Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods

Xu, Feng; Wu, Lijun; Meng, Qingping; Kaltak, Merzuk; Huang, Jianping; Durham, Jessica L.; Fernandez-Serra, Marivi; Sun, Litao; Marschilok, Amy C.; Takeuchi, Esther S.; Takeuchi, Kenneth J.; Hybertsen, Mark S.; Zhu, Yimei

doi:10.1038/ncomms15400

Title: Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods

Abstract

Multiple lithium-ion transport pathways and local phase changes upon lithiation in silver hollandite are revealed via in situ microscopy including electron diffraction, imaging and spectroscopy, coupled with density functional theory and phase field calculations. Here, we report unexpected inter-nanorod lithium-ion transport, where the reaction fronts and kinetics are maintained within the neighbouring nanorod. Notably, this is the first time-resolved visualization of lithium-ion transport within and between individual nanorods, where the impact of oxygen deficiencies is delineated. Initially, fast lithium-ion transport is observed along the long axis with small net volume change, resulting in two lithiated silver hollandite phases distinguishable by orthorhombic distortion. As a result, a slower reaction front is observed, with formation of polyphase lithiated silver hollandite and face-centred-cubic silver metal with substantial volume expansion. Our results indicate lithium-ion transport is not confined within a single nanorod and may provide a paradigm shift for one-dimensional tunnelled materials, particularly towards achieving high-rate capability.

Authors:

Xu, Feng ^[1]; Wu, Lijun ^[2]; Meng, Qingping ^[2]; Kaltak, Merzuk ^[3];

^[4]; Durham, Jessica L. ^[4]; Fernandez-Serra, Marivi ^[5];

^[6]; Marschilok, Amy C. ^[7]; Takeuchi, Esther S. ^[8]; Takeuchi, Kenneth J. ^[7]; Hybertsen, Mark S. ^[9]; Zhu, Yimei ^[2]

Southeast Univ., Nanjing (China). SEU-FEI Nano-Pico Center; Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.
Brookhaven National Lab. (BNL), Upton, NY (United States). Condensed Matter Physics and Materials Science Dept.
Stony Brook Univ., NY (United States). Dept. of Physics and Astronomy
Stony Brook Univ., NY (United States). Dept. of Chemistry
Stony Brook Univ., NY (United States). Dept. of Physics and Astronomy and Inst. for Advanced Computational Science
Southeast Univ., Nanjing (China). SEU-FEI Nano-Pico Center
Stony Brook Univ., NY (United States). Dept. of Chemistry and Dept. of Materials Science and Engineering
Stony Brook Univ., NY (United States). Dept. of Chemistry and Dept. of Materials Science and Engineering; Brookhaven National Lab. (BNL), Upton, NY (United States). Energy Sciences Directorate
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials

Publication Date:: Wed May 24 00:00:00 EDT 2017

Research Org.:: Brookhaven National Laboratory (BNL), Upton, NY (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1372453

Report Number(s):: BNL-114057-2017-JA
Journal ID: ISSN 2041-1723; R&D Project: MA015MACA; KC0201010

Grant/Contract Number:: SC00112704; SC0012673; SC0012704; AC02-05CH11231

Resource Type:: Accepted Manuscript

Journal Name:: Nature Communications

Additional Journal Information:: Journal Volume: 8; Journal ID: ISSN 2041-1723

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY; 25 ENERGY STORAGE; batteries

Citation Formats


                    Xu, Feng, Wu, Lijun, Meng, Qingping, Kaltak, Merzuk, Huang, Jianping, Durham, Jessica L., Fernandez-Serra, Marivi, Sun, Litao, Marschilok, Amy C., Takeuchi, Esther S., Takeuchi, Kenneth J., Hybertsen, Mark S., and Zhu, Yimei. Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods.  United States: N. p., 2017. 
Web.  doi:10.1038/ncomms15400.

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                    Xu, Feng, Wu, Lijun, Meng, Qingping, Kaltak, Merzuk, Huang, Jianping, Durham, Jessica L., Fernandez-Serra, Marivi, Sun, Litao, Marschilok, Amy C., Takeuchi, Esther S., Takeuchi, Kenneth J., Hybertsen, Mark S., & Zhu, Yimei. Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods.  United States.  https://doi.org/10.1038/ncomms15400

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                    Xu, Feng, Wu, Lijun, Meng, Qingping, Kaltak, Merzuk, Huang, Jianping, Durham, Jessica L., Fernandez-Serra, Marivi, Sun, Litao, Marschilok, Amy C., Takeuchi, Esther S., Takeuchi, Kenneth J., Hybertsen, Mark S., and Zhu, Yimei. Wed .  
"Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods".  United States.  https://doi.org/10.1038/ncomms15400.  https://www.osti.gov/servlets/purl/1372453.

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@article{osti_1372453,

  title        = {Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods},

  author       = {Xu, Feng and Wu, Lijun and Meng, Qingping and Kaltak, Merzuk and Huang, Jianping and Durham, Jessica L. and Fernandez-Serra, Marivi and Sun, Litao and Marschilok, Amy C. and Takeuchi, Esther S. and Takeuchi, Kenneth J. and Hybertsen, Mark S. and Zhu, Yimei},

  abstractNote = {Multiple lithium-ion transport pathways and local phase changes upon lithiation in silver hollandite are revealed via in situ microscopy including electron diffraction, imaging and spectroscopy, coupled with density functional theory and phase field calculations. Here, we report unexpected inter-nanorod lithium-ion transport, where the reaction fronts and kinetics are maintained within the neighbouring nanorod. Notably, this is the first time-resolved visualization of lithium-ion transport within and between individual nanorods, where the impact of oxygen deficiencies is delineated. Initially, fast lithium-ion transport is observed along the long axis with small net volume change, resulting in two lithiated silver hollandite phases distinguishable by orthorhombic distortion. As a result, a slower reaction front is observed, with formation of polyphase lithiated silver hollandite and face-centred-cubic silver metal with substantial volume expansion. Our results indicate lithium-ion transport is not confined within a single nanorod and may provide a paradigm shift for one-dimensional tunnelled materials, particularly towards achieving high-rate capability.},

  doi          = {10.1038/ncomms15400},

  journal      = {Nature Communications},

  number       = ,

  volume       = 8,

  place        = {United States},

  year         = {Wed May 24 00:00:00 EDT 2017},

  month        = {Wed May 24 00:00:00 EDT 2017}

}

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Structural Defects of Silver Hollandite, Ag_xMn₈O_y, Nanorods: Dramatic Impact on Electrochemistry

Journal Article Wu, Lijun ; Xu, Feng ; Zhu, Yimei ; ... - ACS Nano

Hollandites (OMS-2) are an enticing class of sorbents, catalysts, and energy storage materials with a tunnel structure permitting one-dimensional insertion and deinsertion of ions and small molecules along the c direction. A 7-fold increase in delivered capacity for Li/Ag_xMn₈O₁₆ electrochemical cells (160 versus 23 mAh/g) observed upon a seemingly small change in silver content (x ~1.1 (L-Ag-OMS-2) and 1.6 (H-Ag-OMS-2)) led us to characterize the structure and defects of the silver hollandite material. In this work, Ag hollandite nanorods are studied through the combined use of local (atomic imaging, electron diffraction, electron energy-loss spectroscopy) and bulk (synchrotron based X-ray diffraction,more »« less
Cited by 77
https://doi.org/10.1021/acsnano.5b03274

Full Text Available
Silver-Containing α-MnO₂ Nanorods: Electrochemistry in Na-Based Battery Systems

Journal Article Huang, Jianping ; Poyraz, Altug S. ; Lee, Seung-Yong ; ... - ACS Applied Materials and Interfaces

Manganese oxides are considered attractive cathode materials for rechargeable batteries due to the high abundance and environmental friendliness of manganese. In particular, cryptomelane and hollandite are desirable due to their ability to host cations within their octahedral molecular sieve (OMS-2) Alpha-MnO₂ structure. In this work, we investigate silver containing Alpha-MnO₂ structured materials (Ag_xMn₈O₁₆, x = 1.22, L-Ag-OMS-2 or 1.66, H-Ag-OMS-2) as host materials for Li ion and Na ion insertion/de-insertion. The results indicate a significant difference in the lithiation versus sodiation process the OMS-2 materials. Initial reduction of Ag_1.22Mn₈O₁₆ to 1.0 V delivered ~370 mAh/g. Cycling of Ag1.22Mn8O16 between voltagemore »« less
Cited by 35
https://doi.org/10.1021/acsami.6b08549

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Tailoring the Ag⁺ Content within the Tunnels and on the Exposed Surfaces of α-MnO₂ Nanowires: Impact on Impedance and Electrochemistry

Journal Article Zhang, Bingjie ; Smith, Paul F. ; Lee, Seung-Yong ; ... - Journal of the Electrochemical Society

Efficient conduction of both electrons and cations (e.g., Li⁺) has a profound effect on the current and capacity of lithium-based batteries. With this study, we focus on cathode effects, with the preparation of pure silver hollandite materials with variable silver ion content within (intra-tunnel) and on the surface of α-MnO₂ tunneled materials, followed by the measurement and analysis of impedance and electrochemistry data. Specifically, pure Ag_xMn₈O_16-y materials with low (x = 1.13) and high (x = 1.54) intra-tunnel silver content are compared with Ag_xMn₈O_16-y·aAg₂O (a = 0.25, 0.63, 1.43) composites prepared via a new Ag₂O coating strategy. When the Ag₂Omore »« less
Cited by 9
https://doi.org/10.1149/2.0261701jes

Full Text Available
Multiple-stripe lithiation mechanism of individual SnO2 nanowires in a flooding geometry

Journal Article Zhong, Li ; Liu, Xiao H. ; Wang, G. F. ; ... - Physical Review Letters, 106(24):Article No. 248302

The atomic scale lithiation mechanism of individual SnO2 nanowires in a flooding geometry with the entire wires being immersed in the electrolyte was revealed by in-situ transmission electron microscopy. The lithiation initiated multiple stripes with width of a few nanometer parallel to {020} planes transversing the entire wires, serving as multiple reaction fronts for late stage of lithiation. Inside the stripes, we identified high density of dislocations and enlarged inter-planar spacing, which provide effective path for lithium ion transport. The density of the stripes increased with further lithiation, and eventually they merged with one another, causing a large enlongation andmore »« less
https://doi.org/10.1103/PhysRevLett.106.248302

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Title: Visualization of lithium-ion transport and phase evolution within and between manganese oxide nanorods

Abstract

Citation Formats

Generalized Gradient Approximation Made Simple journal, October 1996

Synthesis and Characterization of Ag−Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation journal, August 2007

Structural, Magnetic and Electronic Transport Properties of Novel Hollandite-Type Molybdenum Oxide, Rb 1.5 Mo 8 O 16 journal, January 2006

Electrochemical investigation of CrO2.65 doped LiMn2O4 as a cathode material for lithium-ion batteries journal, November 1998

Structural Defects of Silver Hollandite, Ag x Mn 8 O y , Nanorods: Dramatic Impact on Electrochemistry journal, July 2015

Lithium ion insertion and extraction reactions with Hollandite-type manganese dioxide free from any stabilizing cations in its tunnel cavity journal, September 2005

From ultrasoft pseudopotentials to the projector augmented-wave method journal, January 1999

Tracking lithium transport and electrochemical reactions in nanoparticles journal, January 2012

Determination of the Kinetic Parameters of Mixed-Conducting Electrodes and Application to the System Li[sub 3]Sb journal, January 1977

Suppression of Phase Separation in LiFePO4 Nanoparticles During Battery Discharge text, January 2011

Suppression of Phase Separation in LiFePO 4 Nanoparticles During Battery Discharge journal, November 2011

Lead palladium titanate: A room temperature nanoscale multiferroic thin film journal, February 2020

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data journal, October 2011

Particle Size Dependence of the Ionic Diffusivity journal, October 2010

Oxidation state and chemical shift investigation in transition metal oxides by EELS journal, May 2012

Microwave-Assisted Hydrothermal Synthesis of Cryptomelane-Type Octahedral Molecular Sieves (OMS-2) and Their Catalytic Studies journal, June 2010

First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method journal, January 1997

First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method journal, January 1997

Selective exchange of divalent transition metal ions in cryptomelane-type manganic acid with tunnel structure journal, March 1993

Large-Agglomerate-Size Lithium Manganese Oxide Spinel with High Rate Capability for Lithium-Ion Batteries journal, January 2000

High-resolution X-ray luminescence extension imaging journal, February 2021

Synthesis and Characterization of Silver Hollandite and Its Application in Emission Control journal, August 2005

Silver-Containing α-MnO 2 Nanorods: Electrochemistry in Na-Based Battery Systems journal, September 2016

Synthetic Control of Composition and Crystallite Size of Silver Hollandite, Ag x Mn 8 O 16 : Impact on Electrochemistry journal, September 2012

Particle Size Dependence of the Ionic Diffusivity journal, October 2010

First-principles study of Li ion diffusion in LiFePO 4 journal, March 2004

Synthetic Routes to Microporous Manganese Oxides journal, October 1997

Asynchronous Crystal Cell Expansion during Lithiation of K + -Stabilized α-MnO 2 journal, April 2015

Synthesis and Electrochemistry of Silver Hollandite journal, January 2010

The Electrochemistry of Silver Hollandite Nanorods, Ag x Mn 8 O 16 : Enhancement of Electrochemical Battery Performance via Dimensional and Compositional Control journal, January 2013

Free Energy of a Nonuniform System. I. Interfacial Free Energy journal, February 1958

Improved electrochemical performance of nitrogen doped TiO 2 -B nanowires as anode materials for Li-ion batteries journal, January 2015

Todorokite-type manganese oxide nanowires as an intercalation cathode for Li-ion and Na-ion batteries journal, January 2015

AC Impedance Analysis for Li[sup +] Insertion of a Pt∕λ-MnO[sub 2] Electrode in an Aqueous Phase journal, January 1996

Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation journal, August 2011

Direct Sonochemical Synthesis of Manganese Octahedral Molecular Sieve (OMS-2) Nanomaterials Using Cosolvent Systems, Their Characterization, and Catalytic Applications journal, February 2012

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set journal, July 1996

Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation journal, August 2011

Synthesis and lithium ion insertion/extraction properties of hollandite-type MnO2 prepared by acid digestion of Mn2O3 journal, May 2009

Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect journal, February 2020

Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics journal, June 2012

The structure of K 1.33 Mn 8 O 16 and cation ordering in hollandite-type structures journal, April 1986

Lithium insertion and extraction properties of hollandite-type KxTiO2 with different K content in the tunnel space journal, July 2013

Synthesis and Characterization of Silver Hollandite and Its Application in Emission Control. journal, November 2005

Synthesis and Characterization of Ag—Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation. journal, October 2007

Synthetic Control of Composition and Crystallite Size of Silver Hollandite, Ag x Mn 8 O 16 : Impact on Electrochemistry journal, September 2012

Effects of Cu 2+ Ions on the Structure and Reactivity of Todorokite- and Cryptomelane-Type Manganese Oxide Octahedral Molecular Sieves journal, July 1999

Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films journal, January 1980

Synthetic Routes to Microporous Manganese Oxides journal, October 1997

Ag1.8Mn8O16: Square Planar Coordinated Ag⊕ Ions in the Channels of a Novel Hollandite Variant journal, November 1984

Tracking lithium transport and electrochemical reactions in nanoparticles journal, January 2012

Sorption Behavior of Radionuclides on Crystalline Synthetic Tunnel Manganese Oxides journal, December 2000

Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets journal, May 2021

Synthesis and characterization of the hollandite-type MnO2 as a cathode material in lithium batteries journal, March 2000

A Review of Porous Manganese Oxide Materials journal, October 1998

Electrochemistry of Hollandite α-MnO 2 : Li-Ion and Na-Ion Insertion and Li 2 O Incorporation journal, June 2013

Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics journal, June 2012

Structural Defects of Silver Hollandite, Ag x Mn 8 O y , Nanorods: Dramatic Impact on Electrochemistry journal, July 2015

Thermodynamic and Mass Transport Properties of “LiAl” journal, January 1979

Importance of anisotropic Coulomb interactions and exchange to the band gap and antiferromagnetism of β -MnO 2 from DFT+ U journal, November 2012

Energy storage: The future enabled by nanomaterials journal, November 2019

In situ imaging of electrocatalysis in a K–O 2 battery with a hollandite α-MnO 2 nanowire air cathode journal, January 2019

Crystallographic-orientation dependent Li ion migration and reactions in layered MoSe 2 journal, May 2019

In Situ Visualization of Interfacial Sodium Transport and Electrochemistry between Few‐Layer Phosphorene journal, May 2019

Tunable nanomechanical performance regimes in ceramic nanowires journal, September 2019

Charge localization and ordering in A 2 Mn 8 O 16 hollandite group oxides: Impact of density functional theory approaches journal, December 2017

Silver-Containing α-MnO 2 Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO 2 Batteries journal, January 2019

Non-uniform Stress-free Strains in a Spherically Symmetrical Nano-sized Particle and Its Applications to Lithium-ion Batteries journal, March 2018

In situ interface engineering for probing the limit of quantum dot photovoltaic devices journal, August 2019

Defect Control in the Synthesis of 2 D MoS 2 Nanosheets: Polysulfide Trapping in Composite Sulfur Cathodes for Li–S Batteries journal, March 2020

Non-uniform Stress-free Strains in a Spherically Symmetrical Nano-sized Particle and Its Applications to Lithium-ion Batteries journal, March 2018

Temperature‐dependent electrical transport behavior and structural evolution in hollandite‐type titanium‐based oxide journal, May 2019

Generalized Gradient Approximation Made Simple
journal, October 1996

Synthesis and Characterization of Ag−Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation
journal, August 2007

Structural, Magnetic and Electronic Transport Properties of Novel Hollandite-Type Molybdenum Oxide, Rb _1.5 Mo ₈ O ₁₆
journal, January 2006

Electrochemical investigation of CrO_2.65 doped LiMn₂O₄ as a cathode material for lithium-ion batteries
journal, November 1998

Structural Defects of Silver Hollandite, Ag _x Mn ₈ O _{y ,} Nanorods: Dramatic Impact on Electrochemistry
journal, July 2015

Lithium ion insertion and extraction reactions with Hollandite-type manganese dioxide free from any stabilizing cations in its tunnel cavity
journal, September 2005

From ultrasoft pseudopotentials to the projector augmented-wave method
journal, January 1999

Tracking lithium transport and electrochemical reactions in nanoparticles
journal, January 2012

Determination of the Kinetic Parameters of Mixed-Conducting Electrodes and Application to the System Li[sub 3]Sb
journal, January 1977

Suppression of Phase Separation in LiFePO4 Nanoparticles During Battery Discharge
text, January 2011

Suppression of Phase Separation in LiFePO ₄ Nanoparticles During Battery Discharge
journal, November 2011

Lead palladium titanate: A room temperature nanoscale multiferroic thin film
journal, February 2020

VESTA 3 for three-dimensional visualization of crystal, volumetric and morphology data
journal, October 2011

Particle Size Dependence of the Ionic Diffusivity
journal, October 2010

Oxidation state and chemical shift investigation in transition metal oxides by EELS
journal, May 2012

Microwave-Assisted Hydrothermal Synthesis of Cryptomelane-Type Octahedral Molecular Sieves (OMS-2) and Their Catalytic Studies
journal, June 2010

First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method
journal, January 1997

First-principles calculations of the electronic structure and spectra of strongly correlated systems: the LDA + U method
journal, January 1997

Selective exchange of divalent transition metal ions in cryptomelane-type manganic acid with tunnel structure
journal, March 1993

Large-Agglomerate-Size Lithium Manganese Oxide Spinel with High Rate Capability for Lithium-Ion Batteries
journal, January 2000

High-resolution X-ray luminescence extension imaging
journal, February 2021

Synthesis and Characterization of Silver Hollandite and Its Application in Emission Control
journal, August 2005

Silver-Containing α-MnO ₂ Nanorods: Electrochemistry in Na-Based Battery Systems
journal, September 2016

Synthetic Control of Composition and Crystallite Size of Silver Hollandite, Ag _x Mn ₈ O ₁₆ : Impact on Electrochemistry
journal, September 2012

Particle Size Dependence of the Ionic Diffusivity
journal, October 2010

First-principles study of Li ion diffusion in ${LiFePO}_{4}$
journal, March 2004

Synthetic Routes to Microporous Manganese Oxides
journal, October 1997

Asynchronous Crystal Cell Expansion during Lithiation of K ⁺ -Stabilized α-MnO ₂
journal, April 2015

Synthesis and Electrochemistry of Silver Hollandite
journal, January 2010

The Electrochemistry of Silver Hollandite Nanorods, Ag _x Mn ₈ O ₁₆ : Enhancement of Electrochemical Battery Performance via Dimensional and Compositional Control
journal, January 2013

Free Energy of a Nonuniform System. I. Interfacial Free Energy
journal, February 1958

Improved electrochemical performance of nitrogen doped TiO ₂ -B nanowires as anode materials for Li-ion batteries
journal, January 2015

Todorokite-type manganese oxide nanowires as an intercalation cathode for Li-ion and Na-ion batteries
journal, January 2015

AC Impedance Analysis for Li[sup +] Insertion of a Pt∕λ-MnO[sub 2] Electrode in an Aqueous Phase
journal, January 1996

Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation
journal, August 2011

Direct Sonochemical Synthesis of Manganese Octahedral Molecular Sieve (OMS-2) Nanomaterials Using Cosolvent Systems, Their Characterization, and Catalytic Applications
journal, February 2012

Efficiency of ab-initio total energy calculations for metals and semiconductors using a plane-wave basis set
journal, July 1996

Anisotropic Swelling and Fracture of Silicon Nanowires during Lithiation
journal, August 2011

Synthesis and lithium ion insertion/extraction properties of hollandite-type MnO2 prepared by acid digestion of Mn2O3
journal, May 2009

Electronic structure of AlFeN films exhibiting crystallographic orientation change from c- to a-axis with Fe concentrations and annealing effect
journal, February 2020

Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics
journal, June 2012

The structure of K _1.33 Mn ₈ O ₁₆ and cation ordering in hollandite-type structures
journal, April 1986

Lithium insertion and extraction properties of hollandite-type KxTiO2 with different K content in the tunnel space
journal, July 2013

Synthesis and Characterization of Silver Hollandite and Its Application in Emission Control.
journal, November 2005

Synthesis and Characterization of Ag—Hollandite Nanofibers and Its Catalytic Application in Ethanol Oxidation.
journal, October 2007

Synthetic Control of Composition and Crystallite Size of Silver Hollandite, Ag _x Mn ₈ O ₁₆ : Impact on Electrochemistry
journal, September 2012

Effects of Cu ²⁺ Ions on the Structure and Reactivity of Todorokite- and Cryptomelane-Type Manganese Oxide Octahedral Molecular Sieves
journal, July 1999

Application of A-C Techniques to the Study of Lithium Diffusion in Tungsten Trioxide Thin Films
journal, January 1980

Synthetic Routes to Microporous Manganese Oxides
journal, October 1997

Ag1.8Mn8O16: Square Planar Coordinated Ag⊕ Ions in the Channels of a Novel Hollandite Variant
journal, November 1984

Tracking lithium transport and electrochemical reactions in nanoparticles
journal, January 2012

Sorption Behavior of Radionuclides on Crystalline Synthetic Tunnel Manganese Oxides
journal, December 2000

Reducing Dzyaloshinskii-Moriya interaction and field-free spin-orbit torque switching in synthetic antiferromagnets
journal, May 2021

Synthesis and characterization of the hollandite-type MnO2 as a cathode material in lithium batteries
journal, March 2000

A Review of Porous Manganese Oxide Materials
journal, October 1998

Electrochemistry of Hollandite α-MnO ₂ : Li-Ion and Na-Ion Insertion and Li ₂ O Incorporation
journal, June 2013

Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics
journal, June 2012

Structural Defects of Silver Hollandite, Ag _x Mn ₈ O _{y ,} Nanorods: Dramatic Impact on Electrochemistry
journal, July 2015

Thermodynamic and Mass Transport Properties of “LiAl”
journal, January 1979

Importance of anisotropic Coulomb interactions and exchange to the band gap and antiferromagnetism of $β$ -MnO $_{2}$ from DFT+ $U$
journal, November 2012

Energy storage: The future enabled by nanomaterials
journal, November 2019

In situ imaging of electrocatalysis in a K–O ₂ battery with a hollandite α-MnO ₂ nanowire air cathode
journal, January 2019

Crystallographic-orientation dependent Li ion migration and reactions in layered MoSe ₂
journal, May 2019

In Situ Visualization of Interfacial Sodium Transport and Electrochemistry between Few‐Layer Phosphorene
journal, May 2019

Tunable nanomechanical performance regimes in ceramic nanowires
journal, September 2019

Charge localization and ordering in $A_{2} {Mn}_{8} O_{16}$ hollandite group oxides: Impact of density functional theory approaches
journal, December 2017

Silver-Containing α-MnO ₂ Nanorods: Electrochemistry in Rechargeable Aqueous Zn-MnO ₂ Batteries
journal, January 2019

Non-uniform Stress-free Strains in a Spherically Symmetrical Nano-sized Particle and Its Applications to Lithium-ion Batteries
journal, March 2018

In situ interface engineering for probing the limit of quantum dot photovoltaic devices
journal, August 2019

Defect Control in the Synthesis of 2 D MoS ₂ Nanosheets: Polysulfide Trapping in Composite Sulfur Cathodes for Li–S Batteries
journal, March 2020

Non-uniform Stress-free Strains in a Spherically Symmetrical Nano-sized Particle and Its Applications to Lithium-ion Batteries
journal, March 2018

Temperature‐dependent electrical transport behavior and structural evolution in hollandite‐type titanium‐based oxide
journal, May 2019