Global source attribution of sulfate concentration and direct and indirect radiative forcing
Abstract
The global source–receptor relationships of sulfate concentrations, and direct and indirect radiative forcing (DRF and IRF) from 16 regions/sectors for years 2010–2014 are examined in this study through utilizing a sulfur source-tagging capability implemented in the Community Earth System Model (CESM) with winds nudged to reanalysis data. Sulfate concentrations are mostly contributed by local emissions in regions with high emissions, while over regions with relatively low SO2 emissions, the near-surface sulfate concentrations are primarily attributed to non-local sources from long-range transport. Regional source efficiencies of sulfate concentrations are higher over regions with dry atmospheric conditions and less export, suggesting that lifetime of aerosols, together with regional export, is important in determining regional air quality. The simulated global total sulfate DRF is –0.42 W m–2, with –0.31 W m–2 contributed by anthropogenic sulfate and –0.11 W m–2 contributed by natural sulfate, relative to a state with no sulfur emissions. In the Southern Hemisphere tropics, dimethyl sulfide (DMS) contributes 17–84 % to the total DRF. East Asia has the largest contribution of 20–30 % over the Northern Hemisphere mid- and high latitudes. A 20 % perturbation of sulfate and its precursor emissions gives a sulfate incremental IRF of –0.44 W m–2. DMSmore »
- Authors:
-
- Pacific Northwest National Lab. (PNNL), Richland, WA (United States)
- Pacific Northwest National Lab. (PNNL), College Park, MD (United States)
- NASA Goddard Space Flight Center (GSFC), Greenbelt, MD (United States)
- NASA Goddard Space Flight Center (GSFC), Greenbelt, MD (United States); Univ. of Maryland, College Park, MD (United States)
- Publication Date:
- Research Org.:
- Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
- Sponsoring Org.:
- USDOE
- OSTI Identifier:
- 1375377
- Report Number(s):
- PNNL-SA-125012
Journal ID: ISSN 1680-7324; 453040196
- Grant/Contract Number:
- AC05-76RL01830
- Resource Type:
- Accepted Manuscript
- Journal Name:
- Atmospheric Chemistry and Physics (Online)
- Additional Journal Information:
- Journal Name: Atmospheric Chemistry and Physics (Online); Journal Volume: 17; Journal Issue: 14; Journal ID: ISSN 1680-7324
- Publisher:
- European Geosciences Union
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 54 ENVIRONMENTAL SCIENCES; sulfate aerosol; indirect radiative forcing; emissions
Citation Formats
Yang, Yang, Wang, Hailong, Smith, Steven J., Easter, Richard, Ma, Po -Lun, Qian, Yun, Yu, Hongbin, Li, Can, and Rasch, Philip J. Global source attribution of sulfate concentration and direct and indirect radiative forcing. United States: N. p., 2017.
Web. doi:10.5194/acp-17-8903-2017.
Yang, Yang, Wang, Hailong, Smith, Steven J., Easter, Richard, Ma, Po -Lun, Qian, Yun, Yu, Hongbin, Li, Can, & Rasch, Philip J. Global source attribution of sulfate concentration and direct and indirect radiative forcing. United States. https://doi.org/10.5194/acp-17-8903-2017
Yang, Yang, Wang, Hailong, Smith, Steven J., Easter, Richard, Ma, Po -Lun, Qian, Yun, Yu, Hongbin, Li, Can, and Rasch, Philip J. Tue .
"Global source attribution of sulfate concentration and direct and indirect radiative forcing". United States. https://doi.org/10.5194/acp-17-8903-2017. https://www.osti.gov/servlets/purl/1375377.
@article{osti_1375377,
title = {Global source attribution of sulfate concentration and direct and indirect radiative forcing},
author = {Yang, Yang and Wang, Hailong and Smith, Steven J. and Easter, Richard and Ma, Po -Lun and Qian, Yun and Yu, Hongbin and Li, Can and Rasch, Philip J.},
abstractNote = {The global source–receptor relationships of sulfate concentrations, and direct and indirect radiative forcing (DRF and IRF) from 16 regions/sectors for years 2010–2014 are examined in this study through utilizing a sulfur source-tagging capability implemented in the Community Earth System Model (CESM) with winds nudged to reanalysis data. Sulfate concentrations are mostly contributed by local emissions in regions with high emissions, while over regions with relatively low SO2 emissions, the near-surface sulfate concentrations are primarily attributed to non-local sources from long-range transport. Regional source efficiencies of sulfate concentrations are higher over regions with dry atmospheric conditions and less export, suggesting that lifetime of aerosols, together with regional export, is important in determining regional air quality. The simulated global total sulfate DRF is –0.42 W m–2, with –0.31 W m–2 contributed by anthropogenic sulfate and –0.11 W m–2 contributed by natural sulfate, relative to a state with no sulfur emissions. In the Southern Hemisphere tropics, dimethyl sulfide (DMS) contributes 17–84 % to the total DRF. East Asia has the largest contribution of 20–30 % over the Northern Hemisphere mid- and high latitudes. A 20 % perturbation of sulfate and its precursor emissions gives a sulfate incremental IRF of –0.44 W m–2. DMS has the largest contribution, explaining –0.23 W m–2 of the global sulfate incremental IRF. Here, incremental IRF over regions in the Southern Hemisphere with low background aerosols is more sensitive to emission perturbation than that over the polluted Northern Hemisphere.},
doi = {10.5194/acp-17-8903-2017},
journal = {Atmospheric Chemistry and Physics (Online)},
number = 14,
volume = 17,
place = {United States},
year = {Tue Jul 25 00:00:00 EDT 2017},
month = {Tue Jul 25 00:00:00 EDT 2017}
}
Web of Science
Works referenced in this record:
Air pollution: a potentially modifiable risk factor for lung cancer
journal, August 2013
- Fajersztajn, Laís; Veras, Mariana; Barrozo, Ligia Vizeu
- Nature Reviews Cancer, Vol. 13, Issue 9
Decadal trend and interannual variation of outflow of aerosols from East Asia: Roles of variations in meteorological parameters and emissions
journal, January 2015
- Yang, Yang; Liao, Hong; Lou, Sijia
- Atmospheric Environment, Vol. 100
A New Two-Moment Bulk Stratiform Cloud Microphysics Scheme in the Community Atmosphere Model, Version 3 (CAM3). Part I: Description and Numerical Tests
journal, August 2008
- Morrison, Hugh; Gettelman, Andrew
- Journal of Climate, Vol. 21, Issue 15
Historical (1750 - 2014) anthropogenic emissions of reactive gases and aerosols from the Community Emission Data System (CEDS)
preprint, March 2017
- Hoesly, Rachel M.; Smith, Steven J.; Feng, Leyang
- EGU
Toward a minimal representation of aerosols in climate models: description and evaluation in the Community Atmosphere Model CAM5
journal, January 2012
- Liu, X.; Easter, R. C.; Ghan, S. J.
- Geoscientific Model Development, Vol. 5, Issue 3
Regional and global temperature response to anthropogenic SO 2 emissions
from China in three climate models
journal, January 2016
- Kasoar, Matthew; Voulgarakis, Apostolos; Lamarque, Jean-François
- Atmospheric Chemistry and Physics, Vol. 16, Issue 15
Radiative forcing in the ACCMIP historical and future climate simulations
journal, January 2013
- Shindell, D. T.; Lamarque, J. -F.; Schulz, M.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 6
Radiative forcing of the direct aerosol effect from AeroCom Phase II simulations
journal, January 2013
- Myhre, G.; Samset, B. H.; Schulz, M.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 4
Simultaneously Mitigating Near-Term Climate Change and Improving Human Health and Food Security
journal, January 2012
- Shindell, D.; Kuylenstierna, J. C. I.; Vignati, E.
- Science, Vol. 335, Issue 6065
SO 2 over central China: Measurements, numerical simulations and the tropospheric sulfur budget : SULFUR COMPOUNDS OVER CENTRAL CHINA
journal, February 2012
- He, Hao; Li, Can; Loughner, Christopher P.
- Journal of Geophysical Research: Atmospheres, Vol. 117, Issue D16
Observed holiday aerosol reduction and temperature cooling over East Asia
journal, June 2014
- Gong, Dao-Yi; Wang, Wenshan; Qian, Yun
- Journal of Geophysical Research: Atmospheres, Vol. 119, Issue 11
The role of circulation features on black carbon transport into the Arctic in the Community Atmosphere Model version 5 (CAM5): BC TRANSPORT IN OFF-LINE CAM5
journal, May 2013
- Ma, Po-Lun; Rasch, Philip J.; Wang, Hailong
- Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 10
A possible pathway for rapid growth of sulfate during haze days in China
journal, January 2017
- Li, Guohui; Bei, Naifang; Cao, Junji
- Atmospheric Chemistry and Physics, Vol. 17, Issue 5
MERRA: NASA’s Modern-Era Retrospective Analysis for Research and Applications
journal, July 2011
- Rienecker, Michele M.; Suarez, Max J.; Gelaro, Ronald
- Journal of Climate, Vol. 24, Issue 14
An investigation of the sub-grid variability of trace gases and aerosols for global climate modeling
journal, January 2010
- Qian, Y.; Gustafson, W. I.; Fast, J. D.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 14
Changes in atmospheric sulfur burdens and concentrations and resulting radiative forcings under IPCC SRES emission scenarios for 1990-2100: SULFATE UNDER SRES SCENARIOS
journal, March 2005
- Pham, M.; Boucher, O.; Hauglustaine, D.
- Journal of Geophysical Research: Atmospheres, Vol. 110, Issue D6
Regional Atmospheric Pollution and Transboundary air Quality Management
journal, November 2005
- Bergin, Michelle S.; West, J. Jason; Keating, Terry J.
- Annual Review of Environment and Resources, Vol. 30, Issue 1
Sensitivity of remote aerosol distributions to representation of cloud–aerosol interactions in a global climate model
journal, January 2013
- Wang, H.; Easter, R. C.; Rasch, P. J.
- Geoscientific Model Development, Vol. 6, Issue 3
From aerosol-limited to invigoration of warm convective clouds
journal, June 2014
- Koren, I.; Dagan, G.; Altaratz, O.
- Science, Vol. 344, Issue 6188
Global indirect aerosol effects: a review
journal, January 2005
- Lohmann, U.; Feichter, J.
- Atmospheric Chemistry and Physics, Vol. 5, Issue 3
Sulfur dioxide emissions in China and sulfur trends in East Asia since 2000
journal, January 2010
- Lu, Z.; Streets, D. G.; Zhang, Q.
- Atmospheric Chemistry and Physics, Vol. 10, Issue 13
Climate Effects of Aerosol-Cloud Interactions
journal, January 2014
- Rosenfeld, D.; Sherwood, S.; Wood, R.
- Science, Vol. 343, Issue 6169
A fast and sensitive new satellite SO 2 retrieval algorithm based on principal component analysis: Application to the ozone monitoring instrument : NEW OMI PCA SO
journal, December 2013
- Li, Can; Joiner, Joanna; Krotkov, Nickolay A.
- Geophysical Research Letters, Vol. 40, Issue 23
Atmospheric aerosol compositions in China: spatial/temporal variability, chemical signature, regional haze distribution and comparisons with global aerosols
journal, January 2011
- Zhang, X. Y.; Wang, Y. Q.; Niu, T.
- Atmospheric Chemistry and Physics Discussions, Vol. 11, Issue 9
The global aerosol‐cloud first indirect effect estimated using MODIS, MERRA, and AeroCom
journal, February 2017
- McCoy, D. T.; Bender, F. A. ‐M.; Mohrmann, J. K. C.
- Journal of Geophysical Research: Atmospheres, Vol. 122, Issue 3
Atmospheric aerosol compositions in China: spatial/temporal variability, chemical signature, regional haze distribution and comparisons with global aerosols
journal, January 2012
- Zhang, X. Y.; Wang, Y. Q.; Niu, T.
- Atmospheric Chemistry and Physics, Vol. 12, Issue 2
The Community Earth System Model: A Framework for Collaborative Research
journal, September 2013
- Hurrell, James W.; Holland, M. M.; Gent, P. R.
- Bulletin of the American Meteorological Society, Vol. 94, Issue 9
Using an explicit emission tagging method in global modeling of source-receptor relationships for black carbon in the Arctic: Variations, sources, and transport pathways: Source attribution of BC in the Arctic
journal, November 2014
- Wang, Hailong; Rasch, Philip J.; Easter, Richard C.
- Journal of Geophysical Research: Atmospheres, Vol. 119, Issue 22
Aerosol indirect effects in a multi-scale aerosol-climate model PNNL-MMF
journal, January 2011
- Wang, M.; Ghan, S.; Ovchinnikov, M.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 11
Acidic Deposition in the Northeastern United States: Sources and Inputs, Ecosystem Effects, and Management Strategies
journal, January 2001
- Driscoll, Charles T.; Lawrence, Gregory B.; Bulger, Arthur J.
- BioScience, Vol. 51, Issue 3
Transport and Chemical Evolution over the Pacific (TRACE-P) aircraft mission: Design, execution, and first results
journal, January 2003
- Jacob, Daniel J.
- Journal of Geophysical Research, Vol. 108, Issue D20
Anthropogenic sulfur dioxide emissions: 1850–2005
journal, January 2011
- Smith, S. J.; van Aardenne, J.; Klimont, Z.
- Atmospheric Chemistry and Physics, Vol. 11, Issue 3
Persistent sulfate formation from London Fog to Chinese haze
journal, November 2016
- Wang, Gehui; Zhang, Renyi; Gomez, Mario E.
- Proceedings of the National Academy of Sciences, Vol. 113, Issue 48
Evaluating inter-continental transport of fine aerosols: (1) Methodology, global aerosol distribution and optical depth
journal, September 2009
- Liu, Junfeng; Mauzerall, Denise L.; Horowitz, Larry W.
- Atmospheric Environment, Vol. 43, Issue 28
Sulfur dioxide emissions in Asia in the period 1985–1997
journal, August 2000
- Streets, David G.; Tsai, Nancy Y.; Akimoto, Hajime
- Atmospheric Environment, Vol. 34, Issue 26
Response of sulphur dynamics in European catchments to decreasing sulphate deposition
journal, January 2001
- Prechtel, A.; Alewell, C.; Armbruster, M.
- Hydrology and Earth System Sciences, Vol. 5, Issue 3
Untangling aerosol effects on clouds and precipitation in a buffered system
journal, October 2009
- Stevens, Bjorn; Feingold, Graham
- Nature, Vol. 461, Issue 7264
Space-based detection of missing sulfur dioxide sources of global air pollution
journal, May 2016
- McLinden, Chris A.; Fioletov, Vitali; Shephard, Mark W.
- Nature Geoscience, Vol. 9, Issue 7
Haze, air pollution, and health in China
journal, December 2013
- Xu, Peng; Chen, Yongfen; Ye, Xiaojian
- The Lancet, Vol. 382, Issue 9910
Source attribution of black carbon and its direct radiative forcing in China
journal, January 2017
- Yang, Yang; Wang, Hailong; Smith, Steven J.
- Atmospheric Chemistry and Physics, Vol. 17, Issue 6
Anthropogenic sulfur dioxide emissions: 1850–2005
journal, January 2010
- Smith, S. J.; van Aardenne, J.; Klimont, Z.
- Atmospheric Chemistry and Physics Discussions, Vol. 10, Issue 6
Aqueous oxidation of sulfur dioxide by hydrogen peroxide at low pH
journal, January 1981
- Robbin Martin, L.; Damschen, Donald E.
- Atmospheric Environment (1967), Vol. 15, Issue 9
Source-receptor relationships between East Asian sulfur dioxide emissions and Northern Hemisphere sulfate concentrations
journal, January 2008
- Liu, J.; Mauzerall, D. L.; Horowitz, L. W.
- Atmospheric Chemistry and Physics, Vol. 8, Issue 14
Transpacific transport of Asian anthropogenic aerosols and its impact on surface air quality in the United States
journal, January 2006
- Heald, Colette L.; Jacob, Daniel J.; Park, Rokjin J.
- Journal of Geophysical Research, Vol. 111, Issue D14
Six ‘new’ episodes of trans-Pacific transport of air pollutants
journal, January 2003
- Jaffe, Dan; McKendry, Ian; Anderson, Tad
- Atmospheric Environment, Vol. 37, Issue 3
Trans-Pacific transport of black carbon and fine aerosols ( D < 2.5 μ m) into North America
journal, January 2007
- Hadley, O. L.; Ramanathan, V.; Carmichael, G. R.
- Journal of Geophysical Research, Vol. 112, Issue D5
Global and regional radiative forcing from 20 % reductions in BC, OC and
SO 4 – an HTAP2 multi-model study
journal, January 2016
- Stjern, Camilla Weum; Samset, Bjørn Hallvard; Myhre, Gunnar
- Atmospheric Chemistry and Physics, Vol. 16, Issue 21
Global indirect aerosol effects: a review
journal, January 2004
- Lohmann, U.; Feichter, J.
- Atmospheric Chemistry and Physics Discussions, Vol. 4, Issue 6
Natural and transboundary pollution influences on sulfate-nitrate-ammonium aerosols in the United States: Implications for policy
journal, January 2004
- Park, Rokjin J.
- Journal of Geophysical Research, Vol. 109, Issue D15
Exposure to ambient black carbon derived from a unique inventory and high-resolution model
journal, January 2014
- Wang, R.; Tao, S.; Balkanski, Y.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 7
A parameterization of aerosol activation: 2. Multiple aerosol types
journal, March 2000
- Abdul-Razzak, Hayder; Ghan, Steven J.
- Journal of Geophysical Research: Atmospheres, Vol. 105, Issue D5
Aerosols from Overseas Rival Domestic Emissions over North America
journal, August 2012
- Yu, H.; Remer, L. A.; Chin, M.
- Science, Vol. 337, Issue 6094
Technical Note: Estimating aerosol effects on cloud radiative forcing
journal, January 2013
- Ghan, S. J.
- Atmospheric Chemistry and Physics, Vol. 13, Issue 19
Technical Note: On the use of nudging for aerosol–climate model intercomparison studies
journal, January 2014
- Zhang, K.; Wan, H.; Liu, X.
- Atmospheric Chemistry and Physics, Vol. 14, Issue 16
Regional and seasonal radiative forcing by perturbations to aerosol and ozone precursor emissions
journal, January 2016
- Bellouin, Nicolas; Baker, Laura; Hodnebrog, Øivind
- Atmospheric Chemistry and Physics, Vol. 16, Issue 21
Intercontinental transport of pollution and dust aerosols: implications for regional air quality
journal, January 2007
- Chin, Mian; Diehl, T.; Ginoux, P.
- Atmospheric Chemistry and Physics, Vol. 7, Issue 21
A multimodel assessment of the influence of regional anthropogenic emission reductions on aerosol direct radiative forcing and the role of intercontinental transport: AEROSOL INTERCONTINENTAL TRANSPORT
journal, January 2013
- Yu, Hongbin; Chin, Mian; West, J. Jason
- Journal of Geophysical Research: Atmospheres, Vol. 118, Issue 2
Potential influence of inter-continental transport of sulfate aerosols on air quality
journal, October 2007
- Liu, Junfeng; Mauzerall, Denise L.
- Environmental Research Letters, Vol. 2, Issue 4
The Community Earth System Model: A Framework for Collaborative Research
journal, February 2013
- Hurrell, James W.; Holland, M. M.; Gent, P. R.
- Bulletin of the American Meteorological Society
Sensitivity of remote aerosol distributions to representation of cloud-aerosol interactions in a global climate model
journal, January 2013
- Wang, H.; Easter, R. C.; Rasch, P. J.
- Geoscientific Model Development Discussions, Vol. 6, Issue 1
Global indirect aerosol effects: a review
text, January 2005
- Lohmann, Ulrike; Feichter, Johann
- ETH Zurich
Radiative forcing in the ACCMIP historical and future climate simulations
journal, January 2012
- Shindell, D. T.; Lamarque, J. -F.; Schulz, M.
- Atmospheric Chemistry and Physics Discussions, Vol. 12, Issue 8
Historical (1750–2014) anthropogenic emissions of reactive gases and aerosols from the Community Emissions Data System (CEDS)
journal, January 2018
- Hoesly, Rachel M.; Smith, Steven J.; Feng, Leyang
- Geoscientific Model Development, Vol. 11, Issue 1
Technical note: On the use of nudging for aerosol-climate model intercomparison studies
text, January 2014
- Kai, Zhang,; Hui, Wan,; Xiaohong, Liu,
- ETH Zurich
Works referencing / citing this record:
Anthropogenic fine particulate matter pollution will be exacerbated in eastern China due to 21st century GHG warming
journal, January 2019
- Chen, Huopo; Wang, Huijun; Sun, Jianqi
- Atmospheric Chemistry and Physics, Vol. 19, Issue 1
Recent intensification of winter haze in China linked to foreign emissions and meteorology
journal, February 2018
- Yang, Yang; Wang, Hailong; Smith, Steven J.
- Scientific Reports, Vol. 8, Issue 1
Interannual variability and trends of combustion aerosol and dust in major continental outflows revealed by MODIS retrievals and CAM5 simulations during 2003–2017
journal, January 2020
- Yu, Hongbin; Yang, Yang; Wang, Hailong
- Atmospheric Chemistry and Physics, Vol. 20, Issue 1
A light-driven burst of hydroxyl radicals dominates oxidation chemistry in newly activated cloud droplets
journal, May 2019
- Paulson, Suzanne E.; Gallimore, Peter J.; Kuang, Xiaobi M.
- Science Advances, Vol. 5, Issue 5
African volcanic emissions influencing atmospheric aerosols over the Amazon rain forest
journal, January 2018
- Saturno, Jorge; Ditas, Florian; Penning de Vries, Marloes
- Atmospheric Chemistry and Physics, Vol. 18, Issue 14
Modeling of aerosol property evolution during winter haze episodes over a megacity cluster in northern China: roles of regional transport and heterogeneous reactions of SO2
journal, January 2019
- Du, Huiyun; Li, Jie; Chen, Xueshun
- Atmospheric Chemistry and Physics, Vol. 19, Issue 14
A light-driven burst of hydroxyl radicals dominates oxidation chemistry in newly activated cloud droplets.
text, January 2019
- Paulson, Suzanne E.; Gallimore, Peter; Kuang, Xiaobi M.
- Apollo - University of Cambridge Repository