diphosphate Ag2VP2O8: Electrochemistry and characterization of reduced material providing mechanistic insights
journal, April 2013
- Takeuchi, Esther S.; Lee, Chia-Ying; Cheng, Po-Jen
- Journal of Solid State Chemistry, Vol. 200
Comparison of Several Methods for Determining the Internal Resistance of Lithium Ion Cells
journal, June 2010
- Schweiger, Hans-Georg; Obeidi, Ossama; Komesker, Oliver
- Sensors, Vol. 10, Issue 12, p. 5604-5625
Electrochemical reduction of silver vanadium phosphorous oxide, Ag2VO2PO4: Silver metal deposition and associated increase in electrical conductivity
journal, October 2010
- Marschilok, Amy C.; Kozarsky, Eric S.; Tanzil, Kevin
- Journal of Power Sources, Vol. 195, Issue 19
Silver Vanadium Phosphorous Oxide, Ag 0.48 VOPO 4 : Exploration as a Cathode Material in Primary and Secondary Battery Applications
journal, January 2012
- Marschilok, Amy C.; Kim, Young Jin; Takeuchi, Kenneth J.
- Journal of The Electrochemical Society, Vol. 159, Issue 10
In situ visualization of Li/Ag2VP2O8 batteries revealing rate-dependent discharge mechanism
journal, January 2015
- Kirshenbaum, K.; Bock, D. C.; Lee, C. -Y.
- Science, Vol. 347, Issue 6218
Structural Defects of Silver Hollandite, Ag x Mn 8 O y , Nanorods: Dramatic Impact on Electrochemistry
journal, July 2015
- Wu, Lijun; Xu, Feng; Zhu, Yimei
- ACS Nano, Vol. 9, Issue 8
Synthesis and Electrochemistry of Silver Ferrite
journal, January 2011
- Farley, K. E.; Marschilok, A. C.; Takeuchi, E. S.
- Electrochemical and Solid-State Letters, Vol. 15, Issue 2
Ag 6 Mo 2 O 7 F 3 Cl: A New Silver Cathode Material for Enhanced ICD Primary Lithium Batteries
journal, July 2010
- Sauvage, F.; Bodenez, V.; Tarascon, J. -M.
- Inorganic Chemistry, Vol. 49, Issue 14
Silver vanadium phosphorous oxide, Ag2VO2PO4: Chimie douce preparation and resulting lithium cell electrochemistry
journal, August 2011
- Kim, Young Jin; Marschilok, Amy C.; Takeuchi, Kenneth J.
- Journal of Power Sources, Vol. 196, Issue 16
Preparation and Electrochemistry of Silver Vanadium Phosphorous Oxide, Ag[sub 2]VO[sub 2]PO[sub 4]
journal, January 2009
- Marschilok, Amy C.; Takeuchi, Kenneth J.; Takeuchi, Esther S.
- Electrochemical and Solid-State Letters, Vol. 12, Issue 1
GSAS-II : the genesis of a modern open-source all purpose crystallography software package
journal, March 2013
- Toby, Brian H.; Von Dreele, Robert B.
- Journal of Applied Crystallography, Vol. 46, Issue 2
Silver vanadium oxides and related battery applications
journal, October 2001
- Takeuchi*, K.
- Coordination Chemistry Reviews, Vol. 219-221
A reversible copper extrusion–insertion electrode for rechargeable Li batteries
journal, October 2003
- Morcrette, M.; Rozier, P.; Dupont, L.
- Nature Materials, Vol. 2, Issue 11
Batteries used to power implantable biomedical devices
journal, December 2012
- Bock, David C.; Marschilok, Amy C.; Takeuchi, Kenneth J.
- Electrochimica Acta, Vol. 84
Ag 4 V 2 O 6 F 2 (SVOF): A High Silver Density Phase and Potential New Cathode Material for Implantable Cardioverter Defibrillators
journal, October 2008
- Sauvage, Frédéric; Bodenez, Vincent; Vezin, Hervé
- Inorganic Chemistry, Vol. 47, Issue 19
Synthetic control of composition and crystallite size of silver ferrite composites: profound electrochemistry impacts
journal, January 2015
- Durham, Jessica L.; Kirshenbaum, Kevin; Takeuchi, Esther S.
- Chemical Communications, Vol. 51, Issue 24
Electrode Reaction Mechanism of Ag 2 VO 2 PO 4 Cathode
journal, May 2016
- Zhang, Ruibo; Abtew, Tesfaye A.; Quackenbush, Nicholas F.
- Chemistry of Materials, Vol. 28, Issue 10
Ag 3.2 VP 1.5 O 7.8 : A High Voltage Silver Vanadium Phosphate Cathode Material
journal, January 2013
- Kim, Young Jin; Takeuchi, Kenneth J.; Marschilok, Amy C.
- Journal of The Electrochemical Society, Vol. 160, Issue 11
Investigating the Complex Chemistry of Functional Energy Storage Systems: The Need for an Integrative, Multiscale (Molecular to Mesoscale) Perspective
journal, April 2016
- Abraham, Alyson; Housel, Lisa M.; Lininger, Christianna N.
- ACS Central Science, Vol. 2, Issue 6
Solid-State Characterization of Reduced Silver Vanadium Oxide from the Li/SVO Discharge Reaction
journal, December 1994
- Leising, Randolph A.; Thiebolt, William C.; Takeuchi, Esther Sans
- Inorganic Chemistry, Vol. 33, Issue 25
Synthesis, Structural Characterization, and Electronic Structure of Single-Crystalline Cu x V 2 O 5 Nanowires
journal, April 2009
- Patridge, Christopher J.; Jaye, Cherno; Zhang, Hengsong
- Inorganic Chemistry, Vol. 48, Issue 7
Rate Dependent Multi-Mechanism Discharge of Ag 0.50 VOPO 4 ·1.8H 2 O: Insights from In Situ Energy Dispersive X-ray Diffraction
journal, September 2016
- Huie, Matthew M.; Bock, David C.; Zhong, Zhong
- Journal of The Electrochemical Society, Vol. 164, Issue 1
Battery Relevant Electrochemistry of Ag 7 Fe 3 (P 2 O 7 ) 4 : Contrasting Contributions from the Redox Chemistries of Ag + and Fe 3+
journal, October 2016
- Zhang, Yiman; Kirshenbaum, Kevin C.; Marschilok, Amy C.
- Chemistry of Materials, Vol. 28, Issue 21
Microwave-Assisted Synthesis of Silver Vanadium Phosphorus Oxide, Ag 2 VO 2 PO 4 : Crystallite Size Control and Impact on Electrochemistry
journal, March 2016
- Huang, Jianping; Marschilok, Amy C.; Takeuchi, Esther S.
- Chemistry of Materials, Vol. 28, Issue 7
Synthesis and Electrochemistry of Silver Hollandite
journal, January 2010
- Zhu, Shali; Marschilok, Amy C.; Lee, Chia-Ying
- Electrochemical and Solid-State Letters, Vol. 13, Issue 8