Insight into the phase evolution of a NiMgAl catalyst from the reduction stage to the post-reaction stage during the dry reforming of methane [Insight into the phase evolution of NiMgAl catalyst from reduction to post-reaction for dry reforming of methane]
Abstract
Herein, phase evolution of a NiMgAl oxide catalyst at the reduction stage was qualitatively analysed and quantitatively determined by employing the continuous changes in its XRD intensity and TPR information. In conclusion, the stable crystallite size of both the active metal and spinel support was responsible for the long stability of the NiMgAl catalyst without carbon deposition during the DRM reaction.
- Authors:
-
- Mississippi State Univ., Mississippi State, MS (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- U.S. Department of Agriculture (USDA); USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division
- OSTI Identifier:
- 1372485
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Accepted Manuscript
- Journal Name:
- ChemComm
- Additional Journal Information:
- Journal Volume: 53; Journal Issue: 44; Journal ID: ISSN 1359-7345
- Publisher:
- Royal Society of Chemistry
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
Citation Formats
Bao, Zhenghong, Zhan, Yiqiu, Street, Jason, Xu, Wenqian, To, Filip, and Yu, Fei. Insight into the phase evolution of a NiMgAl catalyst from the reduction stage to the post-reaction stage during the dry reforming of methane [Insight into the phase evolution of NiMgAl catalyst from reduction to post-reaction for dry reforming of methane]. United States: N. p., 2017.
Web. doi:10.1039/C7CC03094K.
Bao, Zhenghong, Zhan, Yiqiu, Street, Jason, Xu, Wenqian, To, Filip, & Yu, Fei. Insight into the phase evolution of a NiMgAl catalyst from the reduction stage to the post-reaction stage during the dry reforming of methane [Insight into the phase evolution of NiMgAl catalyst from reduction to post-reaction for dry reforming of methane]. United States. https://doi.org/10.1039/C7CC03094K
Bao, Zhenghong, Zhan, Yiqiu, Street, Jason, Xu, Wenqian, To, Filip, and Yu, Fei. Thu .
"Insight into the phase evolution of a NiMgAl catalyst from the reduction stage to the post-reaction stage during the dry reforming of methane [Insight into the phase evolution of NiMgAl catalyst from reduction to post-reaction for dry reforming of methane]". United States. https://doi.org/10.1039/C7CC03094K. https://www.osti.gov/servlets/purl/1372485.
@article{osti_1372485,
title = {Insight into the phase evolution of a NiMgAl catalyst from the reduction stage to the post-reaction stage during the dry reforming of methane [Insight into the phase evolution of NiMgAl catalyst from reduction to post-reaction for dry reforming of methane]},
author = {Bao, Zhenghong and Zhan, Yiqiu and Street, Jason and Xu, Wenqian and To, Filip and Yu, Fei},
abstractNote = {Herein, phase evolution of a NiMgAl oxide catalyst at the reduction stage was qualitatively analysed and quantitatively determined by employing the continuous changes in its XRD intensity and TPR information. In conclusion, the stable crystallite size of both the active metal and spinel support was responsible for the long stability of the NiMgAl catalyst without carbon deposition during the DRM reaction.},
doi = {10.1039/C7CC03094K},
journal = {ChemComm},
number = 44,
volume = 53,
place = {United States},
year = {Thu May 04 00:00:00 EDT 2017},
month = {Thu May 04 00:00:00 EDT 2017}
}
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Works referenced in this record:
A Selection of Recent Advances in C1 Chemistry
journal, June 2016
- Mesters, Carl
- Annual Review of Chemical and Biomolecular Engineering, Vol. 7, Issue 1
Steam Reforming of Ethanol on Ni/CeO 2 : Reaction Pathway and Interaction between Ni and the CeO 2 Support
journal, April 2013
- Xu, Wenqian; Liu, Zongyuan; Johnston-Peck, Aaron C.
- ACS Catalysis, Vol. 3, Issue 5
In situ studies of CeO2-supported Pt, Ru, and Pt–Ru alloy catalysts for the water–gas shift reaction: Active phases and reaction intermediates
journal, July 2012
- Xu, Wenqian; Si, Rui; Senanayake, Sanjaya D.
- Journal of Catalysis, Vol. 291
Design of modular catalysts derived from NiMgAl-LDH@m-SiO2 with dual confinement effects for dry reforming of methane
journal, January 2013
- Du, Xianjun; Zhang, Dengsong; Gao, Ruihua
- Chemical Communications, Vol. 49, Issue 60
Lithium Insertion in Copper, Indium, Tin Thiospinels Characterized by 119 Sn Mössbauer Spectroscopy and Rietveld Analysis
journal, May 2000
- Dedryvère, R.; Olivier-Fourcade, J.; Jumas, J. C.
- Chemistry of Materials, Vol. 12, Issue 5
In situ observations of lattice expansion and transformation rates of α and β phases in Ti–6Al–4V
journal, January 2005
- Elmer, J. W.; Palmer, T. A.; Babu, S. S.
- Materials Science and Engineering: A, Vol. 391, Issue 1-2
Time-resolved in situ powder X-ray diffraction reveals the mechanisms of molten salt synthesis
journal, January 2016
- Moorhouse, Saul J.; Wu, Yue; Buckley, Hannah C.
- Chemical Communications, Vol. 52, Issue 96
Coke- and sintering-resistant monolithic catalysts derived from in situ supported hydrotalcite-like films on Al wires for dry reforming of methane
journal, January 2013
- Du, Xianjun; Zhang, Dengsong; Shi, Liyi
- Nanoscale, Vol. 5, Issue 7
Promotional effects of rare earth elements (Sc, Y, Ce, and Pr) on NiMgAl catalysts for dry reforming of methane
journal, January 2016
- Cao, Yang; Li, Hongrui; Zhang, Jianping
- RSC Advances, Vol. 6, Issue 113
In situ X-ray diffraction study of irradiation-induced lattice expansion in Al foils by MeV-energy heavy ions
journal, April 2016
- Minagawa, Hideaki; Tsuchida, Hidetsugu; Murase, Ryu
- Nuclear Instruments and Methods in Physics Research Section B: Beam Interactions with Materials and Atoms, Vol. 372
In situ TEM observation of the structural transformation of rutile TiO 2 nanowire during electrochemical lithiation
journal, January 2014
- Kim, Sung Joo; Noh, Sun-Young; Kargar, Alireza
- Chemical Communications, Vol. 50, Issue 69
CO 2 Reforming of CH 4
journal, February 1999
- Bradford, M. C. J.; Vannice, M. A.
- Catalysis Reviews, Vol. 41, Issue 1
In situ X-ray diffraction of CaO based CO2 sorbents
journal, January 2012
- Molinder, R.; Comyn, T. P.; Hondow, N.
- Energy & Environmental Science, Vol. 5, Issue 10
In situ studies of a platform for metastable inorganic crystal growth and materials discovery
journal, July 2014
- Shoemaker, D. P.; Hu, Y. -J.; Chung, D. Y.
- Proceedings of the National Academy of Sciences, Vol. 111, Issue 30
Characterization of Ca-promoted Ni/α-Al2O3 catalyst for CH4 reforming with CO2
journal, October 2003
- Hou, Z.
- Applied Catalysis A: General, Vol. 253, Issue 2
Spray pyrolytic deposition of transparent aluminum oxide (Al2O3) films
journal, November 2011
- Dhonge, Baban P.; Mathews, Tom; Sundari, S. Tripura
- Applied Surface Science, Vol. 258, Issue 3
Kinetic study of methane reforming with carbon dioxide over NiCeMgAl bimodal pore catalyst
journal, November 2016
- Bao, Zhenghong; Lu, Yongwu; Yu, Fei
- AIChE Journal, Vol. 63, Issue 6
Synthesis, characterization and catalytic performances of Ce-SBA-15 supported nickel catalysts for methane dry reforming to hydrogen and syngas
journal, January 2012
- Wang, Ning; Chu, Wei; Zhang, Tao
- International Journal of Hydrogen Energy, Vol. 37, Issue 1
In Situ X-ray Absorption Spectroscopy Investigation of a Bifunctional Manganese Oxide Catalyst with High Activity for Electrochemical Water Oxidation and Oxygen Reduction
journal, June 2013
- Gorlin, Yelena; Lassalle-Kaiser, Benedikt; Benck, Jesse D.
- Journal of the American Chemical Society, Vol. 135, Issue 23
In situ XRD characterization of LaNiAlO model catalysts for CO2 reforming of methane
journal, October 1996
- Slagtern, A.; Olsbye, U.; Blom, R.
- Applied Catalysis A: General, Vol. 145, Issue 1-2
Highly active and stable Ni-based bimodal pore catalyst for dry reforming of methane
journal, February 2015
- Bao, Zhenghong; Lu, Yongwu; Han, Jun
- Applied Catalysis A: General, Vol. 491
Crystal Structure and the Paraelectric-to-Ferroelectric Phase Transition of Nanoscale BaTiO 3
journal, June 2008
- Smith, Millicent B.; Page, Katharine; Siegrist, Theo
- Journal of the American Chemical Society, Vol. 130, Issue 22
Enhanced Carbon-Resistant Dry Reforming Fe-Ni Catalyst: Role of Fe
journal, March 2015
- Theofanidis, Stavros Alexandros; Galvita, Vladimir V.; Poelman, Hilde
- ACS Catalysis, Vol. 5, Issue 5
Facile Route for Synthesizing Ordered Mesoporous Ni–Ce–Al Oxide Materials and Their Catalytic Performance for Methane Dry Reforming to Hydrogen and Syngas
journal, June 2013
- Wang, Ning; Shen, Kui; Huang, Lihong
- ACS Catalysis, Vol. 3, Issue 7
Capturing metal-support interactions in situ during the reduction of a Re promoted Co/γ-Al 2 O 3 catalyst
journal, January 2016
- Tsakoumis, N. E.; Johnsen, R. E.; van Beek, W.
- Chemical Communications, Vol. 52, Issue 15
Works referencing / citing this record:
A comparative study on the NO x storage and reduction performance of Pt/Ni 1 Mg 2 Al 1 O x and Pt/Mn 1 Mg 2 Al 1 O x catalysts
journal, January 2020
- Zhang, Cheng; Gao, Yanshan; Altaf, Naveed
- Dalton Transactions, Vol. 49, Issue 13